CN104844359A - Trace element fertilizer for efficient utilization for paddy fields and preparation method of trace element fertilizer - Google Patents
Trace element fertilizer for efficient utilization for paddy fields and preparation method of trace element fertilizer Download PDFInfo
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- CN104844359A CN104844359A CN201510225685.4A CN201510225685A CN104844359A CN 104844359 A CN104844359 A CN 104844359A CN 201510225685 A CN201510225685 A CN 201510225685A CN 104844359 A CN104844359 A CN 104844359A
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 54
- 239000011573 trace mineral Substances 0.000 title claims abstract description 25
- 235000013619 trace mineral Nutrition 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 241000209094 Oryza Species 0.000 claims abstract description 21
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 21
- 235000009566 rice Nutrition 0.000 claims abstract description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 16
- 241000196324 Embryophyta Species 0.000 claims abstract description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229960000892 attapulgite Drugs 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 7
- 239000011591 potassium Substances 0.000 claims abstract description 7
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000005696 Diammonium phosphate Substances 0.000 claims abstract description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims abstract description 4
- 235000019838 diammonium phosphate Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 8
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 6
- 239000011592 zinc chloride Substances 0.000 claims description 6
- 235000005074 zinc chloride Nutrition 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000012851 eutrophication Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004575 stone Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 6
- 239000000454 talc Substances 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a trace element fertilizer for efficient utilization for paddy fields and a preparation method of the trace element fertilizer. The trace element fertilizer is prepared from such raw materials in parts by weight as 10-15 parts of micalex, 30-45 parts of 0.1mol/L hydrochloric acid solution, 10-12 parts of attapulgite, 4-6 parts of plant ash, 25-30 parts of urea, 1-3 parts of zinc oxide, 5-8 parts of potassium humate, 8-10 parts of trace elements, 15-20 parts of diammonium phosphate, 4-5 parts of fertilizer additive and an appropriate amount of water. The invention specifically relates to a trace element fertilizer for efficient utilization for planting in paddy fields; stone powder particles coated with the fertilizer additive are mixed with the fertilizer, so that the fertilizer can be enabled to have the function of adsorbing, sticking and reserving and storing the fertilizer; after the fertilizer is applied to the paddy fields, the fertilizer is immersed next to the root system of the rice to reduce losses under the water flow action and the water eutrophication; the planted rice is a rice rich in trace elements.
Description
Technical field
The invention belongs to the Technology field of fertilizer, be specifically related to trace element fertilizer of a kind of rice terrace efficiency utilization and preparation method thereof.
Background technology
In view of the present situation of current China chemical fertilizers production application, since the eighties in 20th century, the a large amount of uses on Vegetable produce of chemical fertilizer, agricultural chemicals, cause soil compaction, degree of salinity is aggravated, to the serious threat that agroecological environment is formed, cause underground water to drink pollution simultaneously, landed property area is little per capita in China, how to utilize limited land resources, under the prerequisite ensureing soil sustainable utilization, the vegetables product of production high-quality, safety, becomes the important topic of various countries agricultural science and technology worker research.Based on above reason, people propose to use fertilizer additive, and to improve, utilization rate of fertilizer is low, the feature of the wasting of resources and Water Eutrophication.
Summary of the invention
A kind of trace element fertilizer of rice terrace efficiency utilization, it is characterized in that, be made up of the raw material of following weight part: the hydrochloric acid soln 30 ~ 45 of Muscovitum 10 ~ 15,0.1mol/L, attapulgite 10 ~ 12, plant ash 4 ~ 6, urea 25 ~ 30, zinc chloride 1 ~ 3, potassium humate 5 ~ 8, trace element 8 ~ 10, diammonium phosphate 15 ~ 20, fertilizer additive 4 ~ 5 and appropriate water;
Described fertilizer additive is made up of following raw material: terra alba 10 ~ 15, oleum lini 4 ~ 6, vinylbenzene 10 ~ 12, sodium stearate 1 ~ 2, N hydroxymethyl acrylamide 2 ~ 3, ethanol 8 ~ 10 are appropriate water; Preparation method is: by ethanol and water with 1: 10 ratio dissolve each other after put into reactor, add vinylbenzene and N hydroxymethyl acrylamide, be heated to 70 ~ 80 DEG C, stirring and dissolving, mixing oleum lini and sodium stearate join in the water of 4 ~ 5 times of its total weight parts, bubble after stirring 10min, then join in aforesaid reactor, heating and thermal insulation, and stirring 0.5 ~ 2h carries out composite under the rotating speed of 300 ~ 500r/min, finally terra alba was finely ground to 200 mesh sieves to add in total material to stir and make emulsion, and was incubated for subsequent use and get final product.
