CN104745028A - Waterborne acrylic paint and preparation method thereof - Google Patents
Waterborne acrylic paint and preparation method thereof Download PDFInfo
- Publication number
- CN104745028A CN104745028A CN201510137181.7A CN201510137181A CN104745028A CN 104745028 A CN104745028 A CN 104745028A CN 201510137181 A CN201510137181 A CN 201510137181A CN 104745028 A CN104745028 A CN 104745028A
- Authority
- CN
- China
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- parts
- acrylic acid
- water soluble
- soluble acrylic
- water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003973 paint Substances 0.000 title claims abstract description 38
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- -1 alcohol ester Chemical class 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- 239000013556 antirust agent Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 239000003960 organic solvent Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000012855 volatile organic compound Substances 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 206010019233 Headaches Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 208000002040 neurosyphilis Diseases 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a waterborne acrylic paint. The waterborne acrylic paint comprises the following components in parts by weight: 40-65 parts of acrylic resin, 3-6 parts of disperser, 1-2 parts of wetting agent, 10-20 parts of film forming agent, 1-5 parts of preservative, 0.5-1.5 parts of defoamer, 2-6 parts of thickening agent, 10-25 parts of filler and 30-40 parts of water. Compared with the prior art, the waterborne acrylic paint provided by the invention is strong in adhesive force and particularly high in adhesive force on a metal base material, free of organic solvent, low in VOC content,d excellent in chemical resistance and pollution resistance, nontoxic without organic solvent volatilization in the storing and using process, low in environment pollution and meets the environment protection requirement, has good compatibility with the other paint and has good curing speed. The preparation method of the waterborne acrylic paint provided by the invention is simple, easy for realization of industrialization and low in cost.
Description
Technical field
What the present invention relates to is a kind of aqueous priming paint and preparation method thereof, particularly relates to a kind of water soluble acrylic acid paint and preparation method thereof, as a kind of rust-inhibiting paint, can have excellent antirust function.
Background technology
Oxygen in iron and air, water vapour generation chemical reaction generates ferric oxide, iron rust is except the murder by poisoning to human body, iron rust also can corroding metal, strengthen intermetallic friction, lower the efficiency of mechanical movement, in order to extend the work-ing life of metal or metal machinery, people will do corresponding antirust treatment to it, usual technique means smears rust-inhibiting paint in metallic surface, but after chemical paint paint spraying, its meeting constantly volatile organic compound (VOC) and episome (TDI), not only ozone pollution is produced to the Nature, but also people can be made to cause headache, the malaise symptoms such as general paralysis.
Coating Water-borne modification is protection of the environment and the common prescription saving petroleum resources; maximum feature take water as primary solvent; substitute the dimethylbenzene in conventional oil coatings volatile organic compounds and solvent wet goods; both cost was reduced; the environmental pollution avoiding again organic solvent to volatilize causing and the injury to human body; also there is fire prevention simultaneously, be easy to the advantages such as transport storage; processing is simple; the floating rust of metallic surface need only be gone out during brushing; can directly construct having under water and a small amount of greasy dirt condition, be a kind of extremely promising green environmental friendly coatings.Along with industrial expansion, more and more higher to the requirement of water-miscible paint, cause increasing water-miscible paint not meet service requirements, be mainly manifested in that sticking power is inadequate, rate of drying is slow, water-fast poor solvent resistance, VOC discharge capacity are high.
Summary of the invention
The object of the present invention is to provide a kind of water soluble acrylic acid paint, low-carbon (LC), environmental protection, and have excellent sticking power, rate of drying is fast, the features such as chemical resistance is good.
The present invention is achieved through the following technical solutions:
A kind of water soluble acrylic acid paint, concrete component and part by weight are:
As preferably, also comprise the water-based antirust agent of 2-5 part.N-9000Chassis Clear (water base) product of DAIZO Co., Ltd. of what wherein water-based antirust agent adopted is Japan.
Particularly, described dispersion agent is 2040 dispersion agents, and described wetting agent is 2035 wetting agents, and described sanitas is mica powder, and described defoamer is AMP-95, and described thickening material is Natvosol.In order to better realize the present invention, described 2040 dispersion agents are 2040 type dispersion agents of Guangzhou Cheng Bian Chemical Industry Science Co., Ltd, and described 2035 wetting agents are that high WK-2035 type wetting agent is tieed up in Nanjing, and described defoamer is the AMP-95 type defoamer of LG-DOW.
