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CN104671614B - A kind of phosphorous treatment method of printing and dying wastewater and device - Google Patents

A kind of phosphorous treatment method of printing and dying wastewater and device Download PDF

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CN104671614B
CN104671614B CN201510096021.2A CN201510096021A CN104671614B CN 104671614 B CN104671614 B CN 104671614B CN 201510096021 A CN201510096021 A CN 201510096021A CN 104671614 B CN104671614 B CN 104671614B
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CN104671614A (en
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王莉
万玉山
王晟斌
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Pizhou Borui Investment Management Co ltd
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Changzhou University
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Abstract

The present invention relates to a kind of phosphorous treatment method of printing and dying wastewater and device, comprise wastewater equalization pond, decolouring dephosphorization pond, anoxic anaerobic reation pool, biochemical contact tank, second pond; Decolouring dephosphorization pond comprises mix and blend district and settling region, and anoxic anaerobic reation pool comprises the double oxygen section, anoxic section and the anaerobism section that are separated into by traverse baffle; Biochemical contact tank is provided with water inlet pipe, water distribution pyrometric cone, filler and aeration regulator control system; Waste water through equalizing tank regulating pondage and water quality, then enter decolouring dephosphorization pond, then enter anoxic anaerobic reation pool, biochemical contact tank carries out anoxic, anaerobic and aerobic reaction, qualified discharge after precipitation.

Description

一种含磷印染废水处理方法与装置A method and device for treating phosphorus-containing printing and dyeing wastewater

技术领域technical field

本发明涉及废水处理技术领域,具体涉及一种含磷印染废水处理方法与装置。The invention relates to the technical field of wastewater treatment, in particular to a method and device for treating phosphorus-containing printing and dyeing wastewater.

背景技术Background technique

印染行业是工业废水的排放大户,印染废水中具有色度高、盐含量高、成份复杂、可生化性差、脱色困难等特点,难以采用常规的方法进行治理,同时染整过程中使用表面活性剂造成印染废水中磷的浓度较高,含磷印染废水成为工业废水处理的难题。The printing and dyeing industry is a large discharge of industrial wastewater. The printing and dyeing wastewater has the characteristics of high chroma, high salt content, complex components, poor biodegradability, and difficult decolorization. It is difficult to use conventional methods to treat it. At the same time, surfactants are used in the dyeing and finishing process As a result, the concentration of phosphorus in printing and dyeing wastewater is high, and phosphorus-containing printing and dyeing wastewater has become a difficult problem for industrial wastewater treatment.

在传统的印染废水处理工艺中,色度、BOD5、COD、SS、N-NH3、TN这些指标均能达到国家指标,但总磷常常达不到排放标准,因此探究含磷印染废水的处理技术具有重要的现实意义。In the traditional printing and dyeing wastewater treatment process, the indicators of chroma, BOD 5 , COD, SS, N-NH 3 , and TN can all meet the national indicators, but the total phosphorus often fails to meet the discharge standards. Processing technology has important practical significance.

发明内容Contents of the invention

本发明要解决的技术问题是:为了解决上述含磷印染废水处理中的难题,本发明提供一种含磷印染废水处理方法与装置。The technical problem to be solved by the present invention is: in order to solve the above problems in the treatment of phosphorus-containing printing and dyeing wastewater, the present invention provides a method and device for treating phosphorus-containing printing and dyeing wastewater.

本发明解决其技术问题所采用的技术方案是:一种含磷印染废水处理方法与装置,包括废水调节池、脱色除磷池、缺氧厌氧反应池、生化接触池、二沉池;所述废水调节池、脱色除磷池、缺氧厌氧反应池、生化接触池、二沉池依次连通。The technical solution adopted by the present invention to solve the technical problem is: a method and device for treating phosphorus-containing printing and dyeing wastewater, including a wastewater adjustment tank, a decolorization and phosphorus removal tank, an anoxic anaerobic reaction tank, a biochemical contact tank, and a secondary sedimentation tank; The wastewater regulating pool, the decolorization and phosphorus removal pool, the anoxic anaerobic reaction pool, the biochemical contact pool, and the secondary sedimentation pool are connected in sequence.

所述废水调节池包括废水调节池进水管、pH值测控系统和出水管,用于调节含磷印染废水的pH值、水质和水量。The wastewater regulating tank includes an inlet pipe of the wastewater regulating tank, a pH value measurement and control system and an outlet pipe for adjusting the pH value, water quality and water volume of phosphorus-containing printing and dyeing wastewater.

所述的脱色除磷池包括混合搅拌区和沉淀区,混合搅拌区底部设有脱色除磷池进水管,中上部设有用于添加脱色除磷剂的药液添加系统,在搅拌区中部设置有搅拌装置;所述沉淀区内设有挡板,该挡板与脱色除磷池的内壁形成作为废水进入沉淀区的废水流道,沉淀区的出口处设有三相分离器,沉淀区的出口上部设有溢水堰,沉淀区底部设计成锥形结构,在沉淀区底部设置有沉淀物排放阀。The decolorization and phosphorus removal pool includes a mixing and stirring area and a sedimentation area. The bottom of the mixing and stirring area is provided with a water inlet pipe for the decolorization and phosphorus removal pool. Stirring device; said settling area is provided with a baffle, and the inner wall of the baffle and the decolorization and dephosphorization tank forms a waste water flow path that enters the settling area as waste water, and a three-phase separator is provided at the outlet of the settling area, and the upper part of the outlet of the settling area There is an overflow weir, the bottom of the sedimentation area is designed as a conical structure, and a sediment discharge valve is set at the bottom of the sedimentation area.

