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CN104822188A - Multifunctional glass and production method thereof - Google Patents

Multifunctional glass and production method thereof Download PDF

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Publication number
CN104822188A
CN104822188A CN201510182478.5A CN201510182478A CN104822188A CN 104822188 A CN104822188 A CN 104822188A CN 201510182478 A CN201510182478 A CN 201510182478A CN 104822188 A CN104822188 A CN 104822188A
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CN
China
Prior art keywords
transparent conductive
transparent
conductive oxide
glass substrate
production method
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Pending
Application number
CN201510182478.5A
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Chinese (zh)
Inventor
高中明
林和春
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YANGZHOU MINGSHENG NEW ENERGY TECHNOLOGY Co Ltd
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YANGZHOU MINGSHENG NEW ENERGY TECHNOLOGY Co Ltd
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Priority to CN201510182478.5A priority Critical patent/CN104822188A/en
Publication of CN104822188A publication Critical patent/CN104822188A/en
Pending legal-status Critical Current

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Abstract

The invention relates to multifunctional glass and a production method thereof, and relates to the technical field of machining of functional glass. A transparent conductive oxide film is manufactured on at least one side of a transparent glass substrate first, thereby obtaining transparent conductive oxide glass; then after the transparent conductive oxide glass is cut, edged, cleaned and dried, a bus electrode is manufactured on the transparent conductive oxide film; and finally a photocatalyst layer is manufactured on the transparent conductive oxide film or the transparent glass substrate. The production method of the multifunctional glass is simple in production technology, efficient industrial production is easy to realize, production cost is reduced, and a functional product with single-side and double-side heating and single-side and double-side purification functions can be formed.

