CN104791056B - A Method for Reducing Cold Start Emissions Using Vacuum-Phase Change Insulation - Google Patents
A Method for Reducing Cold Start Emissions Using Vacuum-Phase Change Insulation Download PDFInfo
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Abstract
本发明涉及一种利用真空‑相变保温降低冷启动排放的催化装置。该装置安装在发动机的排气管上,用装有相变材料的封闭腔包裹催化剂载体,使其处在空腔中。发动机停车后,气门开关驱动装置接受电控单元发出的信号,关闭催化器两侧的气门,气泵系统使催化器处在真空环境中,以减少催化器能量的散失,同时相变材料在凝固过程中释放潜热,保证了发动机再次启动时催化器足够高的温度,缩短了催化剂达到起燃温度的时间,大大降低了车辆冷启动排放。采用该装置停车24小时后催化器温度仍保持在250℃。发动机在高负荷工作时,通过向空腔内充入空气,增加其传热系数向往散热,同时相变材料在熔融过程中吸收热量,保证了过高的废气温度不至于使催化剂高温失活。
The invention relates to a catalytic device which utilizes vacuum-phase change heat preservation to reduce cold start emission. The device is installed on the exhaust pipe of the engine, and the catalyst carrier is wrapped with a closed cavity filled with phase-change materials so that it is in the cavity. After the engine stops, the valve switch driving device receives the signal from the electronic control unit and closes the valves on both sides of the catalytic converter. The air pump system keeps the catalytic converter in a vacuum environment to reduce the energy loss of the catalytic converter. At the same time, the phase change material is solidified during the solidification process The release of latent heat in the middle ensures that the temperature of the catalyst is high enough when the engine is restarted, shortens the time for the catalyst to reach the light-off temperature, and greatly reduces vehicle cold start emissions. After using this device to stop for 24 hours, the temperature of the catalytic converter is still maintained at 250°C. When the engine is working at a high load, the cavity is filled with air to increase its heat transfer coefficient to dissipate heat. At the same time, the phase change material absorbs heat during the melting process to ensure that the excessively high exhaust gas temperature will not deactivate the catalyst at high temperature.
Description
技术领域technical field
本发明提供一种利用真空-相变保温降低冷启动排放的催化装置,具体涉及一种新型催化装置的设计及控制方法,属于内燃机领域。The invention provides a catalytic device which utilizes vacuum-phase change heat preservation to reduce cold start emission, and specifically relates to a design and control method of a novel catalytic device, which belongs to the field of internal combustion engines.
背景技术Background technique
随着汽车数量的急剧增加,汽车排放加剧了大气的污染和环境的恶化,汽车排放物成为城市空气污染的主要源头,降低发动机污染气体排放已经成为内燃机继续发展亟待解决的重要问题之一。最新国家标准,全国将于2018年1月1日起实施第五阶段国家机动车排放标准,北京市将于2016年1月1日起提前实施第五阶段国家机动车排放标准。国五标准,相当于欧盟的欧五标准,欧盟已经从2009年起开始执行,其对氮氧化物、碳氢化合物、一氧化碳和悬浮粒子等机动车排放物的限制更为严苛。从国Ⅰ提至国Ⅳ,每提高一次标准,单车污染减少30%至50%。在排放循环测试中,根据美国环境保护署的FTP-75测试得知,配备三效催化转化器的汽油机近80%的HC、CO排放是在冷起动最初的200s内产生的,原因是由于冷启动阶段发动机排气温度较低,氧传感器和三元催化器不能正常工作。因此,如能采取措施控制启动时的HC排放,车用汽油机就能满足更高的排放法规要求。With the rapid increase in the number of automobiles, automobile emissions have aggravated the pollution of the atmosphere and the deterioration of the environment. Automobile emissions have become the main source of urban air pollution. Reducing engine pollutant gas emissions has become one of the important issues to be solved for the continued development of internal combustion engines. The latest national standards, the country will implement the fifth phase of national motor vehicle emission standards on January 1, 2018, and Beijing will implement the fifth phase of national motor vehicle emission standards ahead of schedule on January 1, 2016. The National V standard is equivalent to the Euro V standard of the European Union. The European Union has implemented it since 2009, and its restrictions on motor vehicle emissions such as nitrogen oxides, hydrocarbons, carbon monoxide and suspended particles are more stringent. From National I to National IV, every time the standard is raised, the pollution from single vehicles will be reduced by 30% to 50%. In the emission cycle test, according to the FTP-75 test of the U.S. Environmental Protection Agency, nearly 80% of the HC and CO emissions of a gasoline engine equipped with a three-way catalytic converter are generated within the first 200s of a cold start. During the start-up phase, the exhaust gas temperature of the engine is low, and the oxygen sensor and three-way catalytic converter cannot work normally. Therefore, if measures can be taken to control the HC emission at start-up, the gasoline engine for vehicles can meet higher emission regulations.
