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CN104689718B - Dielectrophoresis butterfly tube type membrane component - Google Patents

Dielectrophoresis butterfly tube type membrane component Download PDF

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Publication number
CN104689718B
CN104689718B CN201510068382.6A CN201510068382A CN104689718B CN 104689718 B CN104689718 B CN 104689718B CN 201510068382 A CN201510068382 A CN 201510068382A CN 104689718 B CN104689718 B CN 104689718B
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CN
China
Prior art keywords
dielectrophoresis
disc
flow guiding
end cover
binding post
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201510068382.6A
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Chinese (zh)
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CN104689718A (en
Inventor
王冰
郑贵堃
盛晓颖
胡海霞
靳治国
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INNER MONGOLIA TIANYI ENVIRONMENTAL TECHNOLOGY Co Ltd
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INNER MONGOLIA TIANYI ENVIRONMENTAL TECHNOLOGY Co Ltd
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Priority to CN201510068382.6A priority Critical patent/CN104689718B/en
Publication of CN104689718A publication Critical patent/CN104689718A/en
Application granted granted Critical
Publication of CN104689718B publication Critical patent/CN104689718B/en
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Abstract

The invention relates to a dielectrophoresis butterfly tube type membrane component. A power supply end cover, a plurality of diversion discs and a water inlet end cover are overlapped in sequence; a central pull rod is fixed in the centers of the components in a penetration mounting manner; a pressure-resistant shell is fixedly mounted outside the power supply end cover and the water inlet end cover in a sealing manner; a raw water channel is formed between the peripheries of the diversion discs and the pressure-resistant shell; a filtering channel is formed in the middle of each diversion disc; a generated water channel is formed between the centers of the diversion discs and the central pull rod; butterfly type membrane bags are arranged between every two adjacent diversion discs in an overlapped manner; electrode plates are mounted inside the overlapped membrane bags; binding posts are mounted inside the inner ends of the electrode plates; every two adjacent electrode plates form a fork electrode; a raw water inlet which is communicated with the raw water channel is formed in the water inlet end cover; a generated water outlet which is communicated with the generated water channel and a concentrated water outlet which is communicated with the filtering channel are formed in the water inlet end cover. Due to adoption of a dielectrophoresis technique, the purposes that concentration polarization is reduced, membrane pollution is prevented, the service life of membranes are prolonged, the electroosmosis effect is achieved, the filtering effect of the membranes is improved, the water generation amount of the membranes is increased and the energy consumption can be reduced are achieved.

Description

A kind of dielectrophoresis dish tubular membrane component
Technical field
The present invention relates to dish tubular membrane segregation apparatus, particularly to a kind of dielectrophoresis dish tubular membrane group Part.
Background technology
Dish tubular membrane component is developed for landfill leachate treatment, and 1988 in German Government Under support, RECHEM company research and develop successfully.Compare with other membrane modules, dish tubular membrane component There is the obvious feature of three below:
Channel width: the passage between diaphragm is 6mm, and the membrane module of rolling encapsulation only has 0.2mm.
Flow process is short: the liquid only 7cm of the flow process on film surface, and the membrane module of rolling encapsulation is 100cm.
Turbulent flow row: due to the effect of high pressure, percolate is formed at a high speed after getting to the salient point on flow guiding disc Turbulent flow, under the washing away of this turbulent flow, film surface not free settling pollutant.Film group in rolling encapsulation In part, network can retain pollutant, causes inner lead thus brings the pollution of diaphragm.
In theory, dish tubular membrane component can tolerate higher float and SDI, it is to avoid fouling and Other fouling membrane, thus extend the diaphragm life-span.But it is dense due to water inlet pollutant in actual motion Degree height, for avoiding fouling membrane, needs to reduce former hardness of water, adds chemical agent simultaneously and avoid film The film surface scale that the concentration polarization phenomenon on surface causes.And it is the osmotic pressure overcoming high-concentration waste water Power, it is thus achieved that higher aquifer yield, needs higher operating pressure.High operating pressure and quantifying greatly Learn the use of medicament, add the operating cost of dish tubular membrane element.