所述缺氧厌氧反应池包括通过折流板分隔成的兼氧段、缺氧段和厌氧段,所述兼氧段首端设有用于供入废水的缺氧厌氧反应池进水管,兼氧段末端与缺氧段首端连通,缺氧段末端与厌氧段首端连通,所述缺氧段和厌氧段进水一侧折流板的下部设置有45度的转角,以避免水流进入时产生的冲击作用,从而起到缓冲水流和均匀布水的作用;厌氧段末端设有三相分离器和溢水堰,溢水堰连接出水管;所述兼氧段、缺氧段和厌氧段底部设计成锥形结构,锥形结构连接污泥排放阀;所述缺氧厌氧反应池的兼氧段、缺氧段和厌氧段上盖设计成圆锥形结构,圆锥形结构顶端都设有独立的甲烷废气集气管。The anoxic-anaerobic reaction pool includes a participatory section, anoxic section and anaerobic section separated by baffles, and the head end of the participatory section is provided with an anoxic-anaerobic reaction pool inlet pipe for feeding waste water , the end of the anoxic section is connected with the head of the anoxic section, and the end of the anoxic section is connected with the head of the anaerobic section. The impact generated when the water flow enters, thereby playing the role of buffering the water flow and uniform water distribution; the end of the anaerobic section is equipped with a three-phase separator and an overflow weir, and the overflow weir is connected to the outlet pipe; the facultative section, the anoxic section and the anaerobic section The bottom of the oxygen section is designed as a conical structure, and the conical structure is connected to the sludge discharge valve; the facultative section, anoxic section and anaerobic section of the anoxic anaerobic reaction tank are designed as a conical structure, and the top of the conical structure is All have independent methane exhaust gas collection pipes.

所述生化接触池内中下部设置有生化接触池进水管,所述生化接触池进水管下部设有布水三角锥;所述布水三角锥下部设有曝气调控系统,所述曝气调控系统包括曝气盘、鼓风机和溶解氧测量调控装置;进一步,所述的曝气盘是均匀设置有微孔的微孔式曝气盘。所述曝气盘通过曝气管连接鼓风机,鼓风机设置在生化接触池外,生化接触池的上部、废水水面下设置溶解氧测量调控装置,所述溶解氧测量调控装置根据氧容量调控鼓风机工作;所述生化接触池进水管上部内置有填料;所述生化接触池的出口处布设有溢流堰。The middle and lower part of the biochemical contact tank is provided with a biochemical contact tank water inlet pipe, and the lower part of the biochemical contact tank water inlet pipe is provided with a water distribution triangular cone; the lower part of the water distribution triangular cone is provided with an aeration control system, and the aeration control system It includes an aeration pan, a blower, and a dissolved oxygen measurement and control device; further, the aeration pan is a microporous aeration pan with micropores uniformly arranged therein. The aeration pan is connected to a blower through an aeration pipe, and the blower is arranged outside the biochemical contact tank, and a dissolved oxygen measurement and control device is arranged on the upper part of the biochemical contact tank and under the wastewater surface, and the dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity; The upper part of the water inlet pipe of the biochemical contact tank is filled with fillers; the outlet of the biochemical contact tank is provided with an overflow weir.

所述生化接触池的出水管连接二沉池,二沉池底部设有污泥回流系统,一部分污泥回流到生化接触池。The outlet pipe of the biochemical contact tank is connected to the secondary settling tank, and a sludge return system is provided at the bottom of the secondary settling tank, and a part of the sludge flows back into the biochemical contact tank.

二沉池沉淀处理后的水经溢流堰后达标排放。The water after the sedimentation treatment in the secondary settling tank passes through the overflow weir and then discharges up to the standard.

所述脱色除磷剂由硅藻土、活性炭、膨润土、铁盐、硫酸钙、硫酸铝、有机絮凝剂按质量比50:20:50:45:40:30:5混合制成。The decolorizing and dephosphorizing agent is prepared by mixing diatomite, activated carbon, bentonite, iron salt, calcium sulfate, aluminum sulfate, and organic flocculant in a mass ratio of 50:20:50:45:40:30:5.

一种采用上述含磷印染废水处理装置进行废水处理的方法,具有如下步骤:A method for wastewater treatment using the above-mentioned phosphorus-containing printing and dyeing wastewater treatment device has the following steps:

①含磷印染废水通过废水调节池进水管进入废水调节池调节废水的pH值、水质和水量。① Phosphorus-containing printing and dyeing wastewater enters the wastewater regulating tank through the inlet pipe of the wastewater regulating tank to adjust the pH value, water quality and water volume of the wastewater.

②调节后的水通过脱色除磷池混合搅拌区底部的脱色除磷池进水管进入脱色除磷池,与来自药液添加系统的脱色除磷剂混合,利用设置在搅拌区中部的搅拌装置进行搅拌;脱色除磷剂通过混凝、沉淀和吸附等作用去除废水的色度和一定量的磷,然后废水进入沉淀区的废水流道,沉淀区的三相分离器实现泥水分离。②The adjusted water enters the decolorization and phosphorus removal pool through the inlet pipe of the decolorization and phosphorus removal tank at the bottom of the mixing zone of the decolorization and phosphorus removal pool, and is mixed with the decolorization and phosphorus removal agent from the chemical liquid addition system, and is mixed with the stirring device set in the middle of the stirring zone. Stirring; the decolorization and phosphorus removal agent removes the color and a certain amount of phosphorus of the wastewater through coagulation, precipitation and adsorption, and then the wastewater enters the wastewater flow channel in the sedimentation area, and the three-phase separator in the sedimentation area realizes the separation of mud and water.

③污泥在重力的作用下下沉到脱色除磷池沉淀区的下部,通过底部的沉淀物排放阀排出。废水通过溢水堰、出水管和连接管连通缺氧厌氧反应池的进水管。③The sludge sinks to the lower part of the sedimentation area of the decolorization and phosphorus removal tank under the action of gravity, and is discharged through the sediment discharge valve at the bottom. The waste water is connected to the inlet pipe of the anoxic anaerobic reaction tank through the overflow weir, the outlet pipe and the connecting pipe.