A preparation method for the trace element fertilizer of rice terrace efficiency utilization, is characterized in that, comprises following step:
(1) pulverized by Muscovitum, grinding and sieving net, must be the particle of 40 ~ 60 mesh sieves, the hydrochloric acid soln putting into 0.1mol/L stirs 5 ~ 10min, washs 2 ~ 3 times after filtering out hydrochloric acid with clear water;
(2) mixing urea, zinc chloride, potassium humate, trace element and bicarbonate of ammonia, be ground into pulvis with pulverizer, appropriate water spray wetted surface but do not dissolve;
(3) preheating fertilizer additive to 100 ~ 110 DEG C in coating machine, are then sprayed at the particle surface described in (1) of rolling, mix under normal temperature after cooling with the pulvis described in (2) with the form of spraying, machinery rolling stirring 10 ~ 15min;
(4) be added to after attapulgite and plant ash being mixed in the total material described in (3), stirring and evenly mixing, adds water to water content 20%, granulation in right amount.
The present invention is according to the root problem in fertilizer current generation, and namely utilization rate of fertilizer is low, and fertilizer efficiency is slow, nutrient supply is unstable and easily cause the shortcoming of body eutrophication, prepares a kind of concentrated fertilizer with fertilizer additive, completes by the following method:
Described fertilizer additive is a kind of with styrene resin alicyclic monomer, binding agent N hydroxymethyl acrylamide is coordinated to be a kind of high performance water-soluble material prepared by main body, wherein add the sliminess that plant oil oleum lini increases main body, add sodium stearate as surfactant, then oleum lini and the perfection of resene monomer agree with, form a kind of additive with high bonding characteristic, present gluing form, finally add terra alba, refining grinding, determine the granularity of terra alba, add as a kind of structural agent, make main body more stable.
This additive generally coordinates bigbore talc particles together to use, the rock particles with improvement soil characteristic is ground into the particulate state of certain particle size size, then acid or base extraction is used, make smooth powder particles surface irregularity, then fertilizer additive to 70 ~ 80 DEG C are heated, join the surface of aforementioned powder particles, stirring and evenly mixing becomes thickener, naturally cooling is also air-dry, again be crushed to fine particle agent after air-dry, coordinate Inorganic chemical composition and organic fermentation material composition etc. to make powder;
The object of such preparation is the bonding characteristic and the adsorption that utilize additive, effectively prevent the loss of fertilizer nutrient, combine with talc particles, in the process of fertilising, if need water fertilising, the fertilizer dissolved can discharge talc particles, talc particles precipitation enters soil, be attached near root system of plant, the scope internal adsorption ability of zonule is strengthened, and the factor of the useful plants growths such as attached microbial, mineral ion and organic acid is adsorbed, and can reach effective utilization rate of fertilizer, promote the absorption of fertilizer, and permanently effective.
Beneficial effect of the present invention: the present invention is a kind of rice terrace plantation trace element fertilizer of efficiency utilization; fertilizer is mixed into by the talc particles of fertilizer additive coating; there is absorption, stick and the reserved function storing fertilizer; after being administered to rice terrace; be immersed near rice root; reduce loss and the body eutrophication of flow action, the paddy rice of plantation is a kind of paddy rice of rich trace elements.
