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CN104599996B - The steam monitoring method of ion injection machine table - Google Patents

The steam monitoring method of ion injection machine table Download PDF

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Publication number
CN104599996B
CN104599996B CN201510052268.4A CN201510052268A CN104599996B CN 104599996 B CN104599996 B CN 104599996B CN 201510052268 A CN201510052268 A CN 201510052268A CN 104599996 B CN104599996 B CN 104599996B
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Prior art keywords
machine table
ion
injection machine
monitor wafer
monitoring method
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CN201510052268.4A
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CN104599996A (en
Inventor
国子明
郭国超
张凌越
姚蕾
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L22/00Testing or measuring during manufacture or treatment; Reliability measurements, i.e. testing of parts without further processing to modify the parts as such; Structural arrangements therefor
    • H01L22/30Structural arrangements specially adapted for testing or measuring during manufacture or treatment, or specially adapted for reliability measurements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/30Electron-beam or ion-beam tubes for localised treatment of objects
    • H01J37/317Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
    • H01J37/3171Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation for ion implantation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L22/00Testing or measuring during manufacture or treatment; Reliability measurements, i.e. testing of parts without further processing to modify the parts as such; Structural arrangements therefor
    • H01L22/30Structural arrangements specially adapted for testing or measuring during manufacture or treatment, or specially adapted for reliability measurements
    • H01L22/34Circuits for electrically characterising or monitoring manufacturing processes, e. g. whole test die, wafers filled with test structures, on-board-devices incorporated on each die, process control monitors or pad structures thereof, devices in scribe line

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Computer Hardware Design (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physical Vapour Deposition (AREA)
  • Testing Or Measuring Of Semiconductors Or The Like (AREA)
  • Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)

Abstract

Present invention is disclosed a kind of steam monitoring method of ion injection machine table, there is provided a monitor wafer;An organic layer is formed in the monitor wafer;The monitor wafer is put into the ion injection machine table, ion implantation technology is carried out to the monitor wafer;Remove the organic layer;And whether the surface of the detection monitor wafer has a surface oxide layer formed in ion implantation technology, if the surface of the monitor wafer has the surface oxide layer, the thickness of the surface oxide layer is detected.The steam monitoring method of the ion injection machine table can conveniently and effectively monitoring ion inject board steam situation.

