CN104910853A - UV rapidly curable warm water fast hydrolyzed glue and preparation method thereof - Google Patents
UV rapidly curable warm water fast hydrolyzed glue and preparation method thereof Download PDFInfo
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- CN104910853A CN104910853A CN201510269939.2A CN201510269939A CN104910853A CN 104910853 A CN104910853 A CN 104910853A CN 201510269939 A CN201510269939 A CN 201510269939A CN 104910853 A CN104910853 A CN 104910853A
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- water
- dispergation
- warm water
- fast setting
- setting warm
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003292 glue Substances 0.000 title abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002635 polyurethane Polymers 0.000 claims abstract description 11
- 239000004814 polyurethane Substances 0.000 claims abstract description 11
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 34
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- -1 polyoxyethylene Polymers 0.000 claims description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 17
- 239000013530 defoamer Substances 0.000 claims description 17
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000976 ink Substances 0.000 claims description 15
- 238000007639 printing Methods 0.000 claims description 15
- 239000000080 wetting agent Substances 0.000 claims description 15
- 239000004902 Softening Agent Substances 0.000 claims description 14
- 229920002472 Starch Polymers 0.000 claims description 8
- 235000019698 starch Nutrition 0.000 claims description 8
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 229940057847 polyethylene glycol 600 Drugs 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 229950009789 cetomacrogol 1000 Drugs 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 claims description 3
- NTTHYVALAYBGDV-LIRMECTJSA-N Kitol Natural products CC(=C/C=C/C1(C)C(CO)C(CO)C(=CC1C=C(/C)C=CC2=C(C)CCCC2(C)C)C)C=CC3=C(C)CCCC3(C)C NTTHYVALAYBGDV-LIRMECTJSA-N 0.000 claims description 3
- NTTHYVALAYBGDV-WHFXJCNXSA-N [(1s,4s,5r,6r)-6-(hydroxymethyl)-2,5-dimethyl-4-[(1e,3e)-2-methyl-4-(2,6,6-trimethylcyclohexen-1-yl)buta-1,3-dienyl]-5-[(1e,3e,5e)-4-methyl-6-(2,6,6-trimethylcyclohexen-1-yl)hexa-1,3,5-trienyl]cyclohex-2-en-1-yl]methanol Chemical compound C(/[C@]1(C)[C@H](C=C(C)[C@@H](CO)[C@H]1CO)\C=C(/C)\C=C\C=1C(CCCC=1C)(C)C)=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C NTTHYVALAYBGDV-WHFXJCNXSA-N 0.000 claims description 3
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 3
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 3
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 238000005498 polishing Methods 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 238000005520 cutting process Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000005553 drilling Methods 0.000 abstract 1
- 239000003906 humectant Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000011112 process operation Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 125000004386 diacrylate group Chemical group 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a UV rapidly curable warm water fast hydrolyzed glue and a preparation method thereof. The hydrolyzed glue is composed of the following raw materials by mass: 50-70 parts of flexible polyurethane acrylic acid modified resin, 10-15 parts of a water-based plasticizer, 2-5 parts of a humectants, 1-5 parts of a water absorbent, 10-40 parts of a water-soluble active monomer, 1-3 parts of a photoinitiator, and 0.5-1 part of a defoaming agent. The preparation method includes: mixing all the ingredients uniformly. The UV hydrolyzed glue provided by the invention has no need of heating, and can reach certain strength only under the irradiation of a UV lamp for 2-5sec so as to carry out the next process operation, like cutting and polishing, drilling and the like. When all the process is finished, decomposition can be carried out in 50-90DEG C water, the glue layer can shed entirely in 2-10min, and no residual glue is left.
Description
Technical field
The present invention relates to a kind of UV fast setting warm water rapid water dispergation and preparation method thereof.
Background technology
For the provisional bonding occasion of needs: such as glass, aluminium alloy, stainless steel, high-grade glass, crystal, jewelry, optical mirror slip, high-grade artwork, provisional bonding in the industry such as electronics processing grinding manufacturing processed, cover and sealing, a kind of glue of usual needs, base material for processing or associated components are fixed, after completing processing, glue is removed in hydrolysis again, in current technology, after hydrolysis glue often solidifies, intensity is on the weak side, good fixed function can not be realized, and after fixation, when being hydrolyzed, often need heating, in the Water Under solution that pH is alkalescence, hydrolysising condition is harsh, also not environmentally.
Summary of the invention
The object of the present invention is to provide a kind of UV fast setting warm water rapid water dispergation and preparation method thereof.
