CN104641002A - Pulverized coal injection device, blast furnace equipment equipped with the pulverized coal injection device, and pulverized coal supply method - Google Patents
Pulverized coal injection device, blast furnace equipment equipped with the pulverized coal injection device, and pulverized coal supply method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
- C21B5/003—Injection of pulverulent coal
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
- C21B7/163—Blowpipe assembly
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
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Abstract
Description
技术领域technical field
本发明涉及煤粉吹入装置、具备该煤粉吹入装置的高炉设备以及煤粉供给方法。The present invention relates to a pulverized coal injection device, a blast furnace facility equipped with the pulverized coal injection device, and a pulverized coal supply method.
背景技术Background technique
高炉设备中的作为辅助燃料的煤粉的吹入(PCI:Pulverized CoalInjection)是取代1970年之前进行的重油吹入的低成本的辅助燃料供给方法。作为高炉吹入用的煤粉(PCI煤)的重要的条件列举有:低水分、低挥发成分且燃烧性优异,燃烧速度与重油同等快的条件;未燃烧碳或灰分等燃烧残留少的条件;具有6500kcal/kg以上的发热量的条件;以及硫成分·磷成分的含有率少的条件等。Injection of pulverized coal (PCI: Pulverized Coal Injection) as an auxiliary fuel in blast furnace equipment is a low-cost auxiliary fuel supply method that replaces heavy oil injection performed before 1970. Important conditions for pulverized coal (PCI coal) to be blown into blast furnaces include: low moisture content, low volatile content, excellent combustibility, and high combustion speed as fast as heavy oil; low combustion residues such as unburned carbon and ash ; a condition with a calorific value of 6500 kcal/kg or more; and a condition with a small content rate of a sulfur component and a phosphorus component, and the like.
为了满足上述的条件,在现状下,如专利文献1所示,使用烟煤等比较高品质且高价格的原煤作为PCI煤的原料。这样的原煤通过粉碎机粉碎至规定的粒度而形成为煤粉,并通过高压的空气或氮等形成的气流搬运,向设置在高炉主体的附近的贮存箱输送而进行贮存。并且,从设置在高炉主体下部的风口将该煤粉与被加热后的高压空气的热风一起向高炉主体吹入,以供燃烧。In order to satisfy the above-mentioned conditions, currently, as shown in Patent Document 1, relatively high-quality and expensive raw coal such as bituminous coal is used as a raw material for PCI coal. Such raw coal is crushed to a predetermined particle size by a pulverizer to form pulverized coal, which is conveyed by an air flow of high-pressure air or nitrogen, and transported to a storage tank installed near the main body of the blast furnace for storage. Then, the pulverized coal is blown into the main body of the blast furnace together with hot air of heated high-pressure air through the tuyeres provided at the lower part of the main body of the blast furnace for combustion.
在先技术文献prior art literature
专利文献patent documents
专利文献1:日本特开2012-173241号公报Patent Document 1: Japanese Patent Laid-Open No. 2012-173241
发明内容Contents of the invention
发明要解决的课题The problem to be solved by the invention
然而,如上所述,由于需要高品质且高价格的原煤作为当成辅助燃料向高炉主体的内部吹入的PCI煤的原料,因此高炉设备的运转成本增加,其结果是,导致生铁的制造成本上升。However, as described above, since high-quality and expensive raw coal is required as a raw material for the PCI coal blown into the blast furnace body as an auxiliary fuel, the operating cost of the blast furnace facility increases, resulting in an increase in the production cost of pig iron. .
另外,煤粉与压缩空气一起向高炉内吹入,但为了避免在该吹入时由压缩空气将炉内冷却,必须预先通过燃烧器等将压缩空气加热至1200℃左右。为此,需要大量的重油等燃料,这一点也成为使高炉设备的运转成本升高的原因。In addition, pulverized coal is blown into the blast furnace together with compressed air, but in order to prevent the furnace from being cooled by the compressed air during the blowing, the compressed air must be heated to about 1200° C. with a burner or the like in advance. For this reason, a large amount of fuel such as heavy oil is required, which also causes an increase in the operating cost of the blast furnace facility.
本发明鉴于上述的情况而提出,其目的在于提供一种能够减少高炉设备的运转成本而实现生铁的制造成本下降的煤粉吹入装置、具备该煤粉吹入装置的高炉设备以及煤粉供给方法。The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a pulverized coal injection device capable of reducing the operating cost of the blast furnace facility to reduce the production cost of pig iron, a blast furnace facility equipped with the pulverized coal injection device, and a pulverized coal supply. method.
用于解决课题的方案Solution to the problem
为了解决上述课题,本发明采用以下的方案。In order to solve the above-mentioned problems, the present invention adopts the following means.
即,本发明的第一方案的煤粉吹入装置以将煤粉与被加热及压缩后的吹入空气一起从高炉主体的风口吹入的方式构成,其中,使用从低品质煤改性而具有自发热性的改性煤作为所述煤粉的原料。That is, the pulverized coal blowing device according to the first aspect of the present invention is configured to blow the pulverized coal together with the heated and compressed blown air from the tuyere of the main body of the blast furnace. Self-heating modified coal is used as the raw material of the pulverized coal.
根据该煤粉吹入装置,作为当成辅助燃料而向高炉主体的内部吹入的煤粉的原料,使用与通常使用的烟煤等原煤相比价格格外廉价的改性煤,因此能够降低辅助燃料的价格而减少高炉设备的运转成本,从而能够实现生铁的制造成本下降。According to this pulverized coal blowing device, as the raw material of the pulverized coal blown into the blast furnace main body as auxiliary fuel, modified coal which is much cheaper than raw coal such as bituminous coal which is generally used is used, so that the cost of auxiliary fuel can be reduced. The operating cost of blast furnace equipment can be reduced by reducing the price, so that the manufacturing cost of pig iron can be reduced.
并且,能够将改性煤的热量有效利用于需要热量的其他的部位而有助于节能化。In addition, the heat of upgraded coal can be effectively used in other parts that require heat, thereby contributing to energy saving.
本发明的第一方案的煤粉吹入装置以上述结构为基础,优选的是,所述煤粉吹入装置设有热移送机构,该热移送机构将所述改性煤的自发热作用产生的热量向需要热量的部位移送。The pulverized coal blowing device according to the first aspect of the present invention is based on the above-mentioned structure. Preferably, the pulverized coal blowing device is provided with a heat transfer mechanism that generates heat from the self-heating effect of the modified coal. The heat is transferred to the parts that need heat.
