CN104893490A - Scrub-resistant coating for decorative boards and preparation method of scrub-resistant coating - Google Patents
Scrub-resistant coating for decorative boards and preparation method of scrub-resistant coating Download PDFInfo
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- CN104893490A CN104893490A CN201510276780.7A CN201510276780A CN104893490A CN 104893490 A CN104893490 A CN 104893490A CN 201510276780 A CN201510276780 A CN 201510276780A CN 104893490 A CN104893490 A CN 104893490A
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- propylene glycol
- decorative sheet
- resistant paint
- isothiazolinone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a scrub-resistant coating for decorative boards and a preparation method of the scrub-resistant coating. The scrub-resistant coating contains the following components in parts by mass: 10-22 parts of melamine-formaldehyde resin, 0.1-2 parts of sodium hydroxide, 0.01-0.05 part of acrylic resin, 0.02-0.06 part of propylene glycol, 1-3 parts of attapulgite, 0.03-0.09 part of polyoxyethylene polyoxypropylene glyceryl ether, 0.8-2.2 parts of propylene glycol, 0.02-0.06 part of sodium tetraborate, 10-20 parts of an vinyl-acrylic emulsion, 77-92 parts of water, 6-13 parts of lithopone, 2-6 parts of pearl powder, 1-3 parts of saponified grease, 6-15 parts of nano-zinc oxide and 0.7-2.5 parts of isothiazolinone. The scrub-resistant coating has excellent scrub resistance, alkali resistance, sterilization performance and fire resistance.
Description
Technical field
The present invention relates to decorative materials technology, particularly relates to a kind of decorative sheet rubbing-resistant paint and preparation method thereof.
Background technology
Decorative sheet is a kind of artificial board.It is with multiple special paper after chemical treatment, the thermoset laminated plastic made with High Temperature High Pressure cementing agent, plate mask has various wood grain or pattern, and light is smooth, bright in colour attractive in appearance, there is the physicals that higher wear-resisting, heat-resisting, cold-resistant, fire prevention etc. is good simultaneously.Wall, the roof in many senior rooms, make cabinet, cupboard, table, the bed be particular about, the worktable of precision instrument, and the shell of the experiment table in laboratory, televisor, receiving set and other broadcast telecommunication equipment, mostly adopts this novel decorative sheet.
In order to improve the use properties of decorative sheet further, need at its surface coating paint.Coating scrubbing resistance, the alkaline resistance properties of current existing coating are poor, and its sterilization, kill the virus and fire resistance poor.Such as (patent No. is 201310441595.X to Chinese invention patent, the applying date 2013/09/24) disclose a kind of coating of decorative panel for building, this coating comprises compound and aliphatic polymeric isocyanate solidifying agent, the component that compound contains and parts by weight are fluorocarbon resin 60 ~ 80, wetting dispersing agent 2 ~ 10, flow agent 0.2 ~ 0.8, filler 30 ~ 45, defoamer 0.1 ~ 0.8 and solvent 15 ~ 40, and the parts by weight of compound and the ratio of weight and number of aliphatic polymeric isocyanate solidifying agent are 100: 5 ~ 11.Coating of the present invention has the following advantages: excellent wear resistance, and the hardness of coating is large, and coating adhesion is large, and top coat anti-soil is good, and lacquer painting levelling property is good.
Summary of the invention
the technical problem solved:for shortcomings such as existing decorative sheet coating scrubbing resistance, alkaline-resisting, sterilization, fire resistance differences, the invention provides a kind of decorative sheet rubbing-resistant paint and preparation method thereof, this coating has excellent scrubbing resistance, alkaline-resisting, sterilization, fire resistance.
technical scheme:a kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 10 ~ 22 parts, 0.1 ~ 2 part, sodium hydroxide, acrylic resin 0.01 ~ 0.05 part, propylene glycol ester 0.02 ~ 0.06 part, attapulgite 1 ~ 3 part, polyoxypropylene ethylene oxide glyceryl ether 0.03 ~ 0.09 part, propylene glycol 0.8 ~ 2.2 part, sodium tetraborate 0.02 ~ 0.06 part, vinyl acetate emulsion 10 ~ 20 parts, 77 ~ 92 parts, water, 6 ~ 13 parts, zinc sulfide white, pearlescence 2 ~ 6 parts, saponification grease 1 ~ 3 part, nano zine oxide 6 ~ 15 parts, isothiazolinone 0.7 ~ 2.5 part.