The technical solution used in the present invention is:
A kind of UV fast setting warm water rapid water dispergation, it is made up of the raw material of following mass fraction: the wetting Agent for Printing Inks of the acrylic acid modified resin of flexible polyurethane of 50-70 part, the water-based softening agent of 10-15 part, 2-5 part, the water-retaining agent of 1-5 part, the water-soluble active monomer of 10-40 part, the light trigger of 1-3 part, the defoamer of 0.5-1 part.
The viscosity of the acrylic acid modified resin of described flexible polyurethane is 10000 ~ 50000 cps/25 DEG C.
The acrylic acid modified resin of described flexible polyurethane be selected from CN966H90 NS, CN969NS, CN980NS, 6118, at least one in 615-100,6152B-80.
Described water-based softening agent is polyoxyethylene glycol.
Described polyoxyethylene glycol is at least one in poly(oxyethylene glycol) 400, Polyethylene Glycol-600, cetomacrogol 1000.
Described wetting Agent for Printing Inks is at least one in propylene glycol, glycerol, dipropylene glycol, two glycerol, lauryl alcohol, kitol, stearyl alcohol.
Described water-retaining agent is starch.
Described water-soluble active monomer is polyoxyethylene glycol acrylics monomer.
Described light trigger is 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 2-dimethylamino-2-benzyl-1-[4-(4-morpholinyl) phenyl]-1-butanone, methyl benzoylformate, at least one in a, a-dimethoxy-a-phenyl acetophenone; Described defoamer is at least one in silicone antifoam agent, polyether antifoam agent, organosilicon modified polyether defoamer.
A preparation method for UV fast setting warm water rapid water dispergation, step is: mixed by each composition.
The invention has the beneficial effects as follows:
UV of the present invention is hydrolyzed glue without the need to heating, only can need namely reach certain intensity at about 2 ~ 5 seconds under UV light irradiation, to carry out the operation of next processing procedure, such as cut polishing, the processing such as boring, when decomposing in 50 ~ 90 DEG C of water after all processing procedures complete, 2 ~ 10min glue-line entirety comes off, and can not leave cull.
Embodiment
A kind of UV fast setting warm water rapid water dispergation, it is made up of the raw material of following mass fraction: the wetting Agent for Printing Inks of the acrylic acid modified resin of flexible polyurethane of 50-70 part, the water-based softening agent of 10-15 part, 2-5 part, the water-retaining agent of 1-5 part, the water-soluble active monomer of 10-40 part, the light trigger of 1-3 part, the defoamer of 0.5-1 part.
Preferably, a kind of UV fast setting warm water rapid water dispergation, it is made up of the raw material of following mass fraction: the wetting Agent for Printing Inks of the acrylic acid modified resin of flexible polyurethane of 55-70 part, the water-based softening agent of 10-12 part, 2-2.5 part, the water-retaining agent of 1.5-2 part, the water-soluble active monomer of 14-27 part, the light trigger of 1.5-2 part, the defoamer of 0.5-1 part.
Preferably, the viscosity of the acrylic acid modified resin of described flexible polyurethane is 10000 ~ 50000 cps/25 DEG C.
Preferred further, the acrylic acid modified resin of described flexible polyurethane is selected from least one in Sartomer CN966H90 NS, CN969NS, CN980NS, Changxing chemical industry 6118,615-100,6152B-80.
Preferably, described water-based softening agent is polyoxyethylene glycol; Preferred further, described polyoxyethylene glycol is at least one in poly(oxyethylene glycol) 400, Polyethylene Glycol-600, cetomacrogol 1000.
Preferably, described wetting Agent for Printing Inks is at least one in propylene glycol, glycerol, dipropylene glycol, two glycerol, lauryl alcohol, kitol, stearyl alcohol; Preferred further, described wetting Agent for Printing Inks is at least one in propylene glycol, glycerol.
Preferably, described water-retaining agent is starch; Preferred further, be food grade and/or technical grade starch.
Described water-soluble active monomer is polyoxyethylene glycol acrylics monomer; Preferred further, be at least one in polyoxyethylene glycol (200) diacrylate, polyoxyethylene glycol (400) diacrylate, polyoxyethylene glycol (600) dimethacrylate, polyoxyethylene glycol (600) diacrylate.
Preferably, described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 2-dimethylamino-2-benzyl-1-[4-(4-morpholinyl) phenyl]-1-butanone, methyl benzoylformate, at least one in a, a-dimethoxy-a-phenyl acetophenone;
Preferably, described defoamer is at least one in silicone antifoam agent, polyether antifoam agent, organosilicon modified polyether defoamer; Preferred further, be silicone antifoam agent.
A preparation method for UV fast setting warm water rapid water dispergation, step is: mixed by each composition.
