CN104629533A - Fine ink with anti-rust effect for water-borne metal printing - Google Patents
Fine ink with anti-rust effect for water-borne metal printing Download PDFInfo
- Publication number
- CN104629533A CN104629533A CN201510032467.9A CN201510032467A CN104629533A CN 104629533 A CN104629533 A CN 104629533A CN 201510032467 A CN201510032467 A CN 201510032467A CN 104629533 A CN104629533 A CN 104629533A
- Authority
- CN
- China
- Prior art keywords
- water
- parts
- ink
- printing
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000007639 printing Methods 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 12
- 239000002184 metal Substances 0.000 title claims abstract description 12
- 230000000694 effects Effects 0.000 title claims abstract description 10
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000004575 stone Substances 0.000 claims abstract description 8
- 239000001530 fumaric acid Substances 0.000 claims abstract description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 5
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- XISFOXBYRQWDNK-UHFFFAOYSA-N 2-(2-methylphenyl)propan-2-amine;hydrochloride Chemical compound [Cl-].CC1=CC=CC=C1C(C)(C)[NH3+] XISFOXBYRQWDNK-UHFFFAOYSA-N 0.000 claims description 6
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- INGDKSPGWBEWMQ-UHFFFAOYSA-N magnesium;pyridine-2-carboxylic acid Chemical compound [Mg].OC(=O)C1=CC=CC=N1 INGDKSPGWBEWMQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- LVACOMKKELLCHJ-UHFFFAOYSA-N 3-trimethoxysilylpropylurea Chemical compound CO[Si](OC)(OC)CCCNC(N)=O LVACOMKKELLCHJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- DMJHMBZIZMPXEH-UHFFFAOYSA-L magnesium;pyridine-2-carboxylate Chemical compound [Mg+2].[O-]C(=O)C1=CC=CC=N1.[O-]C(=O)C1=CC=CC=N1 DMJHMBZIZMPXEH-UHFFFAOYSA-L 0.000 abstract 1
- 238000005498 polishing Methods 0.000 abstract 1
- 229940057950 sodium laureth sulfate Drugs 0.000 abstract 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 238000002844 melting Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the field of printing ink, and particularly relates to fine ink with an anti-rust effect for water-borne metal printing. The ink is prepared from the following raw materials in parts by weight: 0.5-1 part of magnesium picolinate, 3-5 parts of songhua stone powder, 2-3 parts of gamma-ureidopropyltrimethoxysilane, 3-5 parts of fumaric acid, 5-8 parts of water-based polishing oil, 32-40 parts of water-based acrylic resin emulsion with solid content of 45-60 percent, 10-18 parts of pigment, 1-2 parts of sodium laureth sulfate, 15-25 parts of deionized water and 1-2 parts of auxiliary. The printing ink has high drying speed, strong metal adhesion capability, reliable hardness, fine texture, water proofing, oil resistance and certain anti-rust capability; the auxiliary is beneficial to wettability of ink, bubbles of a coating can be prevented; and the ink feels fine, is low in toxicity and environment-friendly, has bright and durable patterns, is convenient to print without screen blockage, can be used for preventing corrosion of the metal surface, and has excellent printing and using performances.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to the water-based metal printing ink that a kind of exquisiteness has antirust effect.
Background technology
Ink is a class coloured material very conventional in daily life, it is by the mode of the printing carrier as word and pattern, it is the gluey fluid of a kind of stickiness, be widely used in the various printings such as books and periodicals, packing and decorating, building decoration, along with social demand increases, ink kind and output is respective extension and growth also, improves the use properties of ink, and the production model reaching efficient energy-saving is the inevitable direction of following ink development all the time.
The factor affecting the use properties of ink is mainly the performance of the moietys such as pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and such as pigment affects weather resistance and the tinting strength of ink; Low-melting ink vehicle directly affects set speed, the rate of drying and printing quality etc. of ink.Therefore, improve the use properties of ink, the performance from improving these compositions is needed to set about, improve the consistency between each raw material simultaneously, reach collaborative effect promoted, thus improve existing ink ubiquitous heap ink, fall the problems such as printing quality such as version, scumming, dirty version, set-off, to enhance productivity, avoid the waste of resource.
