CN104586651B - Makeup removing composition, preparation method thereof and tissue applying makeup removing composition - Google Patents
Makeup removing composition, preparation method thereof and tissue applying makeup removing composition Download PDFInfo
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- CN104586651B CN104586651B CN201310529925.0A CN201310529925A CN104586651B CN 104586651 B CN104586651 B CN 104586651B CN 201310529925 A CN201310529925 A CN 201310529925A CN 104586651 B CN104586651 B CN 104586651B
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- removing composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title abstract description 12
- 239000003094 microcapsule Substances 0.000 claims abstract description 64
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- 239000011162 core material Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 25
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 17
- 239000008158 vegetable oil Substances 0.000 claims abstract description 17
- 108010010803 Gelatin Proteins 0.000 claims abstract description 16
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 16
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 16
- 239000008273 gelatin Substances 0.000 claims abstract description 16
- 229920000159 gelatin Polymers 0.000 claims abstract description 16
- 235000019322 gelatine Nutrition 0.000 claims abstract description 16
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims abstract description 16
- 235000019198 oils Nutrition 0.000 claims abstract description 16
- 239000003906 humectant Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- -1 methyl ethyl Chemical group 0.000 claims description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 6
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- 241000628997 Flos Species 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000008169 grapeseed oil Substances 0.000 claims description 6
- 210000000582 semen Anatomy 0.000 claims description 6
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 5
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 5
- 241001116389 Aloe Species 0.000 claims description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 4
- 235000011399 aloe vera Nutrition 0.000 claims description 4
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 4
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 3
- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 claims description 3
- 235000003880 Calendula Nutrition 0.000 claims description 3
- 240000001432 Calendula officinalis Species 0.000 claims description 3
- 102000008186 Collagen Human genes 0.000 claims description 3
- 108010035532 Collagen Proteins 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- 241000208680 Hamamelis mollis Species 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 3
- 244000299461 Theobroma cacao Species 0.000 claims description 3
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 claims description 3
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 claims description 3
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 claims description 3
- 229930003268 Vitamin C Natural products 0.000 claims description 3
- 229930003427 Vitamin E Natural products 0.000 claims description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 3
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 claims description 3
- 230000002421 anti-septic effect Effects 0.000 claims description 3
- 239000008163 avocado oil Substances 0.000 claims description 3
- 235000021302 avocado oil Nutrition 0.000 claims description 3
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 3
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 3
- 235000014121 butter Nutrition 0.000 claims description 3
- 235000001046 cacaotero Nutrition 0.000 claims description 3
- 239000007766 cera flava Substances 0.000 claims description 3
- 229920001436 collagen Polymers 0.000 claims description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims description 3
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 3
- 229940043351 ethyl-p-hydroxybenzoate Drugs 0.000 claims description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- 239000000845 maltitol Substances 0.000 claims description 3
- 235000010449 maltitol Nutrition 0.000 claims description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 3
- 229940035436 maltitol Drugs 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000010499 rapseed oil Substances 0.000 claims description 3
- 239000003813 safflower oil Substances 0.000 claims description 3
- 235000005713 safflower oil Nutrition 0.000 claims description 3
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 235000020238 sunflower seed Nutrition 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- 235000019165 vitamin E Nutrition 0.000 claims description 3
- 229940046009 vitamin E Drugs 0.000 claims description 3
- 239000011709 vitamin E Substances 0.000 claims description 3
- 239000010497 wheat germ oil Substances 0.000 claims description 3
- 239000000811 xylitol Substances 0.000 claims description 3
- 235000010447 xylitol Nutrition 0.000 claims description 3
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 3
- 229960002675 xylitol Drugs 0.000 claims description 3
- UMHJEEQLYBKSAN-UHFFFAOYSA-N Adipaldehyde Chemical compound O=CCCCCC=O UMHJEEQLYBKSAN-UHFFFAOYSA-N 0.000 claims description 2
- 244000044822 Simmondsia californica Species 0.000 claims description 2
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 230000006866 deterioration Effects 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 43
- 238000004945 emulsification Methods 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 239000005457 ice water Substances 0.000 description 5
- 239000004519 grease Substances 0.000 description 4
- 239000010773 plant oil Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
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- 239000010410 layer Substances 0.000 description 2
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- 238000012986 modification Methods 0.000 description 2
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- 230000002035 prolonged effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229920000832 Cutin Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
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- 229930003231 vitamin Natural products 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
A makeup removing composition comprises a microcapsule and an emulsion, wherein the microcapsule is mixed in the emulsion, the wall material of the microcapsule is Arabic gum and gelatin, and the core material is vegetable oil; the emulsion contains 20-30% of humectant, 3-15% of emulsifier and deionized water; the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule. The invention also provides a paper towel applying the makeup removing composition and a preparation method of the makeup removing composition. The makeup removing composition disclosed by the invention wraps the vegetable oil with oil stains fused in the makeup removing process in the wall material by utilizing the microcapsule, then the microcapsule and the emulsion are mixed, and when the makeup removing composition is used, the microcapsule is broken by rubbing, so that the core material (vegetable oil) overflows and is combined with the emulsion, the purpose of makeup removing is achieved, and the problem of putrefaction and deterioration caused by contact of the vegetable oil with the external environment and other components in the storage process of the makeup removing composition is effectively avoided.