Description

The steam monitoring method of ion injection machine table
Technical field
The present invention relates to technical field of manufacturing semiconductors, the steam monitoring side of more particularly to a kind of ion injection machine table Method.
Background technology
In semiconductor technology, ion implanting, such as p-type ion or N-type ion are the one kind for changing semiconducting electrical conductivity energy Conventional meanses.Ion implanting is carried out in vacuum board, and existing experiment shows, the moisture content size of ion injection machine table, meeting The depth of interfering ion injection, concentration etc..In some cases, even if the vacuum of board meets the requirements, but moisture content is excessive The yield that will also result in wafer is too low.
In the prior art, the moisture content of ion injection machine table by monitoring ion inject board vacuum condition or The residual gas in the vacuum of ion injection machine table is analyzed using residual gas analyzer.However, monitoring ion injects The method of the vacuum condition of board can reactive ion inject the vacuum condition of board, but can not directly effective reactive ion injection The water-air regime of board;The method cost analyzed using residual gas analyzer the residual gas in vacuum is high, uses Condition is harsh, largely effects on production cost.
The content of the invention
It is an object of the present invention to provide a kind of steam monitoring method of ion injection machine table, conveniently and effectively monitor from The steam situation of son injection board.
In order to solve the above technical problems, the present invention provides a kind of steam monitoring method of ion injection machine table, including:
One monitor wafer is provided;
An organic layer is formed in the monitor wafer;
The monitor wafer is put into the ion injection machine table, ion implantation technology is carried out to the monitor wafer;
Remove the organic layer;And
Whether have the surface oxide layer that in ion implantation technology is formed, if institute if detecting the surface of the monitor wafer There is the surface oxide layer in the surface for stating monitor wafer, detect the thickness of the surface oxide layer.
Further, the organic layer is photoresist layer.
Further, the thickness of the photoresist layer is
Further, the atomic weight of the ion elements in the ion implantation technology is more than or equal to 40.
Further, the ion elements are arsenic element, phosphide element or Ge element.
Further, the Implantation Energy of the arsenic element is 40Kev~60Kev, and implantation dosage is 515/cm2~615/cm2, Injection Current is the μ A of 15000 μ A~17500.
Further, the monitor wafer is blank wafer.
Further, the step of removing the organic layer includes:
Cineration technics is carried out to the monitor wafer;
Pickling is carried out to the monitor wafer.
Further, the temperature of the cineration technics is 200 DEG C~300 DEG C, time of the cineration technics for 30min~ 60min。
Further, pickling is carried out to the monitor wafer using sulfuric acid.
Compared with prior art, the steam monitoring method for the ion injection machine table that the present invention is provided has advantages below:
In the steam monitoring method for the ion injection machine table that the present invention is provided, one is formed in the monitor wafer organic Layer, is then put into the ion injection machine table by the monitor wafer, and ion implantation technology, ion are carried out to the monitor wafer Energy can be produced by striking the surface of the monitor wafer, if there is steam in the ion injection machine table, the energy can make The oxygen element obtained in steam is gathered in the surface of the monitor wafer, and forms surface oxide layer, detects the monitor wafer Whether surface has the surface oxide layer, it can be determined that whether there is steam in the ion injection machine table, it is possible to pass through institute The thickness of surface oxide layer is stated, the number of steam judged.
Brief description of the drawings
Fig. 1 is the flow chart for the steam monitoring method that one embodiment of the invention intermediate ion injects board;
Fig. 2 to Fig. 5 be one embodiment of the invention intermediate ion inject board steam monitoring method during monitor wafer The schematic diagram of surface change.
Embodiment
Steam present in ion injection machine table of the prior art is not easy simply and effectively to detect, inventor couple Prior art research finds that, when the chip in the ion injection machine table carries out ion implanting, hydrone can be with injection The oxygen element that is gathered in the surface of chip, hydrone of ion can form surface oxide layer with the pasc reaction in chip.So And, if between blank wafer is put into the ion injection machine table as monitor wafer, the surface oxide layer be difficult retain On the surface of the blank wafer, so that the surface oxide layer can not be detected.
Inventor further study show that, if the blank wafer surface formed an organic layer, when to the ion When injecting in board the chip progress ion implanting with organic layer, hydrone can be gathered in the table of chip with the ion of injection Oxygen element in face, hydrone can form surface oxide layer with the pasc reaction in chip, and the surface oxide layer can be retained in The surface of chip.
Based on the studies above, inventor proposes a kind of steam monitoring method of ion injection machine table, including:
There is provided a monitor wafer by step S11;
Step S12, forms an organic layer in the monitor wafer;
Step S13, the ion injection machine table is put into by the monitor wafer, and ion implanting is carried out to the monitor wafer Technique;
Step S14, removes the organic layer;And
Whether step S15, detecting the surface of the monitor wafer has a surface oxidation formed in ion implantation technology Layer, if the surface of the monitor wafer has the surface oxide layer, detects the thickness of the surface oxide layer.
In step s 13, ionic bombardment can produce energy to the surface of the monitor wafer, if the ion implantation apparatus There is steam in platform, the energy can make it that the oxygen element in steam is gathered in the surface of the monitor wafer, and form Surface Oxygen Change layer, whether have the surface oxide layer, it can be determined that be in the ion injection machine table if detecting the surface of the monitor wafer It is no to there is steam, it is possible to by the thickness of the surface oxide layer, the number of steam judged.
The steam monitoring method of the ion injection machine table of the present invention is described in more detail below in conjunction with schematic diagram, Which show the preferred embodiments of the present invention, it should be appreciated that those skilled in the art can change invention described herein, And still realize the advantageous effects of the present invention.Therefore, description below is appreciated that for the extensive of those skilled in the art Know, and be not intended as limitation of the present invention.
