CN104891812A - Method for producing hollow glass spheres - Google Patents
Method for producing hollow glass spheres Download PDFInfo
- Publication number
- CN104891812A CN104891812A CN201510177507.9A CN201510177507A CN104891812A CN 104891812 A CN104891812 A CN 104891812A CN 201510177507 A CN201510177507 A CN 201510177507A CN 104891812 A CN104891812 A CN 104891812A
- Authority
- CN
- China
- Prior art keywords
- hollow glass
- glass micropearl
- sodium
- paste
- manufacture method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 title abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 10
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 238000001354 calcination Methods 0.000 claims abstract description 6
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 239000006004 Quartz sand Substances 0.000 claims abstract description 5
- 238000000498 ball milling Methods 0.000 claims abstract description 5
- 229910021538 borax Inorganic materials 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000010433 feldspar Substances 0.000 claims abstract description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 5
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 5
- 239000000454 talc Substances 0.000 claims abstract description 5
- 235000012222 talc Nutrition 0.000 claims abstract description 5
- 229910052623 talc Inorganic materials 0.000 claims abstract description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 5
- 239000001913 cellulose Substances 0.000 claims abstract description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims description 33
- 239000011343 solid material Substances 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 5
- 235000013312 flour Nutrition 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- GUBGYTABKSRVRQ-ASMJPISFSA-N alpha-maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-ASMJPISFSA-N 0.000 claims description 2
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- OABYVIYXWMZFFJ-ZUHYDKSRSA-M sodium glycocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCC([O-])=O)C)[C@@]2(C)[C@@H](O)C1 OABYVIYXWMZFFJ-ZUHYDKSRSA-M 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 235000011132 calcium sulphate Nutrition 0.000 abstract 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 abstract 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 235000010980 cellulose Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The invention discloses a method for producing hollow glass spheres, which comprise the following steps: mixing quartz sand, feldspar, soda ash, calcium carbonate, calcium sulfate, talcum, soluble glass, borax, white copperas zinc sulfate and zinc oxide solid raw materials and performing ball milling, passing through a sieve with 500 meshes, adding paste containing starch, cellulose and water, mixing and uniformly grinding, performing spray drying, calcinating through a spheroidizing furnace at 1100-1200 DEG C, and cooling to obtain the hollow glass spheres. According to the method, the production cost is greatly reduced.
Description
Technical field
The present invention relates to glass microballon, specifically the manufacture method of hollow glass micropearl.
Background technology
Hollow glass micropearl is a kind of type material that development in recent years is got up, and its density is low, good heat insulating, is widely used in various light material, lagging material.
CN101704632A discloses a kind of hollow glass micropearl and preparation method thereof, 1. prepare burden, frit is made up of the raw material of following weight proportioning: SiO2 70% ~ 80%, Na2O 8% ~ 12%, CaO 5% ~ 9%, B2O3 2% ~ 6%, SO3 0.2% ~ 0.5%, K2O or Li2O 0 ~ 5%, ZnO or BaO 0 ~ 5%, Al2O3 0 ~ 3%; Chemical constitution formula according to frit takes raw material and mixes; 2. shrend is melted: dropped in melting furnaces by the frit mixed and found, glass smelting temperature is 1350 DEG C ~ 1450 DEG C, and melting time is 1 ~ 2 hour, then pours the glass metal melted in watch-quench tank shrend; 3. dry crushing and classification: dried by frit good for shrend, then grinding classification, crushing and classification adopts jet mill grinding, and glass powder particle size range used is 4 ~ 40 μm; 4. hollow nodularization: the glass powder that classification is good is passed through into the hollow nodularization of pearl stove; Hollow nodularization temperature is 1100 DEG C ~ 1300 DEG C; 5. sorting is collected: collected by the glass powder passing through into pearl stove heated, then isolate hollow glass micropearl by floating method; Its granularity of gained hollow glass micropearl concentrates on 10 ~ 60 μm, density≤0.3g/cm3, ultimate compression strength >=12Mpa, its floatability: >=95%.
CN102320743A discloses a kind of high strength aluminosilicate hollow glass microsphere and preparation method thereof, its chemical constitution is as follows: SiO2 60% ~ 75%, Al2O3 10% ~ 15%, Na2O 10% ~ 15%, CaO 1% ~ 3%, MgO 0 ~ 1%, S 0.02% ~ 0.5%, R2O 0 ~ 3%, Fe2O3 0 ~ 3%, in described R2O, R is the basic metal beyond Na; Described hollow glass micropearl, density 0.2 ~ 0.6g/cm3, ultimate compression strength 3 ~ 130MPa, size≤80 μm, floating rate≤95%, softization Wen Du≤750 DEG C.Hollow glass micropearl of the present invention not only can be used for the every field of plain hollow glass microballon application, and be applicable to plain hollow glass microballon and be beyond one's reach, there are the high temperature of particular requirement, high pressure field, if well depth in the hollow glass micropearl solid buoyancy material of 1000m, 2000m, 4500m and following use under water, oil drilling is more than the well cementation hollow glass micropearl of 6000m and the hollow glass micropearl for plastic hot extrusion moulding.