Summary of the invention
It is an object of the invention to be to overcome the deficiencies in the prior art, it is provided that a kind of dielectrophoresis dish pipe Formula membrane module, this assembly uses dielectrophoresis technology can be decreased or even eliminated in membrane filtration process and sends out Raw fouling and scaling phenomenon, reaches to reduce concentration polarization, prevents the pollution of film, extends film Service life, formation electroosmotic effect, the filter effect of reinforcing membrane, the raising aquifer yield of film, reduction The target of energy consumption.
The present invention solves its technical problem and is achieved through the following technical solutions:
A kind of dielectrophoresis dish tubular membrane component, it is characterised in that: main by pressure casing, power supply End cap, intake end cover, flow guiding disc, disc-type film bag, battery lead plate and center pull rod composition, power supply End cap, multiple flow guiding disc and intake end cover stack successively, and use center pull rod to install in the middle Fixing, pressure casing seals and is installed in outside power supply end cap and intake end cover, and flow guiding disc periphery is with pressure Form former aquaporin between shell, in the middle part of flow guiding disc, form filtration channel, flow guiding disc Center-to-Center Being formed between pull bar and produce aquaporin, closed assembly disc-type film bag between adjacent two flow guiding discs, at lamination The internally installed battery lead plate of formula film bag, battery lead plate the inner is mounted on binding post, two adjacent electrode plates shapes Become interdigital electrode;Intake end cover is shaped with the original water inlet connected with former aquaporin, and intake end cover is also made Have and produce the product water out that aquaporin connects and the dense water out connected with filtration channel.
And, it is shaped with binding post installing hole outside the centre bore of described battery lead plate, pacifies with binding post Dress hole opposite side is shaped with binding post and dodges hole, and two battery lead plates forming interdigital electrode are symmetrically placed, Installing described binding post in the binding post installing hole of battery lead plate, thus battery lead plate forms side wiring Post forms positive terminal after being connected with each other;Opposite side binding post forms negative terminal after being connected with each other Post.
And, described binding post is Y connection post, the binding post of homonymy can mutual plug-in mounting, electricity Source cover internal leaves insulated power supplies wire casing, and is provided with power connection installing hole.
And, described battery lead plate uses stamped metal sheets to form, surface is evenly distributed with equidistantly, Contour pyramidal projections and through-hole structure, this projection and through-hole spacing are 2~6mm.
And, described battery lead plate thickness is 0.1~2mm, and battery lead plate is circular or octagon, Described battery lead plate is shaped with hole, location.
And, described disc-type film bag is formed by two disc-type diaphragm outer rim welded seals, video disc Shi Modai center is shaped with product water out.
And, disc-type diaphragm is the one in reverse osmosis membrane, NF membrane, ultrafilter membrane or micro-filtration membrane.
And, described flow guiding disc surface is uniformly distributed cylindrical projections, and flow guiding disc integral thickness is 5~8mm;Described flow guiding disc center and outward flange are all shaped with location structure.
And, it is provided with insulating liner between power supply end cap and flow guiding disc.
And, pressure casing is cylindric pressure-bearing shell, and material can be rustless steel, fiberglass or work Engineering plastics;Described power supply end cap, intake end cover, center pull rod material are engineering plastics, aluminium alloy Or rustless steel, preferably rustless steel;Described flow guiding disc uses engineering plastics to make, and material includes ABS, Polypropylene or UPVC.
Advantages of the present invention and having the beneficial effect that
1, this dielectrophoresis dish tubular membrane component, according to Jie of solid particle Yu its liquid suspended The difference of electric polarization ability, solid particle is pushed away electrode by dielectrophoresis force, thus slows down and even keeps away Exempt from Flat Membrane separating technology because water is existing to producing the concentration polarization caused water liquid side from material liquid effluent As, to reach the purpose that reinforced film filters.