在形成为上述结构的情况下,通过热移送机构,将改性煤的自发热作用产生的热量向需要热量的部位移送,因此能够削减为了在该部位产生热量所耗费的燃料或电力等,由此能够减少高炉设备的运转成本,进而实现生铁的制造成本下降。In the case of the above-mentioned structure, the heat generated by the self-heating action of the reformed coal is transferred to the location requiring heat by the heat transfer mechanism, so it is possible to reduce the consumption of fuel or electricity for generating heat at the location. This can reduce the operating cost of the blast furnace facility, thereby reducing the production cost of pig iron.
另外,改性煤的热量由热移送机构进行移送,由此将改性煤冷却,因此能够防止改性煤的自燃。In addition, since the heat of the reformed coal is transferred by the heat transfer mechanism, the reformed coal is cooled, so spontaneous combustion of the reformed coal can be prevented.
本发明的第一方案的煤粉吹入装置以上述结构为基础,优选的是,所述热移送机构以使被压缩之前的所述吹入空气与所述改性煤进行热交换的方式构成。The pulverized coal injection device according to the first aspect of the present invention is based on the above structure, and it is preferable that the heat transfer mechanism is configured such that the blown air before being compressed and the reformed coal exchange heat. .
根据上述结构,吹入空气在由专用的加热机构加热之前与改性煤进行热交换,由此被适度地加热。因此,能够节约用于对吹入空气进一步进行加热的能量。尤其是使压缩前的冷的吹入空气与改性煤进行热交换,因此提高改性煤的冷却效果,并且提高吹入空气的压缩热的产生率,由此能够进一步减少吹入空气的加热所需要的能量。According to the above configuration, the blown air is moderately heated by exchanging heat with the reformed coal before being heated by the dedicated heating means. Therefore, energy for further heating the blown air can be saved. In particular, by exchanging heat between the cold blown air before compression and the reformed coal, the cooling effect of the reformed coal is improved, and the generation rate of compression heat of the blown air is increased, thereby further reducing the heating of the blown air energy required.
本发明的第一方案的煤粉吹入装置以上述结构为基础,优选的是,所述热移送机构以将所述改性煤的热量向对所述低品质煤进行改性的改性装置移送的方式构成。The pulverized coal injection device according to the first aspect of the present invention is based on the above-mentioned structure, and it is preferable that the heat transfer mechanism transfers the heat of the reformed coal to the reforming device for reforming the low-quality coal. The method of transfer constitutes.
根据上述结构,在对低品质煤进行改性的改性装置中需要的热量的一部分由改性煤的热量提供,因此能够节约在改性装置中消耗的能量。According to the above configuration, part of the heat required for the reformer for reforming low-quality coal is provided by the heat of the reformed coal, so energy consumed by the reformer can be saved.
本发明的第一方案的煤粉吹入装置以上述结构为基础,优选的是,所述煤粉吹入装置具备非活性化机构,该非活性化机构将所述改性煤非活性化成其自发热作用残留规定量的程度。The pulverized coal injection device according to the first aspect of the present invention is based on the above-mentioned structure, and preferably, the pulverized coal injection device includes an inactivation mechanism for deactivating the modified coal into its The extent to which a specified amount remains due to self-heating.
根据上述结构,改性煤的自发热作用减弱,因此为了避免改性煤自燃而在氮气氛中进行搬运的必要性减少,能够降低氮供给装置的使用率。因此,能够减少高炉设备的运转成本,进而实现生铁的制造成本下降。According to the above configuration, since the self-heating effect of the upgraded coal is weakened, the necessity of conveying the upgraded coal in a nitrogen atmosphere is reduced to avoid spontaneous combustion of the upgraded coal, and the usage rate of the nitrogen supply device can be reduced. Therefore, it is possible to reduce the operating cost of the blast furnace facility, thereby reducing the production cost of pig iron.
本发明的第一方案的煤粉吹入装置以上述结构为基础,优选的是,所述煤粉吹入装置具备混合部,该混合部将由所述改性煤构成的煤粉和通常使用的由原煤构成的煤粉混合,在该混合部及其下游侧,通过所述改性煤的自发热作用使由所述原煤构成的煤粉干燥。The pulverized coal blowing device according to the first aspect of the present invention is based on the above-mentioned structure, and preferably, the pulverized coal blowing device includes a mixing unit that mixes the pulverized coal composed of the modified coal and the commonly used The pulverized coal composed of raw coal is mixed, and the pulverized coal composed of the raw coal is dried by the self-heating action of the reformed coal at the mixing part and its downstream side.
在形成为上述结构的情况下,通过使水分含有率比改性煤高的原煤所构成的煤粉与由改性煤构成的煤粉混合,由此通过具有自发热性的改性煤的热量,来将由原煤构成的煤粉干燥。因此,能够将原煤的干燥工序省略一部分或进行简化。由此,能够削减与干燥工序相关的设备、能量、人员等而减少高炉设备的运转成本,能够实现生铁的制造成本下降。In the case of the above-mentioned structure, by mixing pulverized coal composed of raw coal with a moisture content higher than that of modified coal and pulverized coal composed of modified coal, the heat of the modified coal having self-heating property , to dry the pulverized coal composed of raw coal. Therefore, the drying process of raw coal can be partially omitted or simplified. Thereby, equipment, energy, personnel, etc. related to a drying process can be reduced, and the operation cost of a blast furnace facility can be reduced, and the manufacturing cost of pig iron can be reduced.
本发明的第二方案的高炉设备具备上述任一种结构的煤粉吹入装置。A blast furnace facility according to a second aspect of the present invention includes a pulverized coal injection device having any one of the structures described above.
根据该高炉设备,使用廉价的改性煤作为当成辅助燃料而向高炉主体的内部吹入的煤粉的原料,因此能够降低辅助燃料的价格而减少高炉设备的运转成本,能够实现生铁的制造成本下降,并且能够有效利用改性煤自发热时的热量。According to this blast furnace facility, cheap reformed coal is used as a raw material for the pulverized coal blown into the blast furnace body as an auxiliary fuel, so the price of the auxiliary fuel can be reduced to reduce the operating cost of the blast furnace facility, and the production cost of pig iron can be achieved. Decrease, and can effectively use the heat of self-heating of modified coal.
