CN104860658A - Anti-static ceramic tile and production method thereof - Google Patents
Anti-static ceramic tile and production method thereof Download PDFInfo
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- CN104860658A CN104860658A CN201510221330.8A CN201510221330A CN104860658A CN 104860658 A CN104860658 A CN 104860658A CN 201510221330 A CN201510221330 A CN 201510221330A CN 104860658 A CN104860658 A CN 104860658A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000004927 clay Substances 0.000 claims abstract description 23
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910021343 molybdenum disilicide Inorganic materials 0.000 claims abstract description 9
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001661 Chitosan Polymers 0.000 claims abstract description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229910001649 dickite Inorganic materials 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 7
- 239000005011 phenolic resin Substances 0.000 claims abstract description 7
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 7
- 239000004576 sand Substances 0.000 claims abstract description 7
- 239000002893 slag Substances 0.000 claims abstract description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 238000009413 insulation Methods 0.000 claims description 18
- 239000002002 slurry Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 229910052573 porcelain Inorganic materials 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 241000609240 Ambelania acida Species 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 240000008042 Zea mays Species 0.000 claims description 4
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 4
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004760 aramid Substances 0.000 claims description 4
- 229920003235 aromatic polyamide Polymers 0.000 claims description 4
- 229960000892 attapulgite Drugs 0.000 claims description 4
- 239000010905 bagasse Substances 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- -1 hydroxypropyl Chemical group 0.000 claims description 4
- 235000009973 maize Nutrition 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 239000010902 straw Substances 0.000 claims description 4
- 238000010009 beating Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 239000011812 mixed powder Substances 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- XXLJGBGJDROPKW-UHFFFAOYSA-N antimony;oxotin Chemical compound [Sb].[Sn]=O XXLJGBGJDROPKW-UHFFFAOYSA-N 0.000 abstract 2
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses an anti-static ceramic tile and a production method thereof. The anti-static ceramic tile is formed by the following raw materials of, by weight, 27 to 41 parts of river sand, 19 to 33 parts of lithium China stone, 16 to 28 parts of dickite, 15 to 25 parts of pebble chips, 12 to 24 parts of steel slags, 14 to 22 parts of composite clay, 10 to 15 parts of colloidal graphite powder, 8 to 14 parts of molybdenum disilicide, 3 to 6 parts of tin antimony oxide, 5 to 7 parts of liquid phenolic resin, 2 to 3 parts of sodium lauryl sulfate and 3 to 4 parts of chitosan. According to the anti-static ceramic tile and the production method thereof, the colloidal graphite powder, the molybdenum disilicide, the tin antimony oxide and the other components are added and accordingly the high anti-static function is achieved through the produced ceramic tile, the national anti-static ceramic tile standard GB26539-2011 requirements for the anti-static property are met, the strength is high, the heat stability is good, the abrasion resistance is good, the corrosion resistance is good, the service life of the anti-static ceramic tile is extended, and the use range of the anti-static ceramic tile is expanded.
Description
Technical field
The present invention relates to a kind of anti-static ceramic tile and preparation method thereof, belong to stupalith field.
Background technology
Ceramic tile, with fire-resistant metal oxide and half-metal oxide, via processes such as grinding, mixing, compacting, glazing, sintering, and the building of the porcelain of a kind of acid and alkali-resistance formed or Shi Zhi etc. or the material of decoration, its starting material are many to be mixed by clay, quartz sand and other inorganic non-metallic raw materials etc.In recent years, along with the develop rapidly of China's Building Ceramics Industry, make the performance requriements of people to ceramic tile also more and more higher.Ceramic tile in the market also exists the shortcoming of antistatic performance difference, limits its use range, cannot meet the need of market.
