CN104559580A - High-solid copper acrylate polymer type long-lasting antifouling paint - Google Patents
High-solid copper acrylate polymer type long-lasting antifouling paint Download PDFInfo
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- CN104559580A CN104559580A CN201410837968.XA CN201410837968A CN104559580A CN 104559580 A CN104559580 A CN 104559580A CN 201410837968 A CN201410837968 A CN 201410837968A CN 104559580 A CN104559580 A CN 104559580A
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- Prior art keywords
- acrylate polymer
- polymer type
- type long
- acting
- copper acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 47
- XPLSDXJBKRIVFZ-UHFFFAOYSA-L copper;prop-2-enoate Chemical compound [Cu+2].[O-]C(=O)C=C.[O-]C(=O)C=C XPLSDXJBKRIVFZ-UHFFFAOYSA-L 0.000 title claims abstract description 42
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 42
- 239000007787 solid Substances 0.000 title claims abstract description 35
- 239000003973 paint Substances 0.000 title abstract description 10
- 230000005923 long-lasting effect Effects 0.000 title abstract 4
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 20
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims abstract description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims abstract description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000002952 polymeric resin Substances 0.000 claims abstract description 10
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000004952 Polyamide Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011717 all-trans-retinol Substances 0.000 claims abstract description 6
- 235000019169 all-trans-retinol Nutrition 0.000 claims abstract description 6
- 230000003115 biocidal effect Effects 0.000 claims abstract description 6
- 239000003139 biocide Substances 0.000 claims abstract description 6
- 239000010440 gypsum Substances 0.000 claims abstract description 6
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 6
- 239000010445 mica Substances 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 229920002647 polyamide Polymers 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 229940043810 zinc pyrithione Drugs 0.000 claims abstract description 6
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004359 castor oil Substances 0.000 claims abstract description 5
- 235000019438 castor oil Nutrition 0.000 claims abstract description 5
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims abstract description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 5
- 239000010433 feldspar Substances 0.000 claims abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 239000010949 copper Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 47
- 239000011248 coating agent Substances 0.000 claims description 44
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 4
- 238000005457 optimization Methods 0.000 claims 1
- 238000005498 polishing Methods 0.000 abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract 1
- 229940112669 cuprous oxide Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- KOBKUSXTVUSJEU-UHFFFAOYSA-N copper;prop-2-enoic acid Chemical compound [Cu].OC(=O)C=C KOBKUSXTVUSJEU-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010435 syenite Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses high-solid copper acrylate polymer type long-lasting antifouling paint. The high-solid copper acrylate polymer type long-lasting antifouling paint is characterized by comprising raw materials of components in percentage by weight as follows: 18%-40% of copper acrylate polymer resin containing 5%-20% of copper, 4%-7% of auxiliaries adopting one or more of organobentonite, fumed silica, hydrogenated castor oil and polyamide wax, 30%-38% of biocide adopting one or more of cuprous oxide, copper pyrithione, zinc pyrithione and zineb, 10%-12% of powder filler adopting one or more of zinc oxide, gypsum, talcum powder, mica powder, barite powder and feldspar powder, 6%-10% of a tinting pigment adopting iron oxide red or carbon black and 10%-15% of a solvent adopting dimethylbenzene or trimethylbenzene. The solid content is larger than or equal to 50%, the polishing performance of the antifouling paint is 30-120 mu m per year; the antifouling paint can protect an outer layer of a marine ship from marine organism attachment pollution for more than five years and has long-lasting antifouling performance.
Description
Technical field
The present invention relates to industrial coating technical field, specifically, is a kind of high solid copper acrylate polymer type long-acting and anti-fouling coating being applicable to marine ship and preventing marine organism from adhering to.
Background technology
Sea-freight and ocean exploitation resource can use a large amount of transport ships and various extraordinary marine ship.And the attachment of marine organism (comprising marine microorganism, algae) can make the resistance of boat increase, not only increase fuel oil loss, and affect the speed of a ship or plane, cause described transport ship and ocean special boat and directly or indirectly lose, this is the serious problems that sea-freight and ocean development industry face.At present, solving the most effective means of marine organisms absorption problems is exactly coating in antifouling, the anti-marine organism attachment of hull skin coating.Chinese patent literature CN102702914A discloses " a kind of antifouling paint ", but it does not relate to the solids content of antifouling paint, does not also relate to polishing (corrosion) performance of antifouling coating.