Description
Technical Field
The invention relates to a makeup removing composition, a preparation method thereof and a tissue using the makeup removing composition.
Background
Makeup removal is a daily routine for the cosmetic population. The makeup is not removed or is not completely removed, pores can be blocked when the cosmetics cover the skin for a long time, the skin can not breathe normally, toxic components in the cosmetics can slowly permeate into skin cutin, and the skin can become large in pores, rough in skin and dull in skin for a long time. Therefore, the makeup removing product is a necessary product, the most core main components of the existing makeup removing product are grease and an emulsifier, the principle of dissolving oil in oil is applied, the grease in the makeup removing oil is fused with the makeup removing oil stain on the skin, and the oil stain is taken away in a water emulsification mode, so that the purpose of makeup removing is achieved. However, after the grease is unsealed and used, the grease inevitably contacts oxygen in the air during storage, receives multiple actions of illumination and temperature change and moisture and other substances in products, and often causes the problems of deterioration and putrefaction, bacterial growth and active substance failure. And the fats and oils which have been deteriorated and putrefactive may generate unpleasant taste and smell.
Disclosure of Invention
In view of the above, there is a need for a make-up remover composition that is effective in preventing the decay of oils and fats.
In addition, a tissue added with the makeup removing composition is also needed.
In addition, a preparation method of the makeup removing composition is also needed.
A makeup removing composition comprises a microcapsule and an emulsion, wherein the microcapsule is mixed in the emulsion, the wall material of the microcapsule is Arabic gum and gelatin, and the core material is vegetable oil; the emulsion contains 20-30% of humectant, 3-15% of emulsifier and deionized water; the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule.
A paper towel applying the makeup removing composition, wherein the makeup removing composition is directly applied to at least one surface of paper.
A method of preparing a make-up removal composition comprising the steps of:
dissolving a wall material in deionized water to prepare a wall material solution, wherein the wall material is Arabic gum and gelatin;
adding a core material into the wall material solution, stirring and emulsifying, wherein the core material is vegetable oil;
keeping stirring, adding deionized water, slowly dropwise adding acid to adjust the pH value to 3.7-5.0, and promoting the microcapsules to wrap to form a microcapsule solution;
mixing 20-30% of humectant, 3-15% of emulsifier and a proper amount of deionized water to obtain an emulsion;
adding the microcapsule into the emulsion, and uniformly stirring, wherein the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule.
The makeup removing composition disclosed by the invention wraps the vegetable oil with oil stains fused in the makeup removing process in the wall material by utilizing the microcapsule, then the microcapsule and the emulsion are mixed, and the microcapsule is broken when in use, so that the core material (vegetable oil) overflows and is combined with the emulsion, and the purpose of makeup removing is achieved, therefore, the problem of putrefaction deterioration caused by contact of the vegetable oil with the external environment and other components in the storage process of the makeup removing composition is effectively avoided, and the service life of the makeup removing composition is prolonged.
Detailed Description
The preparation method of the makeup removing composition comprises the following steps:
(a) preparation of wall material solution: adding the wall material into deionized water, heating and dissolving to prepare a wall material solution with the concentration of 8-12% for later use.
The wall material is prepared from Arabic gum and gelatin, wherein the mass ratio of the Arabic gum to the gelatin is 1: 1 and 1: 1.5.