Summary of the invention
Object of the present invention, for the deficiencies in the prior art, provides anti-static ceramic tile that a kind of antistatic performance is good, Heat stability is good, intensity are high and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of anti-static ceramic tile, is made up of the raw material of following weight part: river sand 27-41, lithium porcelain stone 19-33, dickite 16-28, cobble bits 15-25, slag 12-24, compound clay 14-22, oildag powder 10-15, molybdenum disilicide 8-14, tin-antiomony oxide 3-6, liquid phenolic resin 5-7, sodium laurylsulfate 2-3, chitosan 3-4;
The preparation method of described compound clay is as follows:
A, in mass ratio 3-6:2-4:1 take Suzhou soil, attapulgite and mountain mud, mix, pulverize, cross 150-200 mesh sieve, add water to stir and make the slurries that concentration is 50-60%, add the sodium metnylene bis-naphthalene sulfonate, the turkey red oil of 2-4%, the hyaluronate sodium of 1-2% that are equivalent to slurry weight 3-6% again, heating in water bath to 50-60 DEG C, 2000-3000r/min speed lapping 20-30min, suction filtration, dry, stand-by;
B, take 2-3:1-2:1 in mass ratio and take aramid pulp, maize straw and bagasse, mix, pulverize, cross 200-300 mesh sieve, stand-by;
The mixed powder that c, the mineral clay and the step b that are obtained by above-mentioned steps a obtain mixes according to mass ratio 2-3:1, add the polyacrylamide, the hydroxypropyl Staragel 90V of 3-6%, the borax of 2-4% that are equivalent to mineral clay weight 5-10% again, 1000-1500r/min high speed dispersion 10-15min, to obtain final product.
A preparation method for anti-static ceramic tile, comprises the following steps:
(1) get river sand, lithium porcelain stone, dickite, cobble bits mix, put into the hydrochloric acid soln that concentration is 1-1.5mol/L, heating in water bath is to 70-80 DEG C, insulation 1-2h, filters, is washed with distilled water to neutrality, put into the sodium hydroxide solution that concentration is 1.5-2mol/L again, heating in water bath is to 65-75 DEG C, and insulation 1-2h, filters, be washed with distilled water to neutrality, dry, be warming up to 1160-1220 DEG C again after 820-860 DEG C of calcining 0.5-1h, take out and shrend after calcining 1-2h, dry, pulverize, cross 150-200 mesh sieve, stand-by;
(2) powder getting slag, oildag powder, compound clay and step (1) obtained mixes, the slurries that concentration is 50-55% are made in the making beating that adds water, add sodium laurylsulfate and chitosan again, heating in water bath is to 55-60 DEG C, 2500-3500r/min speed lapping 20-30min, then by grinding after slurry spraying dry water content be the particle of 3-4%, stand-by;
(3) particle that step (2) is obtained is mixed with molybdenum disilicide, tin-antiomony oxide, then add liquid phenolic resin, be uniformly mixed 15-20min, stand-by;
(4) material that step (3) mixes is put into forming machine and make type at the pressure of 75-80MPa;
(5) base substrate that step (4) is obtained is carried out drying at the temperature of 40-50 DEG C, be dried to blank water content lower than 2%, then leaching glaze carried out to dried base substrate;
(6) by the N of base substrate obtained for step (5) at 2-3MPa
2under atmosphere with the ramp of 6-9 DEG C/min to 920-980 DEG C, insulation 1-2h, 640-690 DEG C is cooled to again with the speed of 2-4 DEG C/min, insulation 0.5-1h, then under the Ar atmosphere of 3-4MPa with the ramp of 3-5 DEG C/min to 880-940 DEG C, insulation 1-2h, again with the ramp of 2-4 DEG C/min to 1180-1240 DEG C, insulation 2-3h, cool to normal temperature with the furnace, packaging gets product.
Above-mentioned compound clay adopts Suzhou soil, attapulgite and mountain mud three kinds of clay material synergies, and adopt sodium metnylene bis-naphthalene sulfonate, turkey red oil, hyaluronate sodium carries out modification to above-mentioned clay, dispersiveness and the plasticity-of clay can be improved, thus improve suspension and the stability of slurries used by ceramic tile manufacture craft, then aramid pulp is adopted, maize straw and bagasse carry out modification to compound clay, not only make ceramic tile in sintering process, produce abundant air hole structure, the thermal and insulating performance of ceramic tile can also be improved, finally adopt polyacrylamide, hydroxypropyl Staragel 90V, borax carries out modification, the cohesive strength of compound clay can be improved, make porcelain base in shaping and drying process, avoid being out of shape the defect with cracking, and produce higher physical strength.
