CN104787989B - A kind of deep well aeration pond and the method for waste water enhanced nitrogen removal dephosphorization device and waste water enhanced nitrogen removal dephosphorization - Google Patents
A kind of deep well aeration pond and the method for waste water enhanced nitrogen removal dephosphorization device and waste water enhanced nitrogen removal dephosphorization Download PDFInfo
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- 238000005273 aeration Methods 0.000 title claims abstract description 119
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000002351 wastewater Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 16
- 238000007872 degassing Methods 0.000 claims abstract description 88
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 87
- 239000010802 sludge Substances 0.000 claims abstract description 57
- 239000010865 sewage Substances 0.000 claims abstract description 56
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 29
- 239000011574 phosphorus Substances 0.000 claims abstract description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 21
- 230000001546 nitrifying effect Effects 0.000 claims abstract description 19
- 230000014759 maintenance of location Effects 0.000 claims description 20
- 238000004062 sedimentation Methods 0.000 claims description 17
- 238000010992 reflux Methods 0.000 claims description 8
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 7
- 230000009471 action Effects 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 3
- 238000005728 strengthening Methods 0.000 claims 4
- 238000005086 pumping Methods 0.000 claims 1
- 238000012423 maintenance Methods 0.000 abstract description 4
- 238000004065 wastewater treatment Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 241000282414 Homo sapiens Species 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
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- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
一种深井曝气池和废水强化脱氮除磷装置及废水强化脱氮除磷的方法。它涉及一种深井曝气池和废水处理装置及废水处理方法。本发明提供一种适合处理城镇污水、特别是东北地区城镇污水的占地面积小、耗能低、运行维护简单的水处理方法及装置。深井曝气池包括深井曝气池外筒体、深井曝气池内筒、脱气池和曝气装置。废水强化脱氮除磷装置包括储水箱、厌氧池、缺氧池、深井曝气池、第一脱气池、第二脱气池、二沉池、进水泵、污泥回流泵、硝化液回流泵、排水口和排泥阀。废水强化脱氮除磷的方法:一、深井曝气池中驯化活性污泥;二、污水处理;三、经二沉池处理的水通过排水口排出,剩余的污泥通过排泥阀排出。本发明废水强化脱氮除磷装置单位土地面积处理能力为20000立方米/天.m2,有机负荷可达到0.8kgBOD/kgMLSS以上,溶解氧利用率高。
The invention relates to a deep well aeration tank, a wastewater enhanced denitrification and phosphorus removal device and a wastewater enhanced denitrification and phosphorus removal method. It relates to a deep well aeration tank, a waste water treatment device and a waste water treatment method. The invention provides a water treatment method and device suitable for treating urban sewage, especially urban sewage in Northeast China, with small floor space, low energy consumption, and simple operation and maintenance. The deep well aeration tank includes an outer cylinder of the deep well aeration tank, an inner cylinder of the deep well aeration tank, a degassing tank and an aeration device. Wastewater enhanced nitrogen and phosphorus removal device includes water storage tank, anaerobic tank, anoxic tank, deep well aeration tank, first degassing tank, second degassing tank, secondary settling tank, water inlet pump, sludge return pump, nitrifying liquid Return pump, drain port and mud valve. Methods for enhanced denitrification and phosphorus removal of waste water: 1. domesticate activated sludge in the deep well aeration tank; The waste water enhanced denitrification and dephosphorization device of the present invention has a treatment capacity per unit land area of 20,000 cubic meters/day.m 2 , an organic load of more than 0.8kgBOD/kgMLSS, and a high utilization rate of dissolved oxygen.
Description
技术领域technical field
本发明涉及一种深井曝气池和废水处理装置及废水处理方法。The invention relates to a deep well aeration tank, a waste water treatment device and a waste water treatment method.
背景技术Background technique
水资源是人类赖以生存的基本条件,也是我国经济实现可持续发展的基本前提。我国水资源总量位居世界前列,但人均水资源量不到世界平均的1/4。Water resources are the basic conditions for the survival of human beings, and also the basic prerequisite for the sustainable development of my country's economy. my country's total water resources rank among the top in the world, but the per capita water resources are less than 1/4 of the world average.
随着我国经济的发展,人口的增长,工业化和城市发展步伐的加快,用水量也在不断的增加,污水的排放量也在不断的增加,地表水和地下水的污染日趋严重,使得水资源匮乏的情况日益严重。到2007年我国污水排放量达到1050亿t。如此大量的污水排放,直接严重的影响着人类正常生活和健康,严重威胁着人类的生命健康,阻碍了经济的可持续发展;还威胁到自然的生态平衡。所以,污水净化处理具有必要性和重要性。污水净化后回收再利用,可以提高水资源的利用率,减少水资源带来的压力,缓和水资源短缺的矛盾,又可以大大的减轻自然水系污染,达到保护水资源、保护自然的生态平衡。With the development of our country's economy, the growth of population, the acceleration of industrialization and urban development, the water consumption is also increasing, the discharge of sewage is also increasing, and the pollution of surface water and groundwater is becoming more and more serious, making water resources scarce. situation is getting worse. By 2007, my country's sewage discharge will reach 105 billion tons. Such a large amount of sewage discharge directly and seriously affects the normal life and health of human beings, seriously threatens human life and health, hinders the sustainable development of economy, and threatens the ecological balance of nature. Therefore, sewage purification treatment is necessary and important. Recycling and reuse of sewage after purification can improve the utilization rate of water resources, reduce the pressure brought by water resources, alleviate the contradiction of water shortage, and can greatly reduce the pollution of natural water systems, so as to achieve the ecological balance of protecting water resources and nature.