Above-mentioned two parts of patent production methods are complicated, and cost is high.
Summary of the invention
The object of the present invention is to provide a kind of method of low-temperature sintering hollow glass micropearl, greatly can reduce production cost.
The manufacture method of hollow glass micropearl of the present invention is: be quartz sand 40-55% by weight ratio, feldspar 8-16%, soda ash 6-11%, calcium carbonate 5-15%, calcium sulfate 2-5%, talcum 0-1.5%, water glass 0-2.5%, borax 3-10%, zinc sulfate 0-1.5%, the solid material mixing and ball milling of zinc oxide 5-12%, cross 500 mesh sieves, add the Mierocrystalline cellulose of starch containing 2-5wt% and 3-6wt% and the paste of water composition, the weight ratio of solid material and paste is 1 ︰ 1-2.5, mixed grinding is rear spraying dry evenly, through the balling furnace calcination of 1100-1200 DEG C, cooling becomes hollow glass micropearl.
Above-mentioned starch can be flour, Tapioca Starch, ground rice, amylodextrin.
C also containing 0.1-0.5 in paste
12-18sodium soap, C
12-18alkyl sodium sulfonate, dioctyl succinate disulfonate acid, Sodium dodecylbenzene sulfonate, Sodium glycocholate or sodium laurylsulfate.
The present invention utilizes starch and Mierocrystalline cellulose to be separated or dispersion by glass material, do not need raw material to be carried out complicated dispersion and screening before nodularization, in glass microsphere calcination nodularization process, feed particles is disperseed by starch and cellulosic burning nature, the heat produced improves particle temperature, therefore can reduce balling furnace temperature, save energy, and make the abundant vitrifying of microballoon and fully foaming.
Embodiment
Embodiment 1.
By quartz sand 48 kg, feldspar 10 kg, soda ash 8 kg, calcium carbonate 10 kg, calcium sulfate 4 kg, talcum 1 kg, water glass 2 kg, borax 8 kg, zinc sulfate 1 kg, the solid material mixing and ball milling of zinc oxide 8 kg, crosses 500 mesh sieves;
Join in 120 kg water by 3 kg flour, 5 kg Mierocrystalline celluloses and 0.2kg Sodium dodecylbenzene sulfonate, heating is cooked into paste;
Solid material powder after sieving is joined in paste, is uniformly mixed, grinding, spraying dry evenly;
Particle after spraying dry is sent in balling furnace, and with 1120 ± 20 DEG C of calcinations, nodularization, cooling becomes hollow glass micropearl.
After testing, in water, suspensibility is 95%, density 0.34g/ml to obtained hollow glass micropearl, and particle diameter reaches 96.2% at 20-100 microns, softening temperature about 730 DEG C, and intensity test 10MPa breakage rate is 4.3%, 30MPa breakage rate is 12%.
Embodiment 2.
By quartz sand 44 kg, feldspar 13 kg, soda ash 10 kg, calcium carbonate 12 kg, calcium sulfate 3kg, talcum 1 kg, borax 8 kg, zinc sulfate 1 kg, the solid material mixing and ball milling of zinc oxide 8 kg, crosses 500 mesh sieves;
Join in 120 kg water by 4 kg flour, 4 kg Mierocrystalline celluloses and 0.2kg sodium laurylsulfonate, heating is cooked into paste;
Solid material powder after sieving is joined in paste, is uniformly mixed, grinding, spraying dry evenly;
Particle after spraying dry is sent in balling furnace, and with 1120 ± 20 DEG C of calcinations, nodularization, cooling becomes hollow glass micropearl.
After testing, in water, suspensibility is 95%, density 0.30g/ml to obtained hollow glass micropearl, and particle diameter reaches 95.0% at 20-100 microns, softening temperature about 700 DEG C, and intensity test 10MPa breakage rate is 3.3%, 30MPa breakage rate is 16%.
Claims (3)
1. the manufacture method of hollow glass micropearl, it is characterized in that, be quartz sand 40-55% by weight ratio, feldspar 8-16%, soda ash 6-11%, calcium carbonate 5-15%, calcium sulfate 2-5%, talcum 0-1.5%, water glass 0-2.5%, borax 3-10%, zinc sulfate 0-1.5%, the solid material mixing and ball milling of zinc oxide 5-12%, cross 500 mesh sieves, add the starch containing 2-5wt%, the paste of the Mierocrystalline cellulose of 3-6wt% and water composition, the weight ratio of solid material and paste is 1 ︰ 1-2.5, mixed grinding is rear spraying dry evenly, through the balling furnace calcination of 1100-1200 DEG C, cooling becomes hollow glass micropearl.
2. the manufacture method of hollow glass micropearl according to claim 1 or 2, it is characterized in that, described starch is flour, Tapioca Starch, ground rice, amylodextrin.