另外,本发明的第三方案的煤粉供给方法是将煤粉与被加热及压缩后的吹入空气一起从高炉主体的风口吹入时的煤粉供给方法,其中,使用对低品质煤进行改性后的改性煤作为所述煤粉的原料,将该改性煤的自发热作用产生的热量向需要热量的部位移送而利用。In addition, the pulverized coal supply method of the third aspect of the present invention is a pulverized coal supply method when the pulverized coal is blown in from the tuyeres of the main body of the blast furnace together with heated and compressed blown air. The modified modified coal is used as a raw material for the above-mentioned pulverized coal, and the heat generated by the self-heating action of the modified coal is transferred to a location requiring heat.
根据该煤粉供给方法,由于作为辅助燃料而向高炉主体的内部吹入的煤粉成为廉价的改性煤,因此能够使辅助燃料的价格降低而实现生铁的制造成本下降。并且,将改性煤的自发热作用产生的热量向需要热量的部位移送而进行有效利用,能够削减为了在该部位产生热量所耗费的燃料或电力等,从而能够减少高炉设备的运转成本,进而实现生铁的制造成本下降。According to this pulverized coal supply method, since the pulverized coal blown into the inside of the blast furnace body as an auxiliary fuel becomes inexpensive reformed coal, the price of the auxiliary fuel can be lowered to reduce the production cost of pig iron. In addition, the heat generated by the self-heating action of the reformed coal can be effectively used by transferring the heat generated by the self-heating action of the reformed coal to the place where heat is needed, and the fuel or electricity consumed to generate heat at this place can be reduced, thereby reducing the operating cost of the blast furnace equipment, and further Realize the reduction of the manufacturing cost of pig iron.
另外,本发明的第三方案的煤粉供给方法以上述的方法为基础,优选的是,将所述改性煤非活性化成其自发热作用残留规定量的程度。In addition, the pulverized coal supply method according to the third aspect of the present invention is based on the method described above, and preferably deactivates the modified coal to such an extent that a predetermined amount of self-heating action remains.
根据上述方法,改性煤的自发热作用减弱,因此为了避免改性煤自燃而在氮气氛中进行搬运的必要性减少,能够降低氮的供给装置的使用率。因此,能够减少高炉设备的运转成本,进而实现生铁的制造成本下降。According to the method described above, since the self-heating effect of the modified coal is weakened, the necessity of conveying the modified coal in a nitrogen atmosphere is reduced to avoid spontaneous combustion of the modified coal, and the usage rate of the nitrogen supply device can be reduced. Therefore, it is possible to reduce the operating cost of the blast furnace facility, thereby reducing the production cost of pig iron.
本发明的第四方案的煤粉供给方法是将煤粉与被加热及压缩后的吹入空气一起从高炉主体的风口吹入时的煤粉供给方法,其中,将对低品质煤进行改性后的改性煤所构成的煤粉和通常使用的由原煤构成的煤粉混合,通过所述改性煤的自发热作用,使由所述原煤构成的煤粉干燥。The pulverized coal supply method according to the fourth aspect of the present invention is a pulverized coal supply method when the pulverized coal is blown in from the tuyere of the main body of the blast furnace together with the heated and compressed blown air, wherein the low-quality coal is modified The pulverized coal composed of the final modified coal is mixed with the pulverized coal composed of raw coal that is generally used, and the pulverized coal composed of the raw coal is dried by the self-heating action of the modified coal.
根据上述煤粉供给方法,通过使水分含有率比改性煤高的原煤所构成的煤粉与由改性煤构成的煤粉混合,由此通过具有自发热性的改性煤的热量,来将由原煤构成的煤粉干燥,因此能够将原煤的干燥工序省略一部分或进行简化。由此,能够削减与干燥工序相关的设备、能量、人员等而减少高炉设备的运转成本,能够实现生铁的制造成本下降。According to the above pulverized coal supply method, by mixing pulverized coal composed of raw coal having a moisture content higher than that of modified coal and pulverized coal composed of modified coal, the heat generated by the self-heating modified coal is used to generate Since the pulverized coal composed of raw coal is dried, part of the drying process of raw coal can be omitted or simplified. Thereby, equipment, energy, personnel, etc. related to a drying process can be reduced, and the operation cost of a blast furnace facility can be reduced, and the manufacturing cost of pig iron can be reduced.
发明效果Invention effect
如以上所示,根据本发明的煤粉吹入装置、具备该煤粉吹入装置的高炉设备以及煤粉供给方法,能够减少高炉设备的运转成本而实现生铁的制造成本下降。As described above, according to the pulverized-coal injection device, the blast furnace facility including the pulverized-coal injection device, and the pulverized-coal supply method of the present invention, it is possible to reduce the operating cost of the blast furnace facility and reduce the production cost of pig iron.
附图说明Description of drawings
图1是具备本发明的第一实施方式的煤粉吹入装置的高炉设备的简要结构图。Fig. 1 is a schematic configuration diagram of a blast furnace facility equipped with a pulverized coal injection device according to a first embodiment of the present invention.
图2是具备本发明的第二实施方式的煤粉吹入装置的高炉设备的简要结构图。Fig. 2 is a schematic configuration diagram of a blast furnace facility equipped with a pulverized coal injection device according to a second embodiment of the present invention.
图3是具备本发明的第三实施方式的煤粉吹入装置的高炉设备的简要结构图。Fig. 3 is a schematic configuration diagram of a blast furnace facility equipped with a pulverized coal injection device according to a third embodiment of the present invention.
图4是具备本发明的第四实施方式的煤粉吹入装置的高炉设备的简要结构图。Fig. 4 is a schematic configuration diagram of a blast furnace facility equipped with a pulverized coal injection device according to a fourth embodiment of the present invention.
图5是具备本发明的第五实施方式的煤粉吹入装置的高炉设备的简要结构图。Fig. 5 is a schematic configuration diagram of a blast furnace facility equipped with a pulverized coal injection device according to a fifth embodiment of the present invention.
具体实施方式Detailed ways
以下,基于图1~图5,对本发明的多个实施方式进行说明。Hereinafter, several embodiments of the present invention will be described based on FIGS. 1 to 5 .
