CN104559759A - Antistatic transparent wear-resistant paint and preparation method thereof - Google Patents
Antistatic transparent wear-resistant paint and preparation method thereof Download PDFInfo
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- CN104559759A CN104559759A CN201410831380.3A CN201410831380A CN104559759A CN 104559759 A CN104559759 A CN 104559759A CN 201410831380 A CN201410831380 A CN 201410831380A CN 104559759 A CN104559759 A CN 104559759A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 239000003973 paint Substances 0.000 title claims abstract description 31
- -1 alkoxy silane Chemical compound 0.000 claims abstract description 30
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 229910000077 silane Inorganic materials 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 239000002216 antistatic agent Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 34
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 32
- 238000010992 reflux Methods 0.000 claims description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 18
- 239000003112 inhibitor Substances 0.000 claims description 17
- 230000000630 rising effect Effects 0.000 claims description 17
- 230000003068 static effect Effects 0.000 claims description 17
- 125000003545 alkoxy group Chemical group 0.000 claims description 16
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 8
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- 239000003880 polar aprotic solvent Substances 0.000 claims description 6
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 5
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- CIVKKLRUDDHREQ-UHFFFAOYSA-N SC(CC[Si](OC)(OC)C)O Chemical compound SC(CC[Si](OC)(OC)C)O CIVKKLRUDDHREQ-UHFFFAOYSA-N 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 claims description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002250 absorbent Substances 0.000 claims description 4
- 230000002745 absorbent Effects 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 claims description 2
- LJPCNSSTRWGCMZ-UHFFFAOYSA-N 3-methyloxolane Chemical compound CC1CCOC1 LJPCNSSTRWGCMZ-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- WGKSJIPIXCVOON-UHFFFAOYSA-N SC(CC[Si](OCC)(OCC)C)O Chemical compound SC(CC[Si](OCC)(OCC)C)O WGKSJIPIXCVOON-UHFFFAOYSA-N 0.000 claims description 2
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims description 2
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 2
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims description 2
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002048 multi walled nanotube Substances 0.000 claims description 2
- 229950002083 octabenzone Drugs 0.000 claims description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 2
- 230000032683 aging Effects 0.000 abstract description 5
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 2
- 108010009736 Protein Hydrolysates Proteins 0.000 abstract 1
- 239000000413 hydrolysate Substances 0.000 abstract 1
- 238000010792 warming Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 239000003595 mist Substances 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention relates to antistatic transparent wear-resistant paint and a preparation method thereof. The paint is mainly prepared from the following raw materials in proportion by weight: 45-75% of alkoxy silane monomer hydrolysate, 12-40% of an anti-static agent, 0.1-5% of an ultraviolet light absorber, 0.01-0.5% of a flatting agent, 0.1-1% of a curing agent, 5-10% of a silane coupling agent, and 0-20% of a solvent. The preparation method comprises the following steps: adding the alkoxy silane monomer hydrolysate and the antistatic agent into a reactor, and performing temperature rise, backflow and cooling; when the temperature of a system is lower than 50 DGE C, adding the silane coupling agent, stirring, adding the ultraviolet light absorber, the flatting agent, the curing agent and the solvent, and uniformly stirring the mixture so as to obtain the paint. Based on satisfying the performances of transparence, wear resistance and ultraviolet aging resistance, the coating formed by the paint also has the antistatic function.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of electrostatic resistant transparent wear-resistant paint and preparation method thereof.
Background technology
Along with the widespread use of polymeric transparent material, there is new demand and requirement in matching used wear-resistant paint with it, the ageing-resistant performance of polycarbonate plastic proposes on the basis of higher requirement after to coating abrasion performance and application wear-resistant paint, propose certain Functional Requirement to coating, such as coating also should possess anti-static function.
Although the transparent wear-resistant coating at present for polymeric transparent part surface has the performances such as the good transparency, wear resistance, wet-heat resisting, salt spray resistance, resistance to ultraviolet, all do not possess anti-static function.The coating transparent possessing anti-static function is poor, can not meet the service requirements of Transparent Parts.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of electrostatic resistant transparent wear-resistant paint and preparation method thereof, make coating on the basis meeting transparent, wear-resisting and anti-ultraviolet ageing performance, also can have anti-static function.