3. the manufacture method of hollow glass micropearl according to claim 1 or 2, is characterized in that, the C also containing 0.1-0.5 in described paste
12-18sodium soap, C
12-18alkyl sodium sulfonate, dioctyl succinate disulfonate acid, Sodium dodecylbenzene sulfonate, Sodium glycocholate or sodium laurylsulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510177507.9A CN104891812A (en) | 2015-04-15 | 2015-04-15 | Method for producing hollow glass spheres |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510177507.9A CN104891812A (en) | 2015-04-15 | 2015-04-15 | Method for producing hollow glass spheres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104891812A true CN104891812A (en) | 2015-09-09 |
Family
ID=54024847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510177507.9A Pending CN104891812A (en) | 2015-04-15 | 2015-04-15 | Method for producing hollow glass spheres |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104891812A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630615A (en) * | 2016-12-28 | 2017-05-10 | 郑州圣莱特空心微珠新材料有限公司 | Method for manufacturing hollow glass microspheres from waste glass |
| CN107151102A (en) * | 2017-06-09 | 2017-09-12 | 江苏东昇光伏科技有限公司 | A kind of thin-film solar cells modified glass and preparation method thereof |
| CN109914727A (en) * | 2019-03-11 | 2019-06-21 | 重庆大学 | A kind of preparation method of retroreflective sheet applied to wall |
| CN111138796A (en) * | 2019-12-26 | 2020-05-12 | 苏州润佳高分子材料有限公司 | Modified ABS material for automobile |
| CN111691573A (en) * | 2019-03-11 | 2020-09-22 | 重庆大学 | Outer retaining wall structure |
| CN117023952A (en) * | 2023-08-15 | 2023-11-10 | 陕西华特新材料股份有限公司 | Preparation method of porous high silica glass beads |
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| US3838998A (en) * | 1971-01-07 | 1974-10-01 | R Carson | Process for forming hollow glass micro-spheres from admixed high and low temperature glass formers |
| CN1684760A (en) * | 2002-08-23 | 2005-10-19 | 詹姆士·哈代国际金融公司 | Synthetic hollow microspheres |
| CN101704632A (en) * | 2009-11-30 | 2010-05-12 | 中国建材国际工程有限公司 | Preparation method of high-strength low-density hollow glass bead |
| CN101948640A (en) * | 2010-08-09 | 2011-01-19 | 华南理工大学 | Dark infrared reflective insulation material and preparation method thereof |
| CN102320743A (en) * | 2011-09-29 | 2012-01-18 | 蚌埠玻璃工业设计研究院 | Aluminosilicate HS hollow glass micropearl and preparation method thereof |
| CN102503383A (en) * | 2011-11-10 | 2012-06-20 | 中钢集团洛阳耐火材料研究院有限公司 | Method for preparing oxide hollow sphere by using spray granulation process |
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2015
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| US3838998A (en) * | 1971-01-07 | 1974-10-01 | R Carson | Process for forming hollow glass micro-spheres from admixed high and low temperature glass formers |
| CN1684760A (en) * | 2002-08-23 | 2005-10-19 | 詹姆士·哈代国际金融公司 | Synthetic hollow microspheres |
| CN101704632A (en) * | 2009-11-30 | 2010-05-12 | 中国建材国际工程有限公司 | Preparation method of high-strength low-density hollow glass bead |
| CN101948640A (en) * | 2010-08-09 | 2011-01-19 | 华南理工大学 | Dark infrared reflective insulation material and preparation method thereof |
| CN102320743A (en) * | 2011-09-29 | 2012-01-18 | 蚌埠玻璃工业设计研究院 | Aluminosilicate HS hollow glass micropearl and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630615A (en) * | 2016-12-28 | 2017-05-10 | 郑州圣莱特空心微珠新材料有限公司 | Method for manufacturing hollow glass microspheres from waste glass |
| CN106630615B (en) * | 2016-12-28 | 2019-05-21 | 郑州圣莱特空心微珠新材料有限公司 | A method of hollow glass micropearl is manufactured using cullet |
| CN107151102A (en) * | 2017-06-09 | 2017-09-12 | 江苏东昇光伏科技有限公司 | A kind of thin-film solar cells modified glass and preparation method thereof |
| CN109914727A (en) * | 2019-03-11 | 2019-06-21 | 重庆大学 | A kind of preparation method of retroreflective sheet applied to wall |
| CN111691573A (en) * | 2019-03-11 | 2020-09-22 | 重庆大学 | Outer retaining wall structure |
| CN111691573B (en) * | 2019-03-11 | 2021-05-07 | 重庆大学 | an external retaining wall structure |
| CN111138796A (en) * | 2019-12-26 | 2020-05-12 | 苏州润佳高分子材料有限公司 | Modified ABS material for automobile |
| CN117023952A (en) * | 2023-08-15 | 2023-11-10 | 陕西华特新材料股份有限公司 | Preparation method of porous high silica glass beads |
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Application publication date: 20150909 |