Beneficial effect of the present invention:
The present invention with the addition of the compositions such as oildag powder, molybdenum disilicide, tin-antiomony oxide, the ceramic tile obtained is made to have higher electrostatic-proof function, static electricity resistance meets and reaches national anti-static ceramic tile standard GB26539-2011 requirement, and it is high to have intensity, Heat stability is good, wear resistance is good, the feature of good corrosion resistance, extend its work-ing life, expand its use range.
Embodiment
A kind of anti-static ceramic tile, is made up of the raw material of following weight (kg): river sand 36, lithium porcelain stone 27, dickite 23, cobble bits 20, slag 18, compound clay 18, oildag powder 12, molybdenum disilicide 10, tin-antiomony oxide 4.5, liquid phenolic resin 6, sodium laurylsulfate 2.5, chitosan 3.5;
The preparation method of described compound clay is as follows:
A, in mass ratio 4:3:1 take Suzhou soil, attapulgite and mountain mud, mix, pulverize, cross 150 mesh sieves, add water to stir and make the slurries that concentration is 55%, add the sodium metnylene bis-naphthalene sulfonate, the turkey red oil of 3%, the hyaluronate sodium of 1.5% that are equivalent to slurry weight 4% again, heating in water bath to 55 DEG C, 2500r/min speed lapping 25min, suction filtration, dry, stand-by;
B, take 2:1:1 in mass ratio and take aramid pulp, maize straw and bagasse, mix, pulverize, cross 200 mesh sieves, stand-by;
The mixed powder that c, the mineral clay and the step b that are obtained by above-mentioned steps a obtain mixes according to mass ratio 2:1, add the polyacrylamide, the hydroxypropyl Staragel 90V of 4.5%, the borax of 3% that are equivalent to mineral clay weight 7% again, 1500r/min high speed dispersion 10min, to obtain final product.
A preparation method for anti-static ceramic tile, comprises the following steps:
(1) get river sand, lithium porcelain stone, dickite, cobble bits mix, put into the hydrochloric acid soln that concentration is 1mol/L, heating in water bath to 80 DEG C, insulation 1.5h, filters, is washed with distilled water to neutrality, put into the sodium hydroxide solution that concentration is 1.5mol/L again, heating in water bath to 65 DEG C, insulation 2h, filter, be washed with distilled water to neutrality, dry, be warming up to 1180 DEG C again after 840 DEG C of calcining 0.5h, take out and shrend after calcining 1.5h, dry, pulverize, cross 200 mesh sieves, stand-by;
(2) powder getting slag, oildag powder, compound clay and step (1) obtained mixes, the slurries that concentration is 52% are made in the making beating that adds water, add sodium laurylsulfate and chitosan again, heating in water bath to 55 DEG C, 3000r/min speed lapping 25min, then by grinding after slurry spraying dry water content be the particle of 4%, stand-by;
(3) particle that step (2) is obtained is mixed with molybdenum disilicide, tin-antiomony oxide, then add liquid phenolic resin, be uniformly mixed 18min, stand-by;
(4) material that step (3) mixes is put into forming machine and make type at the pressure of 80MPa;
(5) base substrate that step (4) is obtained is carried out drying at the temperature of 45 DEG C, be dried to blank water content lower than 2%, then leaching glaze carried out to dried base substrate;
(6) by the N of base substrate obtained for step (5) at 2-3MPa
2with the ramp to 960 DEG C of 7 DEG C/min under atmosphere, insulation 1.5h, 680 DEG C are cooled to again with the speed of 3 DEG C/min, insulation 0.5h, then under the Ar atmosphere of 3.5MPa with the ramp to 920 DEG C of 4 DEG C/min, insulation 1.5h, again with the ramp to 1220 DEG C of 3 DEG C/min, insulation 2.5h, cool to normal temperature with the furnace, packaging gets product.