④废水通过缺氧厌氧反应池兼氧段的缺氧厌氧反应池进水管进入缺氧厌氧反应池的下部;废水进入缺氧厌氧反应池后沿折流板上下前进,依次通过兼氧段、缺氧段和厌氧段的每个反应室的污泥床,反应池中的污泥随着废水的上下流动和沼气上升的作用而运动,折流板的阻挡作用和污泥自身的沉降作用又使污泥的流速降低,因此大量的污泥都被截留在反应池中,反应池中的微生物与废水中的有机物充分接触。兼氧段的兼性菌、缺氧段和厌氧段的异养菌将废水中的有机物水解为有机酸,使大分子有机物分解为小分子有机物,不溶性的有机物转化成可溶性有机物。④Wastewater enters the lower part of the anoxic anaerobic reaction pool through the inlet pipe of the anoxic anaerobic reaction pool in the anoxic anaerobic section; The sludge bed in each reaction chamber of the oxygen section, the anoxic section and the anaerobic section, the sludge in the reaction tank moves with the up and down flow of wastewater and the rise of biogas, the blocking effect of the baffle plate and the sludge itself The settling effect of the sludge reduces the flow rate of the sludge, so a large amount of sludge is trapped in the reaction tank, and the microorganisms in the reaction tank fully contact with the organic matter in the wastewater. The facultative bacteria in the facultative stage, the heterotrophic bacteria in the anoxic stage and the anaerobic stage hydrolyze the organic matter in the wastewater into organic acids, decompose the macromolecular organic matter into small molecular organic matter, and convert the insoluble organic matter into soluble organic matter.

⑤厌氧反应后的废水在厌氧段末端设有的三相分离器实现泥、水、甲烷气的分离,污泥在重力的作用下下沉到缺氧厌氧反应池的下部,多余的污泥通过底部的污泥排放阀排出。缺氧厌氧反应池产生的甲烷废气通过反应池顶部集气管收集排放。废水通过溢水堰、出水管和连接管连通生化接触池的进水管。⑤ After the anaerobic reaction, the three-phase separator installed at the end of the anaerobic section realizes the separation of mud, water and methane gas, and the sludge sinks to the lower part of the anoxic anaerobic reaction tank under the action of gravity, and the excess The sludge is discharged through the sludge discharge valve at the bottom. The methane waste gas produced by the anoxic anaerobic reaction pool is collected and discharged through the gas header at the top of the reaction pool. The waste water is connected to the water inlet pipe of the biochemical contact tank through the overflow weir, the outlet pipe and the connecting pipe.

⑥废水通过生化接触池进水管进入生化接触池的中下部,在布水三角锥的作用下均匀布水,所述的曝气盘是均匀设置有微孔的微孔式曝气盘,产生大量的微气泡,所述溶解氧测量调控装置根据氧容量调控鼓风机工作,确保生化接触池水中的溶解氧大于2mg/L,处理后的废水通过溢流堰和出水管流出。⑥Waste water enters the middle and lower part of the biochemical contact tank through the water inlet pipe of the biochemical contact tank, and the water is evenly distributed under the action of the water distribution triangle cone. The dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity to ensure that the dissolved oxygen in the biochemical contact pool water is greater than 2mg/L, and the treated wastewater flows out through the overflow weir and the outlet pipe.

⑦生化接触池的出水管连接二沉池的布水管,二沉池的沉淀污泥一部分回流到生化接触池,一部分作为剩余污泥。⑦ The outlet pipe of the biochemical contact tank is connected to the water distribution pipe of the secondary settling tank, part of the sedimented sludge in the secondary settling tank flows back to the biochemical contact tank, and part of it is used as excess sludge.

⑧二沉池沉淀处理后的水经溢流堰后达标排放。⑧The water after the sedimentation treatment in the secondary settling tank passes through the overflow weir and then discharges up to the standard.

⑨脱色除磷池、缺氧厌氧反应池、生化接触池和二沉池产生的剩余污泥脱水后外运。⑨Excess sludge produced in decolorization and phosphorus removal tank, anoxic anaerobic reaction tank, biochemical contact tank and secondary settling tank is dehydrated and transported abroad.

本发明的有益效果是:本发明结构简单,制造成本较低,对含磷印染废水处理具有比较好的深度效果,管理方便。The beneficial effects of the present invention are: the present invention has simple structure, low manufacturing cost, relatively good depth effect on the treatment of phosphorus-containing printing and dyeing wastewater, and convenient management.

附图说明Description of drawings

下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1是本发明实施例脱色除磷池的结构示意图。Fig. 1 is a schematic structural view of a decolorization and phosphorus removal tank according to an embodiment of the present invention.

图1中:1.脱色除磷池,1-1.混合搅拌区,1-2.沉淀区,1-3.脱色除磷池进水管,1-4.药液添加系统,1-5.搅拌装置,1-6.挡板,1-7.三相分离器,1-8.溢水堰,1-9.沉淀物排放阀。In Figure 1: 1. Decolorization and phosphorus removal tank, 1-1. Mixing and stirring zone, 1-2. Sedimentation zone, 1-3. Water inlet pipe of decolorization and phosphorus removal tank, 1-4. Chemical solution adding system, 1-5. Stirring device, 1-6. baffle plate, 1-7. three-phase separator, 1-8. overflow weir, 1-9. sediment discharge valve.

图2是本发明实施例缺氧厌氧反应池的结构示意图。Fig. 2 is a schematic structural view of an anaerobic anaerobic reaction tank according to an embodiment of the present invention.

图2中:2.缺氧厌氧反应池,2-1.折流板,2-2.兼氧段,2-3.缺氧段,2-4.厌氧段,2-5.缺氧厌氧反应池进水管,2-6.缺氧厌氧反应池三相分离器,2-7.缺氧厌氧反应池溢水堰,2-8.污泥排放阀,2-9.上盖,2-10.集气管。In Fig. 2: 2. anoxic anaerobic reaction tank, 2-1. baffle plate, 2-2. concurrent oxygen section, 2-3. anoxic section, 2-4. anaerobic section, 2-5. deficient Inlet pipe of anoxic anaerobic reaction tank, 2-6. Three-phase separator of anoxic anaerobic reaction tank, 2-7. Overflow weir of anoxic anaerobic reaction tank, 2-8. Sludge discharge valve, 2-9. Upper Cover, 2-10. Air collecting pipe.

