A kind of recycling equipment of aquaculture agricultural effluent
Technical field
The present invention relates to agricultural effluent treatment facility field, be specifically related to a kind of recycling equipment of aquaculture agricultural effluent.
Background technology
Over nearly 20 years, intensive aquaculture industry at home and abroad develops rapidly.World Water output reached 1.2 hundred million t in 1996, and wherein 25% for propagating artificially.With this understanding, nitrogen contained by the feed thrown in breeding process, phosphorus approximately only have 9.1% and 17.4% to be assimilated by fish, the pollutent that its remaining feed and fish movement are formed causes severe contamination to water body, settling etc., causes the degeneration of shallow lake, causes marine site, local that red tide occurs; All kinds of pharmaceutical chemicals used in aquaculture and antibiotic residue also pollute water environment, some biological habitats are destroyed, disturbs procreation and the existence of wild stocks, species diversity is reduced; Water pollution simultaneously restricts the development of aquaculture conversely, and therefore, process and the recycle of aquiculture waste water receive publicity gradually.Aquiculture waste water treatment process mainly contains physical treatment process, method of chemical treatment, physicochemical treatment method, biological treatment.
1 physical treatment process 1) filtration method is because the major parts such as the residual bait of the residue in breeding wastewater and aquaculture organism movement are with the existence of suspended state macrobead form, and therefore adopting physical filtering method to remove is method the most quick, economic.Conventional filter plant has mechanical filter, pressure filter, sand filter etc.In actual treatment engineering, mechanical filter (Microfilter) is more, the good mode of filter effect of application.Zeolite filter has filtration and adsorption function concurrently, not only can remove suspended substance, simultaneously again can by dissolved pollutants such as the effective removal heavy metal of adsorption, ammonia nitrogens.
2) foamet foam separation is according to the principle of surface adsorption, and the bubble utilizing ventilation bubbling to be formed in the liquid phase is separated the solute in liquid phase or particle for carrier, is therefore separated also known as steel foams.Its principle passes into air in processed water body, make surfactant in water by micro-bubble sorption, and float to the water surface formation foam, then separating water surface foam with bubble, thus reach the object removing solubilised state and suspended pollutant in waste water.Because the organism such as protein not only can just be removed by foam separating technology before not being mineralized into amide and other toxic substances, avoid toxic substance to accumulate in water body, and necessary dissolved oxygen can be provided to aquaculture water, to safeguarding that aquaculture water ecotope has good action.
Foam separation is the principle according to absorption, to containing surfactant liquid in bubbling, the surfactant in liquid is made to be gathered on liquid-gas interface (surface of bubble), foam layer is formed above main body of liquid, foam layer and liquid phase main body are separated, just can reach the object of condensing surfaces active substance (at foam layer) and purification liquid phase main body.The material be concentrated can be surfactant, also can be can with the material of surfactant phase complexing, but they must possess can complexing or the huge legendary turtle ability of closing with the surfactant of a certain type.
2 methods of chemical treatment 1) there is the suspended substances such as aquaculture organism movement in ozonize method seawater industrial culturing waste water, and the material such as ammonia nitrogen, biodegradable organic, and there is refractory organic.Therefore, utilize the oxygenizement of the chemical oxidizing agents such as ozone, hydrogen peroxide, dioxide peroxide, sodium hypochlorite solution, oxygenolysis difficult for biological degradation dissolved organic matter is the Main Means of breeding wastewater advanced treatment.Therefore adopt O3/UV technique, the consumption that processing efficiency can reduce again ozone can be improved.The object of purification of water quality and water oxygenation can be reached with O3/UV technology purification lake water.The cleaning principle of ozone is that its redox potential in water is 2.07 V, higher than chlorine (1.36 V) and dioxide peroxide (1.5 V).It can destroy the cell walls (film) of Sum decomposition cell, and diffusion is infiltrated in cell rapidly, thus kills pathogenic bacteria.The intermediate material hydroxyl radical free radical (OH) that ozone decomposes in water, has very strong oxidisability, can decompose the organism that general oxygenant difficulty is decomposed.Therefore, use ozonize waste water, can either go out rapidly except objectionable impuritiess such as bacterium, virus and ammonia, oxygen in water can be increased again, thus reach the object of purifying aquaculture waste water.