Application claims protects a kind of electrostatic resistant transparent wear-resistant paint, is mainly prepared from by the raw material of following parts by weight:
Preferably, described electrostatic resistant transparent wear-resistant paint is mainly prepared from by the raw material of following parts by weight:
Preferably, described alkoxy silane monomer hydrolyzed solution is mainly prepared from by the raw material of following parts by weight:
Preferably, described alkaline silica sol particle diameter is 5 ~ 20nm, and described alkaline silica sol is water silica sol.
Preferably, the organoalkoxysilane of at least two described functionality is selected from least one in Union carbide A-162, methyltrimethoxy silane, dimethyldiethoxysilane, dimethyldimethoxysil,ne, phenyl triethoxysilane, phenyltrimethoxysila,e.
Preferably, described alcoholic solvent is selected from least one in ethanol, n-propyl alcohol, Virahol, butanols, isopropylcarbinol.
Preferably, described static inhibitor is mainly prepared from by the raw material of following parts by weight:
Containing the polymkeric substance 40 ~ 70% of many alkoxy bases
Antistatic material 20 ~ 50%
Polar aprotic solvent 5 ~ 15%.
Preferably, the described polymkeric substance number-average molecular weight containing many alkoxy bases is between 10000 ~ 100000.Wherein 1mol contains the amount of contained alkoxyl group in the polymkeric substance of many alkoxy bases between 25mol ~ 150mol
Preferably, described antistatic material is at least one in nano-indium stannum oxide, nano antimony tin oxide, nano oxidized zinc-aluminium, nanometer silver, multi-walled carbon nano-tubes.
Preferably, described polar aprotic solvent is at least one in tetrahydrofuran (THF), 2-methyltetrahydrofuran, 3-methyltetrahydrofuran, acetonitrile, acetone, butanone, pimelinketone.
Preferably, described UV light absorber is at least one in organic uv absorbers or inorganic ultraviolet absorbent.
Preferably, described organic uv absorbers is selected from ESCALOL 567, Octabenzone, 2-(4,6-two (2,4-3,5-dimethylphenyl)-1,3,5-triazine-2-base)-5-octyloxy phenol, 2-(4,6-phenylbenzene-1,3,5-triazine-2) at least one in-5-normal hexane oxygen base phenol.
Preferably, described inorganic ultraviolet absorbent is selected from least one in nano zine oxide, nano-titanium oxide, nano zircite.
Preferably, described flow agent is at least one in polysiloxane-modified polyacrylic ester, acrylic copolymer, the alkoxy compound of alcohol, polydimethylsiloxane.
Preferably, described solidifying agent is at least one in Tetramethylammonium hydroxide, TBAH, N, N-dimethyl benzylamine.
Preferably, described silane coupling agent is γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, γ-(2,3-epoxy third oxygen) propyl-triethoxysilicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, γ-mercapto hydroxypropyl methyl dimethoxysilane, at least one in γ-mercapto hydroxypropyl methyl diethoxy silane.
Preferably, described solvent is at least one in ethanol, n-propyl alcohol, Virahol, butanols, isopropylcarbinol, butyl glycol ether, propylene glycol monomethyl ether, diacetone alcohol, DMF, N,N-dimethylacetamide, ethylene glycol ether acetate.
The preparation method of the present invention's also claimed electrostatic resistant transparent wear-resistant paint, is characterized in that, comprise following steps:
Add alkoxy silane monomer hydrolyzed solution, static inhibitor temperature rising reflux in the reactor, system backflow is after 1 ~ 3 hour, cooling adds silane coupling agent when the temperature of system is less than 50 DEG C, stir after 1 ~ 2 hour, add UV light absorber, flow agent, solidifying agent, solvent stirring, obtain coating.
Preferably, the preparation method of described static inhibitor is: be placed in reactor back flow reaction 3 ~ 8 hours by containing the polymkeric substance of many alkoxy bases, antistatic material and polar aprotic solvent, be cooled to room temperature.
Preferably, the preparation method of described alkoxy silane monomer hydrolyzed solution: the mixed solution adding alkaline silica sol, distilled water and acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip the organoalkoxysilane of at least two functionality and the mixture of alcoholic solvent, within 1 ~ 3 hour, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 0.5 ~ 2 hour, cooling down.
