CN104674205A - Phosphating agent for automobile cast aluminium alloy cylinder body - Google Patents
Phosphating agent for automobile cast aluminium alloy cylinder body Download PDFInfo
- Publication number
- CN104674205A CN104674205A CN201510072300.5A CN201510072300A CN104674205A CN 104674205 A CN104674205 A CN 104674205A CN 201510072300 A CN201510072300 A CN 201510072300A CN 104674205 A CN104674205 A CN 104674205A
- Authority
- CN
- China
- Prior art keywords
- parts
- aluminium alloy
- phosphating agent
- phosphating
- cylinder body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 16
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 12
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims abstract description 5
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019483 Peanut oil Nutrition 0.000 claims abstract description 4
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 4
- 238000000498 ball milling Methods 0.000 claims abstract description 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001981 cobalt nitrate Inorganic materials 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 229940117955 isoamyl acetate Drugs 0.000 claims abstract description 4
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000000312 peanut oil Substances 0.000 claims abstract description 4
- 235000019710 soybean protein Nutrition 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000005266 casting Methods 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 abstract description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 abstract 2
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 229940093474 manganese carbonate Drugs 0.000 abstract 1
- 235000006748 manganese carbonate Nutrition 0.000 abstract 1
- 239000011656 manganese carbonate Substances 0.000 abstract 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 abstract 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 abstract 1
- 235000003270 potassium fluoride Nutrition 0.000 abstract 1
- 239000011698 potassium fluoride Substances 0.000 abstract 1
- 238000012797 qualification Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 239000010687 lubricating oil Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical class [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/42—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a phosphating agent for an automobile cast aluminium alloy cylinder body. The phosphating agent comprises the following components in parts by weight: 50 parts of manganese phosphate, 2 parts of cobalt nitrate, 3 parts of phosphate, 3 parts of phosphotungstic acid, 5 parts of dimethyl ketoxime, 3 parts of peanut oil, 4 parts of soybean protein isolate, 1.5 parts of azelaic acid, 4 parts of isoamyl acetate, 5 parts of potassium fluoride, 2 parts of manganese carbonate, 1.5 parts of dicumyl peroxide, 5 parts of citric acid, and 80 parts of deionized water. The preparation method comprises the steps of sending each component to a ball grinder to continuously perform ball milling for 4 hours, passing a 120-mesh sieve, putting into a reaction kettle, heating to 90+/-5 DEG C, continuously stirring for 50 min at the stirring speed of 200 rpm, keeping the temperature for one hour and taking out of the reaction kettle. By adopting the phosphating agent, a phosphating film with thin crystal and strong adsorbability can be generated on the surface of the cast aluminium alloy workpiece; the quality of the phosphating film layer reaches the standard request, enough lubricants can be abdsorbed by the phosphating agent and the phosphating agent is uniformly distributed; the wear resistance, the corrosion resistance and the lubricity of the workpiece can be improved and the product qualification ratio can be increased.
Description
Technical field
The present invention relates to technical field of chemical products, be specifically related to a kind of automotive casting aluminium alloy and make cylinder body phosphorization agent.
Background technology
It is in main Phosphating Solution that iron and steel, aluminium or zinc workpiece immerse specific acid phosphate, deposits the process of one deck water-fast crystal type phosphate conversion film in its surface, is referred to as phosphatization.The classification of phosphating process has many, wherein can be divided into the type such as Zinc phosphating, Zinc-calcium series phosphatating, ferric solid-acid, manganese-series phosphorized and compound phosphatization by the composition of Phosphating Solution.Manganese phosphate coating has stronger antifriction function, generally be applied to the workpiece higher to dynamic tolerance clearance dimensional requirement, as manufactured the component such as cast aluminium alloy cylinder body and piston of automobile, its phosphatization flow process is that degreasing-washing-alkaline etching-washing-photochemical process-washing-table tune-high temperature is manganese-series phosphorized.But the component phosphorization agents used such as the cast aluminium alloy cylinder body of existing automobile and piston are conventional containing Zn
++, Mn
++, NO
3 -, N0
2 -manganese-series phosphorized dose of ion, workpiece after bonderizing, conforming product rate lower (only below 80%).The low major cause of conforming product rate is formed phosphorization membrane quality dissatisfaction (1-3g/m
2), the lubricating oil of q.s can not be adsorbed; Rete crystallization thickness is uneven simultaneously, and institute absorbs to obtain lubricating oil skewness, can not meet the requirement of workpiece wear resistance, solidity to corrosion and oilness.
Summary of the invention
It is simple that technical problem to be solved by this invention is to provide a kind of composition, and cylinder body phosphorization agent made by the automotive casting aluminium alloy that result of use is good.
Technical problem to be solved by this invention realizes by the following technical solutions.
