CN104673253A - Research on components of novel automotive anti-freeze fluid - Google Patents
Research on components of novel automotive anti-freeze fluid Download PDFInfo
- Publication number
- CN104673253A CN104673253A CN201310638890.4A CN201310638890A CN104673253A CN 104673253 A CN104673253 A CN 104673253A CN 201310638890 A CN201310638890 A CN 201310638890A CN 104673253 A CN104673253 A CN 104673253A
- Authority
- CN
- China
- Prior art keywords
- glycerol
- deicing fluid
- water
- corrosion inhibitor
- freeze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 18
- 230000002528 anti-freeze Effects 0.000 title abstract description 8
- 108010053481 Antifreeze Proteins Proteins 0.000 title abstract 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000005260 corrosion Methods 0.000 claims abstract description 14
- 230000007797 corrosion Effects 0.000 claims abstract description 14
- 239000003112 inhibitor Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 6
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical group C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims description 5
- WDHYRUBXLGOLKR-UHFFFAOYSA-N phosphoric acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OP(O)(O)=O WDHYRUBXLGOLKR-UHFFFAOYSA-N 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 claims description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- XTOQOJJNGPEPMM-UHFFFAOYSA-N o-(2-oxo-1,3,2$l^{5}-dioxaphosphinan-2-yl)hydroxylamine Chemical compound NOP1(=O)OCCCO1 XTOQOJJNGPEPMM-UHFFFAOYSA-N 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002455 scale inhibitor Substances 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention aims at providing a novel automotive anti-freeze fluid. The novel automotive anti-freeze fluid is prepared from the following components: water, glycerin, a corrosion inhibitor, potassium permanganate, an antioxidant, a corrosion and scale inhibitor and an antifoaming agent at the weight percent ratio of 100 to (90-150) to (0.05-0.25) to (0.1-0.4) to (0.2-0.45) to (0.2-1.2) to (1.0-1.5). The novel automotive anti-freeze fluid has the effects of being high in stability, not easy to volatilize, high in anti-freeze property, anti-rust property and fouling resistance, and does not block a pipeline.
Description
Technical field
The present invention is specifically related to a kind of deicing fluid of motor car engine, belongs to chemicals field.
Background of invention
The research of the deicing fluid such as motor car engine, has the history of more than 70 year so far from the thirties, and so far the method for various countries to preparation deicing fluid is still among research at present.Automobile antifreeze solution is generally take alcohols as main component, auxiliary with related auxiliaries, formulated, it is the liquid that a kind of freezing point is lower, can not freeze at low temperatures, there is good mobility, heats a large amount of in engine operation process can be taken away thus ensure engine can low temperature environment normal operation, the composition of current deicing fluid is mainly with methyl alcohol, ethanol and glycerol and calcium chloride are main, but found that with methyl alcohol and ethanol time boiling point and flash-point all too low, volatile, lose larger, thermostability and antifreeze energy are also poor, and calcium chloride easily precipitates.Therefore, choose the preparation that suitable frostproofer carries out deicing fluid more and more to receive publicity.
The present invention is different from other deicing fluid, and with glycerol, water, corrosion inhibitor, antioxidant, anti-incrustation corrosion inhibitor and defoamer composition, antifreezing effect is good.
Summary of the invention
The object of the present invention is to provide a kind of deicing fluid of motor car engine.
In order to achieve the above object, this invention takes following technical scheme:
Technical scheme of the present invention is as follows:
A kind of preparation relating to automobile antifreezing liquid system, it is characterized in that: be made up of glycerol, water, corrosion inhibitor, antioxidant, anti-incrustation corrosion inhibitor and defoamer, made the corresponding automobile engine winterization fluid that can obtain the present invention relates to by the above main ingredient through specialized processes.Wherein:
Described water is preferably from least one in distilled water, deionized water, pure water.
Described glycerol is 1,2-glycerol or 1,3-glycerol.
Described corrosion inhibitor is preferably mercaptobenzothiazole.
Described antioxidant preferably from: one of butylated hydroxytoluene, Tenox PG, Resorcinol, p-ten.-butylcatechol or combination.
Described anti-incrustation corrosion inhibitor is preferably from organic phosphates: one of carboxyl ethylene phosphoric acid, aminotrimethylene phosphoric acid or combination.
Defoamer preferably from: defoamer preferably from one of polyether-modified silicon, organo-siloxane, polyethers or combination.
In formula, the weight ratio of each component is as follows: water: glycerol: corrosion inhibitor: potassium permanganate: antioxidant: anti-incrustation corrosion inhibitor: defoamer is 100:(90-150): (0.05-0.25): (0.1-0.4): (0.2-0.45): (0.2-1.2): (1.0-1.5)
Advantage of the present invention and effect are: stability is high, not volatile, not blocking pipe, and antifreeze, antirust, ant-scaling high.
