CN104844981A - Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof - Google Patents
Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof Download PDFInfo
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- CN104844981A CN104844981A CN201510285569.1A CN201510285569A CN104844981A CN 104844981 A CN104844981 A CN 104844981A CN 201510285569 A CN201510285569 A CN 201510285569A CN 104844981 A CN104844981 A CN 104844981A
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- polyvinyl chloride
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- butadiene rubber
- sheath material
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- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 24
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims abstract description 19
- 229920000459 Nitrile rubber Polymers 0.000 title claims abstract description 13
- 238000004891 communication Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 9
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 9
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 14
- 229920013649 Paracril Polymers 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229920010741 Ultra High Molecular Weight Polyethylene (UHMWPE) Polymers 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 5
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 4
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 abstract 2
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 abstract 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables, which is prepared from the following raw materials in parts by weight: 65-70 parts of polyvinyl chloride, 20-25 parts of nitrile-butadiene rubber, 4-5 parts of high-wear-resistance carbon black, 2.5-3 parts of triallyl isocyanurate, 0.3-0.6 part of dicumyl peroxide, 5-6 parts of ultra-high molecular weight polyethylene, 3-4 parts of carbon nanotube, 0.6-0.8 part of nano silver particle and 0.2-0.3 part of zinc diethyl dithiocarbamate. The polyvinyl chloride and nitrile-butadiene rubber are subjected to secondary crosslinking compounding without vulcanization, thereby greatly simplifying the tool set equipment and technique, enhancing the efficiency and lowering the cost; and thus, the sheath material has high strength and favorable oil resistance, and has better softness and elasticity than the single use of polyvinyl chloride. The carbon nanotube and nano silver particle are utilized to enhance the tensile strength, wear resistance and corrosion resistance of the sheath material. The ultra-high molecular weight polyethylene is utilized to enhance the wear resistance and moisture resistance of the sheath material.
Description
Technical field
The present invention relates to cable jacket material field, particularly relate to a kind of wear-resisting communication cable acrylonitrile butadiene rubber modified pvc sheathing compound and preparation method thereof.
Background technology
Rubbercable is soft with it, there is elasticity, rub resistance and in being widely used in, among the electric power circuit of the frequent movement of the need of low pressure, such as shipboard cable, subway cable, mine electric cable, welding machine cable, studio cable etc. plastic cable is then superior with its electric property, physical strength is high and be widely used in middle high-pressure, among the electric power circuit fixedly laid, in each comfortable each department of national economy, play extremely important effect.In the middle of plastic cable, although cross-inked polyethylene power cable obtains significant progress in recent years, but polyvinyl chloride insulation, polyvinyl chloride boot power cable are still playing an important role, especially in the middle of low-voltage circuit, polyvinyl chloride (PVC) electric wire, cable are still in occupation of dominant position. with regard to production technique, rubbercable and twisted polyethylene cable all more complicated, all need larger facility investment.Comparatively speaking, the production technique of polyvinyl chloride cable will be simply too much, and because it is without the need to sulfuration, facility investment is just much smaller, and production cost is just corresponding much lower.
In addition, the relative rubbercable of polyvinyl chloride cable, CABLE MATERIALS used can industrialized mass production, and rubber material is quite different, it can only be that cable producer is self-produced personal, and due to rubber material variety of raw material many, although also make troubles to production. polyvinyl chloride cable has unique advantage on producing, but with regard to purposes, it still cannot substitute rubbercable, reason is just the flexibility of polyvinyl chloride cable, elasticity cannot be compared with rubbercable.
According to the principle of rubber and plastic compound, " research of polyvinyl chloride-paracril compound elastomer cable material " one literary composition uses polyvinyl chloride and paracril to carry out compound, without the need to sulfuration, obtains elasticity, flexibility, CABLE MATERIALS that oil-proofness is good.But this matrix material just carries out simple compound, the performances such as tensile strength, resistance to air loss, moistureproofness, ageing resistance, wear resistance not, should can not meet the requirement of modern industry to communication cable, need to improve.
