CN104630780A - Cleaning and brightening solution for copper ware - Google Patents
Cleaning and brightening solution for copper ware Download PDFInfo
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- CN104630780A CN104630780A CN201510075453.5A CN201510075453A CN104630780A CN 104630780 A CN104630780 A CN 104630780A CN 201510075453 A CN201510075453 A CN 201510075453A CN 104630780 A CN104630780 A CN 104630780A
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Abstract
The invention discloses a cleaning and brightening solution for copper ware, belonging to the technical field of processing of daily cleaning detergents. The cleaning and brightening solution for copper ware is prepared from glycerol boric acid fatty acid ester, ethanol, citric acid, thiocarbamide, reduced glutathione, EM (effective microorganism) raw liquor, diatomite and sodium carboxymethyl cellulose. The cleaning and brightening solution for copper ware is suitable for copper ware, can also be used for cleaning stainless steel products, aluminum alloy products, enamel, plastic products and the like, and can increase surface gloss.
Description
Technical field:
The invention belongs to the processing technique field of daily cleaning washing composition, particularly relate to a kind of bronze, brass or copper ware cleaning brightener.
Background technology:
Under physical environment, bronze, brass or copper ware is easily dark and gloomy, tarnishes, and even plays verdigris, corrosion, occurs blackspot, loses its due value.A kind of bronze, brass or copper ware cleaning of the present invention brightener can solve the above problems, and makes the clean light of bronze, brass or copper ware, again gorgeous.
Summary of the invention:
A kind of bronze, brass or copper ware cleaning brightener, glycerol boric acid fatty acid ester, ethanol, citric acid, thiocarbamide, reduced glutathion, EM original solution, diatomite, Xylo-Mucine is adopted to be prepared from, not only be applicable to bronze, brass or copper ware, also can be used for the cleaning of Stainless Steel Products, Al-alloy products, enamel, plastics etc., and can surface luster be increased.
The technical measures that the present invention takes:
A kind of bronze, brass or copper ware cleaning brightener, takes raw material by weight: glycerol boric acid fatty acid ester 10-30 part, ethanol 20-60 part, citric acid 15-45 part, thiocarbamide 5-15 part, reduced glutathion 13-40 part, EM original solution 25-75 part, diatomite 15-45 part, Xylo-Mucine 12-36 part, water 300-900 part.
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
Compared with prior art, the present invention has following beneficial effect:
1, adopting the nonionic surface active agent of the good and good environmental protection of antirust detersive power, glycerol boric acid fatty acid ester to be sanitising agent, reduced glutathion can remove the toxin of metal, EM original solution also can decompose hazardous and noxious substances, remove stink, favourable to ecological, environmental protective, can corrosion be removed to metal, increase gloss.
2, adopt thiocarbamide and powder diatomite can increase the luminance brightness of metallic surface, recover gorgeous, washing function is more comprehensive.
3, product of the present invention not only may be used for bronze, brass or copper ware, also can be used for Stainless Steel Ware, the cleaning light of the crusts such as Al-alloy products, enamel and plastics.
Embodiment:
A kind of bronze, brass or copper ware cleaning brightener, it comprises: take raw material by weight: glycerol boric acid fatty acid ester 10-30 part, ethanol 20-60 part, citric acid 15-45 part, thiocarbamide 5-15 part, reduced glutathion 13-40 part, EM original solution 25-75 part, diatomite 15-45 part, Xylo-Mucine 12-36 part, water 300-900 part.
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
Embodiment 1:
A kind of bronze, brass or copper ware cleaning brightener, takes raw material by weight: glycerol boric acid fatty acid ester 10 parts, ethanol 20 parts, citric acid 15 parts, thiocarbamide 5 parts, reduced glutathion 13 parts, EM original solution 25 parts, 15 parts, diatomite, Xylo-Mucine 12 parts, 300 parts, water.
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
Embodiment 2:
A kind of bronze, brass or copper ware cleaning brightener, takes raw material by weight: glycerol boric acid fatty acid ester 20 parts, ethanol 40 parts, citric acid 30 parts, thiocarbamide 10 parts, reduced glutathion 26 parts, EM original solution 50 parts, 30 parts, diatomite, Xylo-Mucine 24 parts, 600 parts, water.
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
Embodiment 3:
A kind of bronze, brass or copper ware cleaning brightener, takes raw material by weight: glycerol boric acid fatty acid ester 30 parts, ethanol 60 parts, citric acid 45 parts, thiocarbamide 15 parts, reduced glutathion 40 parts, EM original solution 75 parts, 45 parts, diatomite, Xylo-Mucine 36 parts, 900 parts, water.