(b) Emulsification of core material and wall material: adding a core material into the wall material solution, and performing mechanical high-speed emulsification, wherein the mass ratio of the core material to the wall material is 4: 1-8: 1.
the core material is vegetable oil, and is selected from one or more of oleum Olivarum, grapeseed oil, calendula oil, oleum Simmondsia chinensis, avocado oil, oleum ricini, cacao butter, oleum Cocois, oleum Maydis, oleum gossypii semen, palm oil, rape oil, safflower seed oil, oleum Sesami, soybean oil, sunflower seed oil, and wheat germ oil. The core material is preferably olive oil or grape seed oil.
(c) Primary formation of microcapsules: after emulsification, adding deionized water under continuous mechanical stirring, continuously stirring, and slowly dropwise adding acid (such as sulfuric acid, acetic acid, and hydrochloric acid) to adjust pH to 3.7-5.0. This step causes the encapsulation of the microcapsules, so that after this step is completed, the microcapsules are initially formed.
(d) Curing of the microcapsules: cooling the microcapsule solution formed in the step (c) to below 8 ℃ (for example, putting the microcapsule solution into an ice water bath), slowly adding the curing agent while keeping the stirring state, keeping the low temperature for continuously stirring after the addition of the curing agent is finished, and uniformly dispersing the curing agent; and then placing the microcapsule solution at room temperature, and continuously stirring for a certain time (about 30-60 minutes) to obtain the cured microcapsule emulsion. The curing agent is at least one of glutaraldehyde, hexanedial and formaldehyde. The addition amount of the curing agent is 6-10% of the gelatin amount in the microcapsule solution.
The curing agent is used for fixing the shape of the capsule, so that the microcapsule is wrapped more stably.
This step is preferably performed.
When the curing agent is added in the step, the curing agent is not uniformly dispersed in the microcapsule solution, and the curing effect of the whole microcapsule system is not uniform due to rapid curing at normal temperature or high temperature, so that the curing agent is uniformly dispersed in the microcapsule solution by stirring at low temperature and then is placed at room temperature for uniform curing.
(e) Preparation of an emulsion: weighing 20-30% of humectant, 3-15% of emulsifier and the balance of deionized water, and mixing the above substances to obtain the emulsion.
Preferably, at least one of a skin care agent and a preservative may be optionally added to the emulsion. When the skin care agent and the preservative are added, the mass percentage of the skin care agent is 5-20%, and the mass percentage of the preservative is 0.1-0.3%.
The humectant is at least one selected from glycerol, diglycerol, propylene glycol, 1, 3-butanediol, polyethylene glycol, sorbitol, glucose, xylitol, maltose, maltitol, mannitol, and trehalose.
The emulsifier is at least one selected from Tween 80, Tween 20, span 20 and span 80.
The skin caring agent is at least one selected from vitamin C, vitamin E, Cera flava, collagen, flos Lonicerae extractive solution, Coicis semen extractive solution, fructus Citri Limoniae extractive solution, fructus Cucumidis Sativi extractive solution, radix Hamamelis mollis extractive solution, flos Matricariae Chamomillae extractive solution, and Aloe extractive solution.
The antiseptic is at least one selected from methyl ethyl p-hydroxybenzoate, methyl isooxazoline ketone (cason), germae, iodopropynyl butyl carbamate (IPBC), benzalkonium chloride, and polyhexamethylene guanidine.
(f) Formation of makeup remover composition: and (d) adding the emulsion prepared in the step (e) into the microcapsule emulsion subjected to curing treatment in the step (d), and uniformly stirring to obtain the makeup removing composition. Wherein the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule.
It is understood that the makeup remover composition may be finally adjusted to a pH of 7.5 to 9.0 with a base (e.g., a 3% to 8% sodium hydroxide solution) in order to bring the pH of the makeup remover composition close to the skin without irritating the skin.
The makeup removing composition contains microcapsules and emulsion, wherein the microcapsules are mixed in the emulsion, the wall materials of the microcapsules are Arabic gum and gelatin, and the core materials of the microcapsules are vegetable oil; the emulsion contains 20-30 wt% of humectant, 3-15 wt% of emulsifier and deionized water, wherein the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule.
The emulsion can also be selectively added with 5 to 20 weight percent of skin care agent and 0.1 to 0.3 weight percent of preservative.
The vegetable oil is selected from one or more of oleum Olivarum, grape seed oil, calendula oil, jojoba oil, avocado oil, oleum ricini, cacao butter, oleum Cocois, oleum Maydis, oleum gossypii semen, palm oil, rape oil, safflower seed oil, oleum Sesami, soybean oil, sunflower seed oil, and wheat germ oil. The core material is preferably olive oil or grape seed oil.