Summary of the invention
The object of the present invention is to provide the acrylonitrile butadiene rubber modified pvc sheathing compound of a kind of wear-resisting communication cable, this sheath material intensity is high, and oil-proofness is good, and flexibility, good springiness are easy to install, and wear resistance, erosion resistance are good.
Technical scheme of the present invention is as follows:
The acrylonitrile butadiene rubber modified pvc sheathing compound of a kind of wear-resisting communication cable, is characterized in that being made up of the raw material of following weight part: polyvinyl chloride 65-70, paracril 20-25, high wear-resistant carbon black 4-5, cyanacrylate 2.5-3, dicumyl peroxide 0.3-0.6, ultrahigh molecular weight polyethylene(UHMWPE) 5-6, carbon nanotube 3-4, nano silver particles 0.6-0.8, zinc diethyldithiocarbamate 0.2-0.3.
The described wear-resisting communication cable production method of acrylonitrile butadiene rubber modified pvc sheathing compound, is characterized in that:
(1) paracril, high wear-resistant carbon black, diethyldithiocar bamic acid, carbon nanotube, nano silver particles, the cyanacrylate of 1/4, the dicumyl peroxide of 1/4 are sent into mixing roll, mixing 3-4min at 160-165 DEG C, obtains cross-linking modified paracril;
(2) polyvinyl chloride, ultrahigh molecular weight polyethylene(UHMWPE), the cyanacrylate of 1/2, the dicumyl peroxide of 1/2 are sent into mixing roll, mixing 3-4min at 160-165 DEG C, obtains cross-linking modified polyvinyl chloride;
(3) material (1) step and (2) step obtained and other remain and send into mixing roll, mixing 3-4min at 160-165 DEG C, send into twin screw extruder, extruding pelletization;
(4) the pellet hot pressing 5-6min at 160-165 DEG C (3) step obtained, is shaped, and send into baking oven, at 110-115 DEG C, aging 45-50h, to obtain final product.
Beneficial effect of the present invention
Polyvinyl chloride, paracril are carried out secondary crosslinking compound by sheath material of the present invention, without the need to sulfuration, thus enormously simplify tooling device and technique, improve efficiency, reduce cost, and intensity is high, oil-proofness is good, use polyvinyl chloride than merely, there is better flexibility, elasticity, easy to install; By using carbon nanotube, nano silver particles, improve tensile strength and wear resistance, the erosion resistance of sheath material; By using ultrahigh molecular weight polyethylene(UHMWPE), improve wear resistance and the moistureproofness of sheath material.
Embodiment
The acrylonitrile butadiene rubber modified pvc sheathing compound of a kind of wear-resisting communication cable, is made up of the raw material of following weight part (kilogram): polyvinyl chloride 67, paracril 23, high wear-resistant carbon black 4.5, cyanacrylate 2.8, dicumyl peroxide 0.4, ultrahigh molecular weight polyethylene(UHMWPE) 5.5, carbon nanotube 3.5, nano silver particles 0.7, zinc diethyldithiocarbamate 0.2.
The described wear-resisting communication cable production method of acrylonitrile butadiene rubber modified pvc sheathing compound, is characterized in that:
(1) paracril, high wear-resistant carbon black, diethyldithiocar bamic acid, carbon nanotube, nano silver particles, the cyanacrylate of 1/4, the dicumyl peroxide of 1/4 are sent into mixing roll, mixing 3min at 163 DEG C, obtains cross-linking modified paracril;
(2) polyvinyl chloride, ultrahigh molecular weight polyethylene(UHMWPE), the cyanacrylate of 1/2, the dicumyl peroxide of 1/2 are sent into mixing roll, mixing 3min at 163 DEG C, obtains cross-linking modified polyvinyl chloride;
(3) material (1) step and (2) step obtained and other remain and send into mixing roll, mixing 3min at 163 DEG C, send into twin screw extruder, extruding pelletization;
(4) the pellet hot pressing 5min at 163 DEG C (3) step obtained, is shaped, and send into baking oven, at 113 DEG C, aging 46h, to obtain final product.