A kind of decorative sheet rubbing-resistant paint described above, in mass parts containing following composition: melamine formaldehyde resin 13 ~ 20 parts, 0.4 ~ 1.5 part, sodium hydroxide, acrylic resin 0.02 ~ 0.04 part, propylene glycol ester 0.03 ~ 0.05 part, attapulgite 1.5 ~ 2.6 parts, polyoxypropylene ethylene oxide glyceryl ether 0.04 ~ 0.07 part, propylene glycol 1 ~ 2 part, sodium tetraborate 0.03 ~ 0.05 part, vinyl acetate emulsion 12 ~ 18 parts, 80 ~ 90 parts, water, 8 ~ 11 parts, zinc sulfide white, pearlescence 3 ~ 5 parts, saponification grease 1.4 ~ 2.7 parts, nano zine oxide 8 ~ 13 parts, isothiazolinone 1 ~ 2.2 part.
A kind of decorative sheet rubbing-resistant paint described above, in mass parts containing following composition: melamine formaldehyde resin 15 ~ 18 parts, 0.8 ~ 1.2 part, sodium hydroxide, acrylic resin 0.025 ~ 0.035 part, propylene glycol ester 0.033 ~ 0.045 part, attapulgite 1.8 ~ 2.2 parts, polyoxypropylene ethylene oxide glyceryl ether 0.05 ~ 0.065 part, propylene glycol 1.3 ~ 1.8 parts, sodium tetraborate 0.035 ~ 0.042 part, vinyl acetate emulsion 13 ~ 16 parts, 83 ~ 88 parts, water, 9 ~ 10 parts, zinc sulfide white, pearlescence 3.5 ~ 4.5 parts, saponification grease 1.9 ~ 2.4 parts, nano zine oxide 9 ~ 12 parts, isothiazolinone 1.4 ~ 1.9 parts.
A kind of decorative sheet rubbing-resistant paint described above, in mass parts containing following composition: melamine formaldehyde resin 16 parts, 1 part, sodium hydroxide, acrylic resin 0.03 part, propylene glycol ester 0.038 part, attapulgite 2 parts, polyoxypropylene ethylene oxide glyceryl ether 0.056 part, propylene glycol 1.55 parts, sodium tetraborate 0.039 part, vinyl acetate emulsion 15 parts, 86 parts, water, 9.5 parts, zinc sulfide white, pearlescence 4 parts, saponification grease 2.2 parts, nano zine oxide 11 parts, isothiazolinone 1.6 parts.
The preparation method of a kind of decorative sheet rubbing-resistant paint described above, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 70 ~ 90 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 40 ~ 50 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7 ~ 8, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 200 ~ 220 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
In the first step described above, water is added in stirrer, be heated to 80 DEG C, then add melamine formaldehyde resin, add acrylic resin after being cooled to 45 DEG C, stir.
In second step described above, regulator solution pH value is 7.5.
In the 3rd step described above, base-material is crossed 210 mesh sieves.
beneficial effect:a kind of decorative sheet rubbing-resistant paint provided by the invention and preparation method thereof; the sticking power of this coating is high, has excellent scrubbing resistance, alkaline resistance properties, its sterilization, kill the virus effective; and there is fp function, year decorative sheet there is well decoration and provide protection.
Embodiment
embodiment 1
A kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 10 parts, 0.1 part, sodium hydroxide, acrylic resin 0.01 part, propylene glycol ester 0.02 part, attapulgite 1 part, polyoxypropylene ethylene oxide glyceryl ether 0.03 part, propylene glycol 0.8 part, sodium tetraborate 0.02 part, vinyl acetate emulsion 10 parts, 77 parts, water, 6 parts, zinc sulfide white, pearlescence 2 parts, saponification grease 1 part, nano zine oxide 6 parts, isothiazolinone 0.7 part.
A preparation method for decorative sheet rubbing-resistant paint, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 70 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 40 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 200 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
embodiment 2
A kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 22 parts, 2 parts, sodium hydroxide, acrylic resin 0.05 part, propylene glycol ester 0.06 part, attapulgite 3 parts, polyoxypropylene ethylene oxide glyceryl ether 0.09 part, propylene glycol 2.2 parts, sodium tetraborate 0.06 part, vinyl acetate emulsion 20 parts, 92 parts, water, 13 parts, zinc sulfide white, pearlescence 6 parts, saponification grease 3 parts, nano zine oxide 15 parts, isothiazolinone 2.5 parts.
A preparation method for decorative sheet rubbing-resistant paint, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 90 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 50 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 8, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 220 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
embodiment 3
A kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 13 parts, 0.4 part, sodium hydroxide, acrylic resin 0.02 part, propylene glycol ester 0.03 part, attapulgite 1.5 parts, polyoxypropylene ethylene oxide glyceryl ether 0.04 part, propylene glycol 1 part, sodium tetraborate 0.03 part, vinyl acetate emulsion 12 parts, 80 parts, water, 8 parts, zinc sulfide white, pearlescence 3 parts, saponification grease 1.4 parts, nano zine oxide 8 parts, isothiazolinone 1 part.