图3是本发明实施例生化接触池的结构示意图。Fig. 3 is a schematic structural diagram of a biochemical contact pool according to an embodiment of the present invention.

图3中:3.生化接触池,3-1.生化接触池进水管,3-2.布水三角锥,3-3.曝气调控系统,3-4.填料,3-5.溢流堰。In Figure 3: 3. Biochemical contact tank, 3-1. Biochemical contact tank inlet pipe, 3-2. Water distribution triangle cone, 3-3. Aeration control system, 3-4. Filling, 3-5. Overflow weir.

图4是本发明实施例的工艺流程图。Fig. 4 is a process flow diagram of an embodiment of the present invention.

具体实施方式detailed description

现在结合附图对本发明作进一步详细的说明。这些附图均为简化的示意图,仅以示意方式说明本发明的基本结构,因此其仅显示与本发明有关的构成。The present invention is described in further detail now in conjunction with accompanying drawing. These drawings are all simplified schematic diagrams, which only illustrate the basic structure of the present invention in a schematic manner, so they only show the configurations related to the present invention.

如图1~图4所示,本发明一种含磷印染废水处理方法与装置,包括废水调节池、脱色除磷池1、缺氧厌氧反应池2、生化接触池3、二沉池;所述废水调节池、脱色除磷池1、缺氧厌氧反应池2、生化接触池3、二沉池依次连通。As shown in Figures 1 to 4, a method and device for treating phosphorus-containing printing and dyeing wastewater according to the present invention includes a wastewater adjustment tank, a decolorization and phosphorus removal tank 1, an anoxic anaerobic reaction tank 2, a biochemical contact tank 3, and a secondary sedimentation tank; The wastewater regulating pool, the decolorization and phosphorus removal pool 1, the anoxic anaerobic reaction pool 2, the biochemical contact pool 3, and the secondary sedimentation pool are connected in sequence.

所述废水调节池包括废水调节池进水管、pH值测控系统和出水管,用于调节含磷印染废水的pH值、水质和水量。The wastewater regulating tank includes an inlet pipe of the wastewater regulating tank, a pH value measurement and control system and an outlet pipe for adjusting the pH value, water quality and water volume of phosphorus-containing printing and dyeing wastewater.

所述的脱色除磷池1包括混合搅拌区1-1和沉淀区1-2,混合搅拌区底部设有脱色除磷池进水管1-3,中上部设有用于添加脱色除磷剂的药液添加系统1-4,在搅拌区中部设置有搅拌装置1-5;所述沉淀区内设有挡板1-6,该挡板与脱色除磷池的内壁形成作为废水进入沉淀区的废水流道,沉淀区的出口处设有三相分离器1-7,沉淀区的出口上部设有溢水堰1-8,沉淀区底部设计成锥形结构,在沉淀区底部设置有沉淀物排放阀1-9。The decolorization and phosphorus removal pool 1 includes a mixing and stirring zone 1-1 and a precipitation zone 1-2. The bottom of the mixing and stirring zone is provided with a decolorization and phosphorus removal pool inlet pipe 1-3, and the upper part is provided with a drug for adding a decolorization and phosphorus removal agent. The liquid addition system 1-4 is provided with a stirring device 1-5 in the middle of the stirring zone; a baffle 1-6 is arranged in the said sedimentation zone, and the baffle and the inner wall of the decolorization and dephosphorization tank form the waste water that enters the sedimentation zone as waste water Flow channel, three-phase separator 1-7 is provided at the outlet of the sedimentation area, overflow weir 1-8 is arranged at the upper part of the outlet of the sedimentation area, the bottom of the sedimentation area is designed as a conical structure, and a sediment discharge valve 1 is arranged at the bottom of the sedimentation area -9.

所述缺氧厌氧反应池2包括通过折流板2-1分隔成的兼氧段2-2、缺氧段2-3和厌氧段2-4,所述兼氧段2-2首端设有用于供入废水的缺氧厌氧反应池进水管2-5,兼氧段2-2末端与缺氧段2-3首端连通,缺氧段2-3末端与厌氧段2-4首端连通,所述缺氧段2-3和厌氧段2-4进水一侧折流板的下部设置有45度的转角,以避免水流进入时产生的冲击作用,从而起到缓冲水流和均匀布水的作用;厌氧段2-4末端设有三相分离器2-6和溢水堰2-7,溢水堰2-7连接出水管;所述兼氧段2-2、缺氧段2-3和厌氧段2-4底部设计成锥形结构,锥形结构连接污泥排放阀2-8;所述缺氧厌氧反应池的兼氧段、缺氧段和厌氧段的上盖2-9设计成圆锥形结构,圆锥形结构顶端都设有独立的甲烷废气集气管2-10。The anoxic-anaerobic reaction tank 2 includes an anoxic section 2-2, an anoxic section 2-3 and anaerobic section 2-4 separated by a baffle plate 2-1, and the anoxic section 2-2 first An anoxic anaerobic reaction pool inlet pipe 2-5 for feeding waste water is provided at the end, the end of the anoxic section 2-2 is connected with the head end of the anoxic section 2-3, and the end of the anoxic section 2-3 is connected with the anaerobic section 2 -4 The head end is connected, and the lower part of the baffle on the water inlet side of the anoxic section 2-3 and the anaerobic section 2-4 is provided with a 45-degree corner to avoid the impact of the water flow when it enters, thereby playing a role The function of buffering water flow and uniform water distribution; the end of the anaerobic section 2-4 is provided with a three-phase separator 2-6 and an overflow weir 2-7, and the overflow weir 2-7 is connected to the outlet pipe; the anaerobic section 2-2, deficient The bottom of the oxygen section 2-3 and the anaerobic section 2-4 is designed as a conical structure, and the conical structure is connected to the sludge discharge valve 2-8; The upper cover 2-9 of the section is designed as a conical structure, and the top of the conical structure is provided with an independent methane waste gas collecting pipe 2-10.

