CN104782650B - A kind of Semen Tritici aestivi special-purpose suspension seed coat agent - Google Patents
A kind of Semen Tritici aestivi special-purpose suspension seed coat agent Download PDFInfo
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Abstract
本发明涉及一种小麦专用悬浮种衣剂,其由以下重量百分比的原料组成:吡虫啉5-10%、丙环唑1-3%、福美双7-12%、芸苔素内酯0.005-0.1%、成膜剂1-2.5%、润湿分散剂1-2.5%、防腐剂1-1.5%、填充剂5-10%、警戒色料1-1.5%、防冻剂1-5%、消泡剂0.5-1%,余量为水。该种衣剂以吡虫啉、丙环唑、福美双和芸苔素内酯复配作为有效成分,四者优势互补,通过播前包衣处理可有效综合防治小麦全蚀病、纹枯病、黑穗病、小麦蚜虫及苗期地下害虫,降低小麦生产中农药使用量和使用种类、次数,减少污染,并提高小麦产量和品质,具有良好的经济效益和生态效益,能够广泛应用于农业推广。The invention relates to a special suspension seed coating agent for wheat, which is composed of the following raw materials in percentage by weight: imidacloprid 5-10%, propiconazole 1-3%, thiram 7-12%, and brassinolide 0.005-0.1% %, film forming agent 1-2.5%, wetting and dispersing agent 1-2.5%, preservative 1-1.5%, filler 5-10%, warning coloring material 1-1.5%, antifreeze agent 1-5%, defoamer 0.5-1%, the balance is water. The seed coating agent is composed of imidacloprid, propiconazole, thiram and brassinolide as active ingredients. The advantages of the four are complementary. The pre-sowing coating treatment can effectively prevent and control wheat take-all, sheath blight, black Ear disease, wheat aphids and underground pests at the seedling stage can reduce the amount, type and frequency of pesticide use in wheat production, reduce pollution, and improve wheat yield and quality. It has good economic and ecological benefits and can be widely used in agricultural promotion.
Description
技术领域technical field
本发明属于种衣剂技术领域,具体涉及一种小麦专用悬浮种衣剂。The invention belongs to the technical field of seed coating agents, in particular to a special suspension seed coating agent for wheat.
背景技术Background technique
在现代农业生产中,利用种衣剂对种子进行药剂处理是防治地下害虫及农作物土传、种传病害的经济简便的方法之一。种衣剂是一种用于作物或其它植物种子处理的、具有成膜特性的农药制剂,它能够在种子表面固化形成称为种衣的膜。种衣剂在土壤中吸水膨胀而不被溶解,允许种子正常发芽所需的水分和空气通过,所含的农药和种肥等物质缓慢释放,能够杀灭地下害虫、苗期害虫,具有防治苗期病害和系统性病害、提高种子发芽率、促进种苗健康生长等功效。悬浮种衣剂是种衣剂的一种,是由农药原药、成膜剂、湿润剂、分散剂、增稠剂、着色剂、填料和水经湿法粉碎而制成的一种可流动的稳定的均匀悬浮液,由于其使用方便、安全,在众多种类的种衣剂中倍受青睐。In modern agricultural production, the use of seed coating agents to treat seeds is one of the most economical and convenient methods to prevent and control underground pests and crop soil-borne and seed-borne diseases. A seed coating is a pesticide formulation with film-forming properties used for the treatment of crop or other plant seeds, which solidifies on the surface of the seed to form a film called a seed coat. The seed coating agent absorbs water and swells in the soil without being dissolved, allowing the water and air required for normal germination of the seeds to pass through, and the contained pesticides and seed fertilizers are slowly released, which can kill underground pests and seedling pests, and has the function of preventing and controlling seedlings. It has the effects of preventing early-stage diseases and systemic diseases, improving seed germination rate, and promoting healthy growth of seedlings. Suspension seed coating agent is a kind of seed coating agent, which is a kind of flowable product made by wet pulverization of pesticide, film forming agent, wetting agent, dispersant, thickener, colorant, filler and water. The stable and homogeneous suspension is favored in many kinds of seed coating agents because of its convenience and safety.
随着农民科学种田意识的提高及种植技术的加强,小麦在播种前进行种子包衣已引起农民的高度重视。使用优秀种衣剂从源头上去解决小麦的病虫害已经成为农民增产增收的一项重要技术。种子包衣是提高科技含量、实现种子质量标准化的一项重要内容,不仅能有效防治病虫害,还能提高种苗抗逆性和作物产量,并能大大减少环境污染。据统计,国内市场种子处理剂的年销量在以20%以上的速度增长。纵观世界农业,种衣剂的应用已经遍布农业发达国家和地区,在农业生产中占据重要地位。随着近年来粮食价格的提高,激发了农民种粮的积极性,而使用种衣剂是科学种田、增产丰收不可或缺的一个重要环节,是未来的一种趋势。随着国家对农业的重视,对农业科技投入的增加,对农民科学种地的倡导,会有越来越多的农民意识到小麦种衣剂的重要性。因此,小麦种衣剂的市场前景非常广阔。With the improvement of farmers' scientific farming awareness and the strengthening of planting technology, wheat seed coating before sowing has attracted great attention from farmers. Using excellent seed coating agents to solve wheat pests and diseases from the source has become an important technology for farmers to increase production and income. Seed coating is an important part of improving scientific and technological content and realizing seed quality standardization. It can not only effectively prevent and control diseases and insect pests, but also improve seedling stress resistance and crop yield, and can greatly reduce environmental pollution. According to statistics, the annual sales of seed treatment agents in the domestic market are growing at a rate of more than 20%. Throughout the world's agriculture, the application of seed coating agents has spread all over agricultural developed countries and regions, occupying an important position in agricultural production. With the increase in grain prices in recent years, farmers have been motivated to grow grain, and the use of seed coating agents is an indispensable part of scientific farming, increasing production and harvest, and will be a trend in the future. With the country's emphasis on agriculture, the increase in investment in agricultural science and technology, and the advocacy of farmers' scientific farming, more and more farmers will realize the importance of wheat seed coating agents. Therefore, the market prospect of wheat seed coating agent is very broad.
