CN104822188A - Multifunctional glass and production method thereof - Google Patents
Multifunctional glass and production method thereof Download PDFInfo
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- CN104822188A CN104822188A CN201510182478.5A CN201510182478A CN104822188A CN 104822188 A CN104822188 A CN 104822188A CN 201510182478 A CN201510182478 A CN 201510182478A CN 104822188 A CN104822188 A CN 104822188A
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- transparent conductive
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- conductive oxide
- glass substrate
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- 239000011521 glass Substances 0.000 title claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 239000011941 photocatalyst Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims description 12
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 11
- 229910001887 tin oxide Inorganic materials 0.000 claims description 11
- 229910052787 antimony Inorganic materials 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 238000007650 screen-printing Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- YCKOAAUKSGOOJH-UHFFFAOYSA-N copper silver Chemical compound [Cu].[Ag].[Ag] YCKOAAUKSGOOJH-UHFFFAOYSA-N 0.000 claims description 5
- 238000007688 edging Methods 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229910003437 indium oxide Inorganic materials 0.000 claims description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000006870 function Effects 0.000 abstract description 4
- 239000000075 oxide glass Substances 0.000 abstract description 4
- 238000000746 purification Methods 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 31
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- 239000003570 air Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 230000000505 pernicious effect Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 229910006404 SnO 2 Inorganic materials 0.000 description 3
- 241000700605 Viruses Species 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 206010019851 Hepatotoxicity Diseases 0.000 description 1
- 206010029350 Neurotoxicity Diseases 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 206010044221 Toxic encephalopathy Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000035568 catharsis Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 231100000304 hepatotoxicity Toxicity 0.000 description 1
- 230000007686 hepatotoxicity Effects 0.000 description 1
- -1 hydroxyl radical free radical Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 231100000417 nephrotoxicity Toxicity 0.000 description 1
- 231100000228 neurotoxicity Toxicity 0.000 description 1
- 230000007135 neurotoxicity Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- Catalysts (AREA)
Abstract
The invention relates to multifunctional glass and a production method thereof, and relates to the technical field of machining of functional glass. A transparent conductive oxide film is manufactured on at least one side of a transparent glass substrate first, thereby obtaining transparent conductive oxide glass; then after the transparent conductive oxide glass is cut, edged, cleaned and dried, a bus electrode is manufactured on the transparent conductive oxide film; and finally a photocatalyst layer is manufactured on the transparent conductive oxide film or the transparent glass substrate. The production method of the multifunctional glass is simple in production technology, efficient industrial production is easy to realize, production cost is reduced, and a functional product with single-side and double-side heating and single-side and double-side purification functions can be formed.
Description
Technical field
The present invention relates to the processing technique field of functional glass.
Background technology
Under light illumination, valence-band electrons is excited to conduction band to nano photo-catalytic, defines electronics and hole, with the O being adsorbed in its surface
2and H
2o effect, generates superoxide anion radical, O
2 -with hydroxyl radical free radical OH
-, its free radical has very strong oxidative decomposition capacity, can destroy the C-C key in organic substance, c h bond, C-N key, C-O key, O-H key, N-H key, and decomposing organic matter is carbon dioxide and water; Destroy simultaneously bacterium cell membrane solidification virus protein, change bacterium, virus living environment thus kill bacterium, virus.
Along with the develop rapidly of social and economic construction and the raising of human living standard, indoor environmental pollution has become the focus of social concerns, and people more and more pay attention to indoor air quality.Pollute the chemical substance substantial amounts of room air, the secondary pollution that the VOC wherein with neurotoxicity, renal toxicity, hepatotoxicity wind agitation and carcinogenicity causes causes great threat to human health.World Health Organization's statistics shows, the whole world is every year because the death toll of indoor environmental pollution reaches 2,800,000; Country's room air detects department's ASSOCIATE STATISTICS display, Newly decorated rooms more than 90% pernicious gas severe overweight, serious threat human health.
The materials such as activated carbon, bamboo carbon, diatomite are often used as the absorption of air pernicious gas, but due to its limited sorption capacity, and little effect can only be played.Photocatalyst technology is considered to the one preferred technique of administering indoor environmental pollution.
Transparent conductive oxide film is generally polycrystalline film, mainly comprise oxide and the composite multi-component oxide film material thereof of In, Sb, Zn and Cd, it has the characteristics such as forbidden band is wide, resistivity is low, is widely used in the fields such as flat panel display device, solar cell, reflection heat mirror, gas sensitization device, resistive heating element.
Summary of the invention
The present invention seeks to propose one and can be used for heating, and there is the multifunctional glass of photocatalysis.
The present invention arranges transparent conductive film and photocatalyst layer in transparent glass substrate, and transparent conductive film also arranges bus electrode layer.
The binding post of power supply with bus electrode layer is connected, transparent conductive film just can be made to obtain electric and generate heat; When photocatalyst layer receives illumination, matchmaker wherein can play the catharsis to ambient air.Therefore, product of the present invention instead of current universal air cleaning equipment or material completely, when needs are to when heating up in space, connects electricity and product can be made to generate heat, reach the effect of heat supply.