所述生化接触池3内中下部设置有生化接触池进水管3-1,所述生化接触池进水管3-1下部设有布水三角锥3-2;所述布水三角锥3-2下部设有曝气调控系统3-3,所述曝气调控系统3-3包括曝气盘、鼓风机和溶解氧测量调控装置;进一步,所述的曝气盘是均匀设置有微孔的微孔式曝气盘。所述曝气盘通过曝气管连接鼓风机,鼓风机设置在生化接触池外,生化接触池的上部、废水水面下设置溶解氧测量调控装置,所述溶解氧测量调控装置根据氧容量调控鼓风机工作;所述进水管上部内置有填料3-4;所述生化接触池的出口处布设有溢流堰3-5。The middle and lower part of the biochemical contact pool 3 is provided with a biochemical contact pool inlet pipe 3-1, and the lower part of the biochemical contact pool inlet pipe 3-1 is provided with a water distribution triangle cone 3-2; the water distribution triangle cone 3-2 The lower part is provided with an aeration control system 3-3, and the aeration control system 3-3 includes an aeration pan, a blower, and a dissolved oxygen measurement and control device; further, the aeration pan is a micropore with micropores evenly arranged type aeration disc. The aeration pan is connected to a blower through an aeration pipe, and the blower is arranged outside the biochemical contact tank, and a dissolved oxygen measurement and control device is arranged on the upper part of the biochemical contact tank and under the wastewater surface, and the dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity; A filler 3-4 is built in the upper part of the water inlet pipe; an overflow weir 3-5 is arranged at the outlet of the biochemical contact tank.

所述生化接触池的出水管连接二沉池,二沉池底部设有污泥回流系统,一部分污泥回流到生化接触池。The outlet pipe of the biochemical contact tank is connected to the secondary settling tank, and a sludge return system is provided at the bottom of the secondary settling tank, and a part of the sludge flows back into the biochemical contact tank.

二沉池沉淀处理后的水经溢流堰后达标排放。The water after the sedimentation treatment in the secondary settling tank passes through the overflow weir and then discharges up to the standard.

所述脱色除磷剂由硅藻土、活性炭、膨润土、铁盐、硫酸钙、硫酸铝、有机絮凝剂按质量比50:20:50:45:40:30:5混合制成。The decolorizing and dephosphorizing agent is prepared by mixing diatomite, activated carbon, bentonite, iron salt, calcium sulfate, aluminum sulfate, and organic flocculant in a mass ratio of 50:20:50:45:40:30:5.

一种采用上述含磷印染废水处理装置进行废水处理的方法,具有如下步骤:A method for wastewater treatment using the above-mentioned phosphorus-containing printing and dyeing wastewater treatment device has the following steps:

①含磷印染废水通过废水调节池进水管进入废水调节池调节废水的pH值、水质和水量。① Phosphorus-containing printing and dyeing wastewater enters the wastewater regulating tank through the inlet pipe of the wastewater regulating tank to adjust the pH value, water quality and water volume of the wastewater.

②调节后的水通过脱色除磷池混合搅拌区1-1底部的脱色除磷池进水管1-3进入脱色除磷池1,与来自药液添加系统1-4的脱色除磷剂混合,利用设置在搅拌区中部的搅拌装置1-5进行搅拌;脱色除磷剂通过混凝、沉淀和吸附等作用去除废水的色度和一定量的磷,然后废水进入沉淀区1-2的废水流道,沉淀区的三相分离器1-7实现泥水分离。②The adjusted water enters the decolorization and phosphorus removal pool 1 through the decolorization and phosphorus removal pool inlet pipe 1-3 at the bottom of the decolorization and phosphorus removal pool mixing zone 1-1, and mixes with the decolorization and phosphorus removal agent from the chemical liquid addition system 1-4, Use the stirring device 1-5 set in the middle of the stirring zone to stir; the decolorization and dephosphorization agent removes the color and a certain amount of phosphorus of the wastewater through coagulation, precipitation and adsorption, and then the wastewater enters the wastewater flow of the precipitation zone 1-2 Road, the three-phase separator 1-7 in the sedimentation area realizes the separation of mud and water.

③污泥在重力的作用下下沉到脱色除磷池沉淀区1-2的下部,通过底部的沉淀物排放阀1-9排出。废水通过溢水堰1-8、出水管和连接管连通缺氧厌氧反应池2的缺氧厌氧反应池进水管2-5。③The sludge sinks under the action of gravity to the lower part of the sedimentation zone 1-2 of the decolorization and phosphorus removal tank, and is discharged through the sediment discharge valve 1-9 at the bottom. The waste water is connected to the anoxic anaerobic reaction tank inlet pipe 2-5 of the anoxic anaerobic reaction tank 2 through the overflow weir 1-8, the outlet pipe and the connecting pipe.

④废水通过缺氧厌氧反应池兼氧段2-2的缺氧厌氧反应池进水管2-5进入缺氧厌氧反应池2的下部;废水进入缺氧厌氧反应池后沿折流板2-1上下前进,依次通过兼氧段2-2、缺氧段2-3和厌氧段2-4的每个反应室的污泥床,反应池中的污泥随着废水的上下流动和沼气上升的作用而运动,折流板2-1的阻挡作用和污泥自身的沉降作用又使污泥的流速降低,因此大量的污泥都被截留在反应池中,反应池中的微生物与废水中的有机物充分接触。兼氧段2-2的兼性菌、缺氧段2-3和厌氧段2-4的异养菌将废水中的有机物水解为有机酸,使大分子有机物分解为小分子有机物,不溶性的有机物转化成可溶性有机物。④The waste water enters the lower part of the anoxic anaerobic reaction pool 2 through the anoxic anaerobic reaction pool inlet pipe 2-5 of the anoxic anaerobic reaction pool and the oxygen section 2-2; the waste water enters the anoxic anaerobic reaction pool and then flows along The plate 2-1 advances up and down, and passes through the sludge bed of each reaction chamber of the facultative section 2-2, the anoxic section 2-3 and the anaerobic section 2-4 in turn, and the sludge in the reaction pool goes up and down with the wastewater The movement of the flow and the rise of biogas, the blocking effect of the baffle plate 2-1 and the sedimentation of the sludge itself reduce the flow rate of the sludge, so a large amount of sludge is trapped in the reaction tank, and the sludge in the reaction tank Microorganisms are in full contact with organic matter in wastewater. The facultative bacteria in the facultative stage 2-2, the heterotrophic bacteria in the anoxic stage 2-3 and the anaerobic stage 2-4 hydrolyze the organic matter in the wastewater into organic acids, and decompose the macromolecular organic matter into small molecular organic matter. Organic matter is converted into soluble organic matter.