Experimental data:
The elongation at break of this sheath material is 485% after tested, resistivity (10
12Ω ° of cm) be 0.477, dielectric loss is 0.085, and tensile strength (MPa) is 21, and aging coefficient is 0.98.
Claims (2)
1. the acrylonitrile butadiene rubber modified pvc sheathing compound of wear-resisting communication cable, is characterized in that being made up of the raw material of following weight part: polyvinyl chloride 65-70, paracril 20-25, high wear-resistant carbon black 4-5, cyanacrylate 2.5-3, dicumyl peroxide 0.3-0.6, ultrahigh molecular weight polyethylene(UHMWPE) 5-6, carbon nanotube 3-4, nano silver particles 0.6-0.8, zinc diethyldithiocarbamate 0.2-0.3.
2. the wear-resisting communication cable production method of acrylonitrile butadiene rubber modified pvc sheathing compound according to claim 1, is characterized in that:
(1) paracril, high wear-resistant carbon black, diethyldithiocar bamic acid, carbon nanotube, nano silver particles, the cyanacrylate of 1/4, the dicumyl peroxide of 1/4 are sent into mixing roll, mixing 3-4min at 160-165 DEG C, obtains cross-linking modified paracril;
(2) polyvinyl chloride, ultrahigh molecular weight polyethylene(UHMWPE), the cyanacrylate of 1/2, the dicumyl peroxide of 1/2 are sent into mixing roll, mixing 3-4min at 160-165 DEG C, obtains cross-linking modified polyvinyl chloride;
(3) material (1) step and (2) step obtained and other remain and send into mixing roll, mixing 3-4min at 160-165 DEG C, send into twin screw extruder, extruding pelletization;
(4) the pellet hot pressing 5-6min at 160-165 DEG C (3) step obtained, is shaped, and send into baking oven, at 110-115 DEG C, aging 45-50h, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510285569.1A CN104844981A (en) | 2015-05-29 | 2015-05-29 | Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510285569.1A CN104844981A (en) | 2015-05-29 | 2015-05-29 | Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof |
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| CN104844981A true CN104844981A (en) | 2015-08-19 |
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| CN201510285569.1A Pending CN104844981A (en) | 2015-05-29 | 2015-05-29 | Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589522A (en) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | Corrosion-resistant and abrasion-resistant polyethylene (PE) pipe |
| CN107603064A (en) * | 2017-09-27 | 2018-01-19 | 中玺新材料（安徽）有限公司 | A kind of ultra-high molecular weight polyethylene cored wire material formula |
| CN108410096A (en) * | 2018-04-16 | 2018-08-17 | 山东迪龙电缆有限公司 | A kind of polyvinyl chloride cable sheath and its processing technology |
| EP4084018A1 (en) * | 2021-04-30 | 2022-11-02 | Nexans | Electrical cable with antimicrobial properties |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746546A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
-
2015
- 2015-05-29 CN CN201510285569.1A patent/CN104844981A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746546A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589522A (en) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | Corrosion-resistant and abrasion-resistant polyethylene (PE) pipe |
| CN107603064A (en) * | 2017-09-27 | 2018-01-19 | 中玺新材料（安徽）有限公司 | A kind of ultra-high molecular weight polyethylene cored wire material formula |
| CN108410096A (en) * | 2018-04-16 | 2018-08-17 | 山东迪龙电缆有限公司 | A kind of polyvinyl chloride cable sheath and its processing technology |
| EP4084018A1 (en) * | 2021-04-30 | 2022-11-02 | Nexans | Electrical cable with antimicrobial properties |
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Application publication date: 20150819 |