Summary of the invention
The object of the invention is to solve the problem, a kind of high solid copper acrylate polymer type long-acting and anti-fouling coating is provided, use mainly as Marine Antifouling Coatings, can be marine ship skin and provide more than 5 years from the pollution of marine organism attachment, there is long-acting and anti-fouling performance.
For achieving the above object, this invention takes following technical scheme.
A kind of high solid copper acrylate polymer type long-acting and anti-fouling coating, it is characterized in that, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 18 ~ 40%;
Auxiliary agent 4 ~ 7%;
Biocide 30 ~ 38%;
Powder stuffing 10 ~ 12%;
Tinting pigment 6 ~ 10%;
Solvent 10 ~ 15%.
A kind of high solid copper acrylate polymer type long-acting and anti-fouling coating, it is characterized in that, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 25 ~ 33%;
Auxiliary agent 5 ~ 6%;
Biocide 33 ~ 35%;
Powder stuffing 10.5 ~ 11.5%;
Tinting pigment 7.5 ~ 9.5%;
Solvent 11 ~ 13%.
Further, the content of described copper acrylate polymer resin copper is 5
~20%.
Further, described auxiliary agent be organobentonite, aerosil, hydrogenated castor oil, polyamide wax one or more.
Further, described biocide be Red copper oxide, copper pyrithione, Zinc Pyrithione, zineb one or more.
Further, described powder stuffing be zinc oxide, gypsum, talcum powder, mica powder, ground barium sulfate, Feldspar Powder one or more.
Further, described tinting pigment is red iron oxide or carbon black.
Further, described solvent is dimethylbenzene or trimethylbenzene.
The positively effect of high solid copper acrylate polymer type long-acting and anti-fouling coating of the present invention is:
As Marine Antifouling Coatings, its amount of solid content>=50%; Polishing (corrosion) performance of antifouling coating is 30
~120 microns/year; More than 5 years can be provided from the pollution of marine organism attachment for marine ship skin, there is long-acting and anti-fouling performance.
Embodiment
Below provide the embodiment of high solid copper acrylate polymer type long-acting and anti-fouling coating of the present invention, provide 4 embodiments.But it should be pointed out that enforcement of the present invention is not limited to following embodiment.
embodiment 1
(1) a high solid copper acrylate polymer type long-acting and anti-fouling coating, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 18%, adopts the vinylformic acid copper type of Wuxi Yao get Xin Chemicals company limited production from polishing resin.
Organobentonite 5%, adopts the organobentonite that Shanghai Feng Chen powder body material company limited produces.
Aerosil 2%, employing goldschmidt chemical corporation is produced, the trade mark is the white carbon black of A200.
Red copper oxide 28%, employing Nantong Bei Bang Chemical Co., Ltd. produces, purity is the Red copper oxide of 97%.
Copper pyrithione 10%, adopts the copper pyrithione that Jinan Zi An Chemical Co., Ltd. produces.
Zinc oxide 12%, adopt Shanghai jump river titanium white heavy chemicals company limited produce zinc oxide.
Red iron oxide 10%, employing Shanghai Yipin Pigments Co., Ltd. produces, the trade mark is the red iron oxide of S130.
Dimethylbenzene 15%, adopts the solvent-borne type dimethylbenzene that Hangzhou Hui Peng coating company limited produces.
(2) preparation method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 1, comprises the following steps:
(1) under low speed (200 ~ 400r/min) stirs, copper acrylate polymer resin, auxiliary agent, biocide, powder stuffing and tinting pigment is added successively; Under low rate mixing, add partial solvent rinse casing wall and stir shaft.
(2) (be greater than 800r/min) at a high speed and disperse 20 ~ 30 minutes, QC checks fineness≤80 μm of coating.
(3) measure the temperature of coating, guarantee that the temperature of coating to remain between 40 ~ 55 DEG C 15 minutes and records the temperature of coating.
(4) under low rate mixing, remaining solvent is added; Middling speed (400 ~ 600r/min) stirs 15 minutes, makes the temperature of coating be cooled to less than 40 DEG C, the temperature of record coating.
(5) QC sampling and testing.
(6) through QC accreditation, filter with 60 eye mesh screens, the packing of product.
(3) using method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 1 preparation
(1) treat the surface fresh water high pressure washing of application by all or generally rinse, removing all oil or grease, soluble pollutants and other foreign matters.
(2) coating electric blender prepared by embodiment 1 is fully stirred evenly.