目前市场推广使用的小麦种衣剂品种虽多,但配方单一,缺乏专用和针对性,不能解决当前小麦生产实际中危害较为严重的蚜虫、全蚀病等病虫害发生的综合防治问题。同时,由于作物品种、生态环境条件和气候差异较大,栽培条件、病虫害种类和土壤类型不尽相同,单一配方的种衣剂在不同地区、不同作物上很难达到理想的防治效果,如不少厂家生产的克百威、多菌灵、三唑酮等对小麦地下害虫及全蚀病防效不佳。吡虫啉用于小麦种衣剂已得到共识并大面积推广,但一些种衣剂的配方及助剂不合理或制剂技术不够完善,包衣效果不良,且易出现药害,一旦播种过深或遭遇干旱,会导致出苗缓慢甚至缺苗断垄的现象。此外,种子包衣的作用机理研究不足,种衣剂不同组分的有效浓度、有效时限、相互作用及对播种后种子发芽、生长的不同效应和作用机制缺乏研究,对种衣剂合理化配方的发展缺乏理论研究和试验依据,随意混配或简单复配,防效不佳,甚至造成不应有的损失,这些技术问题亟待解决。Although there are many kinds of wheat seed coating agents currently used in the market, their formulas are single, lack of specialization and pertinence, and cannot solve the comprehensive control problems of aphids, take-all and other diseases and insect pests that are more serious in the current wheat production practice. At the same time, due to the large differences in crop varieties, ecological environment conditions and climates, cultivation conditions, types of pests and diseases, and soil types, it is difficult to achieve ideal control effects in different regions and different crops with a single formula of seed coating agent. Carbofuran, carbendazim, triadimefon, etc. produced by a few manufacturers have poor control effects on wheat underground pests and take-all. The use of imidacloprid in wheat seed coatings has been recognized and widely promoted, but some seed coating formulations and auxiliaries are unreasonable or the preparation technology is not perfect, the coating effect is poor, and phytotoxicity is prone to occur. Drought will lead to slow emergence or even lack of seedlings and broken ridges. In addition, there is insufficient research on the mechanism of seed coating, the effective concentration, effective time limit, and interaction of different components of seed coating agents, and the different effects and mechanisms of action on seed germination and growth after sowing are lacking. The lack of theoretical research and experimental basis for development, random mixing or simple compounding, poor control effect, and even undue losses, these technical problems need to be solved urgently.
发明内容Contents of the invention
本发明目的在于提供了一种小麦专用悬浮种衣剂,该种衣剂能够有效防治当前小麦实际生产中严重发生的全蚀病、纹枯病、黑穗病等多种病害和蚜虫及苗期地下害虫,并确保该悬浮种衣剂各活性成分无拮抗作用,安全,高效。The purpose of the present invention is to provide a special suspension seed coating agent for wheat, which can effectively prevent and control various diseases such as take-all, sheath blight, smut and other diseases, aphids and seedling stage serious occurrences in current wheat actual production. underground pests, and ensure that the active ingredients of the suspension seed coating agent have no antagonistic effect, are safe and efficient.
为实现上述目的,本发明采用如下技术方案:To achieve the above object, the present invention adopts the following technical solutions:
一种小麦专用悬浮种衣剂,其由以下重量百分比的原料组成:吡虫啉5-10%、丙环唑1-3%、福美双7-12%、芸苔素内酯0.005-0.1%、成膜剂1-2.5%、润湿分散剂1-2.5%、防腐剂1-1.5%、填充剂5-10%、警戒色料1-1.5%、防冻剂1-5%、消泡剂0. 5-1%,余量为水。A special suspension seed coating agent for wheat, which is composed of the following raw materials in percentage by weight: 5-10% imidacloprid, 1-3% propiconazole, 7-12% thiram, 0.005-0.1% brassinolide, Film agent 1-2.5%, wetting and dispersing agent 1-2.5%, preservative 1-1.5%, filler 5-10%, warning coloring material 1-1.5%, antifreeze agent 1-5%, defoamer 0.5 -1%, the balance is water.
进一步的,上述的小麦专用悬浮种衣剂,优选由以下重量百分比的原料组成:吡虫啉8%、丙环唑1.5%、福美双10.5%,芸苔素内酯0.01%、成膜剂2%、润湿分散剂1.5%、防腐剂1.5%、填充剂8%、警戒色料1.5%,防冻剂2%、消泡剂1%,余量为水。Further, the above-mentioned suspension seed coating agent for wheat is preferably composed of the following raw materials in weight percentage: 8% imidacloprid, 1.5% propiconazole, 10.5% thiram, 0.01% brassinolide, 2% film-forming agent, Wetting and dispersing agent 1.5%, preservative 1.5%, filler 8%, warning colorant 1.5%, antifreeze 2%, defoamer 1%, and the balance is water.
具体的,所述成膜剂为阿拉伯胶、果胶、黄原胶、甲基纤维素、乙基纤维素、羧甲基纤维素钠、羟丙基纤维素和聚乙烯醇中的一种或两种以上。Specifically, the film-forming agent is one or more of gum arabic, pectin, xanthan gum, methyl cellulose, ethyl cellulose, sodium carboxymethyl cellulose, hydroxypropyl cellulose and polyvinyl alcohol Two or more.
所述润湿分散剂为芳基磺酸盐、脂肪酸聚乙二醇、十二烷基苯磺酸盐、木质素和脂肪酸乙烷加成物磷酸盐中的一种或两种以上。The wetting and dispersing agent is one or more of aryl sulfonate, fatty acid polyethylene glycol, dodecylbenzene sulfonate, lignin and fatty acid ethane adduct phosphate.
所述防腐剂为苯甲酸、苯甲醛、苯甲酸钠、山梨酸和水杨酸钠中一种或两种以上。The preservative is one or more of benzoic acid, benzaldehyde, sodium benzoate, sorbic acid and sodium salicylate.
所述警戒色料为碱性玫瑰精或碱性大红。The warning pigment is basic rhodamine or basic scarlet.