现在的城市越来越拥挤,发达城市更是如此,可以说是寸土寸金。很多城市没有足够的土地来建设污水处理厂,而常用的污水处理工艺如A2O、氧化沟等工艺往往需要大量的土地进行建设,因此无法实现。Today's cities are getting more and more crowded, especially in developed cities. It can be said that every inch of land is expensive. Many cities do not have enough land to build sewage treatment plants, and commonly used sewage treatment processes such as A2O, oxidation ditch and other processes often require a large amount of land for construction, so they cannot be realized.
小城镇建设污水厂存在建设容易,运行维护难的问题,而且污水处理厂对周边环境容易产生较大影响,特别是VOC(挥发性有机化合物)对水厂周围人民生活产生极大的不便。The construction of sewage plants in small towns has the problems of easy construction and difficult operation and maintenance, and sewage treatment plants are likely to have a greater impact on the surrounding environment, especially VOC (volatile organic compounds) will cause great inconvenience to the lives of people around the water plant.
发明内容Contents of the invention
本发明的目的是提供一种占地面积小、耗能低、运行维护简单的水处理方法及装置。The purpose of the present invention is to provide a water treatment method and device with small footprint, low energy consumption and simple operation and maintenance.
本发明深井曝气池包括深井曝气池外筒体、深井曝气池内筒、脱气池和曝气装置,深井曝气池的进水口和曝气装置都设置在曝气池内筒内底部。The deep well aeration tank of the present invention comprises an outer cylinder of the deep well aeration tank, an inner cylinder of the deep well aeration tank, a degassing tank and an aeration device, and the water inlet and the aeration device of the deep well aeration tank are arranged at the inner bottom of the inner cylinder of the aeration tank.
利用上述深井曝气池的废水强化脱氮除磷装置,废水强化脱氮除磷装置包括储水箱、厌氧池、缺氧池、深井曝气池、第一脱气池、第二脱气池、二沉池、进水泵、污泥回流泵、硝化液回流泵、排水口和排泥阀;Utilize the wastewater enhanced nitrogen and phosphorus removal device of the above-mentioned deep well aeration tank, the wastewater enhanced nitrogen and phosphorus removal device includes a water storage tank, anaerobic tank, anoxic tank, deep well aeration tank, first degassing tank, and second degassing tank , secondary settling tank, water inlet pump, sludge return pump, nitrifying liquid return pump, drain port and sludge discharge valve;
厌氧池、缺氧池、第一脱气池和第二脱气池均设有搅拌器;储水箱通过进水泵分别与厌氧池、缺氧池相连通;第一脱气池与缺氧池相连通,缺氧池与厌氧池相连通,厌氧池通过进水泵与深井曝气池相连通,深井曝气池与第二脱气池相连通,第二脱气池与二沉池相连通,二沉池通过污泥回流泵与第一脱气池相连通,深井曝气池通过硝化液回流泵与第一脱气池相连通;排水口设置在二沉池上部;排泥阀设置在二沉池底部。The anaerobic tank, the anoxic tank, the first degassing tank and the second degassing tank are equipped with agitators; the water storage tank is connected to the anaerobic tank and the anoxic tank respectively through the water inlet pump; The anoxic tank is connected with the anaerobic tank, the anaerobic tank is connected with the deep well aeration tank through the inlet pump, the deep well aeration tank is connected with the second degassing tank, the second degassing tank is connected with the secondary sedimentation tank The secondary settling tank is connected with the first degassing tank through the sludge return pump, and the deep well aeration tank is connected with the first degassing tank through the nitrification liquid return pump; the drain is set on the upper part of the secondary settling tank; the sludge discharge valve Set at the bottom of the secondary sedimentation tank.