Below in conjunction with specific embodiment, the present invention is described further:
embodiment 1:
Sartomer CN966H90 NS 66g, water-based softening agent cetomacrogol 1000 10g, wetting Agent for Printing Inks propylene glycol 2g, water-retaining agent food and starch 2g, water-soluble active monomer polyoxyethylene glycol (200) diacrylate 20g, light trigger 2-hydroxy-2-methyl-1-phenyl-1-acetone 1.5g, defoamer BYK-024 0.5g.
By resin, reactive monomer, defoamer and light trigger put into agitator, stir 5 minutes under the slow speed of revolution (500 revs/min), after being dissolved by light trigger, add water-based softening agent again, wetting Agent for Printing Inks and water-retaining agent stir 20 minutes under (1000 revs/min), cool in whipping process, temperature below 60 DEG C after, the UV stirred is hydrolyzed glue vacuumize 5-10min or naturally place 2-3 hours froth breaking, can packs and make UV hydrolysis glue.
embodiment 2:.
Sartomer CN966H90 NS 55g, water-based softening agent Polyethylene Glycol-600 12g, wetting Agent for Printing Inks glycerol 2g, water-retaining agent food-grade starches 2g, water-soluble active monomer polyoxyethylene glycol (600) dimethacrylate 27g, light trigger 1-hydroxycyclohexyl phenyl ketone 1.5g, defoamer BYK-024 0.5g.
By resin, reactive monomer, defoamer and light trigger put into agitator, stir 5 minutes under the slow speed of revolution (500 revs/min), after being dissolved by light trigger, add water-based softening agent again, wetting Agent for Printing Inks and wash water agent are stirred 20 minutes under (1000 revs/min), cool in whipping process, temperature below 60 DEG C after, the UV stirred is hydrolyzed glue vacuumize 5-10min or naturally place 2-3 hours froth breaking, can packs and make UV hydrolysis glue.
embodiment 3:
Changxing chemical industry 6152B-80 70g; water-based softening agent Polyethylene Glycol-600 10g; wetting Agent for Printing Inks propylene glycol 2.5g; water-retaining agent food-grade starches 1.5g; water-soluble active monomer polyoxyethylene glycol (600) diacrylate 14g, light trigger 2,4; 6-trimethylbenzoy-dipheny phosphine oxide 1.5g, defoamer BYK-025 0.5g.
By resin, reactive monomer, defoamer and light trigger put into agitator, stir 5 minutes under the slow speed of revolution (500 revs/min), after being dissolved by light trigger, add water-based softening agent again, wetting Agent for Printing Inks and wash water agent are stirred 20 minutes under (1000 revs/min), cool in whipping process, temperature below 60 DEG C after, the UV stirred is hydrolyzed glue vacuumize 5-10min or naturally place 2-3 hours froth breaking, can packs and make UV hydrolysis glue.
embodiment 4:
Changxing chemical industry 6152B-80 70g; water-based softening agent Polyethylene Glycol-600 10g; wetting Agent for Printing Inks propylene glycol 2.5g; water-retaining agent food-grade starches 1.5g; water-soluble active monomer polyoxyethylene glycol (600) diacrylate 14g, light trigger 2,4; 6-trimethylbenzoy-dipheny phosphine oxide 2g, defoamer BYK-025 1g.
The UV of preparation hydrolysis glue is got 3-5g to be placed on the glass substrate of 70mm*100mm, by glass substrate onesize for another block gently cover above, place several minutes colloids and be evenly distributed on contact surface, through UV curing 300 mj/cm2 energy-curable, can be good by glassy bond, test cohesive strength.Again by the time that the hydrolysis of the warm water sight glass of 70 DEG C bonding, glass is separated, test comparison detected result lists in table 1:
table 1:
Claims (10)
1. a UV fast setting warm water rapid water dispergation, is characterized in that: it is made up of the raw material of following mass fraction: the wetting Agent for Printing Inks of the acrylic acid modified resin of flexible polyurethane of 50-70 part, the water-based softening agent of 10-15 part, 2-5 part, the water-retaining agent of 1-5 part, the water-soluble active monomer of 10-40 part, the light trigger of 1-3 part, the defoamer of 0.5-1 part.
2. a kind of UV fast setting warm water rapid water dispergation according to claim 1, is characterized in that: the viscosity of the acrylic acid modified resin of described flexible polyurethane is 10000 ~ 50000 cps/25 DEG C.
3. a kind of UV fast setting warm water rapid water dispergation according to claim 1 and 2, is characterized in that: the acrylic acid modified resin of described flexible polyurethane be selected from CN966H90 NS, CN969NS, CN980NS, 6118, at least one in 615-100,6152B-80.
4. a kind of UV fast setting warm water rapid water dispergation according to claim 3, is characterized in that: described water-based softening agent is polyoxyethylene glycol.
5. a kind of UV fast setting warm water rapid water dispergation according to claim 4, is characterized in that: described polyoxyethylene glycol is at least one in poly(oxyethylene glycol) 400, Polyethylene Glycol-600, cetomacrogol 1000.