所述防冻剂为乙二醇、己二醇和尿素中的一种或两种以上。The antifreezing agent is one or more of ethylene glycol, hexanediol and urea.
所述消泡剂为有机硅类消泡剂。The defoamer is a silicone defoamer.
吡虫啉,是硝基亚甲基类内吸杀虫剂,是烟酸乙酰胆碱酯酶受体的作用体,干扰害虫运动神经系统使化学信号传递失灵,无交互抗性问题,广谱、高效、低毒、低残留,害虫不易产生抗性,对人、畜、植物和天敌安全等特点,并有触杀、胃毒和内吸等多重作用,种子处理防治小麦蚜虫,持效期长,防效显著。丙环唑,是一种具有治疗和保护双重作用的内吸性三唑类新型广谱性杀菌剂,可被根、茎、叶部吸收,并能很快地在植物株体内向上传导,防治子囊菌、担子菌和半知菌引起的病害,特别是对小麦全蚀病、白粉病、锈病、根腐病、水稻恶苗病、纹枯病、香蕉叶斑病等病害具有特效,可有效地防治大多数高等真菌引起的病害。福美双,是保护性杀菌剂,有效防治小麦黑穗病,并能促进发芽,提高出苗率。芸苔素内酯是一种促进植物生长的物质,主要功能是促进细胞分裂,提高种子活力,具有强力生根、促进生长、减轻病害缓解药害、协调营养平衡、抗旱抗寒、增强作物抗逆性等多重功能,广泛应用于农业生产,多用于叶面喷施或浸种。种衣剂中添加一定量的芸苔素内酯,通过种子包衣,能缓解苗期药害,抵御冷害,提高保苗率,在水稻和玉米拌种处理已有相关研究应用实例,而在小麦种衣剂中未见相关研究报道。Imidacloprid is a nitromethylene systemic insecticide, it is the action body of the nicotinic acid acetylcholinesterase receptor, it interferes with the motor nervous system of pests and causes chemical signal transmission failure, no cross-resistance problem, broad-spectrum, high efficiency, low Toxic, low residue, pests are not easy to develop resistance, safe for humans, livestock, plants and natural enemies, and has multiple effects such as contact killing, stomach poisoning and systemic absorption. Seed treatment to control wheat aphids, long-lasting and significant control effect . Propiconazole is a new type of systemic triazole broad-spectrum fungicide with dual functions of treatment and protection. It can be absorbed by roots, stems and leaves, and can quickly conduct upwards in plants to prevent and control Diseases caused by Ascomycetes, Basidiomycetes and Deuteromycetes, especially for wheat take-all, powdery mildew, rust, root rot, rice bakanae disease, sheath blight, banana leaf spot and other diseases, can effectively It can effectively control the diseases caused by most higher fungi. Thiram is a protective fungicide, which can effectively prevent and control wheat smut, and can promote germination and increase the emergence rate. Brassinolide is a substance that promotes plant growth. Its main function is to promote cell division, improve seed vigor, have strong rooting, promote growth, reduce diseases, relieve phytotoxicity, coordinate nutritional balance, resist drought and cold, and enhance crop resistance. It is widely used in agricultural production, mostly for foliar spraying or seed soaking. A certain amount of brassinolide is added to the seed coating agent, and through seed coating, it can alleviate the phytotoxicity at the seedling stage, resist chilling damage, and increase the rate of seedling preservation. There are no relevant research reports on seed coatings.
为促进活性组分粒子间润湿分散防止其相互凝聚,本发明所述悬浮种衣剂还包括润湿分散剂,所述润湿分散剂优选为芳基磺酸盐、脂肪酸聚乙二醇、十二烷基苯磺酸盐、木质素和脂肪酸乙烷加成物磷酸盐中的一种或两种以上。为保证有限的农药成分集中作用于种子和根部,不易脱落和飞散,减少农药在环境中的扩散以及对非靶标的接触,所述悬浮种衣剂还需要包括成膜剂。所述成膜剂既要保证所成衣膜透气、透水性好,种子正常萌发生长,又要保证所成衣膜难溶于水,衣膜内活性成分能缓慢释放,持效时间长。本发明所述成膜剂优选为阿拉伯胶、果胶、黄原胶、甲基纤维素、乙基纤维素、羧甲基纤维素钠、羟丙基纤维素和聚乙烯醇中的一种或两种以上。着色剂又称警色剂,可以提高悬浮种衣剂的使用安全,其中,所述着色剂优选为碱性玫瑰精和碱性大红中的一种或两种。为提高种衣剂低温储存的稳定性,本发明所述悬浮种衣剂还添加了防冻剂。所述防冻剂优选为苯甲酸、苯甲醛、苯甲酸钠、山梨酸和水杨酸钠中一种或两种以上。In order to promote the wetting and dispersing of active component particles and prevent them from agglomerating each other, the suspension seed coating agent of the present invention also includes a wetting and dispersing agent, and the wetting and dispersing agent is preferably aryl sulfonate, fatty acid polyethylene glycol, One or more of dodecylbenzenesulfonate, lignin and fatty acid ethane adduct phosphate. In order to ensure that the limited pesticide components are concentrated on the seeds and roots, not easy to fall off and scatter, and reduce the diffusion of pesticides in the environment and contact with non-targets, the suspended seed coating agent also needs to include a film-forming agent. The film-forming agent should not only ensure that the film has good air permeability and water permeability, and the seeds will germinate and grow normally, but also ensure that the film is insoluble in water, and the active ingredients in the film can be released slowly and have a long lasting effect. The film-forming agent of the present invention is preferably one or more of gum arabic, pectin, xanthan gum, methylcellulose, ethylcellulose, sodium carboxymethylcellulose, hydroxypropylcellulose and polyvinyl alcohol Two or more. The coloring agent is also called a color warning agent, which can improve the safety of the suspended seed coating agent, wherein the coloring agent is preferably one or both of rhodamine and basic scarlet. In order to improve the stability of the seed coating agent in low-temperature storage, antifreezing agents are added to the suspension seed coating agent of the present invention. The antifreezing agent is preferably one or more of benzoic acid, benzaldehyde, sodium benzoate, sorbic acid and sodium salicylate.