As preferably, described membrane-forming agent is propylene glycol and/or alcohol ester 12.
As preferably, described filler is titanium dioxide and/or barium sulfate.
A preparation method for above-mentioned water soluble acrylic acid paint, comprises the steps:
1) by acrylic resin, dispersion agent, wetting agent, sanitas, defoamer, filler and 50% water join in agitator, start shooting stirs said components under the rotating speed of 400-600r/min;
2) by membrane-forming agent and thickening material with 50% water latting drown and stir, then slowly add above solution, stir well 10-15 minute in 400-600r/min speed, obtain water soluble acrylic acid paint.
The invention has the beneficial effects as follows: compared with prior art, tool has the following advantages and beneficial effect a kind of water soluble acrylic acid paint provided by the invention:
(1) water soluble acrylic acid paint strong adhesion of the present invention, particularly for the sticking power of metal base;
(2) water soluble acrylic acid paint of the present invention is not containing organic solvent, and VOC content is low, and has excellent chemical resistance and anti-fouling performance
(3) water-miscible paint is nontoxic, and do not have the volatilization of organic solvent in storage, use procedure, environmental pollution is little, meets environmental requirement;
(4) water soluble acrylic acid paint of the present invention and other consistencies of painting good, and curing speed is fast;
(5) a kind of water soluble acrylic acid paint of the present invention preparation method is simply easy to industrialization, cost is low.
Embodiment
The present invention is further detailed explanation now, but embodiments of the present invention are not limited to this.
Specific embodiment 1-5 is in Table 1-1.
Table 1-1:
A preparation method for above-mentioned water soluble acrylic acid paint, comprises the steps:
1) raw material of corresponding weight is taken according to aforementioned proportion, for subsequent use;
2) at normal temperatures and pressures, by acrylic resin, dispersion agent, wetting agent, sanitas, defoamer, filler and 50% water join in agitator, start shooting stirs said components under the rotating speed of 400-600r/min;
3) by membrane-forming agent and thickening material with 50% water latting drown and stir, then slowly add above solution, stir well 10-15 minute in 400-600r/min speed, obtain water soluble acrylic acid paint.
During use, only need add water soluble acrylic acid paint and water by weight the ratio for 1:0.3-0.4, stir, leave standstill to bubble collapse and can use.
Product test data of the present invention are in Table 1-2.
Table 1-2: water-miscible paint is test result after tinplate surface cure film forming
Can be drawn by above data, water soluble acrylic acid paint of the present invention has good sticking power, chemical resistant properties and mechanical property, and VOC content is very low, within reaching 100g/L, and applied range, practical; Meanwhile, this water soluble acrylic acid does not condense, and has good consistency; Curing speed is fast, and production efficiency is high; Applied per area amount is few, and energy consumption is low, can significantly reduce costs.
The water soluble acrylic acid paint of the embodiment of the present invention 5 is entrusted: company limited of middle ring associating (Beijing) authentication center carries out environmental labelling product certification, and its survey report is in Table 1-3:
Table 1-3:
Note 1: detect and be limited to: benzene 40mg/kg, toluene 40mg/kg, dimethylbenzene 50mg/kg, ethylbenzene 40mg/kg
Note 2: detect and be limited to: 0.3mg/kg
Note 3: detect and be limited to: 0.3mg/kg
Note 4: detect and be limited to: 0.01mg/kg
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.
Claims (6)
1. a water soluble acrylic acid paint, concrete component and part by weight are:
2. a kind of water soluble acrylic acid paint as claimed in claim 1, is characterized in that: the water-based antirust agent also comprising 2-5 part.
3. a kind of water soluble acrylic acid paint as claimed in claim 1 or 2, it is characterized in that: described dispersion agent is 2040 dispersion agents, described wetting agent is 2035 wetting agents, and described sanitas is mica powder, described defoamer is AMP-95, and described thickening material is Natvosol.