(3) treat that the surface temperature of painting object must remain at more than dew point at least 3 DEG C.
(4) use Airless spraying spray gun, described coating be sprayed on equably the surface of painting object and meet the requirement of thickness.
embodiment 2
(1) a high solid copper acrylate polymer type long-acting and anti-fouling coating, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 40%, (raw material of employing is with embodiment 1).
Hydrogenated castor oil 3%, adopts the hydrogenated castor oil that Guangzhou Jing Gang Chemical Co., Ltd. produces.
Polyamide wax 1%, adopts the polyamide wax that Jinan Ward Chemical Co., Ltd. produces.
Zinc Pyrithione 10%, adopts the Zinc Pyrithione that Shouguang City Lu Ke chemical industry limited liability company produces.
Zineb 20%, employing Bohu bio tech ltd, Shanghai produces, purity reaches the zineb of 98%.
Talcum powder 4%, adopts the 400 order talcum powder that Foshan City Yuan Lei powder company limited produces.
Mica powder 3%, adopts the 1250 order mica powders that Shanghai Yue Jiang titanium white company produces.
Ground barium sulfate 3%, adopts the 600 order ground barium sulfates that Shanghai Liang Jiang titanium white company produces.
Carbon black 6%, employing goldschmidt chemical corporation is produced, the trade mark is the carbon black of FW200.
Trimethylbenzene 10%, adopts the solvent-borne type trimethylbenzene that Hangzhou Hui Peng coating company limited produces.
(2) preparation method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 2 is with embodiment 1.
(3) using method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 2 preparation is with embodiment 1.
embodiment 3
(1) a high solid copper acrylate polymer type long-acting and anti-fouling coating, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 25%, (raw material of employing is with embodiment 1).
Organobentonite 6%, (raw material of employing is with embodiment 1).
Red copper oxide 10%, (raw material of employing is with embodiment 1).
Zineb 25%, (raw material of employing is with embodiment 2).
Gypsum 3.5%, adopts the high strength gypsum powder that Jinan Guo Shi great achievement Chemical Co., Ltd. produces.
Feldspar Powder 3%, adopts the nepheline syenite powder that Lingshou County mineral products processing factory of China hundred million produces.
Ground barium sulfate 5%, (raw material of employing is with embodiment 2).
Carbon black 9.5%, (raw material of employing is with embodiment 2).
Trimethylbenzene 13%, (raw material of employing is with embodiment 2).
(2) preparation method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 3 is with embodiment 1.
(3) using method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 3 preparation is with embodiment 1.
embodiment 4
(1) a high solid copper acrylate polymer type long-acting and anti-fouling coating, in its component, the weight percent of each raw material is:
Copper acrylate polymer resin 33%, (raw material of employing is with embodiment 1).
Aerosil 3.5%, (raw material of employing is with embodiment 1).
Polyamide wax 1.5%, (raw material of employing is with embodiment 2).
Zinc Pyrithione 15%, (raw material of employing is with embodiment 2).
Red copper oxide 18%, (raw material of employing is with embodiment 1).
Zinc oxide 6%, (raw material of employing is with embodiment 1).
Mica powder 2%, (raw material of employing is with embodiment 2).
Gypsum 2.5%, (raw material of employing is with embodiment 3).
Red iron oxide 7.5%, (raw material of employing is with embodiment 1).
Dimethylbenzene 11%, (raw material of employing is with embodiment 1).
(2) preparation method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 4 is with embodiment 1.
(3) using method of the high solid copper acrylate polymer type long-acting and anti-fouling coating of embodiment 4 preparation is with embodiment 1.
The high solid copper acrylate polymer type long-acting and anti-fouling coating prepared by embodiment 1-4 is prepared into antifouling coating by spraying method: twice paint is having the surface of steel plate of rust-proofing primer rete, build is 150 microns, adopts following method to test.
By the testing method of GB_T 6822-2007, non-volatile content is tested.
By the testing method of GB_T 6822-2007, antifouling coating polishing (abrasion) property is tested.
By the testing method of GB_T 6822-2007, shallow sea immersion property is tested.
By the testing method of GB_T 6822-2007, dynamic analog test is tested.
(note: described GB_T 6822-2007 is " antifouling of ship's hull rust-inhibiting paint system ".）
That tests the results are shown in Table 1.