Description

A kind of multifunctional glass and production method thereof
Technical field
The present invention relates to the processing technique field of functional glass.
Background technology
Under light illumination, valence-band electrons is excited to conduction band to nano photo-catalytic, defines electronics and hole, with the O being adsorbed in its surface 2and H 2o effect, generates superoxide anion radical, O 2 -with hydroxyl radical free radical OH -, its free radical has very strong oxidative decomposition capacity, can destroy the C-C key in organic substance, c h bond, C-N key, C-O key, O-H key, N-H key, and decomposing organic matter is carbon dioxide and water; Destroy simultaneously bacterium cell membrane solidification virus protein, change bacterium, virus living environment thus kill bacterium, virus.
Along with the develop rapidly of social and economic construction and the raising of human living standard, indoor environmental pollution has become the focus of social concerns, and people more and more pay attention to indoor air quality.Pollute the chemical substance substantial amounts of room air, the secondary pollution that the VOC wherein with neurotoxicity, renal toxicity, hepatotoxicity wind agitation and carcinogenicity causes causes great threat to human health.World Health Organization's statistics shows, the whole world is every year because the death toll of indoor environmental pollution reaches 2,800,000; Country's room air detects department's ASSOCIATE STATISTICS display, Newly decorated rooms more than 90% pernicious gas severe overweight, serious threat human health.
The materials such as activated carbon, bamboo carbon, diatomite are often used as the absorption of air pernicious gas, but due to its limited sorption capacity, and little effect can only be played.Photocatalyst technology is considered to the one preferred technique of administering indoor environmental pollution.
Transparent conductive oxide film is generally polycrystalline film, mainly comprise oxide and the composite multi-component oxide film material thereof of In, Sb, Zn and Cd, it has the characteristics such as forbidden band is wide, resistivity is low, is widely used in the fields such as flat panel display device, solar cell, reflection heat mirror, gas sensitization device, resistive heating element.
Summary of the invention
The present invention seeks to propose one and can be used for heating, and there is the multifunctional glass of photocatalysis.
The present invention arranges transparent conductive film and photocatalyst layer in transparent glass substrate, and transparent conductive film also arranges bus electrode layer.
The binding post of power supply with bus electrode layer is connected, transparent conductive film just can be made to obtain electric and generate heat; When photocatalyst layer receives illumination, matchmaker wherein can play the catharsis to ambient air.Therefore, product of the present invention instead of current universal air cleaning equipment or material completely, when needs are to when heating up in space, connects electricity and product can be made to generate heat, reach the effect of heat supply.
In addition, local decorative pattern can also be made on product of the present invention, to improve aesthetic property or the ID product of product.
Not only this multifunctional glass is integrated with heating service, photocatalyst and decoration three functions, may be used in indoor environment, can realize heating service function but also pernicious gas and sterilization in room air of can degrading.
The product above technique made carries out arranged in parallel with the spacing of 0.2 ~ 2mm, and forms functional glass module by various forms is fixing, in air purifier, air-conditioning and antistaling cabinet, plays the function of heating and degraded pernicious gas and sterilization.
In order to improve the utilance of transparent glass substrate, the present invention described transparent glass substrate both sides transparent conductive film is set respectively, just can form the product of Double-side heating.
In addition, photocatalyst layer can be arranged on transparent conductive film.
Also described photocatalyst layer can be set directly in transparent glass substrate.
The present invention also proposes the method for producing above product.
The present invention includes following steps:
1) make transparent conductive oxide film at least one side of transparent glass substrate, obtain transparent conductive oxide;
2) by transparent conductive oxide cutting, edging, cleaning and dry after, transparent conductive oxide film makes bus electrode;
3) on transparent conductive oxide film or transparent glass substrate make photocatalyst layer.
Production technology of the present invention is simple, easily realizes efficient suitability for industrialized production, reduces production cost, can form single, double surface heating, the functional product of single, double surface purification.
The material of described transparent conductive oxide film can take from the indium oxide In of tin supported 2o:Sn (ITO), or the tin oxide Sn of load fluorine 2or the tin oxide SnO of load fluorine and antimony O:F(FTO), 2: F-Sb(FATO), or the zinc oxide ZnO:Al(ZAO of load aluminium).
In order to improve product heating power, product is needed to have higher resistance value, so the preferred transparent conductive oxide film of the present invention is the tin oxide Sn of load fluorine 2or the tin oxide SnO of load fluorine and antimony O:F(FTO), 2: F-Sb(FATO).
The present invention can adopt silk-screen printing technique to make bus electrode.
Described bus electrode be conductive silver electrode, conductive copper electrode, conductive copper silver electrode or conduction carbon resistance rod in any one.
In order to obtain firmly photocatalyst layer on transparent conductive oxide film or transparent glass substrate, photocatalyst dispersion liquid is coated in transparent conductive oxide film or transparent glass substrate by the present invention, solidifies 10 ~ 60 minutes at the temperature of 20 ~ 250 DEG C.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of the present invention.
Fig. 2 is another kind of structural representation of the present invention.
Fig. 3 is the third structural representation of the present invention.
Embodiment
Embodiment 1:
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, makes the tin oxide (SnO of load fluorine and antimony in the one side of transparent glass substrate 2: F-Sb) transparent conductive oxide film, obtain one side transparent conductive oxide (FATO).
Step 2: one side transparent conductive oxide (FATO) is cut into 5cm × 30cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, is printed onto the transparent conductive oxide film surface of electro-conductive glass, makes and obtain bus electrode, and make two bus electrode binding posts by conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry.
Step 4: adopt spraying or roller coating technology to be coated on the transparent conductive oxide film of electro-conductive glass by optical catalyst sol, then solidify 30 minutes under the temperature environment of 60 DEG C.
The product made by above technique is as shown in Figure 1: the same side of transparent glass substrate 1 is provided with transparent conductive film 2, transparent conductive film 2 arranges photocatalyst layer 3.Transparent conductive film 2 also arranges bus electrode layer 4, two binding posts are also set at bus electrode layer 2.
Embodiment 2:
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, makes the tin oxide (SnO of load fluorine and antimony in the one side of transparent glass substrate 2: F-Sb) transparent conductive oxide film, obtain one side transparent conductive oxide (FATO).
Step 2: one side transparent conductive oxide (FATO) is cut into 5cm × 30cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, is printed onto the transparent conductive oxide film surface of electro-conductive glass, makes and obtain bus electrode, and make two bus electrode binding posts by conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry.
Step 4: after electro-conductive glass being placed in optical catalyst sol dipping, solidify 10 minutes under the temperature environment of 250 DEG C.
The product made by above technique is as shown in Figure 2: the side of transparent glass substrate 1 is provided with transparent conductive film 2, on transparent conductive film 2 and the opposite side of transparent glass substrate 1 photocatalyst layer 3 is respectively set.Transparent conductive film 2 also arranges bus electrode layer 4, two binding posts are also set at bus electrode layer 2.
Embodiment 3
Step 1: according to the preparation method of the SnO 2 thin film of the CN201410105524.7 of 2014.7.23 bulletin, at the tin oxide (Sn of the two-sided making load fluorine of transparent glass substrate 2o:F) transparent conductive oxide film, obtains two-side transparent conductive oxide glass (FTO).
Step 2: two-side transparent conductive oxide glass (FTO) is cut into 5cm × 60cm specification, also dry through edging, cleaning, obtain the electro-conductive glass of clean surface.
Step 3: adopt silk-screen printing technique, conductive silver paste, conductive copper paste, conductive copper silver slurry or conduction charcoal slurry are printed onto two transparent conductive oxide film surfaces of electro-conductive glass, make respectively and obtain bus electrode, and make two bus electrode binding posts of each.
Step 4: after electro-conductive glass being placed in optical catalyst sol dipping, solidify 60 minutes under the temperature environment of 20 DEG C.
Step 5: adopt silk-screen printing technique, at the one side printed decoration pattern of semi-products.
The product made by above technique is as shown in Figure 3: be respectively arranged with transparent conductive film 2 in the both sides of transparent glass substrate 1, two transparent conductive films 2 arrange photocatalyst layer 3 respectively.Two transparent conductive films 2 also arrange bus electrode layer 4 respectively, two binding posts are also set at each bus electrode layer 2.