The humectant is at least one selected from glycerol, diglycerol, propylene glycol, 1, 3-butanediol, polyethylene glycol, sorbitol, glucose, xylitol, maltose, maltitol, mannitol, and trehalose.
The emulsifier is at least one selected from Tween 80, Tween 20, span 20 and span 80.
The skin caring agent is at least one selected from vitamin C, vitamin E, Cera flava, collagen, flos Lonicerae extractive solution, Coicis semen extractive solution, fructus Citri Limoniae extractive solution, fructus Cucumidis Sativi extractive solution, radix Hamamelis mollis extractive solution, flos Matricariae Chamomillae extractive solution, and Aloe extractive solution.
The antiseptic is at least one selected from methyl ethyl p-hydroxybenzoate, methyl isooxazoline ketone (cason), germae, iodopropynyl butyl carbamate (IPBC), benzalkonium chloride, and polyhexamethylene guanidine.
The makeup removing composition is characterized in that the microcapsules are added into the emulsion, and the humectant in the emulsion not only can play a role in moisturizing the skin, but also can play a role in dispersing the microcapsules and can prevent the microcapsules from caking; the emulsifier in the emulsion can play a role in an emulsifying formula, the emulsifier is used in the using process of the microcapsule, and oil stains fused with the core materials need to be emulsified with water by the emulsifier to be carried away.
The makeup removing composition disclosed by the invention is characterized in that the plant oil mixed with oil stains in the makeup removing process is wrapped in the wall material by utilizing the microcapsules, so that the plant oil is effectively prevented from contacting with the external environment and other components, the putrefaction and deterioration of the plant oil are prevented, and the service life of the plant oil is prolonged. In addition, the microcapsule is mixed in the emulsifier, and only when the microcapsule is broken, the core material vegetable oil overflows and is combined with the emulsifier, so that the purpose of makeup removal is achieved.
The tissue of the present invention is prepared by applying the above-described make-up removing composition to at least one surface of a paper sheet, preferably to at least one outer surface of the paper sheet. The coating weight of the makeup removing composition is 15-50% of the mass of paper, preferably 20-40%, and more preferably 25-30%. The method for applying the makeup removing composition directly on the surface of the paper can adopt one or a combination of more of coating, spraying, dipping and printing.
The paper may be single ply, double ply, or more plies. The paper is preferably low-gram-weight tissue paper with the basis weight of 10-80 g/m2Preferably, the basis weight is 10 to 40g/m2。
When the paper towel is used, the paper towel can be kneaded firstly, so that the outer wall of most microcapsules is broken in the kneading process, the wrapped vegetable oil overflows, the vegetable oil is mixed with the emulsion, then the paper towel is used for wiping the skin needing makeup removal, and meanwhile, the paper towel is directly contacted with the skin in the wiping process.
The present invention will be further illustrated by the following specific examples.
Example 1
Preparation of makeup remover composition: adding arabic gum and gelatin into deionized water, heating and stirring to dissolve, and collecting 100g of arabic gum solution and gelatin solution respectively, wherein the concentration of arabic gum solution is 10%. Weighing 80g of olive oil, pouring into a solution of Arabic gum and gelatin, and performing high-speed mechanical emulsification treatment. After emulsification is finished, placing the emulsion on a stirrer, adding 220g of preheated deionized water while stirring, continuing stirring after the addition is finished, slowly adding a sulfuric acid solution with the concentration of 3%, adjusting the pH value to 3.7-5.0, and preliminarily forming microcapsules. In order to make the microcapsule package more stable, the emulsion is placed in an ice-water bath, the stirring speed is increased until the temperature of the solution is reduced to below 8 ℃, 8ml of glutaraldehyde with the concentration of 10 percent is added for curing treatment, the stirring is continued for 10 minutes, then the solution is taken out from the ice-water bath, placed at the room temperature and continuously stirred for about 30 minutes, and the cured microcapsule emulsion is prepared. Weighing 60g of glycerol, 20g of vitamin E20g, 10g of beeswax, 15g of Tween 80, 0.2g of 9.5% methyl isooxazoline ketone (Kathon) and 200g of deionized water, mixing the materials, and performing mechanical high-speed emulsification to obtain the emulsion. Then, the above emulsion is added to the cured microcapsule emulsion, and the two are uniformly mixed. And finally, adjusting the pH of the mixed solution to 7.5-9.0 by using a sodium hydroxide solution with the concentration of 3% -8%, thus obtaining the makeup removing composition.