The ceramic tile salient features that above-described embodiment is produced is as shown in the table:
| Project | Unit | Detected result |
| Strength at break | N | 2033 |
| The modulus of rupture | MPa | 45 |
| Water-intake rate | ％ | 0.16 |
| Thermal conductivity | W/m·k | 9.5 |
| Thermal expansivity | m/m·k | 6.0×10 -6 |
| Surface resistivity | Ω | 5.1×10 7 |
| Volume resistance | Ω | 6.3×10 7 |
Claims (2)
1. an anti-static ceramic tile, it is characterized in that, be made up of the raw material of following weight part: river sand 27-41, lithium porcelain stone 19-33, dickite 16-28, cobble bits 15-25, slag 12-24, compound clay 14-22, oildag powder 10-15, molybdenum disilicide 8-14, tin-antiomony oxide 3-6, liquid phenolic resin 5-7, sodium laurylsulfate 2-3, chitosan 3-4;
The preparation method of described compound clay is as follows:
A, in mass ratio 3-6:2-4:1 take Suzhou soil, attapulgite and mountain mud, mix, pulverize, cross 150-200 mesh sieve, add water to stir and make the slurries that concentration is 50-60%, add the sodium metnylene bis-naphthalene sulfonate, the turkey red oil of 2-4%, the hyaluronate sodium of 1-2% that are equivalent to slurry weight 3-6% again, heating in water bath to 50-60 DEG C, 2000-3000r/min speed lapping 20-30min, suction filtration, dry, stand-by;
B, take 2-3:1-2:1 in mass ratio and take aramid pulp, maize straw and bagasse, mix, pulverize, cross 200-300 mesh sieve, stand-by;
The mixed powder that c, the mineral clay and the step b that are obtained by above-mentioned steps a obtain mixes according to mass ratio 2-3:1, add the polyacrylamide, the hydroxypropyl Staragel 90V of 3-6%, the borax of 2-4% that are equivalent to mineral clay weight 5-10% again, 1000-1500r/min high speed dispersion 10-15min, to obtain final product.
2. a preparation method for anti-static ceramic tile as claimed in claim 1, is characterized in that comprising the following steps:
(1) get river sand, lithium porcelain stone, dickite, cobble bits mix, put into the hydrochloric acid soln that concentration is 1-1.5mol/L, heating in water bath is to 70-80 DEG C, insulation 1-2h, filters, is washed with distilled water to neutrality, put into the sodium hydroxide solution that concentration is 1.5-2mol/L again, heating in water bath is to 65-75 DEG C, and insulation 1-2h, filters, be washed with distilled water to neutrality, dry, be warming up to 1160-1220 DEG C again after 820-860 DEG C of calcining 0.5-1h, take out and shrend after calcining 1-2h, dry, pulverize, cross 150-200 mesh sieve, stand-by;
The powder getting slag, oildag powder, compound clay and step (1) obtained mixes, the slurries that concentration is 50-55% are made in the making beating that adds water, add sodium laurylsulfate and chitosan again, heating in water bath is to 55-60 DEG C, 2500-3500r/min speed lapping 20-30min, then by grinding after slurry spraying dry water content be the particle of 3-4%, stand-by;
(3) particle that step (2) is obtained is mixed with molybdenum disilicide, tin-antiomony oxide, then add liquid phenolic resin, be uniformly mixed 15-20min, stand-by;
(4) material that step (3) mixes is put into forming machine and make type at the pressure of 75-80MPa;
(5) base substrate that step (4) is obtained is carried out drying at the temperature of 40-50 DEG C, be dried to blank water content lower than 2%, then leaching glaze carried out to dried base substrate;
(6) by the N of base substrate obtained for step (5) at 2-3MPa
2under atmosphere with the ramp of 6-9 DEG C/min to 920-980 DEG C, insulation 1-2h, 640-690 DEG C is cooled to again with the speed of 2-4 DEG C/min, insulation 0.5-1h, then under the Ar atmosphere of 3-4MPa with the ramp of 3-5 DEG C/min to 880-940 DEG C, insulation 1-2h, again with the ramp of 2-4 DEG C/min to 1180-1240 DEG C, insulation 2-3h, cool to normal temperature with the furnace, packaging gets product.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106007666A (en) * | 2016-05-25 | 2016-10-12 | 钱立群 | Ceramic tile with excellent comprehensive performances and preparation method thereof |