利用上述废水强化脱氮除磷装置进行废水强化脱氮除磷的方法:The method for enhancing denitrification and dephosphorization of wastewater by using the above-mentioned wastewater enhanced denitrification and dephosphorization device:
一、深井曝气池中驯化活性污泥;1. Domesticate activated sludge in the deep well aeration tank;
二、将深井曝气池中驯化好的活性污泥和污水通入到厌氧池、缺氧池、第一脱气池、第二脱气池、二沉池;然后打开进水泵、曝气装置和搅拌器,储水箱中的污水分别进入到厌氧池和缺氧池中,厌氧池的进水量为储水箱总出水量的25%~75%,缺氧池的进水量为储水箱总出水量的75%~25%;缺氧池中污水搅拌混合后推流进入厌氧池,来自缺氧池和储水箱的污水在厌氧池中搅拌混合后泵入深井曝气池,深井曝气池中的污水在曝气作用下形成气提循环、污水沿深井曝气池内筒向上流入深井曝气池外筒体,污水在深井曝气池内筒处理后形成硝化液,硝化液推流进入第二脱气池,在第二脱气池内混合搅拌后推流进入二沉池,二沉池中的污泥通过污泥回流泵回流进第一脱气池,深井曝气池中的硝化液通过硝化液回流泵回流进第一脱气池,污泥和硝化液在第一脱气池中混合搅拌,然后推流进入缺氧池;2. Pass the domesticated activated sludge and sewage in the deep well aeration tank into the anaerobic tank, anoxic tank, the first degassing tank, the second degassing tank, and the secondary sedimentation tank; then turn on the water inlet pump and aerate device and agitator, the sewage in the water storage tank enters the anaerobic pool and the anoxic pool respectively, the water inflow of the anaerobic pool is 25% to 75% of the total water output of the water storage tank, and the water inflow of the anoxic pool is the water storage tank 75% to 25% of the total water output; the sewage in the anoxic tank is stirred and mixed and then pushed into the anaerobic tank. The sewage from the anoxic tank and the water storage tank is mixed in the anaerobic tank and then pumped into the deep well aeration tank The sewage in the aeration tank forms an airlift cycle under the action of aeration, and the sewage flows upward along the inner cylinder of the deep well aeration tank into the outer cylinder of the deep well aeration tank. Enter the second degassing tank, mix and stir in the second degassing tank, push the flow into the secondary settling tank, the sludge in the secondary settling tank flows back into the first degassing tank through the sludge return pump, and the nitrification in the deep well aeration tank The liquid flows back into the first degassing tank through the nitrifying liquid return pump, and the sludge and nitrifying liquid are mixed and stirred in the first degassing tank, and then pushed into the anoxic tank;
三、经二沉池处理的水通过排水口排出,剩余的污泥通过排泥阀排出;即完成废水强化脱氮除磷;3. The water treated by the secondary sedimentation tank is discharged through the drain, and the remaining sludge is discharged through the sludge discharge valve; that is, the enhanced denitrification and phosphorus removal of wastewater is completed;
其中,厌氧池的溶解氧浓度小于0.2mg/L、缺氧池的溶解氧浓度为0.2~0.5mg/L、深井曝气池中部溶解氧浓度为3.2mg/L;缺氧池的水力停留时间为1.0~3.0h,厌氧池的水力停留时间为1.0~3.0h,深井曝气池的水力停留时间为0.5~2.0h,二沉池的水力停留时间为2.5h,第一脱气池和第二脱气池的水力停留时间为0.5h;由二沉池回流至第一脱气池的污泥回流比为50%~100%,由深井曝气池回流至第一脱气池的硝化液回流比为100%~300%。Among them, the dissolved oxygen concentration of the anaerobic tank is less than 0.2 mg/L, the dissolved oxygen concentration of the anoxic tank is 0.2-0.5 mg/L, and the dissolved oxygen concentration in the middle of the deep well aeration tank is 3.2 mg/L; the hydraulic retention of the anoxic tank The time is 1.0-3.0h, the hydraulic retention time of the anaerobic tank is 1.0-3.0h, the hydraulic retention time of the deep well aeration tank is 0.5-2.0h, the hydraulic retention time of the secondary sedimentation tank is 2.5h, and the first degassing tank and the hydraulic retention time of the second degassing tank is 0.5h; the sludge return ratio from the secondary settling tank to the first degassing tank is 50% to 100%, and the sludge returning from the deep well aeration tank to the first degassing tank The reflux ratio of the nitrification solution is 100% to 300%.
本发明采用了改良型的深井曝气池深度达到50米以上、细而高,具有占地面积小的优点,而且深井曝气池中形成气提循环,同样的曝气条件下,本发明深井曝气池中溶解氧的利用率更高。The present invention adopts an improved deep well aeration tank with a depth of more than 50 meters, thin and high, and has the advantages of small footprint, and an air lift cycle is formed in the deep well aeration tank. Under the same aeration conditions, the deep well aeration tank of the present invention can The utilization rate of dissolved oxygen in the aeration tank is higher.
本发明深井曝气池从深井曝气池内筒底部进水,污水在曝气装置推动力的作用下沿内筒上升,再在深井曝气池外筒体内下降,形成气提循环。污水由深井曝气池底部上升至顶部脱气池的过程中溶解氧逐渐降低,形成好氧、缺氧状态的交替,可形成反硝化脱氮,增强脱氮效果。The deep well aeration tank of the present invention enters water from the bottom of the inner cylinder of the deep well aeration tank, and the sewage rises along the inner cylinder under the action of the driving force of the aeration device, and then descends in the outer cylinder of the deep well aeration tank, forming an air lift cycle. Dissolved oxygen gradually decreases during the process of sewage rising from the bottom of the deep well aeration tank to the top degassing tank, forming an alternation of aerobic and anoxic states, which can form denitrification and denitrification, and enhance the denitrification effect.
本发明废水强化脱氮除磷装置单位土地面积处理能力为20000立方米/天.m2,远高于现行处理工艺。The waste water enhanced denitrification and dephosphorization device of the present invention has a treatment capacity per unit land area of 20,000 cubic meters per day.m 2 , which is much higher than the current treatment process.
现有的A2O工艺中原水直接进入厌氧段,大部分进水碳源在厌氧段被消耗掉,缺氧段可利用的碳源比较少,致使反硝化碳源不足,总氮去除率偏低。本发明进水按比例分别进入厌氧段与缺氧段,碳源分配合理,增强了脱氮效果,同时强化了缺氧段的反硝化聚磷菌,起到节省碳源的作用。In the existing A2O process, the raw water directly enters the anaerobic section, most of the influent carbon source is consumed in the anaerobic section, and the available carbon source in the anoxic section is relatively small, resulting in insufficient denitrification carbon source and partial nitrogen removal rate. Low. According to the invention, the influent water enters the anaerobic section and the anoxic section respectively, the carbon source is distributed reasonably, the denitrification effect is enhanced, and the denitrifying phosphorus accumulating bacteria in the anoxic section is strengthened at the same time, so as to save the carbon source.