目前汽油车冷启动排放控制主流技术是通过使三元催化器快速达到起燃温度来降低HC和CO的排放,在使催化器快速起燃研究方面的主要办法是降低催化器的起燃温度和尽快提高催化器温度。而前者由于催化剂技术的限制,效果是有限的,而且还需要加大贵金属的含量,会造成系统成本的增加。故而催化器快速起燃的研究较多的集中在了尽快提高催化器入口温度方面,如近装催化器、催化器燃油加热,催化器电加热等技术。近装催化器无法转化冷启动后第一个60s内的HC;催化器燃油加热,需要一个燃烧室,会产生额外的排放;催化器电加热技术,相对燃油加热催化器结构简单,但要使催化剂温度在短时间内达到起燃温度需要消耗蓄电池大量的电能。At present, the mainstream technology for cold start emission control of gasoline vehicles is to reduce the emission of HC and CO by making the three-way catalytic converter reach the light-off temperature quickly. Increase catalyst temperature as soon as possible. However, due to the limitation of catalyst technology, the effect of the former is limited, and the content of precious metals needs to be increased, which will increase the cost of the system. Therefore, most of the research on rapid light-off of catalytic converters focuses on increasing the inlet temperature of catalytic converters as soon as possible, such as close-mounted catalytic converters, fuel heating of catalytic converters, and electric heating of catalytic converters. Close-mounted catalytic converters cannot convert HC in the first 60s after cold start; catalytic converter fuel heating requires a combustion chamber, which will generate additional emissions; catalytic converter electric heating technology is simpler in structure than fuel heating catalytic converters, but it needs to be used Catalyst temperature to reach the light-off temperature in a short time needs to consume a lot of battery power.
发明内容Contents of the invention
本发明的目的是为了客服现有的发动机冷启动时排放控制装置的上述缺陷,利用发动机的余热,提供了一种利用真空-相变保温降低冷启动排放的催化装置及控制方法,利用该装置可有效降低发动机冷启动时废气排放量。The purpose of the present invention is to overcome the above-mentioned defects of the existing engine cold start emission control device, and use the waste heat of the engine to provide a catalytic device and a control method that utilizes vacuum-phase change heat preservation to reduce cold start emissions. It can effectively reduce the exhaust gas emission when the engine is cold started.
本发明采用如下技术方案:The present invention adopts following technical scheme:
一种利用真空-相变保温降低冷启动排放的催化装置,其特征在于:包括电控单元5、气泵系统4、气门开关驱动系统3、催化剂载体7、空腔8、相变材料9,相变材料9紧挨着催化剂载体7外侧设置,并且和催化剂载体7都封装在密闭腔内,其外侧是空腔8,空腔8内安装压力传感器15.前段排气管1和后段排气管10靠近空腔8处装有气门开关驱动系统3,其中前段排气管1还安装有温度传感器2。A catalytic device using vacuum-phase change heat preservation to reduce cold start emissions, characterized in that it includes an electronic control unit 5, an air pump system 4, a valve switch drive system 3, a catalyst carrier 7, a cavity 8, a phase change material 9, and a phase change material 9. The variable material 9 is arranged next to the outside of the catalyst carrier 7, and is packaged with the catalyst carrier 7 in a closed cavity, the outside of which is a cavity 8, and a pressure sensor 15 is installed in the cavity 8. The front exhaust pipe 1 and the rear exhaust The pipe 10 is equipped with a valve switch drive system 3 near the cavity 8 , and the front exhaust pipe 1 is also equipped with a temperature sensor 2 .