| CN106082998A (en) * | 2016-06-08 | 2016-11-09 | 中国石油天然气股份有限公司 | Wear-resistant antistatic composite ceramic coating powder |
| CN106242522A (en) * | 2016-08-09 | 2016-12-21 | 佛山欧神诺陶瓷股份有限公司 | A kind of slag base anti-static ceramic and preparation method thereof |
| CN106316435A (en) * | 2016-08-05 | 2017-01-11 | 佛山市凯撒大道陶瓷有限公司 | Anti-static tile and production method thereof |
| CN106542803A (en) * | 2016-10-21 | 2017-03-29 | 安徽青花坊瓷业股份有限公司 | A kind of porcelain and its processing technology of tolerance salt air corrosion |
| CN110330260A (en) * | 2019-04-23 | 2019-10-15 | 绍兴市岩彩新型建材有限公司 | A kind of production technology of decorative brick powder |
| CN113248145A (en) * | 2021-05-31 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Antibacterial and antistatic laboratory ceramic table top plate and preparation method thereof |
| CN115594488A (en) * | 2022-12-15 | 2023-01-13 | 佛山市陶莹新型材料有限公司（Cn） | Anti-static ceramic and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475364A (en) * | 2009-02-02 | 2009-07-08 | 山东瓦伦蒂诺陶瓷有限公司 | Antistatic powder for antistatic ceramic tile |
| CN101974310A (en) * | 2010-08-21 | 2011-02-16 | 佛山市顺德区小太阳砂磨材料有限公司 | Antistatic coating formula for coated abrasives |
| CN102030519A (en) * | 2010-11-30 | 2011-04-27 | 广东特地陶瓷有限公司 | Anti-static ceramic brick and production method thereof |
| CN102173157A (en) * | 2011-03-03 | 2011-09-07 | 海能达通信股份有限公司 | Antistatic composite material, electronic device shell and electronic device |
| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN103951402A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-strength ceramic brick and preparation method thereof |
-
2015
- 2015-05-04 CN CN201510221330.8A patent/CN104860658A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475364A (en) * | 2009-02-02 | 2009-07-08 | 山东瓦伦蒂诺陶瓷有限公司 | Antistatic powder for antistatic ceramic tile |
| CN101974310A (en) * | 2010-08-21 | 2011-02-16 | 佛山市顺德区小太阳砂磨材料有限公司 | Antistatic coating formula for coated abrasives |
| CN102030519A (en) * | 2010-11-30 | 2011-04-27 | 广东特地陶瓷有限公司 | Anti-static ceramic brick and production method thereof |
| CN102173157A (en) * | 2011-03-03 | 2011-09-07 | 海能达通信股份有限公司 | Antistatic composite material, electronic device shell and electronic device |
| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN103951402A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-strength ceramic brick and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李希勇等: "《新汶矿区充填开采地表移动规律研究》", 28 February 2013 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106007666A (en) * | 2016-05-25 | 2016-10-12 | 钱立群 | Ceramic tile with excellent comprehensive performances and preparation method thereof |
| CN106082998A (en) * | 2016-06-08 | 2016-11-09 | 中国石油天然气股份有限公司 | Wear-resistant antistatic composite ceramic coating powder |
| CN106316435A (en) * | 2016-08-05 | 2017-01-11 | 佛山市凯撒大道陶瓷有限公司 | Anti-static tile and production method thereof |
| CN106242522A (en) * | 2016-08-09 | 2016-12-21 | 佛山欧神诺陶瓷股份有限公司 | A kind of slag base anti-static ceramic and preparation method thereof |
| CN106542803A (en) * | 2016-10-21 | 2017-03-29 | 安徽青花坊瓷业股份有限公司 | A kind of porcelain and its processing technology of tolerance salt air corrosion |
| CN110330260A (en) * | 2019-04-23 | 2019-10-15 | 绍兴市岩彩新型建材有限公司 | A kind of production technology of decorative brick powder |
| CN110330260B (en) * | 2019-04-23 | 2021-11-26 | 绍兴市岩彩新型建材有限公司 | Production process of decorative brick powder |
| CN113248145A (en) * | 2021-05-31 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Antibacterial and antistatic laboratory ceramic table top plate and preparation method thereof |
| CN115594488A (en) * | 2022-12-15 | 2023-01-13 | 佛山市陶莹新型材料有限公司（Cn） | Anti-static ceramic and preparation method thereof |
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