Cylinder body phosphorization agent made by a kind of automotive casting aluminium alloy, is made up: manganous phosphate 50 parts, Jing Ti/Bao Pian COBALT NITRATE CRYSTALS/FLAKES 2 parts, phosphoric acid salt 3 parts, phospho-wolframic acid 3 parts, DMKO 5 parts, peanut oil 3 parts, soybean protein isolate 4 parts, nonane diacid 1.5 parts, Isoamyl Acetate FCC 4 parts, Potassium monofluoride 5 parts, manganous carbonate 2 parts, dicumyl peroxide 1.5 parts, citric acid 5 parts, deionized water 80 parts of the component of following parts by weight;
The preparation method of above-mentioned phosphorization agent is: each component is sent into ball mill continuous ball milling 4 hours, crosses 120 mesh sieves, and drop in reactor, be warming up to 90+5 DEG C, stirring velocity is at 200 revs/min, and continuously stirring 50 minutes, is incubated one hour, goes out still.
Beneficial effect of the present invention: instant component and preparation technology simple, raw material is easily purchased, cost is low, cast aluminium alloy workpiece surface can generate the phosphatize phosphate coat that fine crystallization, adsorptivity are extremely strong, phosphorization membrane quality reaches standard-required, the lubricating oil of adsorbable q.s and being evenly distributed, can improve the wear resistance of workpiece, solidity to corrosion and oilness, conforming product rate is improved.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
Cylinder body phosphorization agent made by a kind of automotive casting aluminium alloy, is made up: manganous phosphate 50 parts, Jing Ti/Bao Pian COBALT NITRATE CRYSTALS/FLAKES 2 parts, phosphoric acid salt 3 parts, phospho-wolframic acid 3 parts, DMKO 5 parts, peanut oil 3 parts, soybean protein isolate 4 parts, nonane diacid 1.5 parts, Isoamyl Acetate FCC 4 parts, Potassium monofluoride 5 parts, manganous carbonate 2 parts, dicumyl peroxide 1.5 parts, citric acid 5 parts, deionized water 80 parts of the component of following parts by weight;
The preparation method of above-mentioned phosphorization agent is: each component is sent into ball mill continuous ball milling 4 hours, crosses 120 mesh sieves, and drop in reactor, be warming up to 90+5 DEG C, stirring velocity is at 200 revs/min, and continuously stirring 50 minutes, is incubated one hour, goes out still.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (1)
1. cylinder body phosphorization agent made by an automotive casting aluminium alloy, it is characterized in that, be made up of the component of following parts by weight: manganous phosphate 50 parts, Jing Ti/Bao Pian COBALT NITRATE CRYSTALS/FLAKES 2 parts, phosphoric acid salt 3 parts, phospho-wolframic acid 3 parts, DMKO 5 parts, peanut oil 3 parts, soybean protein isolate 4 parts, nonane diacid 1.5 parts, Isoamyl Acetate FCC 4 parts, Potassium monofluoride 5 parts, manganous carbonate 2 parts, dicumyl peroxide 1.5 parts, citric acid 5 parts, deionized water 80 parts;
The preparation method of above-mentioned phosphorization agent is: each component is sent into ball mill continuous ball milling 4 hours, crosses 120 mesh sieves, and drop in reactor, be warming up to 90+5 DEG C, stirring velocity is at 200 revs/min, and continuously stirring 50 minutes, is incubated one hour, goes out still.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510072300.5A CN104674205A (en) | 2015-02-11 | 2015-02-11 | Phosphating agent for automobile cast aluminium alloy cylinder body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510072300.5A CN104674205A (en) | 2015-02-11 | 2015-02-11 | Phosphating agent for automobile cast aluminium alloy cylinder body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104674205A true CN104674205A (en) | 2015-06-03 |
Family
ID=53309771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510072300.5A Pending CN104674205A (en) | 2015-02-11 | 2015-02-11 | Phosphating agent for automobile cast aluminium alloy cylinder body |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104674205A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306100A (en) * | 2000-11-16 | 2001-08-01 | 华萱 | Phosphonation process for heteropoly acid system |
| CN101956191A (en) * | 2010-11-08 | 2011-01-26 | 大连三达奥克化学股份有限公司 | Manganese-based black phosphating agent for automobile casting aluminum alloy cylinder body and piston and manufacturing method |
| CN102719819A (en) * | 2011-03-30 | 2012-10-10 | 重庆市荣时金属表面处理剂有限公司 | General phosphating agent |
| CN102953055A (en) * | 2012-11-07 | 2013-03-06 | 长沙沃尔金属表面技术有限公司 | Black phosphating liquid and use method thereof |
-
2015
- 2015-02-11 CN CN201510072300.5A patent/CN104674205A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306100A (en) * | 2000-11-16 | 2001-08-01 | 华萱 | Phosphonation process for heteropoly acid system |
| CN101956191A (en) * | 2010-11-08 | 2011-01-26 | 大连三达奥克化学股份有限公司 | Manganese-based black phosphating agent for automobile casting aluminum alloy cylinder body and piston and manufacturing method |
| CN102719819A (en) * | 2011-03-30 | 2012-10-10 | 重庆市荣时金属表面处理剂有限公司 | General phosphating agent |
| CN102953055A (en) * | 2012-11-07 | 2013-03-06 | 长沙沃尔金属表面技术有限公司 | Black phosphating liquid and use method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨立会 等: ""常温磷化液工艺改进"", 《腐蚀与保护》 * |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150603 |
|
| RJ01 | Rejection of invention patent application after publication |