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
Note: adopt pure water or distilled water, as needed tap water, must place diel just available, because containing chlorinated lime in tap water, unsuitable with biological EM original solution.
Using method: shaken up by this product, pours out the appropriate and water adding 2-3 times amount and mixes thoroughly, bronze, brass or copper ware is put into liquid and soaks 8-15 minute, and shampoo, spot spot disappears for a moment, rinses well with clear water, clean dry cloth is dried, and namely gloss becomes clear, bright yellow as new bronze, brass or copper ware.Also the vessel such as steel, aluminium, enamel, plastics can be shampooed.
Wherein, the physico-chemical property of each raw material and purposes as follows:
Glycerol boric acid fatty acid ester: another name BS product series (BS-20, BS-40, BS-60, BS-80, BS-83, BS-160, BS-260) these series product lipid acid difference used, can obtain the product that outward appearance is different, they are all water insoluble, are soluble in organic solvent.As metal hydraulic rust-inhibiting additive, be widely used as in fiber process, dyeing, ink and makeup.Here metal cleaner, rust-preventive agent is used as.
Ethanol: i.e. alcohol, colourless transparent liquid, inflammable, volatile, can mix arbitrarily with water ether, chloroform, glycerine etc., multiple organic compound and some mineral compound can be dissolved, reactionless with rare acids, bases, salt, generate aldehyde and acetic acid during oxidation, have weak hormesis to eyes.Here solvent is used as.
Citric acid: name citric acid, white translucent crystal or powder.Fusing point 153 DEG C (anhydride).Relative density D418 1.665 (anhydride) d418 1.542 (monohydrate).The citric acid crystallized out from cold solution contains a part water, in dry air, easily promote crystal water.Soluble in water and ethanol, is dissolved in ether.Flammable.Be widely used in raw material and the additive of makeup, metal cleaner, mordant, non-toxic plasticizer and boilercomposition.Foodstuffs industry is used as acidic flavoring agent, health care industry hematinic, blood transfusion agent and alkalosis toxinicide.
Thiocarbamide: white or light yellow glossiness sheet, column or needle crystal, have bitter taste.Relative density (d204) 1.405.Water-soluble and the ethanol of energy, is dissolved in ether hardly, in atmosphere easy deliquescence.Fusing point 180 ~ 182 DEG C.Ammonium thiocyanate is transformed into 150 DEG C time.Under vacuo 150 ~ 160 DEG C time distillation, when 180 DEG C decompose.There is reductibility, free state iodine can be made to be reduced into iodide ion.This product is imbued with reactivity, in order to prepare various compound.Urea, sulfuric acid and other organic compound can be generated with multiple oxidant reaction, also can make diffluent addition compound with mineral compound.Here be used as metal antirusting agent, increase gloss-imparting agent.
Reduced glutathion: white crystals, general merchandise is pale yellow powder, water-soluble, Diluted Alcohol liquid.Fusing point 195 DEG C, [α] D25-18.9 ° (4.5%), [α] D27-21 ° (2.7%).Gsh, through oxidation deoxidation, makes two molecule gsh be combined into Sleep-promoting factor B (GSSG; Relative molecular mass 612.64).GSSG, without physiological function, is still (reduced form) gsh after reduction.Only has reduced glutathion competence exertion physiological action.Detoxification is had to protect body from the murder by poisoning of heavy metal and epoxy compounds.All there is certain detoxification to the poisoning of CO, heavy metal, organic solvent, carcinogenic substance etc., excrete after combining with it.Play a protective role to by symptoms such as radioactive rays, radiopharmaceuticals or the oligoleukocythemia that causes due to antitumor drug.Here reduced form toxinicide is used as.
EM original solution: the good effect flora liquid be made up of many beneficial microorganisms, can kill and stop harmful microorganism to the oxidative attack effect of organic substance, can also decompose various toxin and effect that is smelly, peculiar smell.Metal products is commonly used EM original solution dilution spray and is wiped, and can prevent corrosion.Wash one's face, the rust stain EM original solution of Porcelain Jar of having a bath, porcelain plate directly wipes and can remove rusty stain, sparkling clean.
Diatomite: plant biogenic white or slight yellow powdery siliceous rock, be made up of amorphous SiO2, and containing a small amount of Fe2O3, CaO, MgO, Al2O3 and organic impurity.Light weight and soft, easy grinding powder, vesicular, porosity reaches about 90%.There is very strong adsorptive power, the water of himself weight 1.5 ~ 4.0 times can be absorbed, also have good filterableness, Bleachability, chemical stability and thermal insulation.Here be used as decontamination, decolouring, deodorizing, deacidify and polish effect.