The beneficial effect that the application compared with prior art has is:
The present invention is directed to polymeric transparent part surface transparent wear Protection, polymeric transparent part is provided on the basis of the performances such as better wear resistance, wet-heat resisting, salt spray resistance, resistance to ultraviolet and possess anti-static function.
Embodiment
Below in conjunction with embodiment the present invention made and illustrating:
Embodiment 1
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip 50g Union carbide A-162, within 2 hours, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 0.5 hour, cooling down.
The preparation of static inhibitor: add polymkeric substance, the nano-indium stannum oxide of 26.0g, the tetrahydrofuran (THF) with 12.0g of 60.0g containing many alkoxy bases in the reactor, after being warming up to system backflow, reacting 7 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: add 70.0g alkoxy silane monomer hydrolyzed solution, 30.0g static inhibitor temperature rising reflux in the reactor, after system refluxes 2 hours, the γ-(2 of 8.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl trimethoxy silicane, stir after 1 hour, add 2.0g nano-titanium oxide, 0.4g polydimethylsiloxane, 0.9g TBAH, 5.0g ethylene glycol ether acetate stir, obtain Finish code 1#.
Embodiment 2
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up and when making the temperature of system reach 60 DEG C, start to drip the mixture of 30g Union carbide A-162 and 10g ethanol, within 2 hours, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 2 hours, cooling down.
The preparation of static inhibitor: add polymkeric substance, the nano-indium stannum oxide of 26.0g, the tetrahydrofuran (THF) with 12.0g of 60.0g containing many alkoxy bases in the reactor, after being warming up to system backflow, reacting 7 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: add 70.0g alkoxy silane monomer hydrolyzed solution, 35.0g static inhibitor in the reactor, temperature rising reflux, after system refluxes 3 hours, the γ-(2 of 8.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl trimethoxy silicane, stir after 1 hour, add 2.0g nano zine oxide, 0.4g polydimethylsiloxane, 0.9g TBAH, 5.0g butyl glycol ether stir, obtain Finish code 2#.
Embodiment 3
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip 50g Union carbide A-162, within 2.5 hours, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 1 hour, cooling down.
The preparation of static inhibitor: add polymkeric substance, the nano-indium stannum oxide of 26.0g, the tetrahydrofuran (THF) with 12.0g of 60.0g containing many alkoxy bases in the reactor, after being warming up to system backflow, reacting 3 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: 70.0g adds alkoxy silane monomer hydrolyzed solution in the reactor, 26.0g static inhibitor temperature rising reflux, after system refluxes 2 hours, the γ-(2 of 8.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl-triethoxysilicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, γ-mercapto hydroxypropyl methyl dimethoxy silicon, stir after 1 hour, add 3.0g2-hydroxyl-4-oxy-octyl benzophenone, 0.4g polydimethylsiloxane, 0.9g Tetramethylammonium hydroxide, 5.0g ethylene glycol ether acetate stirs, obtain Finish code 3#.
Embodiment 4
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip 50g Union carbide A-162, within 2.5 hours, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 1.5 hours, cooling down.
The preparation of static inhibitor: add 60.0g in the reactor containing the polymkeric substance of many alkoxy bases, the nano-indium stannum oxide of 18.0g, the nano antimony tin oxide of 8.0g and the tetrahydrofuran (THF) of 12.0g, after the system that is warming up to refluxes, react 7 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: add 70.0g alkoxy silane monomer hydrolyzed solution in the reactor, 30.0g static inhibitor temperature rising reflux, after system refluxes 2 hours, the γ-(2 of 10.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl-triethoxysilicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, γ-mercapto hydroxypropyl methyl dimethoxy silicon, stir after 1 hour, add 2.0g nano zine oxide, 0.4g polydimethylsiloxane, 0.9g TBAH, 5.0g butyl glycol ether stirs, obtain Finish code 4#.
Embodiment 5
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up and when making the temperature of system reach 60 DEG C, start to drip the mixture of 30g Union carbide A-162 and 10g ethanol, within 1 hour, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 2 hours, cooling down.
The preparation of static inhibitor: add 60.0g in the reactor containing the polymkeric substance of many alkoxy bases, the nano-indium stannum oxide of 18.0g, the nano antimony tin oxide of 8.0g and the tetrahydrofuran (THF) of 12.0g, after the system that is warming up to refluxes, react 8 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: 70.0g alkoxy silane monomer hydrolyzed solution A-2,35.0g antistatic agent B-2 temperature rising reflux in the reactor, after system refluxes 2 hours, the γ-(2 of 8.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl trimethoxy silicane, stir after 1 hour, add 2.0g nano zircite, 0.4g polydimethylsiloxane, 0.9g Tetramethylammonium hydroxide, 5.0g ethylene glycol ether acetate stir, obtain Finish code 5#.