2, this dielectrophoresis dish tubular membrane component, while the normal work keeping membrane filtration process, Additional material such as chemical agent need not be added, generation is decreased or even eliminated in membrane filtration process Fouling and scaling phenomenon, it is possible to slow down the concentration polarization even avoiding occurring in membrane filtration process, Meanwhile, improve membrane lifetime and membrane flux, reduce and eliminate energy that membrane pollution problem consumed and become This.
3, this dielectrophoresis dish tubular membrane component, applies dielectrophoresis force in the solid closing on film surface Granule and moved apart permeable membrane surface thus reached to prevent fouling and scaling, improve film transit dose, Slow down and even avoid concentration polarization, the work efficiency with prolonging service lifetime of film and improving film and product water Amount.
4, this dielectrophoresis dish tubular membrane component, uses dielectrophoresis technology, under electric field action, During solid, liquid contact, solid particle surface can produce electric charge, and these surface charges affect molten in turn Ion distribution in liquid, forms electric double layer, forms electroosmotic effect, and hydrone laterally produces from material liquid Water side migrates, and increases film transit dose, to reach reinforced film filtering technique.
5, this dielectrophoresis dish tubular membrane component, is formed plate type electrode by symmetrically arranged battery lead plate, Electrode plate surface is evenly distributed with contour pyramidal projections and through-hole structure, and two panels battery lead plate can coordinate Use and form interdigitated electrode structure;It is shaped with binding post installing hole outside the centre bore of battery lead plate, and connects Terminal installing hole opposite side is shaped with binding post and dodges hole, and two battery lead plates forming interdigital electrode are right Claiming to place, install described binding post in the binding post installing hole of battery lead plate, thus battery lead plate is formed Side binding post forms positive terminal after being connected with each other;Opposite side binding post is formed after being connected with each other Negative terminal;And, described binding post is Y connection post, and the binding post of homonymy can be mutual Plug-in mounting, battery lead plate binding post structure design science is reasonable, it is easy to install and safety and stability.
6, this dielectrophoresis dish tubular membrane component, uses dielectrophoresis technology, under electric field action, Dielectrophoresis force produces thrust to solid particle in water, can be with reinforcing membrane to solid particle in water Filter effect, improve the filtration grade of film, it is thus achieved that preferably produce water water quality.
7, this dielectrophoresis dish tubular membrane component, is interrupted and applies dielectrophoresis, can eliminate fouling membrane Problem, and energy consumption is low, running cost is low.
8, this dielectrophoresis dish tubular membrane component, scientific structure design is reasonable, uses dielectrophoresis skill Art can be decreased or even eliminated in membrane filtration process the fouling and scaling phenomenon occurred, and reaches to reduce Concentration polarization, prevent film pollution, extend film service life, formed electroosmotic effect, reinforcing membrane Filter effect, improve film aquifer yield, reduce energy consumption target.
Accompanying drawing explanation
Fig. 1 is the front view (without pressure casing) of the present invention;
Fig. 2 is that the A-A of Fig. 1 is to cross-sectional view;
Fig. 3 is the B portion enlarged drawing of Fig. 2;
Fig. 4 is the C portion enlarged drawing of Fig. 3;
Fig. 5 is the structural representation of battery lead plate;
The flow guiding disc structural representation that Fig. 6 is;
Fig. 7 is operation principle schematic diagram of the present invention.
Description of reference numerals
The upper locknut of 1-center pull rod, 2-, 3-upper jacket, 4-power connection installing hole, 5-power supply end cap, Under 6-flow guiding disc, 7-intake end cover, the dense water out of 8-, 9-lower jacket, 10-, locknut, the former water of 11-enter Mouth, 12-pressure casing, 13-power supply wire casing, 14-binding post, 15-produce water out, 16-disc-type film Positioning convex, 21-outside bag, 17-battery lead plate, 18-pyramidal projections, 19-binding post installing hole, 20- Cylindrical projections, 22-dodge hole, 23-filtration channel, 24-notch, 25-produces aquaporin, 26-produces water Hole is dodged in outlet, the former aquaporin of 27-, 28-binding post, 29-positions hole, the latticed flow-guiding cloth of 30-.