Xylo-Mucine: another name CMC.White fibrous or granulated powders, odorless, have taste, has water absorbability.Its water absorbability is different with the degree of etherification of hydroxyl, and soluble in water and basic solution forms transparent viscose body, and the aqueous solution is to thermally-stabilised, and water-soluble viscosity, with pH value, the polymerization degree and different, reduces with the rising of temperature.Be insoluble to ethanol, ether, acetone and other organic solvent.Purposes, as the deposition agent again of the anti-dirt in synthesis of detergent agent prescription, the thickening material of foodstuffs industry, the sizing agent of lotion of toothpaste, thickening material.
Claims (4)
1. a bronze, brass or copper ware cleaning brightener, it is characterized in that: take raw material by weight, glycerol boric acid fatty acid ester 10-30 part, ethanol 20-60 part, citric acid 15-45 part, thiocarbamide 5-15 part, reduced glutathion 13-40 part, EM original solution 25-75 part, diatomite 15-45 part, Xylo-Mucine 12-36 part, water 300-900 part;
Diatomite was dried and was ground into end use, glycerol boric acid fatty acid ester is put into mixing vessel together with ethanol and mixes dissolving thoroughly, add stand-by water to mix thoroughly, add citric acid, thiocarbamide, reduced glutathion and EM original solution successively, add while stirring, finally add diatomite powder and Xylo-Mucine stirs, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning brightener.
2. according to claim 1, a kind of bronze, brass or copper ware cleaning brightener, it is characterized in that: take raw material by weight, glycerol boric acid fatty acid ester 10 parts, ethanol 20 parts, citric acid 15 parts, thiocarbamide 5 parts, reduced glutathion 13 parts, EM original solution 25 parts, 15 parts, diatomite, Xylo-Mucine 12 parts, 300 parts, water.
3. according to claim 1, a kind of bronze, brass or copper ware cleaning brightener, it is characterized in that: take raw material by weight, glycerol boric acid fatty acid ester 20 parts, ethanol 40 parts, citric acid 30 parts, thiocarbamide 10 parts, reduced glutathion 26 parts, EM original solution 50 parts, 30 parts, diatomite, Xylo-Mucine 24 parts, 600 parts, water.
4. according to claim 1, a kind of bronze, brass or copper ware cleaning brightener, it is characterized in that: take raw material by weight, glycerol boric acid fatty acid ester 30 parts, ethanol 60 parts, citric acid 45 parts, thiocarbamide 15 parts, reduced glutathion 40 parts, EM original solution 75 parts, 45 parts, diatomite, Xylo-Mucine 36 parts, 900 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510075453.5A CN104630780A (en) | 2015-02-11 | 2015-02-11 | Cleaning and brightening solution for copper ware |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510075453.5A CN104630780A (en) | 2015-02-11 | 2015-02-11 | Cleaning and brightening solution for copper ware |
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| CN104630780A true CN104630780A (en) | 2015-05-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510075453.5A Pending CN104630780A (en) | 2015-02-11 | 2015-02-11 | Cleaning and brightening solution for copper ware |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0967600A (en) * | 1995-08-30 | 1997-03-11 | Nippon Denko Kk | Metal surface cleaner |
| CN1436228A (en) * | 2000-06-16 | 2003-08-13 | 巴斯福股份公司 | Oxoalcohol-based detergent |
| CN103003923A (en) * | 2010-07-16 | 2013-03-27 | 高级技术材料公司 | Aqueous cleaner for the removal of post-etch residues |
-
2015
- 2015-02-11 CN CN201510075453.5A patent/CN104630780A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0967600A (en) * | 1995-08-30 | 1997-03-11 | Nippon Denko Kk | Metal surface cleaner |
| CN1436228A (en) * | 2000-06-16 | 2003-08-13 | 巴斯福股份公司 | Oxoalcohol-based detergent |
| CN103003923A (en) * | 2010-07-16 | 2013-03-27 | 高级技术材料公司 | Aqueous cleaner for the removal of post-etch residues |
Non-Patent Citations (3)
| Title |
|---|
| 孙宝国: "《日用化工辞典》", 30 June 2002, 化学工业出版社 * |
| 无: "EM（技术）在环保方面的应用", 《农业新技术》 * |
| 王慎敏: "《精细化工原材料及中间体手册 日用化学品》", 30 June 2005, 化学工业出版社 * |
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Application publication date: 20150520 |