For clarity, not describing whole features of practical embodiments.In the following description, it is not described in detail known function And structure, because they can make the present invention chaotic due to unnecessary details.It will be understood that opening in any practical embodiments In hair, it is necessary to make a large amount of implementation details to realize the specific objective of developer, such as according to relevant system or relevant business Limitation, another embodiment is changed into by one embodiment.Additionally, it should think that this development is probably complicated and expended Time, but it is only to those skilled in the art routine work.
The present invention is more specifically described by way of example referring to the drawings in the following passage.Will according to following explanation and right Book is sought, advantages and features of the invention will become apparent from.It should be noted that, accompanying drawing is using very simplified form and using non- Accurately ratio, only for the purpose of facilitating and clarifying the purpose of the embodiments of the invention.
The steam monitoring method for the ion injection machine table that refer to Fig. 1-Fig. 5 below to illustrate the present embodiment, wherein, Fig. 1 is the flow chart for the steam monitoring method that one embodiment of the invention intermediate ion injects board;Fig. 2 to Fig. 5 is real for the present invention one Apply the schematic diagram that monitor wafer surface during the steam monitoring method of intermediate ion injection board changes.
As shown in figure 1, step S11 is carried out first, as shown in Figure 2 there is provided a monitor wafer 100, preferably, the monitoring Chip 100 is blank wafer (bare silicon wafer), can reduce error, still, the monitor wafer 100 is not limited In for blank wafer, the monitor wafer 100 can also have the chip of silicon nitride layer for deposition, as long as will not be produced to testing result Raw influence, also within the thought range of the present invention.
Then step S12 is carried out, as shown in figure 3, an organic layer 110 is formed in the monitor wafer 100, preferably, The organic layer 110 is photoresist layer, and in step s 13, the photoresist layer is conducive to retaining the surface oxide layer in the prison Control the surface of chip 100.Wherein, the thickness of the photoresist layer isFor exampleDeng. The organic layer 110 is not limited to as photoresist layer, and the material of also described organic layer 110 can also be polyimides etc., also have Beneficial to the reservation surface oxide layer in the surface of the monitor wafer 100.
Then step S13 is carried out, with reference to Fig. 4, Fig. 4 has reacted in ion implantation process microenvironment in reaction chamber.Such as Fig. 4 It is shown, the monitor wafer 100 is put into the reaction chamber 200 of the ion injection machine table, the monitor wafer 100 is carried out from Sub- injection technology, wherein, direction of the organic layer 110 just to ion implanting.The ion 201 being injected into is along the solid line in Fig. 4 The direction of arrow is propagated, and gets to the surface of the organic layer 110.The pressure of the propagation regions a-quadrant of the ion 201 is small, institute The pressure for stating the non-propagating region B regions (being located at around the a-quadrant) of ion 201 is big, if the ion injection machine table There is steam 202, the steam 202 dotted arrow direction along along Fig. 4 gathers a-quadrant, so that described in reaction chamber 200 Moisture convergence in reaction chamber 200 is in a-quadrant.Steam 202 in a-quadrant is further by the displacement shape of ion 201 Into ion beam be deposited in the surface of the monitor wafer 100.When the ion 201 injects 100 surface of monitor wafer Shock can produce energy, and the energy can cause the oxygen element in steam 202 to be gathered in the surface of the monitor wafer 100, and shape (do not drawn in Fig. 4) into surface oxide layer.In step s 13, the organic layer 110 may be breakdown, so that described The surface of monitor wafer 100 forms the surface oxide layer.
Preferably, the atomic weight of the element of the ion 201 is more than or equal to 40, such as the element of described ion 201 is arsenic Element, phosphide element or Ge element etc..In the present embodiment, the element of the ion 201 is arsenic element, the note of the arsenic element Enter energy for 40Kev~60Kev, implantation dosage is 515/cm2~615/cm2, Injection Current is the μ A of 15000 μ A~17500.
Step S14 is then carried out, the organic layer 110 is removed, so that the surface oxide layer 120 can expose Carry out surface oxide layer 120, as shown in Figure 5.Specifically, step S14 includes following sub-step:
Sub-step S141:Cineration technics is carried out to the monitor wafer 100, preferably, the temperature of the cineration technics is 200 DEG C~300 DEG C, the time of the cineration technics is 30min~60min.
Sub-step S142:Pickling is carried out to the monitor wafer 100, preferably, using sulfuric acid to the monitor wafer 100 Carry out pickling.
Step S15 is finally carried out, whether detect the surface of the monitor wafer 100 has a formation in ion implantation technology Surface oxide layer 120, if there is steam in the reaction chamber 200 of the ion injection machine table, the monitor wafer 100 There is the surface oxide layer 120 in surface, also, the thickness of the surface oxide layer 120 and the ion injection machine table is anti- How much proportional relations of steam in chamber 200 are answered, therefore, it can detect whether the surface of the monitor wafer 100 has the table Face oxide layer 120, it can be determined that whether there is steam in the ion injection machine table, it is possible to pass through the surface oxide layer 120 thickness, judges the number of steam.
In the particular embodiment, the monitor wafer 100 can be put into film thickness measuring board, table described in direct measurement The thickness of face oxide layer 120, if the thickness of the surface oxide layer 120 is 0, illustrates the reaction of the ion injection machine table Steam is not present in chamber 200:If the thickness of the surface oxide layer 120 is smaller, in a preset range (such as) Within, then illustrate that the steam in the reaction chamber 200 of the ion injection machine table is few, the ion injection machine table can normally make With;If the thickness ratio of the surface oxide layer 120 is larger, more than the preset range (such as), such as described table The thickness of face oxide layer 120 isThen illustrate that the steam in the reaction chamber 200 of the ion injection machine table is more, it is necessary to right The ion injection machine table carries out the processing except steam.
Obviously, those skilled in the art can carry out the essence of various changes and modification without departing from the present invention to the present invention God and scope.So, if these modifications and variations of the present invention belong to the scope of the claims in the present invention and its equivalent technologies Within, then the present invention is also intended to comprising including these changes and modification.