本发明中二沉池污泥与深井曝气池硝化液回流至第一脱气池,第一脱气池中可消耗掉部分溶解氧,减少硝化液回流对缺氧池及厌氧池的干扰。同时第一脱气池中亦可形成较低的溶解氧环境,可形成反硝化脱氮,促进脱氮效果。In the present invention, the sludge from the secondary settling tank and the nitrifying liquid in the deep well aeration tank flow back to the first degassing tank, and part of the dissolved oxygen can be consumed in the first degassing tank, reducing the interference of the nitrifying liquid backflow on the anoxic tank and the anaerobic tank . At the same time, a lower dissolved oxygen environment can also be formed in the first degassing tank, which can form denitrification and denitrification to promote the denitrification effect.
本发明中厌氧池出水直接进入深井曝气池,完成聚磷菌的释磷与吸磷,有利于磷的去除。In the present invention, the effluent from the anaerobic tank directly enters the deep well aeration tank to complete the release and absorption of phosphorus by the phosphorus accumulating bacteria, which is beneficial to the removal of phosphorus.
本发明抗冲击负荷能力强,本发明抗冲击负荷能力强,有机负荷0.8kgBOD/kgMLSS以上。The invention has strong impact load resistance, and the invention has strong impact load resistance, and the organic load is above 0.8kgBOD/kgMLSS.
本发明运行维护简单,人为工作量低。The operation and maintenance of the invention is simple, and the human workload is low.
本发明适合处理工业污水和城市生活污水,可高效去除污水中的氮和磷,本发明处理后出水的COD、氨氮、总氮、总磷分别降至28~46mg/L、1.8~3.3mg/L、6.9~8.1mg/L、0.19~0.31mg/L,优于GB18918-2002一级A排放标准。The invention is suitable for treating industrial sewage and urban domestic sewage, and can efficiently remove nitrogen and phosphorus in sewage. The COD, ammonia nitrogen, total nitrogen, and total phosphorus in the effluent treated by the invention are reduced to 28-46 mg/L and 1.8-3.3 mg/L respectively. L, 6.9~8.1mg/L, 0.19~0.31mg/L, better than GB18918-2002 Class A emission standard.
附图说明Description of drawings
图1是本发明深井曝气池的结构示意图,箭头代表水流方向。Fig. 1 is a schematic diagram of the structure of the deep well aeration tank of the present invention, and the arrows represent the direction of water flow.
图2是本发明废水强化脱氮除磷装置的结构示意图,箭头代表物质运动方向。Fig. 2 is a schematic structural diagram of the waste water enhanced denitrification and dephosphorization device of the present invention, and the arrows represent the direction of material movement.
具体实施方式detailed description
本发明技术方案不局限于以下所列举具体实施方式,还包括各具体实施方式间的任意组合。The technical solution of the present invention is not limited to the specific embodiments listed below, but also includes any combination of the specific embodiments.
具体实施方式一:结合图1说明本实施方式,本实施方式深井曝气池包括深井曝气池外筒体、深井曝气池内筒4-2、脱气池4-3、曝气装置4-1和进气管15,其特征在于深井曝气池的进水口和曝气装置4-1都设置在曝气池内筒4-2内底部,进气管15与曝气装置4-1相连通。Specific embodiment 1: This embodiment is described in conjunction with Figure 1. The deep well aeration tank in this embodiment includes the outer cylinder of the deep well aeration tank, the inner cylinder 4-2 of the deep well aeration tank, the degassing tank 4-3, and the aeration device 4- 1 and an air inlet pipe 15, characterized in that the water inlet of the deep well aeration tank and the aeration device 4-1 are all arranged at the inner bottom of the aeration tank inner tube 4-2, and the air inlet pipe 15 communicates with the aeration device 4-1.
具体实施方式二:结合图2说明本实施方式,本实施方式废水强化脱氮除磷装置包括储水箱1、厌氧池2、缺氧池3、深井曝气池4、第一脱气池5、第二脱气池6、二沉池7、进水泵10、污泥回流泵11、硝化液回流泵12、排水口13和排泥阀14;Specific Embodiment 2: This embodiment is described in conjunction with FIG. 2 . The wastewater enhanced denitrification and phosphorus removal device in this embodiment includes a water storage tank 1, an anaerobic pool 2, an anoxic pool 3, a deep well aeration pool 4, and a first degassing pool 5. , the second degassing tank 6, the secondary settling tank 7, the water inlet pump 10, the sludge return pump 11, the nitrifying liquid return pump 12, the drain port 13 and the sludge discharge valve 14;
厌氧池2、缺氧池3、第一脱气池5和第二脱气池6均设有搅拌器9;储水箱1通过进水泵10分别与厌氧池2、缺氧池3相连通;第一脱气池5与缺氧池3相连通,缺氧池3与厌氧池2相连通,厌氧池2通过进水泵10与深井曝气池4相连通,深井曝气池4与第二脱气池6相连通,第二脱气池6与二沉池7相连通,二沉池7通过污泥回流泵11与第一脱气池5相连通,深井曝气池4通过硝化液回流泵12与第一脱气池5相连通;排水口13设置在二沉池7上部;排泥阀14设置在二沉池7底部。The anaerobic pool 2, the anoxic pool 3, the first degassing pool 5 and the second degassing pool 6 are equipped with agitators 9; the water storage tank 1 is connected with the anaerobic pool 2 and the anoxic pool 3 respectively through the water inlet pump 10 ; The first degassing tank 5 is communicated with anoxic tank 3, and anoxic tank 3 is communicated with anaerobic tank 2, and anaerobic tank 2 is communicated with deep well aeration tank 4 by inlet pump 10, and deep well aeration tank 4 is connected with The second degassing tank 6 is connected, the second degassing tank 6 is connected with the secondary sedimentation tank 7, the secondary sedimentation tank 7 is connected with the first degassing tank 5 through the sludge return pump 11, and the deep well aeration tank 4 is connected by nitrification The liquid return pump 12 is in communication with the first degassing tank 5; the drain port 13 is set on the upper part of the secondary settling tank 7; the sludge discharge valve 14 is set on the bottom of the secondary settling tank 7.