本发明所述悬浮种衣剂采用本领域常规方法制备即可,如:按比例取各原料,将水加热至50-80℃,搅拌加入成膜剂和警戒色料,完全溶解后获得成膜溶剂;再向该成膜溶剂中加入吡虫啉、丙环唑、福美双,芸苔素内酯、润湿分散剂、防腐剂、填充剂、防冻剂和消泡剂后,送入砂磨机或剪切机研磨剪切,直至悬浮液的颗粒细度达到2-3μm,即得产品。在实际用药过程中,本发明可根据当地防治对象发生情况确定所述悬浮种衣剂的适宜用量,通常可按种衣剂与种子的重量比为1:50-60使用。本发明所制备的悬浮种衣剂为枚红色可流动的悬浮液,低温、热贮稳定性合格,热贮分解率小于5 %,悬浮率大于90 %,湿筛试验98%通过45μm标准筛,颗粒细度为2-3μm。The suspension seed coating agent of the present invention can be prepared by conventional methods in the field, such as: take each raw material in proportion, heat water to 50-80°C, stir and add film-forming agent and warning colorant, and obtain film-forming solvent after completely dissolving ; Add imidacloprid, propiconazole, thiram in this film-forming solvent again, after brassinolide, wetting and dispersing agent, preservative, filler, antifreeze and defoamer, send into sand mill or shear The cutting machine grinds and shears until the particle fineness of the suspension reaches 2-3 μm, and the product is obtained. In the actual medication process, the present invention can determine the appropriate amount of the suspended seed coating agent according to the occurrence of local control objects, and usually can be used according to the weight ratio of the seed coating agent to the seeds at 1:50-60. The suspended seed coating agent prepared by the present invention is a red flowable suspension, low temperature, heat storage stability is qualified, heat storage decomposition rate is less than 5%, suspension rate is greater than 90%, wet sieve test 98% passes through a 45 μm standard sieve, The particle size is 2-3μm.
不同的种衣剂活性组分混合后各活性成分由于组成、结构、理化性质的差异,使得各活性成分之间的联合作用通常表示为增效作用、相加作用或拮抗作用。所谓增效作用就是不同物质间的相互协作作用,其产生的效果大于各个成分效果的总合;而相加作用就是其产生的效果等于各个成分效果的总合;拮抗作用是指两种物质作用于生物机体时,一种物质干扰另一种物质的效果,或彼此互相干扰对方的效果,使总体效果下降的现象。本发明按照孙云沛(Sim Y-P)法,计算共毒系数,评价吡虫啉、丙环唑与福美双及植物生长调节剂芸苔素内酯的混用效果,结果显示共毒系数均大于100,表明各组分之间的混合使用具有明显增效作用。此外,本发明分别对所述悬浮种衣剂以及各悬浮种衣剂中各活性成分单剂进行了病害防治试验,并且悬浮种衣剂中各活性成分用量小于单剂用量,结果显示:本发明所述悬浮种衣剂的防效比单剂的防效高,表明本发明所述悬浮种衣剂中各活性成分无交叉抗性,防治效果具有增效作用。由以上技术方案可知:本发明所述悬浮种衣剂以吡虫啉、丙环唑、福美双和芸苔素内酯复配作为有效成分,四者优势互补,可以扩大药剂的防病谱,同时提高药效,提高安全系数,一次用药可防治多种病虫害,降低了农药的使用量和使用种类、次数,能够广泛应用于农业领域。Due to the differences in composition, structure, and physical and chemical properties of the active components of different seed coating agents after mixing, the joint effect between the active components is usually expressed as synergistic effect, additive effect or antagonistic effect. The so-called synergistic effect is the mutual cooperation between different substances, and the effect produced is greater than the sum of the effects of each component; the additive effect is that the effect produced is equal to the sum of the effects of each component; antagonism refers to the effect of two substances. In biological organisms, one substance interferes with the effect of another substance, or interferes with each other's effects, reducing the overall effect. According to the Sun Yunpei (Sim Y-P) method, the present invention calculates the co-toxicity coefficient and evaluates the mixed effect of imidacloprid, propiconazole and thiram and the plant growth regulator brassinolide. The results show that the co-toxicity coefficients are all greater than 100, indicating that each group The mixed use between the parts has obvious synergistic effect. In addition, the present invention has carried out the disease control test on the suspension seed coating agent and each active ingredient in each suspension seed coating agent respectively, and the dosage of each active ingredient in the suspension seed coating agent is less than the single dosage. The results show that: the present invention The control effect of the suspended seed coating agent is higher than that of a single agent, indicating that each active ingredient in the suspended seed coating agent of the present invention has no cross resistance, and the control effect has a synergistic effect. It can be seen from the above technical scheme that the suspension seed coating agent of the present invention is compounded with imidacloprid, propiconazole, thiram and brassinolide as active ingredients, and the advantages of the four are complementary, which can expand the disease prevention spectrum of the medicament and simultaneously improve the The efficacy of the drug improves the safety factor, and a single application can prevent and control a variety of diseases and insect pests, reducing the amount, type and frequency of use of pesticides, and can be widely used in the agricultural field.
本发明的种衣剂适用于小麦种子的包衣,手工包衣或机械包衣均可,按照种衣剂与种子的重量比为1:50~60 的比例直接使用。本发明种衣剂可以有效防治小麦纹枯病、全蚀病、蚜虫及地下害虫,并能提高出苗率,促根壮苗,调节小麦生长发育,增强小麦抗逆性,提高产量。The seed coating agent of the present invention is suitable for coating wheat seeds, either manually or mechanically, and can be used directly according to the weight ratio of the seed coating agent to seeds being 1:50-60. The seed coating agent of the invention can effectively prevent and control wheat sheath blight, take-all, aphids and underground pests, and can increase emergence rate, promote roots and seedlings, regulate wheat growth and development, enhance wheat stress resistance, and increase yield.