4. a kind of water soluble acrylic acid paint as claimed in claim 1 or 2, is characterized in that: described membrane-forming agent is propylene glycol and/or alcohol ester 12.
5. a kind of water soluble acrylic acid paint as claimed in claim 1 or 2, is characterized in that: described filler is titanium dioxide and/or barium sulfate.
6. a preparation method for the water soluble acrylic acid paint as described in any one of claim 1-5, comprises the steps:
1) by acrylic resin, dispersion agent, wetting agent, sanitas, defoamer, filler and 50% water join in agitator, start shooting stirs said components under the rotating speed of 400-600r/min;
2) by membrane-forming agent and thickening material with 50% water latting drown and stir, then slowly add above solution, stir well 10-15 minute in 400-600r/min speed, obtain water soluble acrylic acid paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510137181.7A CN104745028A (en) | 2015-03-26 | 2015-03-26 | Waterborne acrylic paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510137181.7A CN104745028A (en) | 2015-03-26 | 2015-03-26 | Waterborne acrylic paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104745028A true CN104745028A (en) | 2015-07-01 |
Family
ID=53585315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510137181.7A Pending CN104745028A (en) | 2015-03-26 | 2015-03-26 | Waterborne acrylic paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104745028A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106380961A (en) * | 2016-08-30 | 2017-02-08 | 惠州市湾厦表面处理技术有限公司 | Eco-friendly low-odor waterborne acrylic acid paint and preparation method thereof |
| CN107011711A (en) * | 2017-04-27 | 2017-08-04 | 哈尔滨绿科科技有限公司 | A kind of environment-friendly water-based metallic paint and preparation method thereof |
| CN107216738A (en) * | 2016-03-21 | 2017-09-29 | 台州市黄岩铭志装饰材料有限公司 | A kind of water soluble acrylic acid paint and preparation method thereof |
| CN110358400A (en) * | 2019-07-23 | 2019-10-22 | 上海工程技术大学 | A kind of aqueous quick-drying coil steel coating and preparation method thereof based on monodisperse polyacrylic resin |
| CN110373075A (en) * | 2019-07-11 | 2019-10-25 | 广州集泰化工股份有限公司 | Mending paint and preparation method thereof outside a kind of container water soluble acrylic acid |
Citations (5)
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|---|---|---|---|---|
| CN1125752A (en) * | 1994-12-26 | 1996-07-03 | 费县普利机械有限公司 | Water-base propenoic acid antirust paint and its preparation method |
| EP0971007A1 (en) * | 1998-06-23 | 2000-01-12 | Hans Peter Dkfm. Gros | In a thick layer coatable paint and process of its preparation |
| CN1626591A (en) * | 2003-12-12 | 2005-06-15 | 上海石化博蓝涂装材料有限公司 | Aqueous antirust paint |
| CN103468077A (en) * | 2013-09-23 | 2013-12-25 | 江苏华夏制漆科技有限公司 | Water-based antirust paint for steel structure as well as production method thereof |
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-
2015
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| Title |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216738A (en) * | 2016-03-21 | 2017-09-29 | 台州市黄岩铭志装饰材料有限公司 | A kind of water soluble acrylic acid paint and preparation method thereof |
| CN106380961A (en) * | 2016-08-30 | 2017-02-08 | 惠州市湾厦表面处理技术有限公司 | Eco-friendly low-odor waterborne acrylic acid paint and preparation method thereof |
| CN107011711A (en) * | 2017-04-27 | 2017-08-04 | 哈尔滨绿科科技有限公司 | A kind of environment-friendly water-based metallic paint and preparation method thereof |
| CN110373075A (en) * | 2019-07-11 | 2019-10-25 | 广州集泰化工股份有限公司 | Mending paint and preparation method thereof outside a kind of container water soluble acrylic acid |
| CN110358400A (en) * | 2019-07-23 | 2019-10-22 | 上海工程技术大学 | A kind of aqueous quick-drying coil steel coating and preparation method thereof based on monodisperse polyacrylic resin |
| CN110358400B (en) * | 2019-07-23 | 2021-04-09 | 上海工程技术大学 | A kind of water-based quick-drying steel coil coating based on monodisperse polyacrylic resin and preparation method thereof |
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