具体实施方式三:结合图2说明本实施方式,本实施方式废水强化脱氮除磷的方法按以下步骤进行:Specific embodiment three: this embodiment is described in conjunction with Fig. 2, and the method for the enhanced denitrification and phosphorus removal of waste water in this embodiment is carried out according to the following steps:
一、深井曝气池4中驯化活性污泥;1. Domesticated activated sludge in the deep well aeration tank 4;
二、将深井曝气池4中驯化好的活性污泥和污水通入到厌氧池2、缺氧池3、第一脱气池5、第二脱气池6、二沉池7;然后打开进水泵10、曝气装置4-1和搅拌器9,储水箱1中的污水分别进入到厌氧池2和缺氧池3中,厌氧池2的进水量为储水箱1总出水量的25%~75%,缺氧池3的进水量为储水箱1总出水量的75%~25%;缺氧池3中污水搅拌混合后推流进入厌氧池2,来自缺氧池3和储水箱1的污水在厌氧池2中搅拌混合后泵10入深井曝气池4,深井曝气池4中的污水在曝气作用下形成气提循环、污水沿深井曝气池内筒4-2向上流入深井曝气池外筒体,污水在深井曝气池内筒4-2处理后形成硝化液,硝化液推流进入第二脱气池6,在第二脱气池6内混合搅拌后推流进入二沉池7,二沉池7中的污泥通过污泥回流泵11回流进第一脱气池5,深井曝气池4中的硝化液通过硝化液回流泵12回流进第一脱气池5,污泥和硝化液在第一脱气池5中混合搅拌,然后推流进入缺氧池3;Two, pass the activated sludge and sewage domesticated in the deep well aeration tank 4 to the anaerobic tank 2, the anoxic tank 3, the first degassing tank 5, the second degassing tank 6, the secondary sedimentation tank 7; then Turn on the water inlet pump 10, the aeration device 4-1 and the agitator 9, and the sewage in the water storage tank 1 enters the anaerobic pool 2 and the anoxic pool 3 respectively, and the water inflow of the anaerobic pool 2 is the total water output of the water storage tank 1 25% to 75% of the water in the anoxic pool 3, and the water inflow to the anoxic pool 3 is 75% to 25% of the total water output from the water storage tank 1; Stir and mix with the sewage in the water storage tank 1 in the anaerobic tank 2, then pump 10 into the deep well aeration tank 4, the sewage in the deep well aeration tank 4 forms a gas lift cycle under the action of aeration, and the sewage flows along the inner tube 4 of the deep well aeration tank -2 flows upward into the outer cylinder of the deep well aeration tank, and the sewage is treated in the inner cylinder 4-2 of the deep well aeration tank to form nitrifying liquid, which pushes into the second degassing tank 6 and mixes and stirs in the second degassing tank 6 The push flow enters the secondary settling tank 7, the sludge in the secondary settling tank 7 flows back into the first degassing tank 5 through the sludge return pump 11, and the nitrifying liquid in the deep well aeration tank 4 flows back into the first degassing tank 5 through the nitrifying liquid return pump 12. A degassing tank 5, the sludge and nitrification liquid are mixed and stirred in the first degassing tank 5, and then pushed into the anoxic tank 3;
三、经二沉池7处理的水通过排水口13排出,剩余的污泥通过排泥阀14排出;即完成废水强化脱氮除磷;3. The water treated by the secondary settling tank 7 is discharged through the outlet 13, and the remaining sludge is discharged through the sludge discharge valve 14; that is, the enhanced denitrification and phosphorus removal of wastewater is completed;
其中,厌氧池2的溶解氧浓度小于0.2mg/L、缺氧池3的溶解氧浓度为0.2~0.5mg/L、深井曝气池4中部溶解氧浓度为3.2mg/L;缺氧池3的水力停留时间为1.0~3.0h,厌氧池2的水力停留时间为1.0~3.0h,深井曝气池4的水力停留时间为0.5~2.0h,二沉池7的水力停留时间为2.5h,第一脱气池5和第二脱气池6的水力停留时间为0.5h;由二沉池7回流至第一脱气池5的污泥回流比为50%~100%,由深井曝气池4回流至第一脱气池5的硝化液回流比为100%~300%。Among them, the dissolved oxygen concentration in the anaerobic tank 2 is less than 0.2 mg/L, the dissolved oxygen concentration in the anoxic tank 3 is 0.2-0.5 mg/L, and the dissolved oxygen concentration in the middle of the deep well aeration tank 4 is 3.2 mg/L; The hydraulic retention time of 3 is 1.0-3.0h, the hydraulic retention time of anaerobic tank 2 is 1.0-3.0h, the hydraulic retention time of deep well aeration tank 4 is 0.5-2.0h, and the hydraulic retention time of secondary sedimentation tank 7 is 2.5 h, the hydraulic retention time of the first degassing tank 5 and the second degassing tank 6 is 0.5h; the sludge reflux ratio from the secondary settling tank 7 to the first degassing tank 5 is 50% to 100%. The reflux ratio of the nitrification liquid from the aeration tank 4 to the first degassing tank 5 is 100%-300%.