Detailed description of the invention
Below by specific embodiment, the invention will be further described, and following example simply describe Property, it not determinate, it is impossible to limit protection scope of the present invention with this.
A kind of dielectrophoresis dish tubular membrane component, its mainly by pressure casing 12, power supply end cap 5, Intake end cover 7, flow guiding disc 6, disc-type film bag 16, battery lead plate 17 and center pull rod 1 are constituted. Power supply end cap, multiple flow guiding disc and intake end cover stack successively, and use center pull rod in the middle Installing fixing, power end upper part of the cover center pull rod is set with upper jacket 3, upper jacket top is installed Locknut 2.It is set with lower jacket 9 in the center pull rod of intake end cover bottom, and lower locknut 10 is installed.Electricity It is provided with insulating liner, it is ensured that exhausted between battery lead plate and power supply end cap between source lid and flow guiding disc Edge.
Pressure casing seal be installed in outside power supply end cap and intake end cover, flow guiding disc periphery with pressure outside Form former aquaporin 27 between shell, in the middle part of flow guiding disc, be shaped with notch 24, to form filtration channel 23, Formed between flow guiding disc Center-to-Center pull bar and produce aquaporin 25, closed assembly between adjacent two flow guiding discs Disc-type film bag, does not contacts between disc-type film bag and upper and lower flow guiding disc, forms filtration channel. At the stacked internally installed battery lead plate of film bag.Battery lead plate is shaped with binding post installing hole 19, with binding post Installing hole opposite side is shaped with binding post and dodges hole 28, and two battery lead plates forming interdigital electrode are symmetry Placing, install binding post 14 in the binding post installing hole of battery lead plate, thus battery lead plate forms side Binding post forms positive terminal after being connected with each other;Opposite side binding post forms negative pole after being connected with each other Binding post.Binding post is Y connection post, and the binding post of homonymy can mutually plug-in mounting, convenient installation. Power supply cover internal leaves insulated power supplies wire casing 13, and is provided with power connection installing hole 4.Biphase Adjacent battery lead plate forms interdigital electrode;Intake end cover is shaped with the original water inlet 11 connected with former aquaporin, Intake end cover is also shaped with the dense water out 8 connected with filtration channel, and the product water connected with product aquaporin Outlet 15.Produce water out and be formed on lower jacket sidewall.
Battery lead plate uses stamped metal sheets to form, and surface is evenly distributed with equidistant, contour taper Projection 18 and through-hole structure, this projection and through-hole spacing are 2~6mm.Battery lead plate thickness is 0.1~2mm, preferably 0.5mm, battery lead plate is circular or octagon.Battery lead plate is shaped with location Hole 29.
Disc-type film bag is formed by two disc-type diaphragm outer rim welded seals, disc-type Mo Dai center system There is product water out 26.Disc-type diaphragm is in reverse osmosis membrane, NF membrane, ultrafilter membrane or micro-filtration membrane A kind of
Flow guiding disc surface is uniformly distributed cylindrical projections 21, and flow guiding disc integral thickness is 5~8mm, relatively Good for 7mm;Periphery, flow guiding disc center is shaped with dodges hole 22.Flow guiding disc center is shaped with location structure, Flow guiding disc outward flange is all shaped with outside positioning convex 20.Latticed flow-guiding cloth is installed in periphery, flow guiding disc center 30。
Pressure casing is cylindric pressure-bearing shell, and material can be rustless steel, fiberglass or engineering plastics; Described power supply end cap, intake end cover, center pull rod material are engineering plastics, aluminium alloy or rustless steel, Preferably rustless steel;Flow guiding disc uses engineering plastics to make, and material includes ABS, polypropylene or UPVC。
The work process of the present invention is:
Feed liquid enters in pressure casing by the former water inlet of intake end cover, from flow guiding disc with pressure Former aquaporin between shell flows to the other end of assembly, enters flow guiding disc at the other end by passage In filtration channel, processed liquid flows fast through a side form of disc-type film bag with the shortest distance Face, then 180 ° of another faces reversing disc-type film bag, then from the notch stream at flow guiding disc center Enter to next flow guiding disc, thus formed by the flow guiding disc circumference-center of circle-circumference-circle on film surface Double serpentine routes of the heart, concentrated solution finally from dense water out flow out.Produce water edge in the middle of diaphragm Latticed flow-guiding cloth flows to the product aquaporin that center pull rod is peripheral, by the product water out row of charging end cap Go out.Due to the dielectric polarization ability lower relative to water, solid particle is at Yuan Shui (material liquid) In be usually expressed as negative dielectrophoresis character;I.e. in unshapeliness electric field, solid particle is by weak Direction of an electric field moves.Former water (material liquid) is through the surface of film, and the electrode installed under film provides Unshapeliness electric field needed for dielectrophoresis force.When in former water (material liquid), solid particle is near film, I.e. when electrode, will be displaced from and fouling membrane and knot cannot be so decreased or even eliminated near film The generation of structure, slows down the concentration polarization phenomenon even avoided in membrane separation process.Due to pressure effect With formation electric double layer, hydrone laterally produces water liquid side and migrates, improves film saturating from waste water (material liquid) Excess.