2) electrochemical process electrochemistry is the science of research electricity and chemical reaction mutual relationship.Electricity and chemical reaction interact to have come by battery, and also can utilize high voltage electrostatic discharge to realize, the two is referred to as electrochemistry, and the latter is an electrochemical branch, claim discharge chemistry.In the process of aquiculture waste water, the result of study removing nitrite and the ammonia nitrogen dissolved in water by electrochemical process shows, the time that nitrite is removed completely and energy consumption reduce along with the increase of conductivity, when received current is 2A to the maximum, consume energy minimum, pH does not almost affect relative to received current and specific conductivity; Be conducive to the removal of nitrite in acid condition, alkaline condition is conducive to the removal of ammonia, and the removal speed of ammonia is lower than the removal speed of nitrite.
3 biological treatment activated sludge processes are main method of the biological wastewater treatment based on active sludge.Activated sludge process passes into air continuously in waste water, the sludge-like throw out formed because of aerobic microbial reproduction after certain hour.It is perched the micropopulation based on zoogloea, there is very strong absorption and the ability of oxidation of organic compounds.Typical activated sludge process is made up of aeration tank, settling tank, sludge recirculation system and excess sludge removal system.Sewage enters aeration tank and forms mixed solution together with the active sludge of backflow.From the pressurized air that air compressor station is sent here, by being laid on the air-diffuser bottom aeration tank, enter in sewage with the form of tiny bubble, object increases the dissolved oxygen content in sewage, mixed solution is also made to be in the state of vigorous agitation, shape suspended state.Dissolved oxygen, active sludge mix mutually with sewage, fully contact, and activated sludge reaction is normally carried out.First stage, the organic pollutant in sewage is adsorbed on zoogleic surface by activated sludge particles, and this is due to its huge specific surface area and polyose emplastic.Some larger molecular organicses are decomposed into small organic molecule under the effect of bacterium extracellular enzyme simultaneously.Subordinate phase, microorganism, under the condition of oxygen abundance, absorbs these organism, and oxygenolysis, form carbonic acid gas and water, the propagation procreation of part supply self.The result that activated sludge reaction carries out, dirty organic pollutants is degraded and is removed, and active sludge itself is multiplied growth, and sewage is then purified process.Mixed solution after activated sludge purification effect enters secondary sedimentation basins, and the active sludge suspended in mixed solution and other solid matters here precipitate and to be separated with water, and the sewage after clarification discharges system as process water.Mud through precipitation concentration is discharged bottom settling tank, and wherein major part is back to aeration tank as seed sludge, to ensure suspended sediment concentration in aeration tank and microorganism concn; The microorganism of propagation is discharged from system, is called " excess sludge ".In fact, pollutent has been transferred in these excess sludges to a great extent from sewage.
Summary of the invention
The present invention proposes a kind of recycling equipment of aquaculture agricultural effluent, the agricultural effluent produced in reusable edible aquaculture process, cost is low, simple to operate, technical process is short, and the mud obtained can return the fertilizer doing agricultural planting, the water water quality recycled improves greatly, can return and carry out aquaculture.
The technical solution used in the present invention is the recycling equipment being specifically achieved in that a kind of aquaculture agricultural effluent, comprise flocculation plant, clarifying plant and oxidation oxygen-increasing device, described flocculation plant comprises flocculation still, premixer is provided with bottom described flocculation still, described premixer's side is communicated with waste water inlet pipe with flocculation agent inlet pipe, the described flocculation agent inlet pipe the other end is connected with flocculation agent pump, described flocculation agent inlet pipe is provided with spinner-type flowmeter, the described waste water inlet pipe the other end is connected with waste water pump, described flocculation still inside is provided with stirring rake, described stirring rake top is connected with agitator motor, described flocculation still side top is provided with overflow port, the outlet of described overflow port is arranged on the side, top of clarifying plant, clarification inclined tube is provided with in described clarifying plant, described clarifying plant top opposite side is provided with clear liquor overflow port, described oxidation oxygen-increasing device comprises oxidation disinfection bath and oxygenation pond, the outlet of described clear liquor overflow port is arranged on the side, top of oxidation disinfection bath, ozonizer is provided with in described oxidation disinfection bath, over-pass is provided with between described oxidation disinfection bath and oxygenation pond, oxygen-adding tube is provided with in described oxygenation pond, water shoot is provided with bottom described oxygenation pond.