[第一实施方式][first embodiment]
图1是具备本发明的第一实施方式的煤粉吹入装置5A的高炉设备1A的简要结构图。该高炉设备1A具备高炉主体2、原料定量供给装置3、装入输送设备4及煤粉吹入装置5A。Fig. 1 is a schematic configuration diagram of a blast furnace facility 1A provided with a pulverized coal injection device 5A according to a first embodiment of the present invention. This blast furnace facility 1A includes a blast furnace main body 2 , a raw material quantitative supply device 3 , a loading conveyance device 4 , and a pulverized coal injection device 5A.
高炉主体2具备通常的结构,在其顶部设有炉顶料斗7,在下部设有风口8和生铁出口9。吹管11与风口8连接,喷枪12以向该吹管11倾斜合流的方式与该吹管11连接。The blast furnace main body 2 has a general structure, and a top hopper 7 is provided at the top thereof, and a tuyere 8 and a pig iron outlet 9 are provided at the lower part. The blowpipe 11 is connected to the tuyere 8 , and the spray gun 12 is connected to the blowpipe 11 in such a way that it merges obliquely to the blowpipe 11 .
装入输送设备4以从高炉主体2的基部附近朝向炉顶料斗7上升的方式设置,该装入输送设备4的搬运方向下游端(上端部)位于炉顶料斗7的正上方,在搬运方向上游端(下端部)的正上部设置有原料定量供给装置3。The loading and conveying equipment 4 is arranged to rise from the vicinity of the base of the blast furnace main body 2 toward the furnace top hopper 7, and the downstream end (upper end) of the loading and conveying equipment 4 is located directly above the furnace top hopper 7 in the conveying direction. A raw material quantitative supply device 3 is provided directly above the upstream end (lower end).
原料定量供给装置3将在高炉主体2内冶炼的作为生铁14的主原料的铁矿石、作为燃料及还原材料的焦炭、作为杂质除去材料的石灰石这样的原料以恒定的供给速度向装入输送设备4供给,通过装入输送设备4将上述的原料从炉顶料斗7向高炉主体2内装入,冶炼后的生铁14积存在高炉主体2内的底部。冶炼后的生铁14被从生铁出口9取出。The raw material quantitative supply device 3 transports raw materials such as iron ore as the main raw material of pig iron 14 smelted in the blast furnace main body 2, coke as a fuel and reducing material, and limestone as a material for removing impurities to the charge at a constant supply speed. The equipment 4 supplies, and the above-mentioned raw materials are loaded into the blast furnace main body 2 from the furnace top hopper 7 through the loading conveying equipment 4, and the smelted pig iron 14 is accumulated at the bottom of the blast furnace main body 2. The pig iron 14 after smelting is taken out from pig iron outlet 9.
另一方面,煤粉吹入装置5A将作为辅助燃料的煤粉(PCI煤)与被加热及压缩后的热风状的吹入空气一起从高炉主体2的风口8(吹管11)吹入,使高炉主体2内的温度上升。该煤粉吹入装置5A具备改性装置16、装入线路17、氮气送给装置18、旋风分离器19、贮存箱21、煤粉供给管22及吹入空气送给装置23等。On the other hand, the pulverized coal blowing device 5A blows pulverized coal (PCI coal) as an auxiliary fuel together with heated and compressed hot blast-like blown air from the tuyere 8 (blowpipe 11) of the blast furnace main body 2, so that The temperature inside the blast furnace main body 2 rises. This pulverized coal injection device 5A includes a reformer 16, a charging line 17, a nitrogen gas supply device 18, a cyclone separator 19, a storage tank 21, a pulverized coal supply pipe 22, an air blowing device 23, and the like.
改性装置16与旋风分离器19之间由装入线路17连接,在装入线路17的上游部连接有氮气送给装置18。另外,贮存箱21与喷枪12之间由煤粉供给管22连接。而且,在吹入空气送给装置23中生成的热风状的吹入空气向吹管11供给。The reforming device 16 and the cyclone separator 19 are connected by a charging line 17 , and a nitrogen gas feeding device 18 is connected upstream of the charging line 17 . In addition, the pulverized coal supply pipe 22 is connected between the storage tank 21 and the spray gun 12 . Then, the blown air in the form of hot air generated by the blown air supply device 23 is supplied to the blowpipe 11 .
由于改性装置16的结构是公知的,因此省略其详细的说明,但简要地讲,改性装置16是如下这样的装置:将廉价的次烟煤或褐煤等低品质煤的性质改性成适合作为高炉主体2的辅助燃料的性质,并且将其粉碎而生成辅助燃料用的煤粉(PCI煤)。在该改性装置16中,从接受料斗24投入的低品质煤被进行多次干燥·加热处理而除去水分及挥发成分,之后被冷却,且通过磨机粉碎而成为辅助燃料用的煤粉。Since the structure of the modifying device 16 is well known, its detailed description is omitted, but in brief, the modifying device 16 is a device that modifies the properties of low-quality coal such as cheap sub-bituminous coal or lignite to a suitable It is pulverized to produce pulverized coal (PCI coal) as an auxiliary fuel for the blast furnace main body 2 . In this reformer 16, the low-quality coal fed from the receiving hopper 24 is dried and heated multiple times to remove moisture and volatile components, then cooled, and pulverized by a mill to become pulverized coal for auxiliary fuel.
吹入空气送给装置23是如下这样的装置:通过未图示的压缩机将从空气吸入管25吸入的空气压缩,并且通过未图示的加热器或燃烧器将该空气加热至1200℃左右,从而生成煤粉吹入用的高温·高压、且干燥后的吹入空气。The blown air supply device 23 is a device that compresses the air sucked in from the air suction pipe 25 by a compressor not shown, and heats the air to about 1200° C. by a heater or a burner not shown. , thereby generating high-temperature, high-pressure and dried blown air for pulverized coal blowing.
空气吸入管25的中间部分成形为例如在煤粉供给管22的周围环绕多圈的螺旋状,该螺旋部分成为热交换器25a。该热交换器25a作为热移送机构而发挥功能,该热移送机构将在煤粉供给管22的内部通过的改性煤的自发热作用产生的热量向需要热量的部位、例如本实施方式中的吹入空气送给装置23移送。The middle part of the air suction pipe 25 is formed, for example, in a spiral shape that wraps multiple turns around the pulverized coal supply pipe 22, and this spiral part serves as a heat exchanger 25a. This heat exchanger 25a functions as a heat transfer mechanism that transfers the heat generated by the self-heating action of reformed coal passing through the inside of the pulverized coal supply pipe 22 to a location requiring heat, for example, in this embodiment. Blowing air is sent to the device 23 for transfer.