Claims (10)

1. a kind of steam monitoring method of ion injection machine table, it is characterised in that including:
One monitor wafer is provided;
An organic layer is formed in the monitor wafer;
The monitor wafer is put into the ion injection machine table, ion implantation technology is carried out to the monitor wafer;
Remove the organic layer;And
Whether have the surface oxide layer that in ion implantation technology is formed, if the prison if detecting the surface of the monitor wafer There is the surface oxide layer in the surface of control chip, detect the thickness of the surface oxide layer.
2. the steam monitoring method of ion injection machine table as claimed in claim 1, it is characterised in that the organic layer is photoresistance Layer.
3. the steam monitoring method of ion injection machine table as claimed in claim 2, it is characterised in that the thickness of the photoresist layer For
4. the steam monitoring method of ion injection machine table as claimed in claim 1, it is characterised in that the ion implantation technology In ion elements atomic weight be more than or equal to 40.
5. the steam monitoring method of ion injection machine table as claimed in claim 4, it is characterised in that the ion elements are arsenic Element, phosphide element or Ge element.
6. the steam monitoring method of ion injection machine table as claimed in claim 5, it is characterised in that the injection of the arsenic element Energy is 40Kev~60Kev, and implantation dosage is 515/cm2~615/cm2, Injection Current is the μ A of 15000 μ A~17500.
7. the steam monitoring method of ion injection machine table as claimed in claim 1, it is characterised in that the monitor wafer is sky White chip.
8. the steam monitoring method of the ion injection machine table as any one of claim 1 to 7, it is characterised in that remove The step of organic layer, includes:
Cineration technics is carried out to the monitor wafer;
Pickling is carried out to the monitor wafer.
9. the steam monitoring method of ion injection machine table as claimed in claim 8, it is characterised in that the temperature of the cineration technics Spend for 200 DEG C~300 DEG C, the time of the cineration technics is 30min~60min.
10. the steam monitoring method of ion injection machine table as claimed in claim 8, it is characterised in that using sulfuric acid to described Monitor wafer carries out pickling.
CN201510052268.4A 2015-01-31 2015-01-31 The steam monitoring method of ion injection machine table Active CN104599996B (en)

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CN104599996B true CN104599996B (en) 2017-08-25

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3196919B1 (en) * 2016-10-20 2018-09-19 FEI Company Cryogenic specimen processing in a charged particle microscope
CN107239632B (en) * 2017-06-20 2020-12-25 上海华力微电子有限公司 Model for simulating penetration depth of ion implantation photoresist and modeling method thereof
CN110504195B (en) * 2019-08-22 2022-03-18 上海华力集成电路制造有限公司 Water vapor monitoring method for reaction cavity
CN113984788B (en) * 2021-12-24 2022-03-15 北京凯世通半导体有限公司 Method for monitoring ultralow temperature ion implantation equipment through optical detection instrument

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CN1632920A (en) * 2003-12-24 2005-06-29 茂德科技股份有限公司 Method for Precisely Controlling Ion Implantation Concentration and Method for Simultaneously Controlling Pressure Compensation Factor
CN101310360A (en) * 2005-11-14 2008-11-19 艾克塞利斯技术公司 Systems and methods that mitigate contamination and modify surface characteristics during ion implantation processes through the introduction of gases
CN103092009A (en) * 2011-11-08 2013-05-08 无锡华润华晶微电子有限公司 Removing method of photoresist used as masking layer of plasma injection
CN104091767A (en) * 2014-06-25 2014-10-08 京东方科技集团股份有限公司 Ion implantation monitoring method
CN104157591A (en) * 2014-08-27 2014-11-19 上海华虹宏力半导体制造有限公司 Method for detecting water vapor in ion injection machine table

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US6777173B2 (en) * 2002-08-30 2004-08-17 Lam Research Corporation H2O vapor as a processing gas for crust, resist, and residue removal for post ion implant resist strip

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1632920A (en) * 2003-12-24 2005-06-29 茂德科技股份有限公司 Method for Precisely Controlling Ion Implantation Concentration and Method for Simultaneously Controlling Pressure Compensation Factor
CN101310360A (en) * 2005-11-14 2008-11-19 艾克塞利斯技术公司 Systems and methods that mitigate contamination and modify surface characteristics during ion implantation processes through the introduction of gases
CN103092009A (en) * 2011-11-08 2013-05-08 无锡华润华晶微电子有限公司 Removing method of photoresist used as masking layer of plasma injection
CN104091767A (en) * 2014-06-25 2014-10-08 京东方科技集团股份有限公司 Ion implantation monitoring method
CN104157591A (en) * 2014-08-27 2014-11-19 上海华虹宏力半导体制造有限公司 Method for detecting water vapor in ion injection machine table

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Inventor after: Guo Ziming

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