Be provided with relief outlet in the middle of described top, premixer, described relief outlet is in immediately below stirring rake.After waste water and flocculation agent mix in premixer, due to the draft of stirring, mixed waste water can be pumped in flocculation still.
Be be provided with mud relief outlet bottom tapered, described clarifying plant bottom described clarifying plant.Cleaning and the discharge of mud can be facilitated.
Described ozonizer passes into the bottom of oxidation disinfection bath, and described ozonizer is provided with multiple ventilating pit.More effectively can improve the oxidation of ozone and the efficiency of sterilization, overcome the shortcoming that ozone solubleness in water is little, improve the utilization ratio of ozone, reduce costs.
Described oxygen-adding tube is that dendritic, described oxygen-adding tube is provided with multiple aperture.Improve the efficiency of oxygen, increase the oxygen dissolution amount in water.
By mixing of waste water and flocculation agent, the deposition efficiency of mud can be made greatly to increase, improve the treatment capacity of waste water, decrease the time of waste water clarification, improve the efficiency of wastewater treatment.The deposition sloped tube simultaneously arranged, can solid sludge in effectively catching waste water, be tapered bottom clarifying plant simultaneously, tapered bottom is provided with mud relief outlet, the discharge of mud can be facilitated, be provided with ozonizer in simultaneous oxidation sterilization pool, ozonizer passes into the bottom of oxidation disinfection bath, ozonizer is provided with multiple ventilating pit.The oxidable ammonia nitrogen of ozone and organism, make it decompose, thus increase water quality, avoid the eutrophication of water, bacterium and pathogenic bacteria can kill by ozone simultaneously, avoid these bacteriums and pathogenic bacteria to cause the big area of aquatic products sick and dead, ozonizer is laid on bottom oxidation disinfection bath simultaneously, ozonizer is provided with multiple ventilating pit simultaneously, more effectively improve the oxidation of ozone and the efficiency of sterilization, overcome the shortcoming that ozone solubleness in water is little, improve the utilization ratio of ozone, reduce costs.Water after oxidation sterilizing enters oxygenation pond, is provided with oxygen-adding tube in oxygenation pond, and oxygen-adding tube is that dendritic, described oxygen-adding tube is provided with multiple aperture.Improve the efficiency of oxygen, increase the oxygen dissolution amount in water.
The invention has the beneficial effects as follows: the agricultural effluent produced in reusable edible aquaculture process, cost is low, simple to operate, technical process is short, and the mud obtained can return the fertilizer doing agricultural planting, the water water quality recycled improves greatly, can return and carry out aquaculture.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Wherein: 1-flocculation plant, 2-clarifying plant, 3-is oxidized oxygen-increasing device, and 4-flocculates still, 5-premixer, 6-flocculation agent inlet pipe, 7-waste water inlet pipe, 8-flocculation agent pump, 9-spinner-type flowmeter, 10-waste water pump, 11-stirring rake, 12-agitator motor, 13-overflow port, 14-clarifies inclined tube, 15-clear liquor overflow port, 16-oxidation disinfection bath, 17-oxygenation pond, 18-ozonizer, 19-over-pass, 20-oxygen-adding tube, 21-water shoot, 22-relief outlet, 23-mud relief outlet.
Embodiment
Below in conjunction with accompanying drawing, the present invention is described further.