A preparation method for decorative sheet rubbing-resistant paint, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 80 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 45 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7.5, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 210 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
embodiment 4
A kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 15 parts, 0.8 part, sodium hydroxide, acrylic resin 0.025 part, propylene glycol ester 0.033 part, attapulgite 1.8 parts, polyoxypropylene ethylene oxide glyceryl ether 0.05 part, propylene glycol 1.3 parts, sodium tetraborate 0.035 part, vinyl acetate emulsion 13 parts, 83 parts, water, 9 parts, zinc sulfide white, pearlescence 3.5 parts, saponification grease 1.9 parts, nano zine oxide 9 parts, isothiazolinone 1.4 parts.
A preparation method for decorative sheet rubbing-resistant paint, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 80 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 45 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7.5, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 210 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
embodiment 5
A kind of decorative sheet rubbing-resistant paint, in mass parts containing following composition: melamine formaldehyde resin 16 parts, 1 part, sodium hydroxide, acrylic resin 0.03 part, propylene glycol ester 0.038 part, attapulgite 2 parts, polyoxypropylene ethylene oxide glyceryl ether 0.056 part, propylene glycol 1.55 parts, sodium tetraborate 0.039 part, vinyl acetate emulsion 15 parts, 86 parts, water, 9.5 parts, zinc sulfide white, pearlescence 4 parts, saponification grease 2.2 parts, nano zine oxide 11 parts, isothiazolinone 1.6 parts.
A preparation method for decorative sheet rubbing-resistant paint, the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 80 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 45 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7.5, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 210 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
comparative example 1
Patent of invention publication number is the patent of CN 103484007A, this coating comprises compound and aliphatic polymeric isocyanate solidifying agent, the component that compound contains and parts by weight are fluorocarbon resin 60 ~ 80, wetting dispersing agent 2 ~ 10, flow agent 0.2 ~ 0.8, filler 30 ~ 45, defoamer 0.1 ~ 0.8 and solvent 15 ~ 40, and the parts by weight of compound and the ratio of weight and number of aliphatic polymeric isocyanate solidifying agent are 100: (5 ~ 11).
The above-mentioned technical performance index stating the coating of the coating of embodiment 1 ~ embodiment 5 and comparative example 1, its detected result is as follows:
Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 |
Sticking power | 1 grade | 1 grade | 1 grade | 1 grade | 1 grade | 2 grades |
Scrub resistance | 2620 times | 2675 times | 2634 times | 2683 times | 2698 times | 1543 times |
Resistance to 20%NaOH | 52h | 56h | 57h | 62h | 65h | 32h |
To streptococcus aureus sterilizing rate | 98.7% | 99.2% | 99.4% | 99.9% | 99.9% | 67.5% |
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. a decorative sheet rubbing-resistant paint, to it is characterized in that in mass parts containing following composition: melamine formaldehyde resin 10 ~ 22 parts, 0.1 ~ 2 part, sodium hydroxide, acrylic resin 0.01 ~ 0.05 part, propylene glycol ester 0.02 ~ 0.06 part, attapulgite 1 ~ 3 part, polyoxypropylene ethylene oxide glyceryl ether 0.03 ~ 0.09 part, propylene glycol 0.8 ~ 2.2 part, sodium tetraborate 0.02 ~ 0.06 part, vinyl acetate emulsion 10 ~ 20 parts, 77 ~ 92 parts, water, 6 ~ 13 parts, zinc sulfide white, pearlescence 2 ~ 6 parts, saponification grease 1 ~ 3 part, nano zine oxide 6 ~ 15 parts, isothiazolinone 0.7 ~ 2.5 part.
2. a kind of decorative sheet rubbing-resistant paint according to claim 1, to it is characterized in that in mass parts containing following composition: melamine formaldehyde resin 13 ~ 20 parts, 0.4 ~ 1.5 part, sodium hydroxide, acrylic resin 0.02 ~ 0.04 part, propylene glycol ester 0.03 ~ 0.05 part, attapulgite 1.5 ~ 2.6 parts, polyoxypropylene ethylene oxide glyceryl ether 0.04 ~ 0.07 part, propylene glycol 1 ~ 2 part, sodium tetraborate 0.03 ~ 0.05 part, vinyl acetate emulsion 12 ~ 18 parts, 80 ~ 90 parts, water, 8 ~ 11 parts, zinc sulfide white, pearlescence 3 ~ 5 parts, saponification grease 1.4 ~ 2.7 parts, nano zine oxide 8 ~ 13 parts, isothiazolinone 1 ~ 2.2 part.