Embodiment
Embodiment 1:
A kind of trace element fertilizer of rice terrace efficiency utilization, it is characterized in that, be made up of the raw material of following weight part (Kg): the hydrochloric acid soln 45 of Muscovitum 12,0.1mol/L, attapulgite 10, plant ash 4, urea 25, zinc chloride 1, potassium humate 6, trace element 10, diammonium phosphate 15, fertilizer additive 5 and appropriate water;
Described fertilizer additive is made up of following raw material: terra alba 12, oleum lini 5, vinylbenzene 12, sodium stearate 1, N hydroxymethyl acrylamide 2, ethanol 10 are appropriate water; Preparation method is: by ethanol and water with 1: 10 ratio dissolve each other after put into reactor, add vinylbenzene and N hydroxymethyl acrylamide, be heated to 70 ~ 80 DEG C, stirring and dissolving, mixing oleum lini and sodium stearate join in the water of 4 ~ 5 times of its total weight parts, bubble after stirring 10min, then join in aforesaid reactor, heating and thermal insulation, and stirring 0.5 ~ 2h carries out composite under the rotating speed of 300 ~ 500r/min, finally terra alba was finely ground to 200 mesh sieves to add in total material to stir and make emulsion, and was incubated for subsequent use and get final product.
A preparation method for the trace element fertilizer of rice terrace efficiency utilization, is characterized in that, comprises following step:
(1) pulverized by Muscovitum, grinding and sieving net, must be the particle of 40 ~ 60 mesh sieves, the hydrochloric acid soln putting into 0.1mol/L stirs 5 ~ 10min, washs 2 ~ 3 times after filtering out hydrochloric acid with clear water;
(2) mixing urea, zinc chloride, potassium humate, trace element and bicarbonate of ammonia, be ground into pulvis with pulverizer, appropriate water spray wetted surface but do not dissolve;
(3) preheating fertilizer additive to 100 ~ 110 DEG C in coating machine, are then sprayed at the particle surface described in (1) of rolling, mix under normal temperature after cooling with the pulvis described in (2) with the form of spraying, machinery rolling stirring 10 ~ 15min;
(4) be added to after attapulgite and plant ash being mixed in the total material described in (3), stirring and evenly mixing, adds water to water content 20%, granulation in right amount.
The trace element fertilizer of rice terrace efficiency utilization of the present invention is used for the plantation of 5 mu of rice terraces as rice terrace plantation fertilizer; result shows; this fertilizer can save Fertilizer application amount greatly; the resistance of paddy rice strengthens; salting of soil weakens; have provide protection to soil, nutritive props and the everyway of paddy rice are more outstanding than common rice.
Claims (2)
1. the trace element fertilizer of a rice terrace efficiency utilization, it is characterized in that, be made up of the raw material of following weight part: the hydrochloric acid soln 30 ~ 45 of Muscovitum 10 ~ 15,0.1mol/L, attapulgite 10 ~ 12, plant ash 4 ~ 6, urea 25 ~ 30, zinc chloride 1 ~ 3, potassium humate 5 ~ 8, trace element 8 ~ 10, diammonium phosphate 15 ~ 20, fertilizer additive 4 ~ 5 and appropriate water;
Described fertilizer additive is made up of following raw material: terra alba 10 ~ 15, oleum lini 4 ~ 6, vinylbenzene 10 ~ 12, sodium stearate 1 ~ 2, N hydroxymethyl acrylamide 2 ~ 3, ethanol 8 ~ 10 are appropriate water; Preparation method is: by ethanol and water with 1: 10 ratio dissolve each other after put into reactor, add vinylbenzene and N hydroxymethyl acrylamide, be heated to 70 ~ 80 DEG C, stirring and dissolving, mixing oleum lini and sodium stearate join in the water of 4 ~ 5 times of its total weight parts, bubble after stirring 10min, then join in aforesaid reactor, heating and thermal insulation, and stirring 0.5 ~ 2h carries out composite under the rotating speed of 300 ~ 500r/min, finally terra alba was finely ground to 200 mesh sieves to add in total material to stir and make emulsion, and was incubated for subsequent use and get final product.