在以上那样构成的煤粉吹入装置5A中,通过改性装置16从低品质煤改性得到的改性煤所构成的煤粉向装入线路17输送,与从氮气送给装置18送给的氮气混合而成为固气二相流,并在氮气的非活性气氛中向旋风分离器19送给。旋风分离器19是离心分离装置的一种,通过离心力将氮气从煤粉进行分离·脱气,并将氮气向外部放出或回收。之后,煤粉积存于贮存箱21,仅将必要的量从煤粉供给管22向喷枪12供给。In the pulverized coal blowing device 5A constituted as above, the pulverized coal composed of the reformed coal obtained by reforming the low-quality coal through the reformer 16 is conveyed to the charging line 17, and is sent from the nitrogen gas feeding device 18. Nitrogen gas is mixed to form a solid-gas two-phase flow, which is sent to the cyclone separator 19 in an inert atmosphere of nitrogen gas. The cyclone separator 19 is a type of centrifugal separation device, and separates and degasses nitrogen gas from pulverized coal by centrifugal force, and releases or recovers nitrogen gas to the outside. Thereafter, the pulverized coal is stored in the storage tank 21 , and only a necessary amount is supplied from the pulverized coal supply pipe 22 to the spray gun 12 .
另一方面,从空气吸入管25吸入并向吹入空气送给装置23供给的空气(外部气体)通过在空气吸入管25的中途形成的热交换器25a时,与在煤粉供给管22的内部以比较缓慢的速度下降的改性煤所构成的煤粉具有的自发热作用产生的热量进行热交换,从而温度上升,载持该热量并向吹入空气送给装置23供给,在吹入空气送给装置23中被进一步压缩、加热而成为1200℃左右的高温·高压的热风。即,吹入空气在由吹入空气送给装置23压缩·加热之前与改性煤进行热交换。On the other hand, when the air (external air) sucked from the air suction pipe 25 and supplied to the blown air delivery device 23 passes through the heat exchanger 25a formed in the middle of the air suction pipe 25, it is connected with the air in the pulverized coal supply pipe 22. The heat generated by the self-heating effect of the pulverized coal composed of modified coal that descends at a relatively slow speed in the interior is exchanged for heat, so that the temperature rises, and the heat is carried and supplied to the blowing air supply device 23. The air is further compressed and heated in the air supply device 23 to become high-temperature and high-pressure hot air at about 1200°C. That is, the blown air exchanges heat with the reformed coal before being compressed and heated by the blown air supply device 23 .
然后,供给到喷枪12中的煤粉(改性煤)与供给到吹管11中的吹入空气混合,煤粉与高温的热风状的吹入空气接触而点火·燃烧,在吹管11的前端变成火焰而形成燃烧空窝(raceway),使装入到高炉主体2内的焦炭燃烧。由此,与焦炭一起装入的铁矿石被还原而成为生铁(铁液)14,从生铁出口9被取出。Then, the pulverized coal (modified coal) supplied to the spray gun 12 is mixed with the blown air supplied to the blowpipe 11, and the pulverized coal is ignited and combusted in contact with the high-temperature hot air blown air, and becomes A flame is formed to form a combustion raceway, and coke charged into the blast furnace main body 2 is combusted. Thereby, the iron ore charged together with the coke is reduced to become pig iron (liquid iron) 14 , which is taken out from the pig iron outlet 9 .
以上那样构成的煤粉吹入装置5A使用从低品质煤改性而具有自发热性的改性煤所构成的煤粉,作为与被加热及压缩后的吹入空气一起从高炉主体2的风口8吹入的煤粉。改性煤与通常使用的烟煤等原煤相比价格非常低,因此能够降低辅助燃料的价格而减少高炉设备1A的运转成本,从而能够实现生铁的制造成本下降。另外,能够将改性煤的热量有效利用于需要热量的其他的部位而有助于节能化。The pulverized coal blowing device 5A configured as above uses pulverized coal composed of self-heating self-heating reformed coal as a tuyere from the blast furnace main body 2 together with the heated and compressed blown air. 8 Blown in pulverized coal. Since reformed coal is much cheaper than raw coal such as bituminous coal that is generally used, the price of auxiliary fuel can be reduced to reduce the operating cost of the blast furnace facility 1A, thereby reducing the production cost of pig iron. In addition, the heat of upgraded coal can be effectively used in other parts that require heat, thereby contributing to energy saving.
另外,在本实施方式中,作为将从改性煤生成的煤粉的自发热作用产生的热量向需要热量的其他的部位移送的热移送机构的一例,在由吹入空气送给装置23吸入的空气所通过的空气吸入管25的中间部分设置热交换器25a,在该热交换器25a的内部通过的空气与在煤粉供给管22的内部通过的煤粉的热量进行热交换。因此,吹入空气在其吹入之前与煤粉进行热交换而被适度加热。In addition, in this embodiment, as an example of the heat transfer mechanism that transfers the heat generated by the self-heating action of the pulverized coal generated from the reformed coal to other parts that require heat, the blown air supply device 23 inhales The middle part of the air suction pipe 25 through which the air passes is provided with a heat exchanger 25a, and the heat of the air passing through the inside of the heat exchanger 25a and the heat of the pulverized coal passing through the inside of the pulverized coal supply pipe 22 are exchanged. Therefore, the blown air is moderately heated by exchanging heat with the pulverized coal before blowing it in.
因此,能够大幅节约在吹入空气送给装置23中为了对吹入空气进一步加热所耗费的燃料或电力等能量,能够进一步减少高炉设备1A的运转成本而有助于生铁的制造成本下降。另外,在煤粉供给管22内通过的改性煤的热量由热交换器25a移送,从而将改性煤冷却,因此能够防止改性煤的自燃。Therefore, energy such as fuel and electric power consumed to further heat the blown air in the blown air feeding device 23 can be greatly saved, and the operating cost of the blast furnace facility 1A can be further reduced to contribute to the reduction of the production cost of pig iron. In addition, since the heat of the reformed coal passing through the pulverized coal supply pipe 22 is transferred by the heat exchanger 25a to cool the reformed coal, spontaneous combustion of the reformed coal can be prevented.