应用所述的装置的方法,其特征在于步骤如下:The method for applying the device is characterized in that the steps are as follows:
1)该装置根据发动机的启动信号11和停车信号12控制气门6的开启和关闭;发动机处于运行状态下,气门6保持开启;发动机启动时,电控单元5将发动机的启动信号11传递给气门开关驱动系统3,气门开关驱动系统3开启气门6.温度传感器2检测流经前段排气管1内的废气温度并传递给电控单元5;1) The device controls the opening and closing of the valve 6 according to the start signal 11 and the stop signal 12 of the engine; when the engine is running, the valve 6 remains open; when the engine starts, the electronic control unit 5 transmits the start signal 11 of the engine to the valve The switch drive system 3, the valve switch drive system 3 opens the valve 6. The temperature sensor 2 detects the temperature of the exhaust gas flowing through the front exhaust pipe 1 and transmits it to the electronic control unit 5;
发动机处于停车状态下,气门6保持闭合,空腔8为真空腔,空腔8内的真空减少装置内热量的散失;When the engine is in a stopped state, the valve 6 remains closed, the cavity 8 is a vacuum cavity, and the vacuum in the cavity 8 reduces heat loss in the device;
2)当电控单元5接受的温度信号大于800℃时,电控单元5向气泵系统4发出充气信号13,气泵系统4接受到充气信号13后向空腔内充入空气,直到腔内压力与外界压力平衡;随着充入空气量越大,腔内的传热系数越大,有利于废气热量的散失,防止催化剂高温失活;当电控单元5接受的温度信号小于800℃时,电控单元5向气泵系统4发出抽气信号14,气泵系统4接受到抽气信号14后从空腔内向外抽空气;随着空气减少,传热系数减小,热量散失减少;2) When the temperature signal received by the electronic control unit 5 is greater than 800°C, the electronic control unit 5 sends an inflation signal 13 to the air pump system 4, and the air pump system 4 fills the cavity with air after receiving the inflation signal 13 until the pressure in the cavity Balanced with the external pressure; as the amount of air charged increases, the heat transfer coefficient in the cavity increases, which is conducive to the heat loss of the exhaust gas and prevents the catalyst from being deactivated at high temperature; when the temperature signal received by the electronic control unit 5 is less than 800°C, The electronic control unit 5 sends an air pumping signal 14 to the air pump system 4, and the air pump system 4 pumps air from the cavity to the outside after receiving the air pumping signal 14; as the air decreases, the heat transfer coefficient decreases and the heat loss decreases;
发动机停车时,电控单元5将发动机的停车信号12传递给气门开关驱动系统3,气门开关驱动系统3关闭气门6,此时通过压力传感器15判断空腔8是否为真空,如果空腔8不是真空,电控单元5向气泵系统4发出抽气信号14,气泵系统接受到抽气信号14后从空腔内向外抽空气,保证停车状态下空腔8为真空腔。When the engine is stopped, the electronic control unit 5 transmits the stop signal 12 of the engine to the valve switch drive system 3, and the valve switch drive system 3 closes the valve 6. At this time, the pressure sensor 15 is used to judge whether the cavity 8 is a vacuum. If the cavity 8 is not Vacuum, the electronic control unit 5 sends an air pumping signal 14 to the air pump system 4, and the air pump system pumps air from the cavity to the outside after receiving the pumping signal 14, ensuring that the cavity 8 is a vacuum chamber in the parking state.
本装置中提到的相变材料为硅铝合金材料,相变材料在发生相变过程中吸收或释放大量的潜热。The phase change material mentioned in this device is a silicon aluminum alloy material, and the phase change material absorbs or releases a large amount of latent heat during the phase change process.
本发明的工作原理:该装置安装在汽车发动机排气管上,用装有相变材料的封闭腔包裹催化剂载体,使其处在气体传热系数可变的空腔内(气体传热系数由真空度调节)。发动机停车后,关闭催化器两侧的气门,使催化器处在真空环境中,以减少催化器能量的散失,同时相变材料在凝固过程中释放潜热,保证了发动机再次启动时催化器足够高的温度。发动机在高负荷工作时,可以通过向空腔内充入空气,增加其传热系数向往散热,同时相变材料在熔融过程中吸收热量,保证了过高的废气温度不至于使催化剂高温失活。Working principle of the present invention: the device is installed on the automobile engine exhaust pipe, wraps the catalyst carrier with a closed chamber equipped with phase change material, so that it is in the cavity with variable gas heat transfer coefficient (gas heat transfer coefficient is determined by vacuum adjustment). After the engine is stopped, close the valves on both sides of the catalytic converter so that the catalytic converter is in a vacuum environment to reduce the energy loss of the catalytic converter. At the same time, the phase change material releases latent heat during the solidification process to ensure that the catalytic converter is sufficiently high when the engine is restarted. temperature. When the engine is working at a high load, it can fill the cavity with air to increase its heat transfer coefficient and yearn for heat dissipation. At the same time, the phase change material absorbs heat during the melting process to ensure that the excessively high exhaust gas temperature will not deactivate the catalyst at high temperature. .