⑤厌氧反应后的废水在厌氧段2-4末端设有的三相分离器2-6实现泥、水、甲烷气的分离,污泥在重力的作用下下沉到缺氧厌氧反应池的下部,多余的污泥通过底部的污泥排放阀2-8排出。缺氧厌氧反应池产生的甲烷废气通过反应池顶部的集气管2-10收集排放。废水通过溢水堰、出水管和连接管连通生化接触池3的生化接触池进水管。⑤ The waste water after the anaerobic reaction is separated from mud, water and methane by the three-phase separator 2-6 at the end of the anaerobic section 2-4, and the sludge sinks under the action of gravity to the anoxic anaerobic reaction In the lower part of the pool, excess sludge is discharged through the sludge discharge valve 2-8 at the bottom. The methane waste gas produced by the anoxic anaerobic reaction tank is collected and discharged through the gas collecting pipe 2-10 on the top of the reaction tank. The waste water is connected to the biochemical contact tank inlet pipe of the biochemical contact tank 3 through the overflow weir, the outlet pipe and the connecting pipe.

⑥废水通过生化接触池进水管3-1进入生化接触池3的中下部,在布水三角锥3-2的作用下均匀布水,所述的曝气盘是均匀设置有微孔的微孔式曝气盘,产生大量的微气泡,所述溶解氧测量调控装置根据氧容量调控鼓风机工作,确保生化接触池水中的溶解氧大于2mg/L,处理后的废水通过溢流堰3-5和出水管流出。⑥The waste water enters the middle and lower part of the biochemical contact tank 3 through the water inlet pipe 3-1 of the biochemical contact tank, and the water is evenly distributed under the action of the water distribution triangle cone 3-2. Type aeration disc, produce a large amount of micro-bubbles, the dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity to ensure that the dissolved oxygen in the biochemical contact pool water is greater than 2mg/L, and the treated wastewater passes through the overflow weir 3-5 and The outlet pipe is flowing out.

⑦生化接触池3的出水管连接二沉池的布水管,二沉池的沉淀污泥一部分回流到生化接触池,一部分作为剩余污泥。⑦ The outlet pipe of the biochemical contact tank 3 is connected to the water distribution pipe of the secondary settling tank, and part of the settled sludge in the secondary settling tank flows back to the biochemical contact tank, and part of it is used as excess sludge.

⑧二沉池沉淀处理后的水经二沉池溢流堰后达标排放。⑧The water after sedimentation treatment in the secondary settling tank passes through the overflow weir of the secondary settling tank and then discharges up to the standard.

⑨脱色除磷池1、缺氧厌氧反应池2、生化接触池3和二沉池产生的剩余污泥脱水后外运。⑨Excess sludge from decolorization and phosphorus removal tank 1, anoxic anaerobic reaction tank 2, biochemical contact tank 3 and secondary sedimentation tank is dehydrated and transported abroad.

以上述依据本发明的理想实施例为启示,通过上述的说明内容,相关工作人员完全可以在不偏离本项发明技术思想的范围内进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。Inspired by the above-mentioned ideal embodiment according to the present invention, through the above-mentioned description content, relevant workers can make various changes and modifications within the scope of not departing from the technical idea of the present invention. The technical scope of the present invention is not limited to the content in the specification, but must be determined according to the scope of the claims.

Claims (2)