Embodiment 6
The preparation of alkoxy silane monomer hydrolyzed solution: the mixed solution adding 50g alkaline silica sol and 2.5g acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip 50g Union carbide A-162, within 2.5 hours, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 1 hour, cooling down.
The preparation of static inhibitor: add 60.0g in the reactor containing the polymkeric substance of many alkoxy bases, the nano-indium stannum oxide of 18.0g, the nano antimony tin oxide of 8.0g and the tetrahydrofuran (THF) of 12.0g, after the system that is warming up to refluxes, react 6 hours, be cooled to room temperature.
Electrostatic resistant transparent wear-resistant paint preparation method: add 70.0g alkoxy silane monomer hydrolyzed solution in the reactor, 40.0g static inhibitor temperature rising reflux, after system refluxes 2 hours, the γ-(2 of 8.0g is added when being cooled to 45 DEG C, 3-epoxy third oxygen) propyl-triethoxysilicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, γ-mercapto hydroxypropyl methyl dimethoxy silicon, stir after 1 hour, add 3.0g2-hydroxyl-4-oxy-octyl benzophenone, 0.4g polydimethylsiloxane, 0.9g TBAH, 5.0g butyl glycol ether stirs, obtain Finish code 6#.
Implementation result:
Be respectively 1# to numbering, the coating of 2#, 3#, 4#, 5#, 6# prepares wear-resistant coating on synthetic glass surface.After paint spraying, surface drying time is not less than 30min, and toast in the environment of 80 DEG C ~ 85 DEG C after surface drying, baking time is not less than 120min.Transparent, wear-resisting, the ultraviolet aging resistance of coating, the performance such as antistatic are tested.The transparency represents with mist degree, and the less expression transparency of numerical value is better; Wear resistance adopts Q/6S 1204 to test, and test mist degree after carrying out stroke type wearing and tearing with quartz sand, mist degree rising value is the smaller the better; Ultraviolet aging resistance adopts GB/T 23987 standard testing, and 240h tests the sticking power of coating and xanthochromia
Table 2 coating performance is tested
Above-described embodiment is only for example of the present invention is clearly described, and is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, other multi-form change or change can also be made on the basis of the above description.Within the spirit and principles in the present invention all, any amendment made, equivalent replacement, improvement etc. are all included among protection scope of the present invention.
Claims (10)
1. an electrostatic resistant transparent wear-resistant paint, is mainly prepared from by the raw material of following parts by weight:
2. electrostatic resistant transparent wear-resistant paint as claimed in claim 1, it is characterized in that, it is mainly prepared from by the raw material of following parts by weight:
3. the electrostatic resistant transparent wear-resistant paint as described in one of claim 1-2, is characterized in that, described alkoxy silane monomer hydrolyzed solution is mainly prepared from by the raw material of following parts by weight:
4. electrostatic resistant transparent wear-resistant paint as claimed in claim 3, is characterized in that:
Described alkaline silica sol particle diameter is 5 ~ 20nm, and described alkaline silica sol is water silica sol;
Or the organoalkoxysilane of at least two described functionality is selected from least one in Union carbide A-162, methyltrimethoxy silane, dimethyldiethoxysilane, dimethyldimethoxysil,ne, phenyl triethoxysilane, phenyltrimethoxysila,e;
Or described alcoholic solvent is selected from least one in ethanol, n-propyl alcohol, Virahol, butanols, isopropylcarbinol.
5. the electrostatic resistant transparent wear-resistant paint as described in one of claim 1-2, is characterized in that, described static inhibitor is mainly prepared from by the raw material of following parts by weight:
Containing the polymkeric substance 40 ~ 70% of many alkoxy bases
Antistatic material 20 ~ 50%
Polar aprotic solvent 5 ~ 15%.