和现有技术相比,本发明的有益效果:Compared with prior art, the beneficial effect of the present invention:
本发明悬浮种衣剂以吡虫啉、丙环唑、福美双和芸苔素内酯复配作为有效成分,四者优势互补,通过播前包衣处理可有效综合防治小麦全蚀病、纹枯病、黑穗病、小麦蚜虫及苗期地下害虫,降低小麦生产中农药使用量和使用种类、次数,减少污染,并提高小麦产量和品质,具有良好的经济效益和生态效益,能够广泛应用于农业推广。The suspension seed coating agent of the present invention uses imidacloprid, propiconazole, thiram and brassinolide compound as active ingredients, and the advantages of the four are complementary, and the coating treatment before sowing can effectively prevent and control wheat take-all and sheath blight , smut, wheat aphids and underground pests at the seedling stage, reduce the amount, type and frequency of pesticide use in wheat production, reduce pollution, and improve wheat yield and quality. It has good economic and ecological benefits and can be widely used in agriculture promote.
具体实施方式detailed description
为了进一步理解本发明,下面结合实施例对本发明提供的一种悬浮种衣剂进行详细说明。In order to further understand the present invention, a suspension seed coating agent provided by the present invention will be described in detail below in conjunction with the examples.
实施例1Example 1
一种小麦专用悬浮种衣剂,其由以下重量百分比的原料组成:吡虫啉8%、丙环唑1.5%、福美双10.5%,芸苔素内酯0.01%、成膜剂2%、润湿分散剂1.5%、防腐剂1.5%、填充剂8%、警戒色料1.5%,防冻剂2%、消泡剂1%,余量为水;所述成膜剂为羧甲基纤维素钠,所述润湿分散剂为十二烷基苯磺酸盐,所述防腐剂为苯甲酸钠,所述警戒色料为碱性大红,所述防冻剂为乙二醇,所述消泡剂为有机硅类消泡剂。A special suspension seed coating agent for wheat, which is composed of the following raw materials in percentage by weight: 8% imidacloprid, 1.5% propiconazole, 10.5% thiram, 0.01% brassinolide, 2% film-forming agent, wetting and dispersing 1.5% preservative, 1.5% preservative, 8% filler, 1.5% warning colorant, 2% antifreeze, 1% defoamer, and the balance is water; the film-forming agent is sodium carboxymethyl cellulose, and the The wetting and dispersing agent is dodecylbenzene sulfonate, the preservative is sodium benzoate, the warning colorant is basic scarlet, the antifreeze is ethylene glycol, and the defoamer is silicone defoamer. foaming agent.
实施例2Example 2
一种小麦专用悬浮种衣剂,其由以下重量百分比的原料组成:吡虫啉10%、丙环唑1%、福美双8%,芸苔素内酯0.03%、成膜剂1%、润湿分散剂1%、防腐剂1.5%、填充剂6%、警戒色料1.5%,防冻剂3%、消泡剂0.6%,余量为水;所述成膜剂为羟丙基纤维素,所述润湿分散剂为芳基磺酸盐,所述防腐剂为山梨酸,所述警戒色料为碱性大红,所述防冻剂为尿素,所述消泡剂为有机硅类消泡剂。A special suspension seed coating agent for wheat, which is composed of the following raw materials in percentage by weight: 10% imidacloprid, 1% propiconazole, 8% thiram, 0.03% brassinolide, 1% film-forming agent, wetting and dispersing 1% preservative, 1.5% preservative, 6% filler, 1.5% warning colorant, 3% antifreeze, 0.6% defoamer, and the balance is water; the film-forming agent is hydroxypropyl cellulose, and the moisturizer The wet dispersant is aryl sulfonate, the preservative is sorbic acid, the warning colorant is basic scarlet, the antifreeze is urea, and the defoamer is an organosilicon defoamer.
实施例3Example 3
一种小麦专用悬浮种衣剂,其由以下重量百分比的原料组成:吡虫啉6%、丙环唑2.5%、福美双12%,芸苔素内酯0.08%、成膜剂2.5%、润湿分散剂2.5%、防腐剂1.5%、填充剂10%、警戒色料1.5%,防冻剂4%、消泡剂1%,余量为水;所述成膜剂为聚乙烯醇,所述润湿分散剂为木质素,所述防腐剂为山梨酸,所述警戒色料为碱性大红,所述防冻剂为尿素,所述消泡剂为有机硅类消泡剂。A special suspension seed coating agent for wheat, which is composed of the following raw materials in weight percentage: 6% imidacloprid, 2.5% propiconazole, 12% thiram, 0.08% brassinolide, 2.5% film-forming agent, wetting and dispersing 2.5% preservative, 1.5% preservative, 10% filler, 1.5% warning colorant, 4% antifreeze, 1% defoamer, and the balance is water; the film-forming agent is polyvinyl alcohol, and the wetting and dispersing The preservative is lignin, the preservative is sorbic acid, the warning colorant is basic scarlet, the antifreeze is urea, and the defoamer is a silicone defoamer.
上述各实施例所述悬浮种衣剂采用下述常规方法制备:按比例取各原料,将水加热至65℃,搅拌加入成膜剂和警戒色料,完全溶解后获得成膜溶剂;再向该成膜溶剂中加入吡虫啉、丙环唑、福美双,芸苔素内酯、润湿分散剂、防腐剂、填充剂、防冻剂和消泡剂后,送入砂磨机内研磨混合,直至悬浮液的颗粒细度达到2-3μm,即得产品。The suspension seed coating agent described in each of the above embodiments is prepared by the following conventional method: take each raw material in proportion, heat the water to 65° C., stir and add the film-forming agent and warning colorant, and obtain the film-forming solvent after completely dissolving; After adding imidacloprid, propiconazole, thiram, brassinolide, wetting and dispersing agent, preservative, filler, antifreeze and defoamer into the film-forming solvent, send it into the sand mill for grinding and mixing until suspended The particle fineness of the liquid reaches 2-3 μm, and the product is obtained.
