CN104830208B - Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent - Google Patents
Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent Download PDFInfo
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- CN104830208B CN104830208B CN201510218793.9A CN201510218793A CN104830208B CN 104830208 B CN104830208 B CN 104830208B CN 201510218793 A CN201510218793 A CN 201510218793A CN 104830208 B CN104830208 B CN 104830208B
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- coloring agent
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- bogging
- filling
- modified epoxy
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- 239000003086 colorant Substances 0.000 title claims abstract description 9
- 238000011049 filling Methods 0.000 title claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000005516 engineering process Methods 0.000 claims description 9
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 9
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 210000003205 muscle Anatomy 0.000 claims description 7
- 238000000016 photochemical curing Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 238000007665 sagging Methods 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 17
- 239000002023 wood Substances 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 5
- 238000004040 coloring Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000037452 priming Effects 0.000 abstract description 4
- 239000004593 Epoxy Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000011229 interlayer Substances 0.000 abstract description 2
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- -1 neopentyl glycol diacrylates Ester Chemical class 0.000 description 7
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 6
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000012965 benzophenone Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 2
- 125000006188 2-phenyl benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C1=C(C([H])=C([H])C([H])=C1[H])C([H])([H])* 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 230000003370 grooming effect Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical compound PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
A rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent comprises, by mass, 10-20% of modified epoxy acrylic resin, 40-50% of an active monomer and 5-8% of a photoinitiator, and has the advantages of good dispersion stability and adhesion, high hardness, good leveling, good fullness, fast drying speed, high production efficiency, few organic volatile matters, and simple and convenient construction. The coloring agent has good compatibility and interlayer binding force with various aqueous priming paints and finishes, well improves the wood grain contrast of the surface of wood, and also has the characteristics of safety, environmental protection, no pungent smell, uniform coloring, plump filling, and excellent color fixation.
Description
Technical field
The present invention relates to the coloring of IPC International Classification of Patents C09C inorganic material or filling technique or C09D coating compositions are applied
Material technology, especially explosion-proof muscle or the high filling glaze coloring agent of sagging environment-friendly type photocuring.
Background technology
Furniture primer painting process is mainly with polyurethanes at present（Polyurethane, abridge PU, referred to as poly-
Urethane）Or unsaturated polyester varnish（ PE）Based on, the levelability of this two classes paint is excellent, and good sanding, adhesion performance are good
It is good.But volatile matter（ VOC）Content is higher（About 50～60%）, pot-life is short（The paint for preparing need to be used as early as possible
It is complete）, temperature influence is larger, and low production efficiency hinders the development of furniture enterprise.UV paints are ultraviolet light cured paints（
Ultraviolet Curing Paint ）Abbreviation, also referred to as light-initiated coating, photocureable coating are coated to furniture plate surface
After upper, promote decomposition of initiator under the irradiation of ultraviolet light, produce free radical, cause resin reaction, instantaneous solidification into
Film, is current most environmentally friendly paint, with advantages below：（ 1）UV paint films are stereo structure structures, and hardness is big, wear-resisting
Property is good, and transparency is good, the resistance to scratching of product, rub resistance, stands the test of time；（ 2）Mechanized equipment overcomes people
Anthropic factor in work operation, makes product aberration less, steady quality；（ 3）In manufacturing process, by the nuisance in sheet material
Matter is decomposed, and by ultraviolet photo-curing machine drying and processing, product more health environment-friendly.As UV is painted in furniture at home
The increase of ratio, user are also also introduced into the construction technology of traditional solvent-borne woodcare paint in UV paints, painting such as modelled after an antique
Dress technique etc..Photocureable coating refers mainly to a class new coating of the rapid crosslinking curing film forming under ultraviolet light, Yin Qigao
Effect coated solidified and environmental friendliness feature, are approved by world's coating industry and most of administrative organization, in furniture row
Widely used already.Overwhelming majority photocuring glaze contains a large amount of nitrocottons and organic solvent at present, not only in work progress
Middle curing efficiency is low, discharge a large amount of organic solvent pollution environment, human body is damaged, and is also easy to cause wood surface to apply take on
Now the phenomenon such as sunken, quick-fried muscle, is not also very smooth in the utilization of the furniture industries such as such as office furniture, suite room furniture, timber.
Glaze is a kind of translucent to transparent pigment colorant, is dissolved in oil solvent by resin and is constituted, and is done
It is dry slow, can be wiped, grooming and done level light and shade, make soft integral color, nature, stereovision by force, the overwhelming majority is in NC
Used in paint.Glaze can be inserted color in the pore of timber, and can pass through to wipe the light and shade depth of adjustment color, increase
Plus the definition of the stereovision of film color and wood grain, it is the indispensable color-tinted product of American and European style.It is mainly used in nitro
The solid wood of application, the erasing coloring for pasting the various wood furniture products such as veneer, the density board edge sealing for being also applied to nitro application are false
Wood grain garland.Glaze coloring agent:Antiquing paint is can be described as again, is in slow curing and the oil for being easy to wipe or resin, translucent
Or transparent pigment is dissolved in made by oil solvent.Its object is to using its translucence to reduce brightness, make face soft
With, it is contrasted and hatching effect, the interest for producing allusion is hidden.