1.一种含磷印染废水处理装置,其特征在于:包括废水调节池、脱色除磷池(1)、缺氧厌氧反应池(2)、生化接触池(3)、二沉池;1. A phosphorus-containing printing and dyeing wastewater treatment device, characterized in that: it comprises a wastewater regulating tank, a decolorization and phosphorus removal tank (1), an anoxic anaerobic reaction tank (2), a biochemical contact tank (3), and a secondary sedimentation tank; 所述废水调节池包括废水调节池进水管、pH值测控系统和废水调节池出水管,用于调节含磷印染废水的pH值、水质和水量;The wastewater regulating tank includes a wastewater regulating tank inlet pipe, a pH measurement and control system, and a wastewater regulating tank outlet pipe for adjusting the pH value, water quality and water volume of phosphorus-containing printing and dyeing wastewater; 所述的脱色除磷池(1)包括混合搅拌区(1-1)和沉淀区(1-2),混合搅拌区底部设有脱色除磷池进水管(1-3),中上部设有用于添加脱色除磷剂的药液添加系统(1-4),在搅拌区中部设置有搅拌装置(1-5);所述沉淀区内设有挡板(1-6),该挡板与脱色除磷池的内壁形成作为废水进入沉淀区的废水流道,沉淀区的出口处设有三相分离器(1-7),沉淀区的出口上部设有溢水堰(1-8),沉淀区底部设计成锥形结构,在沉淀区底部设置有沉淀物排放阀(1-9);The decolorization and dephosphorization pool (1) includes a mixing zone (1-1) and a precipitation zone (1-2). The bottom of the mixing zone is provided with a water inlet pipe (1-3) for the decolorization and dephosphorization tank, and the upper part is provided with a In the chemical solution adding system (1-4) for adding the decolorizing and dephosphorizing agent, a stirring device (1-5) is provided in the middle of the stirring zone; a baffle (1-6) is provided in the precipitation zone, and the baffle is connected with the The inner wall of the decolorization and phosphorus removal tank forms a waste water flow channel for the wastewater to enter the sedimentation area. A three-phase separator (1-7) is installed at the outlet of the sedimentation area, and an overflow weir (1-8) is arranged on the upper part of the outlet of the sedimentation area. The bottom is designed as a conical structure, and a sediment discharge valve (1-9) is set at the bottom of the sedimentation area; 所述缺氧厌氧反应池(2)包括通过折流板(2-1)分隔成的兼氧段(2-2)、缺氧段(2-3)和厌氧段(2-4),所述兼氧段(2-2)首端设有用于供入废水的缺氧厌氧反应池进水管(2-5),兼氧段(2-2)末端与缺氧段(2-3)首端连通,缺氧段(2-3)末端与厌氧段(2-4)首端连通;所述缺氧段(2-3)和厌氧段(2-4)的进水一侧折流板的下部设置有45度的转角,以避免水流进入时产生的冲击作用,从而起到缓冲水流和均匀布水的作用;厌氧段(2-4)末端设有三相分离器(2-6)和溢水堰(2-7),溢水堰(2-7)连接出水管;所述兼氧段(2-2)、缺氧段(2-3)和厌氧段(2-4)底部设计成锥形结构,锥形结构连接污泥排放阀(2-8);所述缺氧厌氧反应池的兼氧段、缺氧段和厌氧段上盖(2-9)设计成圆锥形结构,圆锥形结构顶端都设有甲烷废气集气管(2-10);The anoxic-anaerobic reaction tank (2) comprises a part-aerobic section (2-2), anoxic section (2-3) and anaerobic section (2-4) separated by a baffle plate (2-1) , the head end of the part-aerobic section (2-2) is provided with an anoxic anaerobic reaction tank inlet pipe (2-5) for feeding waste water, and the end part of the part-aerobic section (2-2) is connected to the anoxic section (2-2) 3) The head end is connected, and the end of the anoxic section (2-3) is connected with the head end of the anaerobic section (2-4); the influent of the anoxic section (2-3) and the anaerobic section (2-4) The lower part of the baffle on one side is provided with a 45-degree corner to avoid the impact of the water flow when it enters, so as to buffer the water flow and distribute water evenly; the end of the anaerobic section (2-4) is equipped with a three-phase separator (2-6) and overflow weir (2-7), overflow weir (2-7) connects outlet pipe; Described concurrent oxygen section (2-2), anoxic section (2-3) and anaerobic section (2 -4) The bottom is designed as a conical structure, and the conical structure is connected to the sludge discharge valve (2-8); ) is designed as a conical structure, and the top of the conical structure is provided with methane waste gas collecting pipes (2-10); 所述生化接触池(3)内中下部设置生化接触池进水管(3-1),所述生化接触池进水管(3-1)下部设有布水三角锥(3-2);所述布水三角锥(3-2)下部设有曝气调控系统(3-3),所述曝气调控系统(3-3)包括曝气盘、鼓风机和溶解氧测量调控装置,进一步的,所述的曝气盘是均匀设置有微孔的微孔式曝气盘;所述曝气盘通过曝气管连接鼓风机,鼓风机设置在生化接触池外,生化接触池的上部、废水水面下设置溶解氧测量调控装置,所述溶解氧测量调控装置根据氧容量调控鼓风机工作;所述生化接触池进水管上部内置有填料(3-4);所述生化接触池的出口处布设有溢流堰(3-5);The middle and lower part of the biochemical contact pool (3) is provided with a biochemical contact pool water inlet pipe (3-1), and the lower part of the biochemical contact pool water inlet pipe (3-1) is provided with a water distribution triangle cone (3-2); The lower part of the water distribution triangular cone (3-2) is provided with an aeration control system (3-3), and the aeration control system (3-3) includes an aeration pan, a blower and a dissolved oxygen measurement and control device, further, the The aeration pan described above is a microporous aeration pan with micropores uniformly arranged on it; the aeration pan is connected to a blower through an aeration pipe, and the blower is arranged outside the biochemical contact pool, and the upper part of the biochemical contact pool and the wastewater surface are arranged to dissolve An oxygen measurement and control device, the dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity; the upper part of the inlet pipe of the biochemical contact tank is equipped with a filler (3-4); the outlet of the biochemical contact tank is equipped with an overflow weir ( 3-5); 所述生化接触池(3)的出水管连接二沉池,二沉池底部设有污泥回流系统,一部分污泥回流到生化接触池。The outlet pipe of the biochemical contact tank (3) is connected to a secondary settling tank, and a sludge return system is provided at the bottom of the secondary settling tank, and a part of the sludge flows back into the biochemical contact tank. 2.