本发明公开了一种悬浮种衣剂。本领域技术人员可以借鉴本文内容,适当改进工艺参数实现。需要特别指出的是:所有类似的替换和改动对本领域技术人员来说是显而易见的,它们都被视为包括在本发明内。本发明的产品已经通过较佳实施例进行了描述,相关人员能在明显不脱离本发明内容、精神和范围内对本文所述的产品进行改动或适当变更与组合,来实现和应用本发明技术。The invention discloses a suspension seed coating agent. Those skilled in the art can refer to the content of this article to appropriately improve the process parameters to achieve. It should be pointed out that all similar substitutions and modifications are obvious to those skilled in the art, and they are all considered to be included in the present invention. The product of the present invention has been described through preferred embodiments, and relevant personnel can make changes or appropriate changes and combinations to the product described herein without departing from the content, spirit and scope of the present invention to realize and apply the technology of the present invention .
以下以实施例1所述小麦专用悬浮种衣剂进行相关小麦效果试验。Carry out relevant wheat effect test with the special suspension seed coating agent for wheat described in Example 1 below.
效果实例病虫害防效试验Effect example Pest control effect test
1、材料和方法1. Materials and methods
1.1 试验药剂1.1 Test drug
供试药剂:本发明小麦专用悬浮种衣剂Test agent: special suspension seed coating agent for wheat of the present invention
对照药剂:Comparative drug:
(1) 600克/升吡虫啉悬浮种衣剂 拜耳(中国)作物科学有限公司(1) 600 g/L Imidacloprid Suspended Seed Coating Agent Bayer (China) Crop Science Co., Ltd.
(2) 250克/升丙环唑乳油 瑞士先正达作物保护有限公司(2) 250 g/L propiconazole EC Swiss Syngenta Crop Protection Co., Ltd.
(3) 14%甲·戊·福美双悬浮种衣剂 河南开封市种衣剂厂(3) 14% A·E·Thiram double-suspension seed coating agent Henan Kaifeng Seed Coating Agent Factory
品种:小麦,郑麦7698Variety: Wheat, Zhengmai 7698
防治对象:小麦蚜虫,苗期地下害虫,小麦纹枯病,全蚀病Control objects: wheat aphids, seedling underground pests, wheat sheath blight, take-all
1.2 试验地点1.2 Test location
河南省农业科学院试验地Experimental Site of Henan Academy of Agricultural Sciences
1.3 栽培条件1.3 Cultivation conditions
试验地地势平坦,土壤类型为两合土,土壤肥力均匀一致,土壤pH值为7左右,前茬作物为玉米。播种前亩施小麦专用复合肥50公斤;10 月10 日播种,精播机条播,基本苗15万/亩。各小区栽培管理条件一致,田间管理方法与生产上相同,防治地下害虫方面未采取其它措施。The terrain of the test site is flat, the soil type is mixed soil, the soil fertility is uniform, the soil pH value is about 7, and the previous crop is corn. Before sowing, 50 kg of special compound fertilizer for wheat should be applied per mu; on October 10, the seedlings should be drilled with precision seeders, and the basic seedlings should be 150,000 per mu. The cultivation and management conditions of each plot are the same, the field management method is the same as that of production, and no other measures have been taken to prevent and control underground pests.
1.4 试验处理1.4 Test treatment
本试验共6 个处理:There are 6 treatments in this experiment:
1、本发明的小麦专用悬浮种衣剂,药种比1:50 包衣;1. The special suspension seed coating agent for wheat of the present invention is coated with a drug-to-species ratio of 1:50;
2、本发明的小麦专用悬浮种衣剂,药种比1:60 包衣;2. The special suspension seed coating agent for wheat of the present invention is coated with a drug-to-species ratio of 1:60;
3、600克/升吡虫啉悬浮种衣剂,药种比1:200包衣;3. 600 g/L imidacloprid suspension seed coating agent, coating with a drug-to-species ratio of 1:200;
4、250克/升丙环唑乳油,按推荐剂量稀释拌种;4. 250 g/L propiconazole emulsifiable concentrate, diluted according to the recommended dose for seed dressing;
5、14%甲·戊·福美双悬浮种衣剂,药种比1:50包衣;5. 14% A·E·Thiram double-suspension seed coating agent, coating with a drug-to-species ratio of 1:50;
6、空白对照(ck),不施任何药剂。6. Blank control (ck), without any medicine.
1.5 试验设计1.5 Experimental design
本试验采用随机区组设计,4 次重复,小区面积30m2(10m×3m)。This experiment adopts randomized block design with 4 repetitions, and the plot area is 30m 2 (10m×3m).
1.5 试验方法1.5 Test method
1.5.1 拌种方法1.5.1 Seed dressing method
各处理按药种比例称好后放入塑料袋内,握紧袋口,使袋内充满空气,充分摇动,直至种子包衣均匀,晾干后拌种。Each treatment is weighed according to the proportion of the drug species and put into a plastic bag, hold the mouth of the bag tightly so that the bag is filled with air, shake it fully until the seeds are evenly coated, and then dry and then dress the seeds.
1.5.2 播种方法1.5.2 Seeding method
试验于10 月10 日播种,精播机条播,播量为基本苗15 万/亩。The experiment was sown on October 10, drilled with a precision seeder, and the sowing rate was 150,000 basic seedlings/mu.
1.6 调查方法1.6 Survey method
1.6.1 发芽势及发芽率调查1.6.1 Germination potential and germination rate survey
每处理单独选取100 粒种子,在室内进行发芽试验,调查发芽势及发芽率。100 seeds were selected for each treatment, and germination tests were carried out indoors to investigate the germination potential and germination rate.
1.6.2 药害调查1.6.2 Investigation of Phytotoxicity
出苗后至生育期结束,随时注意观察小麦生长情况及是否有药害发生。After emergence to the end of the growth period, pay attention to observe the growth of wheat and whether there is phytotoxicity at any time.
1.6.3 苗期地下害虫调查1.6.3 Investigation of underground pests at seedling stage
在小麦3叶期,进行地下害虫调查。每小区随机调查3个1米双行的样段,凡是被蝼蛄、蛴螬、金针虫或地老虎等地下害虫咬伤或咬死的麦苗均为虫伤苗,记录虫伤苗数,计算虫伤苗率及防治效果。In the 3-leaf stage of wheat, the investigation of underground pests was carried out. Randomly investigate three 1-meter double-row samples in each plot. All wheat seedlings bitten or killed by underground pests such as mole crickets, grubs, needleworms or cutworms are insect-injured seedlings. Record the number of insect-injured seedlings and calculate insect damage Seedling rate and control effect.