Published improved technology is less.
Chinese patent application 201310208024.1 provides a kind of UV glazes, including：Bisphenol type epoxy acrylic acid tree
Fat 5-10 weight portions；Reactive diluent 5-10 weight portions；Nitrocotton 5-8 weight portions；Dispersant 0.01-1 weight portions；Peace bar powder 5-
10 weight portions；Solvent 50-80 weight portions；Light trigger 1-1.5 weight portions.And solve thorn to human body during UV paint uses
Sharp property, can apply in the antique coating of various woodwork furniture.
Chinese patent application 201110079237.X is used for glaze wiping stain of coating aqueous carpentry and preparation method thereof
Belong to paint field.Wiping stain includes color development component and fixation component.Color development component contains a kind of pigment that rises and carries and cohere work
Amphiphilic polymers resin, makes pigment sprawl and infiltration in wood surface well;Fixation component contains acrylate and gathers
Compound, with excellent colour retention and weatherability.
Chinese patent application 201210507675.6 is related to a kind of ultraviolet light polymerization（UV）Electrostatic spraying transparent priming woodenware
Coating, the coating are made up of two component of A, B, and component A is made up of following composition, epoxy acrylate（EA）, modified epoxy third
Olefin(e) acid ester（EA）, reactive diluent, defoamer, dust-proofing agent, color stuffing, light trigger, B component is made up of following composition：Vinegar
Acetoacetic ester.Its construction technology：Component A presses 100 with B component:10-15 ratio mixed constructions.
The content of the invention
It is an object of the invention to provide explosion-proof muscle or the high filling glaze coloring agent of sagging environment-friendly type photocuring, environmental protection
Stable performance, explosion-proof muscle or sagging performance are projected.
The purpose of the present invention will be realized by following technical measures：Factory formula is：
| Material name | Mass fraction % |
| Modified epoxy acrylate resin | 10-20% |
| Activated monomer | 40-50% |
| Light trigger | 5-8% |
| Color essence | 0-10% |
| Moistening flatting agent | 0.1-0.5% |
| Dispersant | 0.5-1% |
| Filler | 10-15% |
| Aerosil | 1-5% |
Production technology is：First by modified epoxy acrylate resin, activated monomer and light trigger mix homogeneously, then add profit
Wet levelling agent, dispersant, then after filler is uniformly dispersed at a high speed are slowly added aerosil, finally add in proportion
Additive color essence is uniformly dispersed.
Especially, wherein, modified epoxy acrylate resin be ETERNAL6202, ETERNAL622-100, CN2101,
At least one in CN112C60, EB3702, LR8986；Activated monomer is PO-NPGDA (the third oxidation neopentyl glycol diacrylates
Ester), PEG (400) DMA (Polyethylene Glycol（400）Dimethylacrylate), PEG (600) DMA (Polyethylene Glycol（600）Dimethyl
Acrylate), DEGDMA (dimethacrylate), 3EGDMA（TEGDMA）、
EOTMPTA（Ethoxyquin tri methylol triacrylate）In at least one；Light trigger is 1173（α-hydroxyisopropyl benzene
Ketone）、184（α-hydroxyl ring ethylo benzene ketone）、BP（Benzophenone）、651（Benzoin dimethylether）、Irgacure369【2-
Phenyl benzyl -2- dimethyl amine -1- (4- morpholine benzyl phenyl) butanone】、819【It is double（2,4,6- trimethylbenzoyls）Phenyl oxygen
Change phosphine】In at least one；Moistening flatting agent be BYK358N, BYK306, TEGO450, EFKA3777, BYK333 at least
One kind, dispersant are at least one in BYK164, BYK103, BYK110, EFKA4010, NUOSPERSE9100；Filler is
600 mesh, 800 mesh, 1250 mesh Pulvis Talci, or at least one in TA-2500, or silicon powder；Aerosil is
At least one in A200, M-5, HS973, A-360.
Advantages of the present invention and effect：With preferable dispersion stabilization and adhesive force, hardness is high, levelling is good, richness
Well, rate of drying is fast, production efficiency is high, organic volatile is few, construction is simple and convenient.Show with various aqueous priming paints and finish paint
Go out the good compatibility and inter-layer bonding force, improve well the wood grain contrast of wood surface, with safety and environmental protection, non-stimulated
Property abnormal smells from the patient, uniform coloring, fill full and excellent fixation the features such as.
Specific embodiment
The principle of the invention is, by selecting suitable light-cured resin and extremely low toxicity, zest activated monomer, to obtain
A kind of new photocuring glaze, solves above-mentioned deficiency, the glaze wood surface application both can background color, can fill out again
Timber conduit is filled, the coating weight of priming paint is reduced, organic solvent-free volatilization completes solidification, efficiency under ultraviolet light in 5 seconds
Height, is adapted to industrialized production.