Preparation of the paper towel: the double-layer makeup removing tissue paper is prepared by selecting the tissue paper with the gram weight of 30g, carrying out laminating and calendaring treatment on the two layers of tissue paper, then uniformly coating the makeup removing composition on the two outer surfaces of the laminated tissue paper, wherein the coating amount is 30%, and naturally airing the tissue paper after coating is finished.
Example 2
Preparation of makeup remover composition: adding arabic gum and gelatin into deionized water, heating and stirring to dissolve, and collecting 100g of arabic gum solution and gelatin solution respectively, wherein the concentration of arabic gum solution is 10%. 100g of grape seed oil is weighed and poured into a solution of Arabic gum and gelatin for mechanical high-speed emulsification treatment. After emulsification is finished, placing the emulsion on a stirrer, adding 220g of preheated deionized water while stirring, continuing stirring after the addition is finished, slowly adding a sulfuric acid solution with the concentration of 3% -4%, and adding the pH to 3.7-5.0 to preliminarily form microcapsules. In order to make the microcapsule package more stable, the emulsion is placed in an ice-water bath, the stirring speed is increased until the temperature of the solution is reduced to below 8 ℃, 8ml of glutaraldehyde with the concentration of 10 percent is added for curing treatment, the stirring is continued for 10 minutes, then the solution is taken out from the ice-water bath, placed at the room temperature and continuously stirred for about 30 minutes, and the cured microcapsule emulsion is prepared. Weighing 50g of glycerol, 16g of aloe gel freeze-dried powder, 12.5g of tween 20, 0.2g of 9.5% methyl isooxazoline ketone (kason) and deionized water to 200g, stirring and mixing the materials without emulsification treatment. Then, the above emulsion is added to the cured microcapsule emulsion, and the two are uniformly mixed. And finally, adjusting the pH of the mixed solution to 7.5-9.0 by using a sodium hydroxide solution with the concentration of 3% -8%, thus obtaining the makeup removing composition.
Preparation of the paper towel: selecting a piece of tissue paper with the gram weight of 30g, coating any one or two surfaces of the tissue paper with the makeup removing microcapsules, wherein the coating amount is 30%, and naturally airing the tissue paper after coating to obtain the single-layer makeup removing tissue paper.
Through use tests, the paper towel of the embodiment 1-2 is convenient to use and has good makeup removing effect; in addition, the storage time is long and the deterioration does not occur.
In addition, various modifications, additions and substitutions in other forms and details may occur to those skilled in the art within the scope and spirit of the invention as disclosed in the claims. It is understood that various modifications, additions, substitutions and the like can be made without departing from the spirit of the invention as disclosed in the accompanying claims.
Claims (8)
1. A method of preparing a makeup removing composition comprising microcapsules and an emulsion, the method comprising the steps of:
dissolving a wall material in deionized water to prepare a wall material solution, wherein the wall material is Arabic gum and gelatin;
adding a core material into the wall material solution, stirring and emulsifying, wherein the core material is vegetable oil;
keeping stirring, adding deionized water, slowly dropwise adding acid to adjust the pH value to 3.7-5.0, and promoting the microcapsules to wrap to form a microcapsule solution;
reducing the temperature of the microcapsule solution to below 8 ℃, adding the curing agent in a stirring state, keeping the low temperature for continuously stirring after the addition of the curing agent is finished, and uniformly dispersing the curing agent; then placing the microcapsule solution at room temperature, and continuously stirring to obtain a cured microcapsule emulsion, wherein the addition amount of the curing agent is 6-10% of the gelatin amount in the microcapsule solution;
mixing 20-30% of humectant, 3-15% of emulsifier and a proper amount of deionized water to obtain an emulsion;
and adding the microcapsule emulsion into the emulsion, and uniformly stirring, wherein the mass of the emulsifier in the emulsion is 10-15% of the mass of the core material in the microcapsule.
2. The method of preparing the makeup removing composition according to claim 1, characterized in that: the mass ratio of the arabic gum to the gelatin in the wall material is 1: 1 and 1: 1.5, the mass ratio of the core material to the wall material is 4: 1-8: 1.
3. the method of preparing the makeup removing composition according to claim 1, characterized in that: the humectant is at least one selected from glycerol, diglycerol, propylene glycol, 1, 3-butanediol, polyethylene glycol, sorbitol, glucose, xylitol, maltose, maltitol, mannitol, and trehalose; the emulsifier is at least one selected from Tween 80, Tween 20, span 20 and span 80.