本发明的有益效果是,通过采用电控真空-相变保温装置,提高了发动机冷启动时催化器的温度,缩短了催化剂达到起燃温度的时间,大大降低了车辆冷启动排放。发动机台架试验表明,采用该装置停车24小时后催化器温度仍保持在250℃,从而降低发动机冷启动HC排放80%以上,CO排放40%以上,NOx排放40%以上,使普通车辆不进行大的结构改动达到欧4以上排放标准。The beneficial effect of the invention is that, by adopting the electronically controlled vacuum-phase change heat preservation device, the temperature of the catalytic converter during the cold start of the engine is increased, the time for the catalyst to reach the light-off temperature is shortened, and the vehicle cold start emission is greatly reduced. The engine bench test shows that the temperature of the catalytic converter remains at 250°C after 24 hours of parking with this device, thereby reducing engine cold start HC emissions by more than 80%, CO emissions by more than 40%, and NOx emissions by more than 40%, so that ordinary vehicles do not Major structural changes meet Euro 4 or higher emission standards.
附图说明Description of drawings
图1本发明的结构和工作原理图Fig. 1 structure and working principle diagram of the present invention
图中:1、前段排气管,2、温度传感器,3、气门开关驱动系统,4、气泵系统,5、电控单元,6、气门,7、催化剂载体,8、空腔,9、相变材料,10、后段排气管,11、发动机启动信号,12、发动机停车信号,13、充气信号,14、抽气信号,15、压力传感器。In the figure: 1. Front exhaust pipe, 2. Temperature sensor, 3. Valve switch drive system, 4. Air pump system, 5. Electronic control unit, 6. Valve, 7. Catalyst carrier, 8. Cavity, 9. Phase Change material, 10, rear section exhaust pipe, 11, engine start signal, 12, engine stop signal, 13, inflation signal, 14, pumping signal, 15, pressure sensor.
具体实施方式detailed description
下面结合附图和具体实施方式对于本发明做进一步的说明:Below in conjunction with accompanying drawing and specific embodiment the present invention will be further described:
本装置主要包括电控单元5、气泵系统4、气门开关驱动系统3、催化剂载体7、空腔8、相变材料9,相变材料9封装在紧挨着催化剂载体7外侧的密闭腔内,其外侧是空腔8,空腔8的真空度由气泵系统4根据电控单元5发出的充气信号13和抽气信号14调节,空腔8安装压力传感器15.前段排气管1和后段排气管10靠近空腔8处装有气门开关驱动系统3,其中前段排气管1还安装有温度传感器2,该驱动装置根据发动机的启动信号11和停车信号12控制气门6的开启和关闭。发动机处于运行状态下,气门6保持开启;发动机处于停车状态下,气门6保持闭合,空腔8为真空腔。The device mainly includes an electronic control unit 5, an air pump system 4, a valve switch drive system 3, a catalyst carrier 7, a cavity 8, and a phase change material 9, and the phase change material 9 is packaged in a closed cavity adjacent to the outside of the catalyst carrier 7. Its outer side is a cavity 8, the vacuum degree of which is adjusted by the air pump system 4 according to the inflation signal 13 and the pumping signal 14 sent by the electronic control unit 5, and the cavity 8 is equipped with a pressure sensor 15. The front section exhaust pipe 1 and the rear section The exhaust pipe 10 is equipped with a valve switch driving system 3 near the cavity 8, wherein the front exhaust pipe 1 is also equipped with a temperature sensor 2, and the driving device controls the opening and closing of the valve 6 according to the engine start signal 11 and stop signal 12 . When the engine is running, the valve 6 remains open; when the engine is stopped, the valve 6 remains closed, and the cavity 8 is a vacuum chamber.
调查数据表明,90%以上的车辆在停车24小时之内会重新启动,保证发动机启动时的温度对于降低车辆启动时的排放至关重要。相变材料采用相变温度较低的硅铝合金材料。Survey data show that more than 90% of vehicles will be restarted within 24 hours of parking, and ensuring the temperature of the engine when starting is crucial to reducing emissions when the vehicle is started. The phase change material adopts silicon-aluminum alloy material with a relatively low phase change temperature.