Factory formula of the present invention is：
| Material name | Mass fraction % |
| Modified epoxy acrylate resin | 10-20% |
| Activated monomer | 40-50% |
| Light trigger | 5-8% |
| Color essence | 0-10% |
| Moistening flatting agent | 0.1-0.5% |
| Dispersant | 0.5-1% |
| Filler | 10-15% |
| Aerosil | 1-5% |
Wherein, modified epoxy acrylate resin be ETERNAL6202, ETERNAL622-100, CN2101, CN112C60,
At least one in EB3702, LR8986；Activated monomer is PO-NPGDA (the third oxidation neopentylglycol diacrylate), PEG
(400) DMA (Polyethylene Glycol（400）Dimethylacrylate), PEG (600) DMA (Polyethylene Glycol（600）Dimethacrylate
Ester), DEGDMA (dimethacrylate), 3EGDMA（TEGDMA）、EOTMPTA（Second
Oxidation tri methylol triacrylate）In at least one；Light trigger is 1173（α-hydroxyisopropyl benzophenone）、184
（α-hydroxyl ring ethylo benzene ketone）、BP（Benzophenone）、651（Benzoin dimethylether）、Irgacure369【2- phenyl benzyl -2-
Dimethyl amine -1- (4- morpholine benzyl phenyl) butanone】、819【It is double（2,4,6- trimethylbenzoyls）Phenyl phosphine oxide】In
It is at least one；Moistening flatting agent is at least one in BYK358N, BYK306, TEGO450, EFKA3777, BYK333, is disperseed
Agent is at least one in BYK164, BYK103, BYK110, EFKA4010, NUOSPERSE9100；Filler be 600 mesh, 800
Mesh, 1250 mesh Pulvis Talci, or at least one in TA-2500, or silicon powder；Aerosil be A200, M-5,
At least one in HS973, A-360.
Production technology is：First by modified epoxy acrylate resin, activated monomer and light trigger mix homogeneously, then add profit
Wet levelling agent, dispersant, then after filler is uniformly dispersed at a high speed are slowly added aerosil, finally add in proportion
Additive color essence is uniformly dispersed.
The present invention is mainly used on woodwork, be especially suitable for needing high filling, it is anti-sink, the office furniture of explosion-proof muscle,
On the products such as suite room furniture, timber.
It is an advantage of the invention that：Adhesive force is good, richness is good, processing temperature is low, high, organic without pot-life, production efficiency
Volatile matter is few etc..
Ultimate principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description this
The principle of invention, of the invention without departing from the spirit and scope of the present invention also to have various changes and modifications, these changes
Change and improvement is both fallen within scope of the claimed invention.Although the present invention has been explained in detail and has been cited embodiment,
But for one of ordinary skill in the art, it is clear that can as specified above and make various schemes, modification and change,
Should be construed as being included within the scope of claim.
Claims (1)
1. the high filling glaze coloring agent of explosion-proof muscle or sagging environment-friendly type photocuring, it is characterised in that factory formula is：
Production technology is：First by modified epoxy acrylate resin, activated monomer and light trigger mix homogeneously, then add moistening stream
Flat agent, dispersant are uniform, then are slowly added aerosil after filler is uniformly dispersed at a high speed, finally add in proportion
Additive color essence is uniformly dispersed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510218793.9A CN104830208B (en) | 2015-05-04 | 2015-05-04 | Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510218793.9A CN104830208B (en) | 2015-05-04 | 2015-05-04 | Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104830208A CN104830208A (en) | 2015-08-12 |
| CN104830208B true CN104830208B (en) | 2017-04-12 |
Family
ID=53808418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510218793.9A Active CN104830208B (en) | 2015-05-04 | 2015-05-04 | Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent |
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| CN107129723A (en) * | 2017-05-24 | 2017-09-05 | 鹤山市君子兰涂料有限公司 | A novel colored filler and its preparation method |
| CN109456647A (en) * | 2018-10-16 | 2019-03-12 | 鹤山市君子兰涂料有限公司 | A novel environmentally friendly and safe LED curing rubbing agent and preparation method thereof |
| CN109852148A (en) * | 2019-03-06 | 2019-06-07 | 上海君子兰新材料股份有限公司 | LED-UV photocuring glaze wiping stain |
| CN110903706A (en) * | 2019-12-20 | 2020-03-24 | 广东花王涂料有限公司 | Water-oil universal environment-friendly woodware coloring agent and preparation method thereof |
| CN111589679A (en) * | 2020-06-19 | 2020-08-28 | 合肥志邦木业有限公司 | Water-based paint spraying process |
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| CN103937377A (en) * | 2013-01-21 | 2014-07-23 | 上海参爱贸易有限公司 | Low gloss ultraviolet curing coating |
| CN103265873A (en) * | 2013-05-30 | 2013-08-28 | 上海长润发涂料有限公司 | UV (Ultraviolet) light white finish |
| CN103602224B (en) * | 2013-11-20 | 2016-06-01 | 广东美涂士建材股份有限公司 | A kind of white solvent-free finish paint and its preparation method and construction technology |
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