4. The method of preparing the makeup removing composition according to claim 1, characterized in that: the emulsion also contains 5-20% of skin care agent and 0.1-0.3% of preservative.
5. The method for preparing the makeup removing composition according to claim 4, characterized in that: the skin caring agent is at least one selected from vitamin C, vitamin E, Cera flava, collagen, flos Lonicerae extractive solution, Coicis semen extractive solution, fructus Citri Limoniae extractive solution, fructus Cucumidis Sativi extractive solution, radix Hamamelis mollis extractive solution, flos Matricariae Chamomillae extractive solution, and Aloe extractive solution; the antiseptic is at least one selected from methyl ethyl p-hydroxybenzoate, methyl isooxazoline ketone, germae, iodopropynyl butyl carbamate, benzalkonium chloride and polyhexamethylene guanidine.
6. The method of preparing the makeup removing composition according to claim 1, characterized in that: the vegetable oil is selected from one or more of oleum Olivarum, grape seed oil, calendula oil, oleum Simmondsia chinensis, avocado oil, oleum ricini, cacao butter, oleum Cocois, oleum Maydis, oleum gossypii semen, palm oil, rape oil, safflower seed oil, oleum Sesami, soybean oil, sunflower seed oil, and wheat germ oil.
7. The method of preparing the makeup removing composition according to claim 1, characterized in that: the curing agent is at least one of glutaraldehyde, hexanedial and formaldehyde.
8. The method of preparing the makeup removing composition according to claim 1, characterized in that: the method also comprises the step of adjusting the pH value of the makeup removing composition to 7.5-9.0.
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| CN106038458A (en) * | 2016-07-06 | 2016-10-26 | 兰汉斌 | Makeup removal wet tissue |
| CN107837200B (en) * | 2017-10-31 | 2020-06-02 | 广州市科能化妆品科研有限公司 | Novel efficient water-locking moisturizing toner and preparation method thereof |
| CN109846760A (en) * | 2019-04-23 | 2019-06-07 | 上海舒彩网络科技有限公司 | Vegetable fat composite and application, clean face oil and preparation method in cosmetics |
| CN113907501A (en) * | 2021-11-15 | 2022-01-11 | 上海理工大学 | Nanofiber membrane material for makeup removing cotton and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101869450A (en) * | 2010-06-29 | 2010-10-27 | 大连欧派科技有限公司 | Makeup removing wet tissue |
| CN102373110A (en) * | 2011-09-30 | 2012-03-14 | 天津市中科健新材料技术有限公司 | Microcapsule sustained release agent and preparation method and application thereof |
| CN102561103A (en) * | 2011-12-22 | 2012-07-11 | 金红叶纸业集团有限公司 | Production technology of household paper with moisturizing functions |
| CN102704340A (en) * | 2012-06-19 | 2012-10-03 | 金红叶纸业集团有限公司 | Paper for daily use and production process of paper |
| CN103126964A (en) * | 2013-02-22 | 2013-06-05 | 金红叶纸业集团有限公司 | Skin-care composition and paper towel applying skin-care composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20110088711A1 (en) * | 2009-06-24 | 2011-04-21 | L'oreal | Wipe with an emulsion containing a thickening polymer and a hydrophobic modified inulin |
| CN108042373B (en) * | 2012-06-12 | 2021-10-26 | 连津格股份公司 | Liquid-retaining sheet and face mask |
| CN204181906U (en) * | 2014-09-01 | 2015-03-04 | 吴浩祥 | Makeup removing paper |
-
2013
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101869450A (en) * | 2010-06-29 | 2010-10-27 | 大连欧派科技有限公司 | Makeup removing wet tissue |
| CN102373110A (en) * | 2011-09-30 | 2012-03-14 | 天津市中科健新材料技术有限公司 | Microcapsule sustained release agent and preparation method and application thereof |
| CN102561103A (en) * | 2011-12-22 | 2012-07-11 | 金红叶纸业集团有限公司 | Production technology of household paper with moisturizing functions |
| CN102704340A (en) * | 2012-06-19 | 2012-10-03 | 金红叶纸业集团有限公司 | Paper for daily use and production process of paper |
| CN103126964A (en) * | 2013-02-22 | 2013-06-05 | 金红叶纸业集团有限公司 | Skin-care composition and paper towel applying skin-care composition |
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