尤其是使由吹入空气送给装置23压缩之前的冷的吹入空气与改性煤进行了热交换,因此能够提高煤粉供给管22中的改性煤的冷却效果,并且提高吹入空气的压缩热的产生率,且使吹入空气的加热用的能量进一步减少。In particular, the cold blown air before being compressed by the blown air delivery device 23 is heat-exchanged with the reformed coal, so the cooling effect of the reformed coal in the pulverized coal supply pipe 22 can be improved, and the blown air can be improved. The generation rate of compression heat, and the energy for heating the blown air is further reduced.
[第二实施方式][Second Embodiment]
图2是具备本发明的第二实施方式的煤粉吹入装置5B的高炉设备1B的简要结构图。Fig. 2 is a schematic configuration diagram of a blast furnace facility 1B provided with a pulverized coal injection device 5B according to a second embodiment of the present invention.
在该煤粉吹入装置5B中,与第一实施方式(图1)的煤粉吹入装置5A的不同点在于,具备从改性装置16延伸出的热移送管32(热移送机构),该热移送管32以在煤粉供给管22的周围环绕多圈而再次向改性装置16返回的方式配设。该热移送管32的环绕部分成为与第一实施方式的煤粉吹入装置5A的热交换器25a同样的热交换器32a。成为热介质的流体在热移送管32的内部循环。其他的部分的结构与第一实施方式的煤粉吹入装置5A相同,因此对各部分标注同一符号而省略说明。This pulverized coal injection device 5B differs from the pulverized coal injection device 5A of the first embodiment (FIG. 1) in that it includes a heat transfer pipe 32 (heat transfer mechanism) extending from the reformer 16, The heat transfer pipe 32 is arranged so as to loop around the pulverized coal supply pipe 22 multiple times and return to the reforming device 16 again. The surrounding portion of the heat transfer pipe 32 is the same heat exchanger 32a as the heat exchanger 25a of the pulverized coal injection device 5A of the first embodiment. A fluid serving as a heat medium circulates inside the heat transfer pipe 32 . The configuration of other parts is the same as that of the pulverized-coal injection device 5A of the first embodiment, and therefore the same reference numerals are assigned to the respective parts, and description thereof will be omitted.
通过在该热移送管32及热交换器32a的内部流动的热介质,将在煤粉供给管22的内部通过的改性煤的自发热作用产生的热量向改性装置16进行热移送。在改性装置16中,该热量例如在使低品质煤干燥的工序中使用。由此,能够节约为了使低品质煤干燥所耗费的能量。The heat generated by the self-heating action of reformed coal passing through the pulverized coal supply pipe 22 is transferred to the reformer 16 by the heat medium flowing through the heat transfer pipe 32 and the heat exchanger 32 a. In the reformer 16, this heat is used, for example, in a step of drying low-quality coal. Thereby, the energy consumed for drying low-quality coal can be saved.
[第三实施方式][Third Embodiment]
图3是具备本发明的第三实施方式的煤粉吹入装置5C的高炉设备1C的简要结构图。Fig. 3 is a schematic configuration diagram of a blast furnace facility 1C including a pulverized coal injection device 5C according to a third embodiment of the present invention.
在该煤粉吹入装置5C中,与第一实施方式(图1)的煤粉吹入装置5A的不同点仅在于,在改性装置16的下游侧夹装有非活性化装置42(非活性化机构),其他部分的结构与煤粉吹入装置5A相同,因此对各部分标注同一符号而省略说明。In this pulverized coal blowing device 5C, the only difference from the pulverized coal blowing device 5A of the first embodiment (FIG. Activation mechanism), and the structure of other parts is the same as that of the pulverized coal injection device 5A, so the same symbols are attached to each part and descriptions are omitted.
在非活性化装置42中,将通过改性装置16从低品质煤改性得到的改性煤非活性化成其自发热作用残留规定量的程度。作为具体的非活性化方法,将在改性装置16中以300℃~500℃干馏后进行冷却了的煤在非活性化装置42中暴露于含有氧的处理气体气氛中,来进行使氧向表面及内部吸附(浸透)的处理。通过对该氧的吸附量进行调整,能够调整改性煤的自发热作用的程度。In the deactivation unit 42 , the reformed coal reformed by the reformer 16 from low-quality coal is deactivated to such an extent that a predetermined amount of self-heating action remains. As a specific deactivation method, the coal that has been carbonized at 300° C. to 500° C. in the reformer 16 and then cooled is exposed to a treatment gas atmosphere containing oxygen in the deactivation device 42 to transfer oxygen to the gas. Surface and internal adsorption (soaking) treatment. By adjusting the amount of oxygen absorbed, the degree of self-heating of the modified coal can be adjusted.
在本实施方式中,由非活性化装置42结束非活性化处理而向装入线路17送出的改性煤将非活性化装置42中的处理的程度设定为保存一定程度的自发热作用的程度。In this embodiment, the degree of treatment in the deactivation device 42 is set to preserve a certain degree of self-heating effect for the upgraded coal sent to the charging line 17 after finishing the deactivation treatment by the deactivation device 42. degree.
通过设置这样的非活性化装置42,能够减弱改性煤的自发热作用,因此能够消除为了避免改性煤自燃而在氮气氛中进行搬运的必要性,或者降低氮气的使用量。因此,能够降低氮气送给装置18的运转率降低,减少高炉设备1C的运转成本,进而实现生铁的制造成本下降。By providing such an inactivation device 42, the self-heating effect of the reformed coal can be weakened, so the necessity of transporting the reformed coal in a nitrogen atmosphere to avoid spontaneous combustion can be eliminated, or the amount of nitrogen gas used can be reduced. Therefore, it is possible to reduce the decrease in the operating rate of the nitrogen gas feeding device 18, reduce the operating cost of the blast furnace facility 1C, and further reduce the production cost of pig iron.
[第四实施方式][Fourth Embodiment]
图4是具备本发明的第四实施方式的煤粉吹入装置5D的高炉设备1D的简要结构图。Fig. 4 is a schematic configuration diagram of a blast furnace facility 1D including a pulverized coal injection device 5D according to a fourth embodiment of the present invention.