1.6.4 纹枯病调查1.6.4 Investigation of sheath blight
在2月中旬每小区随机抽取3个1米双行的样段调查纹枯病发病情况,记录病株数及总株数,计算发病率及防治效果。In mid-February, three 1-meter double-row samples were randomly selected from each plot to investigate the incidence of sheath blight, the number of diseased plants and the total number of plants were recorded, and the incidence rate and control effect were calculated.
1.6.5 全蚀病调查1.6.5 Take-all disease survey
采用对角线5点取样法调查,分别于小麦返青期和孕穗期调查小麦全蚀病发生情况。进入翌年5月份,间隔15d调查小麦根部和穗部表现症状,成熟期随时观察病情发展,及时记载发病情况。Using the diagonal 5-point sampling method to investigate the occurrence of wheat take-all at the turning green stage and booting stage respectively. In May of the next year, investigate the symptoms of wheat roots and ears at intervals of 15 days, observe the development of the disease at any time during the mature stage, and record the disease in time.
1.6.6 蚜虫调查1.6.6 Aphid survey
沿小区对角线5点取样,每点20株,定点定株调查整株上的活蚜数。由于从播种至翌年3月下旬小麦田麦蚜发生量极少,于3月份27日开始调查,每15天调查1次,共调查4次,计算百株蚜量和防治效果。Sampling was done at 5 points along the diagonal of the plot, 20 plants at each point, and the number of live aphids on the whole plant was investigated at fixed points. Since the occurrence of wheat aphids in wheat fields was very small from sowing to late March of the following year, the survey was started on March 27, once every 15 days, and a total of 4 surveys were conducted to calculate the number of aphids in 100 plants and the control effect.
防治效果=(空白对照区蚜虫数-处理区蚜虫数)/空白对照区蚜虫数×100%Control effect = (the number of aphids in the blank control area - the number of aphids in the treatment area) / the number of aphids in the blank control area × 100%
1.6.7 产量测定1.6.7 Yield determination
用小区收割机全区收获,晾干后各小区分别称重,计算产量及增产率。Harvest the whole area with a plot harvester, weigh each plot after drying, and calculate the yield and yield increase rate.
2.试验结果2. Test results
2.1 室内发芽试验结果(表1)2.1 Results of indoor germination test (Table 1)
本发明的小麦用悬浮种衣剂各处理对小麦发芽势和发芽率均无不良影响(表1),并能提高出苗率,促进苗齐、苗壮。Each treatment of the suspension seed coating agent for wheat of the present invention has no adverse effect on the germination potential and germination rate of wheat (Table 1), and can increase the emergence rate and promote the uniformity and robustness of seedlings.
2.2 药害情况2.2 Phytotoxicity
经观察,在小麦生长的整个生育期内,本发明的小麦用悬浮种衣剂对小麦出苗和生长无不良影响,未见药害发生。It is observed that during the whole growth period of wheat growth, the suspended seed coating agent for wheat of the present invention has no adverse effect on wheat seedling emergence and growth, and no phytotoxicity occurs.
2.3 对小麦地下害虫的防治效果(表2)2.3 Control effect on wheat underground pests (Table 2)
从表2 可以看出,试验中本发明的小麦用悬浮种衣剂以药种比为1:50、1:60包衣拌种,两处理对地下害虫的平均防效分别为85.21%、74.09%,使用剂量增加,防效随之提高。在1:50 剂量下,其防效略高于600g/升吡虫啉悬浮种衣剂对地下害虫的防效(80.77%);在1:60 剂量下,其防效略高于14%甲·戊·福美双悬浮种衣剂对地下害虫的防效(71.24%)。由此可知,在1:50-60 范围内,本发明的小麦用悬浮种衣剂对地下害虫具有良好的防效。As can be seen from Table 2, in the test, the suspended seed coating agent for wheat of the present invention is 1:50, 1:60 for coating seed dressing with the drug type ratio, and the average control effects of the two treatments on subterranean pests are 85.21%, 74.09%, respectively. %, the dosage increases, and the control effect increases accordingly. At the dose of 1:50, its control effect is slightly higher than that of 600g/L imidacloprid suspension seed coating against subterranean pests (80.77%); at the dose of 1:60, its control effect is slightly higher than that of 14% A·V ·The control effect of thiram double-suspended seed coating on underground pests (71.24%). It can be seen that, within the range of 1:50-60, the suspension seed coating agent for wheat of the present invention has a good control effect on underground pests.
2.5 对小麦纹枯病的防治效果(表3)2.5 Control effect on wheat sheath blight (Table 3)
结果表明,本发明的小麦用悬浮种衣剂在药种比为1:50、1:60 情况下,各处理对纹枯病的平均防效分别为89.72%、84.71%,随着使用剂量的增加,防效相应有所提高。在1:50 剂量下,其防效略高于250克/升丙环唑乳油对纹枯病的防效(86.42%);在1:60 剂量下,其防效高于14%甲·戊·福美双悬浮种衣剂(83.26%)。由此可以看出:以药种比1:50-60包衣,本发明的小麦用悬浮种衣剂对纹枯病具有良好的防效。The results show that the suspension seed coating agent for wheat of the present invention is 1:50, 1:60 under the situation of drug species ratio, each treatment is respectively 89.72%, 84.71% to the average control effect of sheath blight, with the increase of dosage increase, the control effect is correspondingly improved. At a dose of 1:50, its control effect is slightly higher than that of 250 g/L propiconazole EC against sheath blight (86.42%); at a dose of 1:60, its control effect is higher than that of 14% A·V ·Thiram double-suspension seed coating (83.26%). It can be seen that the suspension seed coating agent for wheat of the present invention has a good control effect on sheath blight with a drug-to-species ratio of 1:50-60.