Dielectrophoresis concept involved in the present invention and operation principle be:
Dielectrophoresis (Dielectrophoresis) technology has been successfully applied to biomedical work Industry separates, richness is amassed, capture microgranule and cell.What this technology described is in non-well-balanced electric field The translational motion that neutral corpuscle produces due to the effect of dielectric polarization, produces the dipole on microgranule Square can be represented by two identical carried charges but opposite polarity electric charge.When they are at particle interface During upper mal-distribution, produce a macroscopical dipole moment.When this dipole moment is positioned at unshapeliness electricity In Chang, the different of the local electric field strength on microgranule both sides produce resulting net force, referred to as a dielectrophoresis Power.Owing to the microgranule that is suspended in medium has different dielectric properties (dielectric constant) from medium, Microgranule can by or the direction of higher electric field intensity move, be referred to as positive dielectrophoresis, or The direction of more weak electric field intensity is moved, the most negative dielectrophoresis.
In membrane filtration separation liquid liquid occur separation permeable membrane pollute, be all solid particle (microgranule, Colloidal particles, solute crystalline solid, antibacterial is relative with insoluble Organic substance drop and larger molecular organics Exist in liquid.In such a system, due to solid particle and its liquid suspended The difference of dielectric polarization ability, solid particle is pushed away electrode or by solid particle by dielectrophoresis force Absorption, on electrode, shows or negative dielectrophoresis character or positive dielectrophoresis character.
Due to the dielectric polarization ability lower relative to water, solid particle generally shows in waste water For negative dielectrophoresis character;I.e. in unshapeliness electric field, solid particle is moved to weak electric field direction Dynamic.As it is shown in fig. 7, waste water (material liquid) is through the surface of film, the electrode installed under film carries For the unshapeliness electric field needed for dielectrophoresis force.When solid particle is near film, i.e. near interdigital electricity During pole, will be displaced from and cannot be near film.Fouling membrane and the generation of stifled film are so decreased or even eliminated.
As above, due to the dielectric polarization ability lower relative to water, solid particle is at waste water for principle (material liquid) is usually expressed as negative dielectrophoresis character;I.e. in unshapeliness electric field, solid Granule is moved to weak electric field direction.While water passes through film flow direction driving liquid side from material liquid side, Dielectrophoretic force solute in material liquid is moved apart and cannot near film, solute can not at film surface enrichment, So slow down and even avoid in Flat Membrane separating technology because water causes to driving liquid side from material liquid effluent Concentration polarization phenomenon, improve water transit dose.
Although disclose embodiments of the invention and accompanying drawing for the purpose of illustration, but the technology of this area Personnel are understood that without departing from the present invention and spirit and scope of the appended claims, various Replace, to change and modifications be all possible, therefore, the scope of the present invention be not limited to embodiment and Accompanying drawing disclosure of that.