In addition, local decorative pattern can also be made on product of the present invention, to improve aesthetic property or the ID product of product.
Not only this multifunctional glass is integrated with heating service, photocatalyst and decoration three functions, may be used in indoor environment, can realize heating service function but also pernicious gas and sterilization in room air of can degrading.
The product above technique made carries out arranged in parallel with the spacing of 0.2 ~ 2mm, and forms functional glass module by various forms is fixing, in air purifier, air-conditioning and antistaling cabinet, plays the function of heating and degraded pernicious gas and sterilization.
In order to improve the utilance of transparent glass substrate, the present invention described transparent glass substrate both sides transparent conductive film is set respectively, just can form the product of Double-side heating.
In addition, photocatalyst layer can be arranged on transparent conductive film.
Also described photocatalyst layer can be set directly in transparent glass substrate.
The present invention also proposes the method for producing above product.
The present invention includes following steps:
1) make transparent conductive oxide film at least one side of transparent glass substrate, obtain transparent conductive oxide;
2) by transparent conductive oxide cutting, edging, cleaning and dry after, transparent conductive oxide film makes bus electrode;
3) on transparent conductive oxide film or transparent glass substrate make photocatalyst layer.
Production technology of the present invention is simple, easily realizes efficient suitability for industrialized production, reduces production cost, can form single, double surface heating, the functional product of single, double surface purification.
The material of described transparent conductive oxide film can take from the indium oxide In of tin supported
2o:Sn (ITO), or the tin oxide Sn of load fluorine
2or the tin oxide SnO of load fluorine and antimony O:F(FTO),
2: F-Sb(FATO), or the zinc oxide ZnO:Al(ZAO of load aluminium).
In order to improve product heating power, product is needed to have higher resistance value, so the preferred transparent conductive oxide film of the present invention is the tin oxide Sn of load fluorine
2or the tin oxide SnO of load fluorine and antimony O:F(FTO),
2: F-Sb(FATO).
The present invention can adopt silk-screen printing technique to make bus electrode.
Described bus electrode be conductive silver electrode, conductive copper electrode, conductive copper silver electrode or conduction carbon resistance rod in any one.
In order to obtain firmly photocatalyst layer on transparent conductive oxide film or transparent glass substrate, photocatalyst dispersion liquid is coated in transparent conductive oxide film or transparent glass substrate by the present invention, solidifies 10 ~ 60 minutes at the temperature of 20 ~ 250 DEG C.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of the present invention.
Fig. 2 is another kind of structural representation of the present invention.
Fig. 3 is the third structural representation of the present invention.
Embodiment
Embodiment 1:
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, makes the tin oxide (SnO of load fluorine and antimony in the one side of transparent glass substrate
2: F-Sb) transparent conductive oxide film, obtain one side transparent conductive oxide (FATO).
Step 2: one side transparent conductive oxide (FATO) is cut into 5cm × 30cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, is printed onto the transparent conductive oxide film surface of electro-conductive glass, makes and obtain bus electrode, and make two bus electrode binding posts by conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry.
Step 4: adopt spraying or roller coating technology to be coated on the transparent conductive oxide film of electro-conductive glass by optical catalyst sol, then solidify 30 minutes under the temperature environment of 60 DEG C.
The product made by above technique is as shown in Figure 1: the same side of transparent glass substrate 1 is provided with transparent conductive film 2, transparent conductive film 2 arranges photocatalyst layer 3.Transparent conductive film 2 also arranges bus electrode layer 4, two binding posts are also set at bus electrode layer 2.
Embodiment 2:
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, makes the tin oxide (SnO of load fluorine and antimony in the one side of transparent glass substrate
2: F-Sb) transparent conductive oxide film, obtain one side transparent conductive oxide (FATO).
Step 2: one side transparent conductive oxide (FATO) is cut into 5cm × 30cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, is printed onto the transparent conductive oxide film surface of electro-conductive glass, makes and obtain bus electrode, and make two bus electrode binding posts by conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry.
Step 4: after electro-conductive glass being placed in optical catalyst sol dipping, solidify 10 minutes under the temperature environment of 250 DEG C.
The product made by above technique is as shown in Figure 2: the side of transparent glass substrate 1 is provided with transparent conductive film 2, on transparent conductive film 2 and the opposite side of transparent glass substrate 1 photocatalyst layer 3 is respectively set.Transparent conductive film 2 also arranges bus electrode layer 4, two binding posts are also set at bus electrode layer 2.
Embodiment 3
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, at the tin oxide (Sn of the two-sided making load fluorine of transparent glass substrate
2o:F) transparent conductive oxide film, obtains two-side transparent conductive oxide glass (FTO).
Step 2: two-side transparent conductive oxide glass (FTO) is cut into 5cm × 60cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry are printed onto two transparent conductive oxide film surfaces of electro-conductive glass, make respectively and obtain bus electrode, and make two bus electrode binding posts of each.