2.7 对全蚀病的防效(表4)2.7 Control effect on take-all disease (Table 4)
调查结果显示, 5月13日空白对照区及处理3区出现少量次生根病株,5月17日处理2、处理4、处理5出现病株;5月18日处理1出现病株;5月23日,各处理区均出现不同程度次生根黑根病状,处理3及空白对照区偏重。从调查结果看:各处理对全蚀病均有一定的防治效果,其中,处理1(本发明的小麦悬浮种衣剂1:50包衣)防效最好,平均防效达到63.96%,其次为处理4(250克/升丙环唑乳油),防效为63.47%,处理2(本发明的小麦悬浮种衣剂1:60包衣)和处理5(14%甲·戊·福美双悬浮种衣剂)对全蚀病的平均防效分别为57.38%和61.28%。可见,本发明的小麦用悬浮种衣剂对全蚀病防效突出,随包衣剂量增加,防效相应提高。The survey results showed that a small number of secondary rooting diseased plants appeared in the blank control area and treatment area 3 on May 13, and diseased plants appeared in treatment 2, treatment 4, and treatment 5 on May 17; diseased plants appeared in treatment 1 on May 18; On the 23rd, secondary roots and black roots appeared in different degrees in each treatment area, and the treatment 3 and blank control areas were more severe. From the results of the investigation: each treatment has a certain control effect on take-all, and wherein, treatment 1 (wheat suspension seed coating agent 1:50 coating of the present invention) has the best control effect, and the average control effect reaches 63.96%, followed by For treatment 4 (250 g/L propiconazole emulsifiable concentrate), the control effect is 63.47%, treatment 2 (coating of wheat suspension seed coating agent 1:60 of the present invention) and treatment 5 (14% formazan thiram double suspension Seed coating agent) on the average control effect of take-all were 57.38% and 61.28%. It can be seen that the suspension seed coating agent for wheat of the present invention has outstanding control effect on take-all, and the control effect increases correspondingly with the increase of coating dosage.
2.8 对蚜虫的防效(表5)2.8 Control effect on aphids (Table 5)
由试验结果得知,处理1(本发明的小麦悬浮种衣剂1:50包衣)、处理2(本发明的小麦悬浮种衣剂1:60包衣)、处理3(600g/升吡虫啉悬浮种衣剂)对小麦蚜虫的控制均表现出长达7个月的持效期,且前中后期均表现出较高防效。在麦蚜整个发生时期,或者说在小麦整个发育期,吡虫啉包衣拌种可以基本上控制蚜虫的发生危害,具有持久性和高效性。采用本发明小麦用悬浮种衣剂以播前以药种1:50-60的方式施药,能够减少污染,保护天敌,具有良好的经济效益和生态效益。Known from test result, process 1 (wheat suspension seed coating agent 1:50 coating of the present invention), process 2 (wheat suspension seed coating agent 1:60 coating of the present invention), process 3 (600g/liter imidacloprid suspension Seed coating agent) showed a long-lasting effect of up to 7 months in the control of wheat aphids, and showed high control effects in the early, middle and late stages. During the entire occurrence period of wheat aphids, or in other words, during the entire development period of wheat, imidacloprid-coated seed dressing can basically control the occurrence and damage of aphids, and has persistence and high efficiency. The suspension seed coating agent for wheat of the present invention is applied in the manner of 1:50-60 of medicine seeds before sowing, which can reduce pollution, protect natural enemies, and has good economic and ecological benefits.
2.7 对小麦产量的影响2.7 Effects on Wheat Yield
表6的试验结果显示,各药剂处理对小麦产量均具有增产增收的效果,以本发明的小麦用悬浮种衣剂1:50包衣处理增产效果最为显著,高达18.26%,其次为本发明的小麦用悬浮种衣剂1:60包衣处理,为15.20%。The test result of table 6 shows, each medicament treatment all has the effect of increasing production and income to wheat output, with the suspension seed coating agent 1:50 coating process of wheat of the present invention increases production effect most significantly, up to 18.26%, followed by the present invention's The wheat was treated with the suspension seed coating agent 1:60, which was 15.20%.
3 结论3 Conclusion
3.1 本发明的小麦用悬浮种衣剂对小麦的发芽、出苗和生长均无不良影响。3.1 The suspension seed coating agent for wheat of the present invention has no adverse effects on the germination, emergence and growth of wheat.
3.2 本发明的小麦用悬浮种衣剂在药种比为1:50、1:60情况下,对地下害虫的平均防效分别为85.21%、74.09%,对纹枯病的平均防效分别为89.72%、84.71%,对小麦全蚀病的平均防效分别为63.96%、57.38%,并可有效控制小麦整个生育期内的蚜虫。同时,又能促根壮苗,促进分蘖,调节生长发育,增强小麦抗逆性,提高产量和品质。3.2 When the suspension seed coating agent for wheat of the present invention is 1:50 and 1:60, the average control effects on underground pests are 85.21% and 74.09%, respectively, and the average control effects on sheath blight are respectively 89.72%, 84.71%, the average control effect on wheat take-all is 63.96%, 57.38%, and can effectively control aphids throughout the growth period of wheat. At the same time, it can promote roots and seedlings, promote tillering, regulate growth and development, enhance wheat stress resistance, and improve yield and quality.
鉴于近年来我国小麦病虫害的综合发生,需要环保高效新型杀虫剂和杀菌剂复配使用,才能达到更好的防病治虫的效果,而本发明正是有效的将杀虫剂和杀菌剂以及植物生长调节剂复配,通过播前包衣,减轻蚜虫、纹枯病、全蚀病等多种病虫害的发病程度,减少田间打药次数,在当前农村打工经济发展,农村以妇女、老人为主要劳动力的形势下,该产品有广阔的推广应用前景。In view of the comprehensive occurrence of wheat diseases and insect pests in my country in recent years, it is necessary to use environmentally friendly and efficient new insecticides and fungicides in combination to achieve better effects of disease prevention and pest control. The plant growth regulator is compounded, and the incidence of various diseases and insect pests such as aphids, sheath blight, and take-all can be reduced by coating before sowing, and the number of spraying in the field can be reduced. In the current rural economic development, women and the elderly are the mainstays in rural areas. Under the situation of the labor force, the product has broad prospects for promotion and application.
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