本实施方式回流污泥与回流硝化液在第一脱气池5中进行脱气,去除掉部分溶解氧以后再进入缺氧段。In this embodiment, the returning sludge and returning nitrifying liquid are degassed in the first degassing tank 5, and then enter the anoxic section after removing part of the dissolved oxygen.
本实施方式厌氧池2出水直接进入深井曝气池4,完成微生物磷的释放与吸收。In this embodiment, the effluent from the anaerobic tank 2 directly enters the deep well aeration tank 4 to complete the release and absorption of microbial phosphorus.
具体实施方式四:本实施方式与具体实施方式三的不同点是:步骤一中深井曝气池4内活性污泥按以下方法驯化:将污水厂取来的二沉池污泥与新鲜污水倒入深井曝气池4中,打开曝气装置4-1在温度为25℃左右的条件下培养10d,即得到驯化好的活性污泥。其它步骤及参数与实施方式三相同。Specific embodiment four: the difference between this embodiment and specific embodiment three is: the activated sludge in the deep well aeration tank 4 is domesticated by the following method in the step one: the secondary sedimentation tank sludge and fresh sewage that the sewage plant is taken are poured out Enter the deep well aeration tank 4, turn on the aeration device 4-1 and incubate for 10 days at a temperature of about 25°C to obtain domesticated activated sludge. Other steps and parameters are the same as those in the third embodiment.
具体实施方式五:本实施方式与具体实施方式三或四的不同点是:步骤二中缺氧池3中搅拌器的转速为30r/min~50r/min;厌氧池2中搅拌器的转速为30r/min~50r/min;第二脱气池6中搅拌器的转速为30r/min~50r/min;第一脱气池5中搅拌器的转速为30r/min~50r/min。其它步骤及参数与实施方式三或四相同。Embodiment five: the difference between this embodiment and embodiment three or four is: the rotating speed of the agitator in the anoxic pool 3 in step 2 is 30r/min~50r/min; the rotating speed of the agitator in the anaerobic pool 2 30r/min~50r/min; the rotational speed of the agitator in the second degassing pool 6 is 30r/min~50r/min; the rotational speed of the agitator in the first degassing pool 5 is 30r/min~50r/min. Other steps and parameters are the same as those in Embodiment 3 or 4.
具体实施方式六:本实施方式与具体实施方式三、四或五的不同点是:步骤二中在深井曝气池4、厌氧池2和缺氧池3中投加生物膜填料。其它步骤及参数与实施方式三、四或五相同。Embodiment 6: The difference between this embodiment and Embodiment 3, 4 or 5 is that in step 2, biofilm fillers are added in deep well aeration tank 4, anaerobic tank 2 and anoxic tank 3. Other steps and parameters are the same as those in Embodiment 3, 4 or 5.
本实施方式在深井曝气池4、厌氧池2和缺氧池3中投加生物膜填料,可以增加生物量、提高水体湍动程度。本实施方式多相流体湍动程度以剪切强度表征为不低于0.3。In this embodiment, biofilm fillers are added to the deep well aeration tank 4, the anaerobic tank 2 and the anoxic tank 3, which can increase the biomass and improve the turbulence of the water body. The degree of turbulence of the multiphase fluid in this embodiment is characterized by a shear strength of not less than 0.3.
具体实施方式七:本实施方式与具体实施方式三、四、五或六的不同点是:步骤二中在深井曝气池4中汽水比为1.2~1.5:1。其它步骤及参数与实施方式三、四、五或六相同。Embodiment 7: The difference between this embodiment and Embodiment 3, 4, 5 or 6 is that in step 2, the steam-water ratio in the deep well aeration tank 4 is 1.2-1.5:1. Other steps and parameters are the same as those in Embodiment 3, 4, 5 or 6.
本实施方式中活性污泥随着水流深度的变化,所承受的压力和溶解氧浓度不断调整变化,水中溶解氧利用率明显提高,有机物消耗速度提高,并且有比较明显的脱氮效果。In this embodiment, with the change of water flow depth, the pressure and dissolved oxygen concentration of activated sludge are constantly adjusted and changed, the utilization rate of dissolved oxygen in water is significantly improved, the consumption rate of organic matter is increased, and there is a relatively obvious denitrification effect.