在该煤粉吹入装置5D中,与第一实施方式(图1)的煤粉吹入装置5A的不同点在于,在煤粉吹入装置5A中,仅将由改性装置16改性后的改性煤所构成的煤粉向高炉主体2供给,与此相对,在该煤粉吹入装置5D中,将由改性煤构成的煤粉和通常使用的由原煤构成的煤粉混合而向高炉主体2供给。In this pulverized coal blowing device 5D, the point of difference from the pulverized coal blowing device 5A of the first embodiment (FIG. 1) is that in the pulverized coal blowing device 5A, only the The pulverized coal composed of modified coal is supplied to the blast furnace main body 2. On the other hand, in the pulverized coal injection device 5D, the pulverized coal composed of modified coal and the pulverized coal composed of raw coal generally used are mixed and supplied to the blast furnace. Subject 2 supplies.
在煤粉吹入装置5D中具备2台旋风分离器19A、19B,在旋风分离器19A、19B的下游部设有混合管52(混合部),该混合管52与贮存箱21连接。其他部分的结构与煤粉吹入装置5A相同,因此对各部分标注同一符号而省略说明。The pulverized coal injection device 5D includes two cyclones 19A, 19B, and a mixing pipe 52 (mixing section) is provided downstream of the cyclones 19A, 19B, and the mixing pipe 52 is connected to the storage tank 21 . Since the structure of other parts is the same as 5A of pulverized-coal injection apparatuses, the same code|symbol is attached|subjected to each part, and description is abbreviate|omitted.
在该煤粉吹入装置5D中,将由改性装置16改性后的改性煤所构成的煤粉从装入线路17向旋风分离器19A供给。另外,将由原煤构成的煤粉通过未图示的供给装置向旋风分离器19B供给。而后,在混合管52中将2种煤粉混合并向贮存箱21积存。然后,将2种煤粉以混合的状态与经由煤粉供给管22从吹入空气送给装置23供给的热风状的吹入空气一起向高炉主体2供给。In this pulverized coal injection device 5D, pulverized coal composed of reformed coal reformed by the reformer 16 is supplied from the charging line 17 to the cyclone 19A. In addition, pulverized coal made of raw coal is supplied to the cyclone 19B through a supply device not shown. Then, the two types of pulverized coal are mixed in the mixing pipe 52 and stored in the storage tank 21 . Then, the two kinds of pulverized coal are supplied to the blast furnace main body 2 in a mixed state together with hot air blown air supplied from the blown air supply device 23 via the pulverized coal supply pipe 22 .
在上述结构中,由于由改性煤构成的煤粉和由原煤构成的煤粉在混合管52中混合,因此在混合管52以及其下游侧的贮存箱21及煤粉供给管22内,通过由改性煤构成的煤粉的自发热作用,使由原煤构成的煤粉中含有的水分干燥。In the above structure, since the pulverized coal composed of upgraded coal and the pulverized coal composed of raw coal are mixed in the mixing pipe 52, in the mixing pipe 52 and the storage tank 21 and the pulverized coal supply pipe 22 on the downstream side, the The self-heating action of the pulverized coal composed of modified coal dries the moisture contained in the pulverized coal composed of raw coal.
因此,由原煤构成的煤粉、或原煤自身的干燥工序能够省略一部分或进行简化。由此,能够削减与原煤的干燥工序相关的设备、能量、人员等而减少高炉设备1D的运转成本,从而实现生铁的制造成本下降。Therefore, it is possible to omit a part or simplify the drying process of the pulverized coal made of raw coal or the raw coal itself. Thereby, equipment, energy, personnel, etc. related to the drying process of raw coal can be reduced, and the operation cost of blast furnace facility 1D can be reduced, and the manufacturing cost of pig iron can be reduced.
[第五实施方式][Fifth Embodiment]
图5是具备本发明的第五实施方式的煤粉吹入装置5E的高炉设备1E的简要结构图。Fig. 5 is a schematic configuration diagram of a blast furnace facility 1E provided with a pulverized coal injection device 5E according to a fifth embodiment of the present invention.
该煤粉吹入装置5E是在第四实施方式(图4)的煤粉吹入装置5D中具备在第三实施方式(图3)的煤粉吹入装置5C中设置的非活性化装置42的结构。通过该非活性化装置42,将通过改性装置16从低品质煤改性得到的改性煤非活性化成其自发热作用残留规定量的程度。其他部分的结构与煤粉吹入装置5D相同。This pulverized coal injection device 5E is equipped with the deactivation device 42 provided in the pulverized coal injection device 5C of the third embodiment ( FIG. 3 ) in the pulverized coal injection device 5D of the fourth embodiment ( FIG. 4 ). Structure. The deactivation device 42 deactivates the reformed coal obtained by reforming the low-quality coal by the reformer 16 to such an extent that a predetermined amount of self-heating action remains. The structure of other parts is the same as that of the pulverized coal blowing device 5D.
改性煤当被完全非活性化时,丧失自发热性,因此在非活性化装置42中避免使改性煤完全非活性化,在由该改性煤构成的煤粉和由原煤构成的煤粉从混合管52通过煤粉供给管22向高炉主体2供给之前的期间,通过由改性煤构成的煤粉的自发热将由原煤构成的煤粉中含有的水分干燥。When the modified coal is completely deactivated, it loses self-heating property, so in the deactivation device 42, the modified coal is prevented from being completely deactivated. Before the pulverized coal is supplied from the mixing pipe 52 to the blast furnace main body 2 through the pulverized coal supply pipe 22, the moisture contained in the pulverized coal composed of raw coal is dried by self-heating of the pulverized coal composed of upgraded coal.
根据该煤粉吹入装置5E,能够将原煤的干燥工序局部省略一部分或进行简化,能够削减与原煤的干燥工序相关的设备、能量、人员等而减少高炉设备1E的运转成本,从而实现生铁的制造成本下降。According to this pulverized coal injection device 5E, the drying process of the raw coal can be partially omitted or simplified, and the equipment, energy, and personnel related to the drying process of the raw coal can be reduced, and the operating cost of the blast furnace equipment 1E can be reduced. Manufacturing costs are reduced.
另外,通过非活性化装置42能够减弱改性煤的自发热作用,因此能够消除为了避免改性煤自燃而在氮气氛中进行搬运的必要性,或者降低氮气的使用量。因此,能够降低氮气送给装置18的运转率,通过这一点也能减少高炉设备1E的运转成本,进而有助于生铁的制造成本下降。In addition, since the self-heating effect of the upgraded coal can be weakened by the deactivation device 42, the necessity of transporting the upgraded coal in a nitrogen atmosphere to avoid spontaneous combustion of the upgraded coal can be eliminated, or the amount of nitrogen gas used can be reduced. Therefore, the operating rate of the nitrogen gas feeding device 18 can be reduced, and this can also reduce the operating cost of the blast furnace facility 1E, thereby contributing to the reduction of the production cost of pig iron.