6. electrostatic resistant transparent wear-resistant paint as claimed in claim 5, is characterized in that:
The described polymkeric substance number-average molecular weight containing many alkoxy bases is between 10000 ~ 100000, and wherein 1mol contains the amount of contained alkoxyl group in the polymkeric substance of many alkoxy bases between 25mol ~ 150mol;
Or described antistatic material is at least one in nano-indium stannum oxide, nano antimony tin oxide, nano oxidized zinc-aluminium, nanometer silver, multi-walled carbon nano-tubes;
Or described polar aprotic solvent is at least one in tetrahydrofuran (THF), 2-methyltetrahydrofuran, 3-methyltetrahydrofuran, acetonitrile, acetone, butanone, pimelinketone.
7. the electrostatic resistant transparent wear-resistant paint as described in one of claim 1-2, is characterized in that:
Described UV light absorber is at least one in organic uv absorbers or inorganic ultraviolet absorbent; Wherein, described organic uv absorbers is selected from ESCALOL 567, Octabenzone, 2-(4,6-two (2,4-3,5-dimethylphenyl)-1,3,5-triazine-2-base)-5-octyloxy phenol, 2-(4,6-phenylbenzene-1,3,5-triazine-2) at least one in-5-normal hexane oxygen base phenol; Or described inorganic ultraviolet absorbent is selected from least one in nano zine oxide, nano-titanium oxide, nano zircite;
Or described flow agent is at least one in polysiloxane-modified polyacrylic ester, acrylic copolymer, the alkoxy compound of alcohol, polydimethylsiloxane;
Or described solidifying agent is at least one in Tetramethylammonium hydroxide, TBAH, N, N-dimethyl benzylamine;
Or, described silane coupling agent is γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, γ-(2,3-epoxy third oxygen) propyl-triethoxysilicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, γ-mercapto hydroxypropyl methyl dimethoxysilane, at least one in γ-mercapto hydroxypropyl methyl diethoxy silane;
Or described solvent is at least one in ethanol, n-propyl alcohol, Virahol, butanols, isopropylcarbinol, butyl glycol ether, propylene glycol monomethyl ether, diacetone alcohol, DMF, N,N-dimethylacetamide, ethylene glycol ether acetate.
8. a preparation method for the electrostatic resistant transparent wear-resistant paint as described in any one of claim 1-7, is characterized in that, comprise following steps:
Add alkoxy silane monomer hydrolyzed solution, static inhibitor temperature rising reflux in the reactor, system backflow is after 1 ~ 3 hour, cooling adds silane coupling agent when the temperature of system is less than 50 DEG C, stir after 1 ~ 2 hour, add UV light absorber, flow agent, solidifying agent, solvent stirring, obtain coating.
9. the preparation method of a kind of electrostatic resistant transparent wear-resistant paint as claimed in claim 8, it is characterized in that: the preparation method of described static inhibitor is: be placed in reactor back flow reaction 3 ~ 8 hours by containing the polymkeric substance of many alkoxy bases, antistatic material and polar aprotic solvent, be cooled to room temperature.
10. the preparation method of a kind of electrostatic resistant transparent wear-resistant paint as claimed in claim 8, it is characterized in that: the preparation method of described alkoxy silane monomer hydrolyzed solution is: the mixed solution adding alkaline silica sol, distilled water and acetic acid in the reactor, heat up when making the temperature of system reach 60 DEG C and start to drip the organoalkoxysilane of at least two functionality and the mixture of alcoholic solvent, within 1 ~ 3 hour, dropwise, the temperature of reaction system is controlled between 60 DEG C ~ 72 DEG C in dropping process, dropwise rear temperature rising reflux 0.5 ~ 2 hour, cooling down.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103436974A (en) * | 2013-09-02 | 2013-12-11 | 江苏红豆实业股份有限公司 | Sheath-core acrylon with antistatic and far-infrared functions |
| CN103694888A (en) * | 2013-12-17 | 2014-04-02 | 中昊北方涂料工业研究设计院有限公司 | Transparent wear-resistant paint containing silicon and preparation method thereof |
-
2014
- 2014-12-26 CN CN201410831380.3A patent/CN104559759A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103436974A (en) * | 2013-09-02 | 2013-12-11 | 江苏红豆实业股份有限公司 | Sheath-core acrylon with antistatic and far-infrared functions |
| CN103694888A (en) * | 2013-12-17 | 2014-04-02 | 中昊北方涂料工业研究设计院有限公司 | Transparent wear-resistant paint containing silicon and preparation method thereof |
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