2. the preparation method of a kind of trace element fertilizer of rice terrace efficiency utilization according to claim 1, is characterized in that, comprise following step:
(1) pulverized by Muscovitum, grinding and sieving net, must be the particle of 40 ~ 60 mesh sieves, the hydrochloric acid soln putting into 0.1mol/L stirs 5 ~ 10min, washs 2 ~ 3 times after filtering out hydrochloric acid with clear water;
(2) mixing urea, zinc chloride, potassium humate, trace element and bicarbonate of ammonia, be ground into pulvis with pulverizer, appropriate water spray wetted surface but do not dissolve;
(3) preheating fertilizer additive to 100 ~ 110 DEG C in coating machine, are then sprayed at the particle surface described in (1) of rolling, mix under normal temperature after cooling with the pulvis described in (2) with the form of spraying, machinery rolling stirring 10 ~ 15min;
(4) be added to after attapulgite and plant ash being mixed in the total material described in (3), stirring and evenly mixing, adds water to water content 20%, granulation in right amount.
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CN201510225685.4A CN104844359A (en) | 2015-05-06 | 2015-05-06 | Trace element fertilizer for efficient utilization for paddy fields and preparation method of trace element fertilizer |
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CN201510225685.4A CN104844359A (en) | 2015-05-06 | 2015-05-06 | Trace element fertilizer for efficient utilization for paddy fields and preparation method of trace element fertilizer |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152774A (en) * | 2015-09-01 | 2015-12-16 | 安徽省安庆市金太阳生物科技有限责任公司 | Novel paddy rice reviving tillering granular fertilizer and preparation method thereof |
CN105237196A (en) * | 2015-10-08 | 2016-01-13 | 定远县蒋集镇丰润蔬菜种植专业合作社 | Cucumber fertilizer prepared from modified peat and preparation method thereof |
CN105967821A (en) * | 2016-02-25 | 2016-09-28 | 马鞍山市全润农业科技有限公司 | Modified-Chinese-chestnut-protein-coated slow-release fertilizer special for rice |
CN107827682A (en) * | 2017-12-22 | 2018-03-23 | 苏州艾捷尔斯生物科技有限公司 | A kind of fertilizer special for organic for improving rice yield and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102653493A (en) * | 2012-04-09 | 2012-09-05 | 马鞍山科邦生态肥有限公司 | Drought-resistant fertilizer specially for rice and preparing method of fertilizer |
CN104311220A (en) * | 2014-09-24 | 2015-01-28 | 林公传 | Eggplant planting controlled-release fertilizer and preparation method thereof |
-
2015
- 2015-05-06 CN CN201510225685.4A patent/CN104844359A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102653493A (en) * | 2012-04-09 | 2012-09-05 | 马鞍山科邦生态肥有限公司 | Drought-resistant fertilizer specially for rice and preparing method of fertilizer |
CN104311220A (en) * | 2014-09-24 | 2015-01-28 | 林公传 | Eggplant planting controlled-release fertilizer and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152774A (en) * | 2015-09-01 | 2015-12-16 | 安徽省安庆市金太阳生物科技有限责任公司 | Novel paddy rice reviving tillering granular fertilizer and preparation method thereof |
CN105237196A (en) * | 2015-10-08 | 2016-01-13 | 定远县蒋集镇丰润蔬菜种植专业合作社 | Cucumber fertilizer prepared from modified peat and preparation method thereof |
CN105967821A (en) * | 2016-02-25 | 2016-09-28 | 马鞍山市全润农业科技有限公司 | Modified-Chinese-chestnut-protein-coated slow-release fertilizer special for rice |
CN107827682A (en) * | 2017-12-22 | 2018-03-23 | 苏州艾捷尔斯生物科技有限公司 | A kind of fertilizer special for organic for improving rice yield and preparation method thereof |
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Application publication date: 20150819 |