Embodiment
Below in conjunction with embodiment, the present invention is described further, but is not limited only to this.
Embodiment 1:
Raw material and proportioning:
Water: 110kg, glycerol: 140kg: mercaptobenzothiazole 0.2kg, potassium permanganate: 0.2kg, p-ten.-butylcatechol 0.35kg, carboxyl ethylene phosphatase 11 .0kg, organo-siloxane: 0.8kg
Preparation method:
Press formula ratio respectively, successively by after water, glycerol, mercaptobenzothiazole, potassium permanganate, p-ten.-butylcatechol, carboxyl ethylene phosphoric acid, organo-siloxane mix and blend 2-4h, can automobile freeze-proof liquid be obtained.
Embodiment 2:
Raw material and proportioning:
Water: 100kg, glycerol: 120kg: mercaptobenzothiazole 0.25kg, potassium permanganate: 0.3kg, p-ten.-butylcatechol 0.3kg, carboxyl ethylene phosphoric acid 0.8kg, organo-siloxane: 1.0kg
Concrete preparation method is with embodiment 1.
Above-described embodiment is only and clearly the invention example is described, and the restriction not to the invention embodiment.For those of ordinary skill in the field, other multi-form change and variations can also be made on the basis of the above description.Here exhaustive without the need to also giving all embodiments.
Claims (7)
1. an automobile freeze-proof liquid, is characterized in that: with water: glycerol: corrosion inhibitor: potassium permanganate: antioxidant: anti-incrustation corrosion inhibitor: defoamer is 100:(90-150): (0.05-0.25): (0.1-0.4): (0.2-0.45): (0.2-1.2): (1.0-1.5).
2. deicing fluid as claimed in claim 1, described water is preferably from least one in distilled water, deionized water, pure water.
3. deicing fluid as claimed in claim 1, described glycerol is 1,2-glycerol or 1,3-glycerol.
4. deicing fluid as claimed in claim 1, described corrosion inhibitor is preferably mercaptobenzothiazole.
5. deicing fluid as claimed in claim 1, described antioxidant is preferably from one of butylated hydroxytoluene, Tenox PG, Resorcinol, p-ten.-butylcatechol or combination.
6. deicing fluid as claimed in claim 1, described anti-incrustation corrosion inhibitor is preferably from organic phosphates: one of carboxyl ethylene phosphoric acid, aminotrimethylene phosphoric acid or combination.
7. deicing fluid as claimed in claim 1, defoamer is preferably from one of polyether-modified silicon, organo-siloxane, polyethers or combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310638890.4A CN104673253A (en) | 2013-12-03 | 2013-12-03 | Research on components of novel automotive anti-freeze fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310638890.4A CN104673253A (en) | 2013-12-03 | 2013-12-03 | Research on components of novel automotive anti-freeze fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104673253A true CN104673253A (en) | 2015-06-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310638890.4A Pending CN104673253A (en) | 2013-12-03 | 2013-12-03 | Research on components of novel automotive anti-freeze fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104673253A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108018027A (en) * | 2017-12-13 | 2018-05-11 | 安徽江淮航天技术开发有限公司 | Organic environmental-protection liquid heat-conducting medium |
| CN108219758A (en) * | 2018-01-29 | 2018-06-29 | 广州顺爽汽车科技有限公司 | The anhydrous noncongeable oil of superconduction and its application |
| CN109689834A (en) * | 2016-06-24 | 2019-04-26 | 丰田自动车株式会社 | Coolant composition, and the method for operation internal combustion engine is concentrated in automobile engine coolant composition, automobile engine |
| CN112662382A (en) * | 2019-10-16 | 2021-04-16 | 中国石油化工股份有限公司 | Data center heat conduction working medium |
-
2013
- 2013-12-03 CN CN201310638890.4A patent/CN104673253A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109689834A (en) * | 2016-06-24 | 2019-04-26 | 丰田自动车株式会社 | Coolant composition, and the method for operation internal combustion engine is concentrated in automobile engine coolant composition, automobile engine |
| CN109689834B (en) * | 2016-06-24 | 2021-04-16 | 丰田自动车株式会社 | Automotive engine coolant composition, automotive engine concentrated coolant composition, and method of operating an internal combustion engine |
| CN108018027A (en) * | 2017-12-13 | 2018-05-11 | 安徽江淮航天技术开发有限公司 | Organic environmental-protection liquid heat-conducting medium |
| CN108219758A (en) * | 2018-01-29 | 2018-06-29 | 广州顺爽汽车科技有限公司 | The anhydrous noncongeable oil of superconduction and its application |
| CN112662382A (en) * | 2019-10-16 | 2021-04-16 | 中国石油化工股份有限公司 | Data center heat conduction working medium |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150603 |