如以上说明那样,根据上述的各实施方式的煤粉吹入装置5A~5E及煤粉吹入方法,能够减少高炉设备1A~1E的运转成本而实现生铁的制造成本下降。As described above, according to the pulverized coal injection devices 5A to 5E and the pulverized coal injection method of each of the above-mentioned embodiments, it is possible to reduce the operating cost of the blast furnace facilities 1A to 1E and reduce the production cost of pig iron.
本发明没有仅限定为上述各实施方式的结构,在不脱离本发明的主旨的范围内能够适当施加变更或改良,这样施加变更或改良后的实施方式也包含在本发明的权利范围内。The present invention is not limited to the configurations of the above-mentioned embodiments, and changes or improvements can be appropriately added without departing from the gist of the present invention. Embodiments with such changes or improvements are also included in the scope of rights of the present invention.
例如,对改性煤的自发热性产生的热量进行移送的目的地可以不必为高炉设备的内部,也可以向相邻的成套设备、其他的设备移送热量。另外,也可以将各实施方式的结构适当进行组合等。For example, the destination of transferring the heat generated by the self-heating property of reformed coal does not have to be the inside of the blast furnace facility, and the heat may be transferred to adjacent plants or other facilities. In addition, the configurations of the respective embodiments may be combined appropriately.
符号说明:Symbol Description:
1A、1B、1C、1D、1E 高炉设备1A, 1B, 1C, 1D, 1E blast furnace equipment
2 高炉主体2 blast furnace body
3 原料定量供给装置3 Raw material quantitative supply device
4 装入输送设备4 Loading into the conveying equipment
5A、5B、5C、5D、5E 煤粉吹入装置5A, 5B, 5C, 5D, 5E Pulverized coal injection device
7 炉顶料斗7 Furnace top hopper
8 风口8 outlets
9 生铁出口9 pig iron export
11 吹管11 Blowpipe
12 喷枪12 spray guns
14 生铁14 pig iron
16 改性装置16 Modification device
17 装入线路17 load line
18 氮气送给装置18 Nitrogen delivery device
19、19A、19B 旋风分离器19, 19A, 19B cyclone separator
21 贮存箱21 storage boxes
22 煤粉供给管22 Pulverized coal supply pipe
23 吹入空气送给装置23 Blowing air into the device
24 接受料斗24 Accept Hopper
25 空气吸入管25 air suction pipe
25a 热交换器(热移送机构)25a heat exchanger (heat transfer mechanism)
32 热移送管(热移送机构)32 hot transfer tube (hot transfer mechanism)
32a 热交换器(热移送机构)32a heat exchanger (heat transfer mechanism)
42 非活性化装置(非活性化机构)42 Inactivation device (inactivation mechanism)
52 混合管(混合部)52 Mixing tube (mixing part)
Claims (10)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-207274 | 2012-09-20 | ||
| JP2012207274A JP6012360B2 (en) | 2012-09-20 | 2012-09-20 | Pulverized coal blowing device, blast furnace equipment equipped with the same, and pulverized coal supply method |
| PCT/JP2013/074404 WO2014045946A1 (en) | 2012-09-20 | 2013-09-10 | Pulverized coal injection device, blast furnace comprising same, and pulverized coal supply method |
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| CN104641002A true CN104641002A (en) | 2015-05-20 |
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| CN201380048340.5A Pending CN104641002A (en) | 2012-09-20 | 2013-09-10 | Pulverized coal injection device, blast furnace equipment equipped with the pulverized coal injection device, and pulverized coal supply method |
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| Country | Link |
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| US (1) | US20150225804A1 (en) |
| JP (1) | JP6012360B2 (en) |
| KR (1) | KR101648686B1 (en) |
| CN (1) | CN104641002A (en) |
| DE (1) | DE112013004589T5 (en) |
| IN (1) | IN2015DN01917A (en) |
| WO (1) | WO2014045946A1 (en) |
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| CN107119160A (en) * | 2017-07-10 | 2017-09-01 | 中冶华天南京工程技术有限公司 | A kind of blast-furnace coal powder injection method preheated with compressed gas and system |
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| KR101611115B1 (en) * | 2012-01-18 | 2016-04-08 | 미츠비시 쥬고교 가부시키가이샤 | Blast furnace |
| JP6551470B2 (en) * | 2016-07-29 | 2019-07-31 | Jfeスチール株式会社 | Blast furnace operation method |
| JP6551471B2 (en) * | 2016-07-29 | 2019-07-31 | Jfeスチール株式会社 | Blast furnace operation method |
| CN107763651A (en) * | 2017-09-14 | 2018-03-06 | 云南中翼鼎东能源科技开发有限公司 | The method and its coal supply system of a kind of boiler coal feeding |
| CN112725556B (en) * | 2021-01-19 | 2022-06-28 | 付光明 | Method and device for heating pulverized coal by using blast furnace molten iron dedusting circulating hot flue gas |
| CN119040534B (en) * | 2024-10-31 | 2025-02-07 | 太原科峰喷煤有限公司 | An intelligent coal powder injection collection device |
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- 2013-09-10 KR KR1020157006470A patent/KR101648686B1/en not_active Expired - Fee Related
- 2013-09-10 DE DE112013004589.3T patent/DE112013004589T5/en not_active Withdrawn
- 2013-09-10 US US14/428,558 patent/US20150225804A1/en not_active Abandoned
- 2013-09-10 CN CN201380048340.5A patent/CN104641002A/en active Pending
- 2013-09-10 WO PCT/JP2013/074404 patent/WO2014045946A1/en not_active Ceased
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| Publication number | Publication date |
|---|---|
| WO2014045946A8 (en) | 2015-03-12 |
| WO2014045946A1 (en) | 2014-03-27 |
| IN2015DN01917A (en) | 2015-08-07 |
| KR101648686B1 (en) | 2016-08-16 |
| US20150225804A1 (en) | 2015-08-13 |
| JP6012360B2 (en) | 2016-10-25 |
| KR20150040361A (en) | 2015-04-14 |
| DE112013004589T5 (en) | 2015-06-11 |
| JP2014062292A (en) | 2014-04-10 |
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