利用如上所述汽车冷启动排放吸附装置进行废气吸附,是按照以下步骤进行控制的:Using the above-mentioned automobile cold start emission adsorption device for exhaust gas adsorption is controlled according to the following steps:
1)发动机处于停车状态下,气门6处于闭合状态,空腔8内的真空可以减少装置内热量的散失。发动机启动时,电控单元5将发动机的启动信号11传递给气门开关驱动系统3,气门开关驱动系统3开启气门6.温度传感器2检测流经前段排气管1内的废气温度并传递给电控单元5.1) When the engine is in a stopped state and the valve 6 is in a closed state, the vacuum in the cavity 8 can reduce the heat loss in the device. When the engine starts, the electronic control unit 5 transmits the engine start signal 11 to the valve switch drive system 3, and the valve switch drive system 3 opens the valve 6. The temperature sensor 2 detects the temperature of the exhaust gas flowing through the front exhaust pipe 1 and transmits it to the electric valve. Control unit 5.
2)当电控单元5接受的温度信号大于800℃时,电控单元5向气泵系统4发出充气信号13,气泵系统4接受到充气信号13后向空腔内充入空气,直到腔内压力与外界压力平衡。随着充入空气量越大,腔内的传热系数越大,有利于废气热量的散失,防止催化剂高温失活。当电控单元5接受的温度信号小于800℃时,电控单元5向气泵系统4发出抽气信号14,气泵系统4接受到抽气信号14后从空腔内向外抽空气。随着空气减少,传热系数减小,热量散失减少。2) When the temperature signal received by the electronic control unit 5 is greater than 800°C, the electronic control unit 5 sends an inflation signal 13 to the air pump system 4, and the air pump system 4 fills the cavity with air after receiving the inflation signal 13 until the pressure in the cavity Balance with external pressure. As the amount of air charged increases, the heat transfer coefficient in the cavity increases, which is beneficial to the heat loss of the exhaust gas and prevents the catalyst from deactivating at high temperature. When the temperature signal received by the electronic control unit 5 is less than 800°C, the electronic control unit 5 sends an air pumping signal 14 to the air pump system 4, and the air pump system 4 pumps air from the cavity to the outside after receiving the air pumping signal 14. With less air, the heat transfer coefficient decreases and heat loss decreases.
3)发动机停车时,电控单元5将发动机的停车信号12传递给气门开关驱动系统3,气门开关驱动系统3关闭气门6.此时可以通过压力传感器15判断空腔8是否为真空,如果空腔8不是真空,电控单元5向气泵系统4发出抽气信号14,气泵系统接受到抽气信号14后从空腔内向外抽空气,保证停车状态下空腔8为真空腔。3) When the engine is stopped, the electronic control unit 5 transmits the stop signal 12 of the engine to the valve switch drive system 3, and the valve switch drive system 3 closes the valve 6. At this time, the pressure sensor 15 can be used to judge whether the cavity 8 is a vacuum. The cavity 8 is not a vacuum, the electronic control unit 5 sends an air pumping signal 14 to the air pump system 4, and the air pump system pumps air from the cavity to the outside after receiving the pumping signal 14, ensuring that the cavity 8 is a vacuum cavity in the parking state.
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CN1144551A (en) * | 1994-01-27 | 1997-03-05 | 戴维·K·本森 | Heat Treatment of Automobile Exhaust System |
DE3835939C2 (en) * | 1987-10-31 | 1998-01-15 | Volkswagen Ag | Exhaust system |
US6128898A (en) * | 1997-11-19 | 2000-10-10 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purifying apparatus for internal combustion engine |
US6162403A (en) * | 1998-11-02 | 2000-12-19 | General Motors Corporation | Spin formed vacuum bottle catalytic converter |
CN103742235A (en) * | 2013-12-31 | 2014-04-23 | 高志男 | Automatic heating and warming device used for motor vehicle exhaust emission |
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JPH04101010A (en) * | 1990-08-17 | 1992-04-02 | Mazda Motor Corp | Exhaust fine particle eliminating device for diesel engine |
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DE3835939C2 (en) * | 1987-10-31 | 1998-01-15 | Volkswagen Ag | Exhaust system |
CN1144551A (en) * | 1994-01-27 | 1997-03-05 | 戴维·K·本森 | Heat Treatment of Automobile Exhaust System |
US6128898A (en) * | 1997-11-19 | 2000-10-10 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purifying apparatus for internal combustion engine |
US6162403A (en) * | 1998-11-02 | 2000-12-19 | General Motors Corporation | Spin formed vacuum bottle catalytic converter |
CN103742235A (en) * | 2013-12-31 | 2014-04-23 | 高志男 | Automatic heating and warming device used for motor vehicle exhaust emission |
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