一种采用如权利要求1所述的含磷印染废水处理装置进行废水处理的方法,具有如下步骤:2. A method for wastewater treatment using the phosphorus-containing printing and dyeing wastewater treatment device as claimed in claim 1, has the following steps: ①含磷印染废水通过废水调节池进水管进入废水调节池调节废水的pH值、水质和水量;①Phosphorus-containing printing and dyeing wastewater enters the wastewater regulating tank through the inlet pipe of the wastewater regulating tank to adjust the pH value, water quality and water volume of the wastewater; ②调节后的水通过脱色除磷池混合搅拌区(1-1)底部的脱色除磷池进水管(1-3)进入脱色除磷池(1),与来自药液添加系统(1-4)的脱色除磷剂混合,利用设置在搅拌区中部的搅拌装置(1-5)进行搅拌;脱色除磷剂通过混凝、沉淀和吸附等作用去除废水的色度和一定量的磷,然后废水进入沉淀区(1-2)的废水流道,沉淀区的三相分离器(1-7)实现泥水分离;②The adjusted water enters the decolorization and phosphorus removal tank (1) through the decolorization and phosphorus removal pool inlet pipe (1-3) at the bottom of the decolorization and phosphorus removal pool mixing zone (1-1), and is mixed with the chemical solution addition system (1-4 ) is mixed with the decolorizing and dephosphorizing agent, and stirred by the stirring device (1-5) arranged in the middle of the stirring zone; the decolorizing and dephosphorizing agent removes the chroma and a certain amount of phosphorus of the waste water through coagulation, precipitation and adsorption, etc., and then The waste water enters the waste water flow channel of the settling area (1-2), and the three-phase separator (1-7) in the settling area realizes the separation of mud and water; ③污泥在重力的作用下下沉到脱色除磷池沉淀区(1-2)的下部,通过底部的沉淀物排放阀(1-9)排出;废水通过溢水堰(1-8)、出水管和连接管连通缺氧厌氧反应池(2)的缺氧厌氧反应池进水管(2-5);③The sludge sinks under the action of gravity to the lower part of the sedimentation area (1-2) of the decolorization and dephosphorization tank, and is discharged through the sediment discharge valve (1-9) at the bottom; the waste water passes through the overflow weir (1-8), the outlet The water pipe and the connecting pipe are connected to the anoxic anaerobic reaction tank inlet pipe (2-5) of the anoxic anaerobic reaction tank (2); ④废水通过缺氧厌氧反应池兼氧段的缺氧厌氧反应池进水管(2-5)进入缺氧厌氧反应池(2)的下部;废水进入缺氧厌氧反应池后沿折流板(2-1)上下前进,依次通过兼氧段(2-2)、缺氧段(2-3)和厌氧段(2-4)的每个反应室的污泥床,反应池中的污泥随着废水的上下流动和沼气上升的作用而运动,折流板(2-1)的阻挡作用和污泥自身的沉降作用又使污泥的流速降低,因此大量的污泥都被截留在反应池中,反应池中的微生物与废水中的有机物充分接触;兼氧段(2-2)的兼性菌、缺氧段(2-3)和厌氧段(2-4)的异养菌将废水中的有机物水解为有机酸,使大分子有机物分解为小分子有机物,不溶性的有机物转化成可溶性有机物;④Wastewater enters the lower part of the anoxic anaerobic reaction pool (2) through the anoxic anaerobic reaction pool inlet pipe (2-5) of the anoxic anaerobic reaction pool and the anoxic section; The flow plate (2-1) advances up and down, successively passing through the sludge bed of each reaction chamber of the facultative section (2-2), anoxic section (2-3) and anaerobic section (2-4), and the reaction tank The sludge in the tank moves with the up and down flow of wastewater and the rise of biogas, and the blocking effect of the baffle (2-1) and the sedimentation of the sludge itself reduce the flow rate of the sludge, so a large amount of sludge is Trapped in the reaction tank, the microorganisms in the reaction tank fully contact with the organic matter in the wastewater; facultative bacteria in the facultative section (2-2), anoxic section (2-3) and anaerobic section (2-4) The heterotrophic bacteria in the wastewater hydrolyze organic matter into organic acids, decompose macromolecular organic matter into small molecular organic matter, and convert insoluble organic matter into soluble organic matter; ⑤厌氧反应后的废水在厌氧段(2-4)末端设有的三相分离器(2-6)实现泥、水、甲烷气的分离,污泥在重力的作用下下沉到缺氧厌氧反应池的下部,多余的污泥通过底部的污泥排放阀(2-8)排出;缺氧厌氧反应池产生的甲烷废气通过反应池顶部集气管(2-10)收集排放;废水通过溢水堰、出水管和连接管连通生化接触池(3)的生化接触池进水管;⑤ After the anaerobic reaction, the three-phase separator (2-6) provided at the end of the anaerobic section (2-4) realizes the separation of mud, water and methane gas, and the sludge sinks to the bottom of the gap under the action of gravity. In the lower part of the anaerobic reaction tank, the excess sludge is discharged through the sludge discharge valve (2-8) at the bottom; the methane waste gas produced by the anoxic anaerobic reaction tank is collected and discharged through the gas collecting pipe (2-10) at the top of the reaction tank; The waste water is connected to the biochemical contact tank inlet pipe of the biochemical contact tank (3) through the overflow weir, the outlet pipe and the connecting pipe; ⑥废水通过生化接触池进水管(3-1)进入生化接触池(3)的中下部,在布水三角锥(3-2)的作用下均匀布水,所述的曝气盘是均匀设置有微孔的微孔式曝气盘,产生大量的微气泡,所述溶解氧测量调控装置根据氧容量调控鼓风机工作,确保生化接触池水中的溶解氧大于2mg/L,处理后的废水通过溢流堰(3-5)和出水管流出;⑥Wastewater enters the middle and lower part of the biochemical contact tank (3) through the biochemical contact tank water inlet pipe (3-1), and distributes water evenly under the action of the water distribution triangle cone (3-2), and the aeration disc is evenly arranged The microporous aeration disc with micropores produces a large number of microbubbles. The dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity to ensure that the dissolved oxygen in the biochemical contact pool water is greater than 2 mg/L. The treated wastewater passes through the overflow Flow weir (3-5) and outlet pipe flow out; ⑦生化接触池(3)的出水管连接二沉池的布水管,二沉池的沉淀污泥一部分回流到生化接触池,一部分作为剩余污泥;⑦The outlet pipe of the biochemical contact tank (3) is connected to the water distribution pipe of the secondary settling tank, and part of the settled sludge in the secondary settling tank flows back to the biochemical contact tank, and part of it is used as residual sludge; ⑧二沉池沉淀处理后的水经二沉池溢流堰后达标排放;⑧The water after sedimentation treatment in the secondary settling tank passes through the overflow weir of the secondary settling tank and then discharges up to the standard; ⑨脱色除磷池(1)、缺氧厌氧反应池(2)、生化接触池(3)和二沉池产生的剩余污泥脱水后外运。⑨Excess sludge produced in decolorization and phosphorus removal tank (1), anoxic anaerobic reaction tank (2), biochemical contact tank (3) and secondary sedimentation tank is dehydrated and transported abroad.
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