3. a kind of decorative sheet rubbing-resistant paint according to claim 1, to it is characterized in that in mass parts containing following composition: melamine formaldehyde resin 15 ~ 18 parts, 0.8 ~ 1.2 part, sodium hydroxide, acrylic resin 0.025 ~ 0.035 part, propylene glycol ester 0.033 ~ 0.045 part, attapulgite 1.8 ~ 2.2 parts, polyoxypropylene ethylene oxide glyceryl ether 0.05 ~ 0.065 part, propylene glycol 1.3 ~ 1.8 parts, sodium tetraborate 0.035 ~ 0.042 part, vinyl acetate emulsion 13 ~ 16 parts, 83 ~ 88 parts, water, 9 ~ 10 parts, zinc sulfide white, pearlescence 3.5 ~ 4.5 parts, saponification grease 1.9 ~ 2.4 parts, nano zine oxide 9 ~ 12 parts, isothiazolinone 1.4 ~ 1.9 parts.
4. a kind of decorative sheet rubbing-resistant paint according to claim 1, to it is characterized in that in mass parts containing following composition: melamine formaldehyde resin 16 parts, 1 part, sodium hydroxide, acrylic resin 0.03 part, propylene glycol ester 0.038 part, attapulgite 2 parts, polyoxypropylene ethylene oxide glyceryl ether 0.056 part, propylene glycol 1.55 parts, sodium tetraborate 0.039 part, vinyl acetate emulsion 15 parts, 86 parts, water, 9.5 parts, zinc sulfide white, pearlescence 4 parts, saponification grease 2.2 parts, nano zine oxide 11 parts, isothiazolinone 1.6 parts.
5. the preparation method of a kind of decorative sheet rubbing-resistant paint as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
The first step: added by water in stirrer, is heated to 70 ~ 90 DEG C, then adds melamine formaldehyde resin, adds acrylic resin, stir after being cooled to 40 ~ 50 DEG C;
Second step: add sodium hydroxide again in stirrer, regulator solution pH value is 7 ~ 8, then adds propylene glycol ester, attapulgite, polyoxypropylene ethylene oxide glyceryl ether, propylene glycol, sodium tetraborate, vinyl acetate emulsion, obtains base-material;
3rd step: after base-material being crossed 200 ~ 220 mesh sieves, mixes with zinc sulfide white, pearlescence, saponification grease, nano zine oxide, isothiazolinone, obtains decorative sheet rubbing-resistant paint.
6. the preparation method of a kind of decorative sheet rubbing-resistant paint according to claim 5, it is characterized in that: in the described the first step, water is added in stirrer, be heated to 80 DEG C, then add melamine formaldehyde resin, add acrylic resin after being cooled to 45 DEG C, stir.
7. the preparation method of a kind of decorative sheet rubbing-resistant paint according to claim 5, is characterized in that: in described second step, regulator solution pH value is 7.5.
8. the preparation method of a kind of decorative sheet rubbing-resistant paint according to claim 5, is characterized in that: in described 3rd step, base-material is crossed 210 mesh sieves.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107502111A (en) * | 2017-09-01 | 2017-12-22 | 北京宝辰联合科技股份有限公司 | A kind of dry powder opalescent lacquers and preparation method thereof |
Citations (4)
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CN1224741A (en) * | 1998-12-14 | 1999-08-04 | 童忠良 | Aqueous fragrant colored building paint and its preparation |
CN101891991A (en) * | 2010-07-08 | 2010-11-24 | 中国科学院宁波材料技术与工程研究所 | A kind of high hardness anti-fingerprint paint and preparation method thereof |
CN102329550A (en) * | 2011-03-23 | 2012-01-25 | 长沙耐丽卡环保科技有限公司 | Nano-zinc oxide waterborne epoxy resin special protective paint and preparation method thereof |
CN104341946A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Glass paint with functions of refreshing mind and inducing resuscitation and preparation method thereof |
-
2015
- 2015-05-27 CN CN201510276780.7A patent/CN104893490A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1224741A (en) * | 1998-12-14 | 1999-08-04 | 童忠良 | Aqueous fragrant colored building paint and its preparation |
CN101891991A (en) * | 2010-07-08 | 2010-11-24 | 中国科学院宁波材料技术与工程研究所 | A kind of high hardness anti-fingerprint paint and preparation method thereof |
CN102329550A (en) * | 2011-03-23 | 2012-01-25 | 长沙耐丽卡环保科技有限公司 | Nano-zinc oxide waterborne epoxy resin special protective paint and preparation method thereof |
CN104341946A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Glass paint with functions of refreshing mind and inducing resuscitation and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107502111A (en) * | 2017-09-01 | 2017-12-22 | 北京宝辰联合科技股份有限公司 | A kind of dry powder opalescent lacquers and preparation method thereof |
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Application publication date: 20150909 |