As accompanying drawing, the technical solution adopted for the present invention to solve the technical problems is: a kind of recycling equipment of aquaculture agricultural effluent, comprise flocculation plant 1, clarifying plant 2 and oxidation oxygen-increasing device 3, described flocculation plant 1 comprises flocculation still 4, premixer 5 is provided with bottom described flocculation still 4, described premixer 5 side is communicated with waste water inlet pipe 7 with flocculation agent inlet pipe 6, described flocculation agent inlet pipe 6 the other end is connected with flocculation agent pump 8, described flocculation agent inlet pipe 6 is provided with spinner-type flowmeter 9, described waste water inlet pipe 7 the other end is connected with waste water pump 10, described flocculation still 4 inside is provided with stirring rake 11, described stirring rake 11 top is connected with agitator motor 12, described flocculation still 4 side top is provided with overflow port 13, the outlet of described overflow port 13 is arranged on the side, top of clarifying plant 2, clarification inclined tube 14 is provided with in described clarifying plant 2, described clarifying plant 2 top opposite side is provided with clear liquor overflow port 15, described oxidation oxygen-increasing device 3 comprises oxidation disinfection bath 16 and oxygenation pond 17, the outlet of described clear liquor overflow port 15 is arranged on the side, top of oxidation disinfection bath 16, ozonizer 18 is provided with in described oxidation disinfection bath 16, over-pass 19 is provided with between described oxidation disinfection bath 16 and oxygenation pond 17, oxygen-adding tube 20 is provided with in described oxygenation pond 17, water shoot 21 is provided with bottom described oxygenation pond 17.
Be provided with relief outlet 22 in the middle of described top, premixer 5, described relief outlet 22 is in immediately below stirring rake 11.After waste water and flocculation agent mix in premixer, due to the draft of stirring, mixed waste water can be pumped in flocculation still.
Be be provided with mud relief outlet 23 bottom tapered, described clarifying plant 2 bottom described clarifying plant 2.Cleaning and the discharge of mud can be facilitated.
Described ozonizer 18 passes into the bottom of oxidation disinfection bath 16, and described ozonizer 18 is provided with multiple ventilating pit.More effectively can improve the oxidation of ozone and the efficiency of sterilization, overcome the shortcoming that ozone solubleness in water is little, improve the utilization ratio of ozone, reduce costs.
Described oxygen-adding tube 20 is that dendritic, described oxygen-adding tube 20 is provided with multiple aperture.Improve the efficiency of oxygen, increase the oxygen dissolution amount in water.
Waste water and flocculation agent are added according to certain ratio by waste water pump and flocculation agent pump, due to flocculation agent inlet pipe being provided with spinner-type flowmeter, can conveniently measure flocculation dosage, then flocculation agent enters the premixer in flocculation still together with waste water, tentatively mix, then discharging from relief outlet enters in flocculation still, through stirring, then flow in clarifying plant from overflow port, the deposition sloped tube that clarifying plant is arranged, can solid sludge in effectively catching waste water, be tapered bottom clarifying plant simultaneously, tapered bottom is provided with mud relief outlet, the discharge of mud can be facilitated, the supernatant liquor of clarification enters in oxidation disinfection bath from clear liquor overflow port, ozonizer is provided with in oxidation disinfection bath, ozonizer passes into the bottom of oxidation disinfection bath, ozonizer is provided with multiple ventilating pit.The oxidable ammonia nitrogen of ozone and organism, make it decompose, thus increase water quality, avoid the eutrophication of water, bacterium and pathogenic bacteria can kill by ozone simultaneously, avoid these bacteriums and pathogenic bacteria to cause the big area of aquatic products sick and dead, ozonizer is laid on bottom oxidation disinfection bath simultaneously, ozonizer is provided with multiple ventilating pit simultaneously, more effectively improve the oxidation of ozone and the efficiency of sterilization, overcome the shortcoming that ozone solubleness in water is little, improve the utilization ratio of ozone, reduce costs.Water after oxidation sterilizing enters oxygenation pond from over-pass, is provided with oxygen-adding tube in oxygenation pond, and oxygen-adding tube is that dendritic, described oxygen-adding tube is provided with multiple aperture.Improve the efficiency of oxygen, increase the oxygen dissolution amount in water.Water after oxygenation is discharged from water shoot, returns and carries out aquaculture, and the mud of discharging from mud relief outlet can return fertilizer as farm crop owing to being rich in N, P etc.
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.