具体实施方式八:本实施方式与具体实施方式四、五、六或七的不同点是:步骤一中新鲜污水的COD值为215mg/L~550mg/L,氨氮值为32mg/L~55mg/L,总氮值为38mg/L~62mg/L,总磷值为3.9mg/L~7.4mg/L。其它步骤及参数与实施方式四、五、六或七相同。Embodiment 8: The difference between this embodiment and Embodiment 4, 5, 6 or 7 is: the COD value of the fresh sewage in step 1 is 215mg/L~550mg/L, and the ammonia nitrogen value is 32mg/L~55mg/L L, the total nitrogen value is 38mg/L~62mg/L, and the total phosphorus value is 3.9mg/L~7.4mg/L. Other steps and parameters are the same as Embodiments 4, 5, 6 or 7.
具体实施方式九:本实施方式与具体实施方式三至八之一的不同点是:步骤二中储水箱1中的污水分别进入厌氧池2和缺氧池3,厌氧池2与缺氧池3的进水量比为1:2、1:1或2:1。其它步骤及参数与实施方式三至八之一相同。Specific embodiment nine: the difference between this embodiment and one of the specific embodiments three to eight is: the sewage in the water storage tank 1 enters the anaerobic pool 2 and the anoxic pool 3 respectively in the step 2, and the anaerobic pool 2 and the anoxic pool The water inflow ratio of pool 3 is 1:2, 1:1 or 2:1. Other steps and parameters are the same as those of Embodiments 3 to 8.
实施例1Example 1
废水强化脱氮除磷的方法按以下步骤进行:The method for enhanced denitrification and dephosphorization of waste water is carried out according to the following steps:
一、深井曝气池4中驯化活性污泥;1. Domesticated activated sludge in the deep well aeration tank 4;
二、将深井曝气池4中驯化好的活性污泥和污水通入到厌氧池2、缺氧池3、第一脱气池5、第二脱气池6、二沉池7;然后打开进水泵10、曝气装置4-1和搅拌器9,储水箱1中的污水分别进入到厌氧池2和缺氧池3中,厌氧池2的进水量为储水箱1总出水量的25%~75%,缺氧池3的进水量为储水箱1总出水量的75%~25%;缺氧池3中污水搅拌混合后推流进入厌氧池2,来自缺氧池3和储水箱1的污水在厌氧池2中搅拌混合后泵10入深井曝气池4,深井曝气池4中的污水在曝气作用下形成气提循环、污水沿深井曝气池内筒4-2向上流入深井曝气池外筒体,污水在深井曝气池内筒4-2处理后形成硝化液,硝化液推流进入第二脱气池6,在第二脱气池6内混合搅拌后推流进入二沉池7,二沉池7中的污泥通过污泥回流泵11回流进第一脱气池5,深井曝气池4中的硝化液通过硝化液回流泵12回流进第一脱气池5,污泥和硝化液在第一脱气池5中混合搅拌,然后推流进入缺氧池3;Two, pass the activated sludge and sewage domesticated in the deep well aeration tank 4 to the anaerobic tank 2, the anoxic tank 3, the first degassing tank 5, the second degassing tank 6, the secondary sedimentation tank 7; then Turn on the water inlet pump 10, the aeration device 4-1 and the agitator 9, and the sewage in the water storage tank 1 enters the anaerobic pool 2 and the anoxic pool 3 respectively, and the water inflow of the anaerobic pool 2 is the total water output of the water storage tank 1 25% to 75% of the water in the anoxic pool 3, and the water inflow to the anoxic pool 3 is 75% to 25% of the total water output from the water storage tank 1; Stir and mix with the sewage in the water storage tank 1 in the anaerobic tank 2, then pump 10 into the deep well aeration tank 4, the sewage in the deep well aeration tank 4 forms a gas lift cycle under the action of aeration, and the sewage flows along the inner tube 4 of the deep well aeration tank -2 flows upward into the outer cylinder of the deep well aeration tank, and the sewage is treated in the inner cylinder 4-2 of the deep well aeration tank to form nitrifying liquid, which pushes into the second degassing tank 6 and mixes and stirs in the second degassing tank 6 The push flow enters the secondary settling tank 7, the sludge in the secondary settling tank 7 flows back into the first degassing tank 5 through the sludge return pump 11, and the nitrifying liquid in the deep well aeration tank 4 flows back into the first degassing tank 5 through the nitrifying liquid return pump 12. A degassing tank 5, the sludge and nitrification liquid are mixed and stirred in the first degassing tank 5, and then pushed into the anoxic tank 3;
三、经二沉池7处理的水通过排水口13排出,剩余的污泥通过排泥阀14排出;即完成废水强化脱氮除磷;3. The water treated by the secondary settling tank 7 is discharged through the outlet 13, and the remaining sludge is discharged through the sludge discharge valve 14; that is, the enhanced denitrification and phosphorus removal of wastewater is completed;