Claims (9)

1. a dielectrophoresis dish tubular membrane component, it is characterised in that: mainly by pressure casing, Power supply end cap, intake end cover, flow guiding disc, disc-type film bag, battery lead plate and center pull rod composition, Power supply end cap, multiple flow guiding disc and intake end cover stack successively, and use center to draw in the middle Bar installs fixing, and pressure casing seals and is installed in outside power supply end cap and intake end cover, outside flow guiding disc Form former aquaporin between week and pressure casing, in the middle part of flow guiding disc, form filtration channel, flow guiding disc Formed between Center-to-Center pull bar and produce aquaporin, closed assembly disc-type between adjacent two flow guiding discs Film bag, at the disc-type internally installed battery lead plate of film bag, battery lead plate the inner is mounted on binding post, Two adjacent electrode plates form interdigital electrode;Intake end cover is shaped with the former water connected with former aquaporin and enters Mouthful, intake end cover is also shaped with and produces product water out that aquaporin connect and connect with filtration channel Dense water out;Binding post installing hole it is shaped with, with binding post outside the centre bore of described battery lead plate Installing hole opposite side is shaped with binding post and dodges hole, and two battery lead plates forming interdigital electrode are symmetry Placing, install described binding post in the binding post installing hole of battery lead plate, thus battery lead plate is formed Side binding post forms positive terminal after being connected with each other;Opposite side binding post is connected with each other rear shape Become negative terminal.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Described binding post is Y connection post, the mutual plug-in mounting of binding post of homonymy, power supply cover internal Leave insulated power supplies wire casing, and power connection installing hole is installed.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Described battery lead plate uses stamped metal sheets to form, and surface is evenly distributed with equidistant, contour Pyramidal projections and through-hole structure, this projection and through-hole spacing are 2~6mm.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Described battery lead plate thickness is 0.1~2mm, and battery lead plate is circular or octagon, described electricity Pole plate is shaped with hole, location.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Described disc-type film bag is formed, in disc-type film bag by two disc-type diaphragm outer rim welded seals The heart is shaped with product water out.
Dielectrophoresis dish tubular membrane component the most according to claim 5, it is characterised in that: Disc-type diaphragm is the one in reverse osmosis membrane, NF membrane, ultrafilter membrane or micro-filtration membrane.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Described flow guiding disc surface is uniformly distributed cylindrical projections, and flow guiding disc integral thickness is 5~8mm; Described flow guiding disc center and outward flange are all shaped with location structure.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: It is provided with insulating liner between power supply end cap and flow guiding disc.
Dielectrophoresis dish tubular membrane component the most according to claim 1, it is characterised in that: Pressure casing is cylindric pressure-bearing shell, and material is rustless steel, fiberglass or engineering plastics;Described Power supply end cap, intake end cover, center pull rod material are engineering plastics, aluminium alloy or rustless steel; Described flow guiding disc uses engineering plastics to make, and material includes ABS, polypropylene or UPVC.
CN201510068382.6A 2015-02-10 2015-02-10 Dielectrophoresis butterfly tube type membrane component Expired - Fee Related CN104689718B (en)

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CN106517447A (en) * 2015-09-15 2017-03-22 内蒙古天环境技术有限公司 In-line type membrane stack capable of realizing self purification
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CN106925123B (en) * 2015-12-29 2023-07-25 天津津盛远航知识产权运营管理有限公司 Dielectrophoresis electrode structure capable of emitting non-uniform electric field to outside
CN105771665A (en) * 2016-03-23 2016-07-20 内蒙古天环境技术有限公司 Disc tube type membrane component using columnar dielectrophoresis electrodes
CN105771666A (en) * 2016-04-12 2016-07-20 成都美富特膜科技有限公司 Membrane filtration assembly
CN106517257A (en) * 2016-12-02 2017-03-22 成都美富特膜科技有限公司 Lithium chloride liquid purification method and lithium chloride liquid purification equipment
CN110217856A (en) * 2019-06-01 2019-09-10 龙口市海丰环境科技工程有限公司 Butterfly water treatment system
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