Step 4: after electro-conductive glass being placed in optical catalyst sol dipping, solidify 60 minutes under the temperature environment of 20 DEG C.
Step 5: adopt silk-screen printing technique, at the one side printed decoration pattern of semi-products.
The product made by above technique is as shown in Figure 3: be respectively arranged with transparent conductive film 2 in the both sides of transparent glass substrate 1, two transparent conductive films 2 arrange photocatalyst layer 3 respectively.Two transparent conductive films 2 also arrange bus electrode layer 4 respectively, two binding posts are also set at each bus electrode layer 2.
Claims (10)
1. a multifunctional glass, comprises transparent glass substrate, it is characterized in that in transparent glass substrate, arrange transparent conductive film and photocatalyst layer, and transparent conductive film also arranges bus electrode layer.
2. multifunctional glass according to claim 1, it is characterized in that described transparent glass substrate both sides transparent conductive film is set respectively.
3. multifunctional glass according to claim 1 or 2, is characterized in that being arranged on transparent conductive film at described photocatalyst layer.
4. multifunctional glass according to claim 1, is characterized in that described photocatalyst layer is arranged in transparent glass substrate.
5. the production method of multifunctional glass as claimed in claim 1, is characterized in that comprising the following steps:
1) make transparent conductive oxide film at least one side of transparent glass substrate, obtain transparent conductive oxide;
2) by transparent conductive oxide cutting, edging, cleaning and dry after, transparent conductive oxide film makes bus electrode;
3) on transparent conductive oxide film or transparent glass substrate make photocatalyst layer.
6. the production method of multifunctional glass according to claim 5, is characterized in that described transparent conductive oxide film is the indium oxide of tin supported, or the tin oxide of load fluorine, or the tin oxide of load fluorine and antimony, or the zinc oxide of load aluminium.
7. the production method of multifunctional glass according to claim 6, is characterized in that described transparent conductive oxide film is the tin oxide of load fluorine, or the tin oxide of load fluorine and antimony.
8. the production method of multifunctional glass according to claim 5, is characterized in that making bus electrode with silk-screen printing technique.
9. the production method of multifunctional glass according to claim 5 or 8, is characterized in that described bus electrode is any one in conductive silver electrode, conductive copper electrode, conductive copper silver electrode or conduction carbon resistance rod.
10. the production method of multifunctional glass according to claim 5, is characterized in that described step 3) coats in transparent conductive oxide film or transparent glass substrate by photocatalyst dispersion liquid, solidifies 10 ~ 60 minutes at the temperature of 20 ~ 250 DEG C.
Priority Applications (1)
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CN201510182478.5A CN104822188A (en) | 2015-04-17 | 2015-04-17 | Multifunctional glass and production method thereof |
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CN201510182478.5A CN104822188A (en) | 2015-04-17 | 2015-04-17 | Multifunctional glass and production method thereof |
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Publication Number | Publication Date |
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CN104822188A true CN104822188A (en) | 2015-08-05 |
Family
ID=53732320
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109375400A (en) * | 2018-10-12 | 2019-02-22 | 中航华东光电有限公司 | Novel optical heater and preparation method thereof |
Citations (5)
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CN1562842A (en) * | 2004-03-25 | 2005-01-12 | 卢秀强 | Structured multilayered films coated glass and production method |
CN101036418A (en) * | 2004-09-17 | 2007-09-12 | 法国圣-戈班玻璃公司 | Electric heating structure |
CN102471147A (en) * | 2009-08-14 | 2012-05-23 | 旭硝子株式会社 | Substrate with transparent conductive film and substrate for plasma display panel |
CN104148072A (en) * | 2014-07-17 | 2014-11-19 | 苏州大学 | Photocatalytic water splitting catalyzing structure and preparation method thereof |
CN204498401U (en) * | 2015-04-17 | 2015-07-22 | 扬州明晟新能源科技有限公司 | A kind of multifunctional glass |
-
2015
- 2015-04-17 CN CN201510182478.5A patent/CN104822188A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1562842A (en) * | 2004-03-25 | 2005-01-12 | 卢秀强 | Structured multilayered films coated glass and production method |
CN101036418A (en) * | 2004-09-17 | 2007-09-12 | 法国圣-戈班玻璃公司 | Electric heating structure |
CN102471147A (en) * | 2009-08-14 | 2012-05-23 | 旭硝子株式会社 | Substrate with transparent conductive film and substrate for plasma display panel |
CN104148072A (en) * | 2014-07-17 | 2014-11-19 | 苏州大学 | Photocatalytic water splitting catalyzing structure and preparation method thereof |
CN204498401U (en) * | 2015-04-17 | 2015-07-22 | 扬州明晟新能源科技有限公司 | A kind of multifunctional glass |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109375400A (en) * | 2018-10-12 | 2019-02-22 | 中航华东光电有限公司 | Novel optical heater and preparation method thereof |
CN109375400B (en) * | 2018-10-12 | 2021-09-21 | 中航华东光电有限公司 | Novel optical heater and preparation method thereof |
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