其中,厌氧池2的溶解氧浓度小于0.2mg/L、缺氧池3的溶解氧浓度为0.2~0.5mg/L、深井曝气池4中部溶解氧浓度为3.2mg/L;缺氧池3的水力停留时间为1.0~3.0h,厌氧池2的水力停留时间为1.0~3.0h,深井曝气池4的水力停留时间为0.5~2.0h,二沉池7的水力停留时间为2.5h,第一脱气池5和第二脱气池6的水力停留时间为0.5h;由二沉池7回流至第一脱气池5的污泥回流比为50%~100%,由深井曝气池4回流至第一脱气池5的硝化液回流比为100%~300%;Among them, the dissolved oxygen concentration in the anaerobic tank 2 is less than 0.2 mg/L, the dissolved oxygen concentration in the anoxic tank 3 is 0.2-0.5 mg/L, and the dissolved oxygen concentration in the middle of the deep well aeration tank 4 is 3.2 mg/L; The hydraulic retention time of 3 is 1.0-3.0h, the hydraulic retention time of anaerobic tank 2 is 1.0-3.0h, the hydraulic retention time of deep well aeration tank 4 is 0.5-2.0h, and the hydraulic retention time of secondary sedimentation tank 7 is 2.5 h, the hydraulic retention time of the first degassing tank 5 and the second degassing tank 6 is 0.5h; the sludge reflux ratio from the secondary settling tank 7 to the first degassing tank 5 is 50% to 100%. The reflux ratio of the nitrifying liquid from the aeration tank 4 to the first degassing tank 5 is 100% to 300%;
其中,步骤一中深井曝气池4内活性污泥按以下方法驯化:将污水厂取来的二沉池污泥与新鲜污水倒入深井曝气池4中,打开曝气装置4-1在温度为25℃条件下培养10d,即得到驯化好的活性污泥;Among them, the activated sludge in the deep well aeration tank 4 in step 1 is domesticated according to the following method: pour the secondary sedimentation tank sludge and fresh sewage from the sewage plant into the deep well aeration tank 4, open the aeration device 4-1 Cultivate for 10 days at a temperature of 25°C to obtain domesticated activated sludge;
步骤二中缺氧池3中搅拌器的转速为30r/min~50r/min;厌氧池2中搅拌器的转速为30r/min~50r/min;第二脱气池6中搅拌器的转速为30r/min~50r/min;第一脱气池5中搅拌器的转速为30r/min~50r/min。The speed of the agitator in the anoxic pool 3 in step 2 is 30r/min~50r/min; the speed of the agitator in the anaerobic pool 2 is 30r/min~50r/min; the speed of the agitator in the second degassing pool 6 30r/min-50r/min; the rotational speed of the agitator in the first degassing tank 5 is 30r/min-50r/min.
储水箱1中的预处理污水的COD值为215mg/L~550mg/L,氨氮值为32mg/L~55mg/L,总氮值为38mg/L~62mg/L,总磷值为3.9mg/L~7.4mg/L。The COD value of the pretreated sewage in the water storage tank 1 is 215mg/L-550mg/L, the ammonia nitrogen value is 32mg/L-55mg/L, the total nitrogen value is 38mg/L-62mg/L, and the total phosphorus value is 3.9mg/L L~7.4mg/L.
实施例2Example 2
除采用深井曝气装置(CN201210244816.X)替代本发明深井曝气池、储水箱1中的污水全部进入到缺氧池3之外,其他水处理反应器和参数均与实施例1相同。Except that the deep well aeration device (CN201210244816.X) is used to replace the deep well aeration tank of the present invention, and all the sewage in the water storage tank 1 enters the anoxic tank 3, other water treatment reactors and parameters are the same as in Example 1.
预处理污水与实施例1相同,储水箱1中的预处理污水的COD值为215mg/L~550mg/L,氨氮值为32mg/L~55mg/L,总氮值为38mg/L~62mg/L,总磷值为3.9mg/L~7.4mg/L。The pretreated sewage is the same as in Example 1, the COD value of the pretreated sewage in the water storage tank 1 is 215mg/L~550mg/L, the ammonia nitrogen value is 32mg/L~55mg/L, and the total nitrogen value is 38mg/L~62mg/L L, the total phosphorus value is 3.9mg/L~7.4mg/L.
实验结果:Experimental results:
实施例1处理后出水COD值为28~46mg/L,氨氮值为1.8~3.3mg/L,总氮值为6.9~8.1mg/L,总磷值为0.19~0.31mg/L,达到了国家一级A排放标准。After the treatment in Example 1, the COD value of the effluent was 28-46 mg/L, the ammonia nitrogen value was 1.8-3.3 mg/L, the total nitrogen value was 6.9-8.1 mg/L, and the total phosphorus value was 0.19-0.31 mg/L, reaching the national Tier 1 A emission standard.
实施例2处理后出水COD值为31~51mg/L,氨氮值为2.8~4.6mg/L,总氮值为9.6~15.4mg/L,总磷值为0.21~0.37mg/L,基本能够达到了国家一级A排放标准。After the treatment in Example 2, the effluent COD value is 31-51 mg/L, the ammonia nitrogen value is 2.8-4.6 mg/L, the total nitrogen value is 9.6-15.4 mg/L, and the total phosphorus value is 0.21-0.37 mg/L, which can basically reach Meet the national level A emission standard.
实验结果证明本发明深井曝气池溶解氧利用率高,并且在深井曝气池中产生反硝化脱氮的效果(脱氮效果增强);进水碳源得到合理分配,污染物去除能力得到强化,净化效果明显优于实施例2,特别是脱氮效果。本发明在占地面积小,能耗低的条件下达到了污染物的深度消减,对水污染的防治,水环境的保护起到了积极的作用。Experimental results prove that the utilization rate of dissolved oxygen in the deep well aeration tank of the present invention is high, and the effect of denitrification and denitrification (enhanced denitrification effect) is produced in the deep well aeration tank; the influent carbon source is reasonably allocated, and the pollutant removal ability is strengthened , the purification effect is obviously better than that of Example 2, especially the denitrification effect. The invention achieves the deep reduction of pollutants under the conditions of small floor area and low energy consumption, and plays a positive role in the prevention and control of water pollution and the protection of water environment.
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