Summary of the invention
The object of the invention is to, provide the water-based metal printing ink that a kind of exquisiteness has antirust effect, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of exquisiteness has the water-based metal printing ink of antirust effect, it is characterized in that, this ink is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5-1, preserved egg stone flour 3-5, urea propyl trimethoxy silicane 2-3, fumaric acid 3-5, water-based gloss oil 5-8, solid content are water based acrylic resin emulsion 32-40, the pigment 10-18 of 45-60%, laureth sodium sulfovinate 1-2, deionized water 15-25, auxiliary agent 1-2;
The raw material of following weight part is comprised: polymine 1-2 in described auxiliary agent, Triethylene glycol 0.5-0.8, trimethyl benzyl ammonia chloride 0.1-0.2, silicon sol 5-8, microfine diatomaceous 1-3, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 20-30%, add Triethylene glycol again, trimethyl benzyl ammonia chloride, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
Described a kind of exquisiteness has the water-based metal printing ink of antirust effect, its preparation method is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 30-50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 60-80min, mix with other remaining component and be heated to 50-60 DEG C, leave standstill 20-30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Ink prepared by the present invention is using water based acrylic resin emulsion as low-melting ink vehicle, rate of drying is fast, adhesive ability is strong, hardness is reliable, with the preserved egg stone flour after urea propyl trimethoxy silicane mixed grinding and pigment, quality is fine and smooth, and waterproof oil resistant and antirust ability strengthen, auxiliary agent contributes to the wettability improving ink, prevents coating bubbles.This ink feel is fine and smooth, low toxic and environment-friendly, fast drying, and with metal adhere firmly, pattern light durable, the convenient not network blocking of printing, can also prevent metallic surface corrosion, have good printing and use properties.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5, preserved egg stone flour 5, urea propyl trimethoxy silicane 3, fumaric acid 3, water-based gloss oil 6, solid content are water based acrylic resin emulsion 34, pigment 14, laureth sodium sulfovinate 2, deionized water 25, the auxiliary agent 1 of 60%; Wherein auxiliary agent is made up of the raw material of following weight part: polymine 1, Triethylene glycol 0.5, trimethyl benzyl ammonia chloride 0.1, silicon sol 6, microfine diatomaceous 2, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 30%, add Triethylene glycol, trimethyl benzyl ammonia chloride again, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
The preparation method of this printing-ink is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 70min, mix with other remaining component and be heated to 50-60 DEG C, leaving standstill 30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, makes the particle diameter of gained slurry be≤20 μm, to obtain final product.
By on the ink printing aluminium sheet obtained by the present embodiment, after its complete drying, the surface property test result of this ink is:
| Test item | Detected result |
| Tinting strength | 100 |
| Viscosity (s/25 DEG C) | 33.4 |
| Sticking power/% | ≥100 |
| First dryness (mm) | 23 |
| Glossiness (60 DEG C, specular gloss instrument) | ＞80 |
| Ethanol-tolerant, soda acid, water tolerance | Nondiscoloration, not come off |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. an exquisiteness has the water-based metal printing ink of antirust effect, it is characterized in that, this printing-ink is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5-1, preserved egg stone flour 3-5, urea propyl trimethoxy silicane 2-3, fumaric acid 3-5, water-based gloss oil 5-8, solid content are water based acrylic resin emulsion 32-40, the pigment 10-18 of 45-60%, laureth sodium sulfovinate 1-2, deionized water 15-25, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: polymine 1-2, Triethylene glycol 0.5-0.8, trimethyl benzyl ammonia chloride 0.1-0.2, silicon sol 5-8, microfine diatomaceous 1-3, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 20-30%, add Triethylene glycol again, trimethyl benzyl ammonia chloride, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
2. a kind of exquisiteness as claimed in claim 1 has the water-based metal printing ink of antirust effect, its preparation method is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 30-50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 60-80min, mix with other remaining component and be heated to 50-60 DEG C, leave standstill 20-30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510032467.9A CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510032467.9A CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104629533A true CN104629533A (en) | 2015-05-20 |
Family
ID=53208794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510032467.9A Pending CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104629533A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679401A (en) * | 2018-12-19 | 2019-04-26 | 王景泉 | A kind of metal surface LED cured printing ink matrix resin and preparation method thereof |
| CN112143266A (en) * | 2020-10-14 | 2020-12-29 | 吉林省春之元硅藻新材料科技有限公司 | Modified pine pollen environment-friendly coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125977A (en) * | 2006-08-15 | 2008-02-20 | 东莞市英科水墨有限公司 | Water flexible painting plate ink and preparing method thereof |
| CN102911558A (en) * | 2012-11-07 | 2013-02-06 | 四川爱科新材料股份有限公司 | Fluorescent water-based ink and preparation method thereof |
| CN104263071A (en) * | 2014-09-09 | 2015-01-07 | 句容市给力包装制品厂 | Water-based gravure ink and preparation method thereof |
-
2015
- 2015-01-22 CN CN201510032467.9A patent/CN104629533A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125977A (en) * | 2006-08-15 | 2008-02-20 | 东莞市英科水墨有限公司 | Water flexible painting plate ink and preparing method thereof |
| CN102911558A (en) * | 2012-11-07 | 2013-02-06 | 四川爱科新材料股份有限公司 | Fluorescent water-based ink and preparation method thereof |
| CN104263071A (en) * | 2014-09-09 | 2015-01-07 | 句容市给力包装制品厂 | Water-based gravure ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679401A (en) * | 2018-12-19 | 2019-04-26 | 王景泉 | A kind of metal surface LED cured printing ink matrix resin and preparation method thereof |
| CN112143266A (en) * | 2020-10-14 | 2020-12-29 | 吉林省春之元硅藻新材料科技有限公司 | Modified pine pollen environment-friendly coating and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150520 |