6. a kind of UV fast setting warm water rapid water dispergation according to claim 1 or 5, is characterized in that: described wetting Agent for Printing Inks is at least one in propylene glycol, glycerol, dipropylene glycol, two glycerol, lauryl alcohol, kitol, stearyl alcohol.
7. a kind of UV fast setting warm water rapid water dispergation according to claim 6, is characterized in that: described water-retaining agent is starch.
8. a kind of UV fast setting warm water rapid water dispergation according to claim 1 or 7, is characterized in that: described water-soluble active monomer is polyoxyethylene glycol acrylics monomer.
9. a kind of UV fast setting warm water rapid water dispergation according to claim 1, it is characterized in that: described light trigger is 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 2-dimethylamino-2-benzyl-1-[4-(4-morpholinyl) phenyl]-1-butanone, methyl benzoylformate, at least one in a, a-dimethoxy-a-phenyl acetophenone; Described defoamer is at least one in silicone antifoam agent, polyether antifoam agent, organosilicon modified polyether defoamer.
10. the preparation method of a kind of UV fast setting warm water rapid water dispergation according to claim 1, is characterized in that: step is: mixed by each composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269939.2A CN104910853B (en) | 2015-05-25 | 2015-05-25 | A kind of UV rapid curings warm water rapid water dispergation and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269939.2A CN104910853B (en) | 2015-05-25 | 2015-05-25 | A kind of UV rapid curings warm water rapid water dispergation and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104910853A true CN104910853A (en) | 2015-09-16 |
| CN104910853B CN104910853B (en) | 2017-09-29 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016317A (en) * | 2019-03-11 | 2019-07-16 | 广州拓棒环保科技有限公司 | A kind of preparation method of the good high temperature facile hydrolysis UV glue of pair of metal adhesion |
| CN110082937A (en) * | 2019-05-24 | 2019-08-02 | 业成科技（成都）有限公司 | The means of defence of camera aperture |
| CN112625642A (en) * | 2020-12-17 | 2021-04-09 | 镝普材料(深圳)有限公司 | UV single-component temporary solid adhesive capable of being rapidly dissolved in water and degummed and preparation method thereof |
| CN112760042A (en) * | 2020-12-24 | 2021-05-07 | 上海仁速新材料有限公司 | Threaded hole protective glue and preparation method and application thereof |
| CN115044344A (en) * | 2022-07-29 | 2022-09-13 | 浙江国能科技有限公司 | UV hydrolysis adhesive for temporary fixing of microelectronic device and preparation method thereof |
| CN116376482A (en) * | 2023-04-25 | 2023-07-04 | 合肥微晶材料科技有限公司 | Hydrolysis UV adhesive for ultrathin glass lamination processing and application method thereof |
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| JP2003138239A (en) * | 2001-10-30 | 2003-05-14 | Auto Kagaku Kogyo Kk | One-component moisture-curable polyurethane adhesive and method for bonding flooring material using the same |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016317A (en) * | 2019-03-11 | 2019-07-16 | 广州拓棒环保科技有限公司 | A kind of preparation method of the good high temperature facile hydrolysis UV glue of pair of metal adhesion |
| CN110082937A (en) * | 2019-05-24 | 2019-08-02 | 业成科技（成都）有限公司 | The means of defence of camera aperture |
| CN112625642A (en) * | 2020-12-17 | 2021-04-09 | 镝普材料(深圳)有限公司 | UV single-component temporary solid adhesive capable of being rapidly dissolved in water and degummed and preparation method thereof |
| CN112760042A (en) * | 2020-12-24 | 2021-05-07 | 上海仁速新材料有限公司 | Threaded hole protective glue and preparation method and application thereof |
| CN115044344A (en) * | 2022-07-29 | 2022-09-13 | 浙江国能科技有限公司 | UV hydrolysis adhesive for temporary fixing of microelectronic device and preparation method thereof |
| CN116376482A (en) * | 2023-04-25 | 2023-07-04 | 合肥微晶材料科技有限公司 | Hydrolysis UV adhesive for ultrathin glass lamination processing and application method thereof |
| CN116376482B (en) * | 2023-04-25 | 2024-05-14 | 合肥微晶材料科技有限公司 | A hydrolyzed UV adhesive for ultra-thin glass lamination processing and its application method |
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Denomination of invention: UV rapidly curable warm water fast hydrolyzed glue and preparation method thereof Effective date of registration: 20200320 Granted publication date: 20170929 Pledgee: China Co truction Bank Corp Guangzhou green finance reform and innovation pilot area Huadu Branch Pledgor: UV TECH MATERIAL Ltd. Registration number: Y2020980000908 |