Claims (10)

1. a multifunctional glass, comprises transparent glass substrate, it is characterized in that in transparent glass substrate, arrange transparent conductive film and photocatalyst layer, and transparent conductive film also arranges bus electrode layer.
2. multifunctional glass according to claim 1, it is characterized in that described transparent glass substrate both sides transparent conductive film is set respectively.
3. multifunctional glass according to claim 1 or 2, is characterized in that being arranged on transparent conductive film at described photocatalyst layer.
4. multifunctional glass according to claim 1, is characterized in that described photocatalyst layer is arranged in transparent glass substrate.
5. the production method of multifunctional glass as claimed in claim 1, is characterized in that comprising the following steps:
1) make transparent conductive oxide film at least one side of transparent glass substrate, obtain transparent conductive oxide;
2) by transparent conductive oxide cutting, edging, cleaning and dry after, transparent conductive oxide film makes bus electrode;
3) on transparent conductive oxide film or transparent glass substrate make photocatalyst layer.
6. the production method of multifunctional glass according to claim 5, is characterized in that described transparent conductive oxide film is the indium oxide of tin supported, or the tin oxide of load fluorine, or the tin oxide of load fluorine and antimony, or the zinc oxide of load aluminium.
7. the production method of multifunctional glass according to claim 6, is characterized in that described transparent conductive oxide film is the tin oxide of load fluorine, or the tin oxide of load fluorine and antimony.
8. the production method of multifunctional glass according to claim 5, is characterized in that making bus electrode with silk-screen printing technique.
9. the production method of multifunctional glass according to claim 5 or 8, is characterized in that described bus electrode is any one in conductive silver electrode, conductive copper electrode, conductive copper silver electrode or conduction carbon resistance rod.
10. the production method of multifunctional glass according to claim 5, is characterized in that described step 3) coats in transparent conductive oxide film or transparent glass substrate by photocatalyst dispersion liquid, solidifies 10 ~ 60 minutes at the temperature of 20 ~ 250 DEG C.
CN201510182478.5A 2015-04-17 2015-04-17 Multifunctional glass and production method thereof Pending CN104822188A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510182478.5A CN104822188A (en) 2015-04-17 2015-04-17 Multifunctional glass and production method thereof

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Application Number Priority Date Filing Date Title
CN201510182478.5A CN104822188A (en) 2015-04-17 2015-04-17 Multifunctional glass and production method thereof

Publications (1)

Publication Number Publication Date
CN104822188A true CN104822188A (en) 2015-08-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109375400A (en) * 2018-10-12 2019-02-22 中航华东光电有限公司 Novel optical heater and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1562842A (en) * 2004-03-25 2005-01-12 卢秀强 Structured multilayered films coated glass and production method
CN101036418A (en) * 2004-09-17 2007-09-12 法国圣-戈班玻璃公司 Electric heating structure
CN102471147A (en) * 2009-08-14 2012-05-23 旭硝子株式会社 Substrate with transparent conductive film and substrate for plasma display panel
CN104148072A (en) * 2014-07-17 2014-11-19 苏州大学 Photocatalytic water splitting catalyzing structure and preparation method thereof
CN204498401U (en) * 2015-04-17 2015-07-22 扬州明晟新能源科技有限公司 A kind of multifunctional glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1562842A (en) * 2004-03-25 2005-01-12 卢秀强 Structured multilayered films coated glass and production method
CN101036418A (en) * 2004-09-17 2007-09-12 法国圣-戈班玻璃公司 Electric heating structure
CN102471147A (en) * 2009-08-14 2012-05-23 旭硝子株式会社 Substrate with transparent conductive film and substrate for plasma display panel
CN104148072A (en) * 2014-07-17 2014-11-19 苏州大学 Photocatalytic water splitting catalyzing structure and preparation method thereof
CN204498401U (en) * 2015-04-17 2015-07-22 扬州明晟新能源科技有限公司 A kind of multifunctional glass

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109375400A (en) * 2018-10-12 2019-02-22 中航华东光电有限公司 Novel optical heater and preparation method thereof
CN109375400B (en) * 2018-10-12 2021-09-21 中航华东光电有限公司 Novel optical heater and preparation method thereof

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