The performance of high solid copper acrylate polymer type long-acting and anti-fouling paint coatings prepared by table 1. embodiment 1-4
。
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from each component weight percentage ranges of the present invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. a high solid copper acrylate polymer type long-acting and anti-fouling coating, is characterized in that, in its component, the weight percent of each raw material is:
2. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1, it is characterized in that, in described component, the optimization range of each raw material weight per-cent is:
3. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, it is characterized in that, the content of described copper acrylate polymer resin copper is 5 ~ 20%.
4. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, is characterized in that, described auxiliary agent be organobentonite, aerosil, hydrogenated castor oil, polyamide wax one or more.
5. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, is characterized in that, described biocide be Red copper oxide, copper pyrithione, Zinc Pyrithione, zineb one or more.
6. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, is characterized in that, described powder stuffing be zinc oxide, gypsum, talcum powder, mica powder, ground barium sulfate, Feldspar Powder one or more.
7. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, it is characterized in that, described tinting pigment is red iron oxide or carbon black.
8. high solid copper acrylate polymer type long-acting and anti-fouling coating according to claim 1 and 2, it is characterized in that, described solvent is dimethylbenzene or trimethylbenzene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837968.XA CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837968.XA CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104559580A true CN104559580A (en) | 2015-04-29 |
| CN104559580B CN104559580B (en) | 2017-02-01 |
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| CN201410837968.XA Active CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108641597A (en) * | 2018-04-09 | 2018-10-12 | 福建师范大学泉港石化研究院 | A kind of antifouling paint and preparation method thereof based on laccol copper polymer |
| CN109651907A (en) * | 2018-11-07 | 2019-04-19 | 成都普瑞斯特新材料有限公司 | Novel tin-free self-polishing type antifouling paint |
| CN111375535A (en) * | 2020-03-30 | 2020-07-07 | 广西平班水电开发有限公司 | Antifouling coating process for preventing shells from adhering to underwater metal structure of hydropower station and antifouling coating |
| US11168287B2 (en) | 2016-05-26 | 2021-11-09 | Kimberly-Clark Worldwide, Inc. | Anti-adherent compositions and methods of inhibiting the adherence of microbes to a surface |
| US12037497B2 (en) | 2016-01-28 | 2024-07-16 | Kimberly-Clark Worldwide, Inc. | Anti-adherent composition against DNA viruses and method of inhibiting the adherence of DNA viruses to a surface |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| CN101550305A (en) * | 2008-04-02 | 2009-10-07 | 上海海悦涂料有限公司 | Long-life self-polishing antifouling coating |
| CN103289007A (en) * | 2013-04-12 | 2013-09-11 | 中国科学院烟台海岸带研究所 | Improved preparation method for zinc/copper acrylate resin |
| US20130289160A1 (en) * | 2010-12-21 | 2013-10-31 | Akzo Noble Coatings International B.V. | Antifouling coating composition |
| CN103709319A (en) * | 2013-12-25 | 2014-04-09 | 浙江海洋学院 | Preparation method and application of copper/zinc-containing metal polyacrylate resin |
-
2014
- 2014-12-25 CN CN201410837968.XA patent/CN104559580B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550305A (en) * | 2008-04-02 | 2009-10-07 | 上海海悦涂料有限公司 | Long-life self-polishing antifouling coating |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| US20130289160A1 (en) * | 2010-12-21 | 2013-10-31 | Akzo Noble Coatings International B.V. | Antifouling coating composition |
| CN103289007A (en) * | 2013-04-12 | 2013-09-11 | 中国科学院烟台海岸带研究所 | Improved preparation method for zinc/copper acrylate resin |
| CN103709319A (en) * | 2013-12-25 | 2014-04-09 | 浙江海洋学院 | Preparation method and application of copper/zinc-containing metal polyacrylate resin |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12037497B2 (en) | 2016-01-28 | 2024-07-16 | Kimberly-Clark Worldwide, Inc. | Anti-adherent composition against DNA viruses and method of inhibiting the adherence of DNA viruses to a surface |
| US11168287B2 (en) | 2016-05-26 | 2021-11-09 | Kimberly-Clark Worldwide, Inc. | Anti-adherent compositions and methods of inhibiting the adherence of microbes to a surface |
| CN108641597A (en) * | 2018-04-09 | 2018-10-12 | 福建师范大学泉港石化研究院 | A kind of antifouling paint and preparation method thereof based on laccol copper polymer |
| CN109651907A (en) * | 2018-11-07 | 2019-04-19 | 成都普瑞斯特新材料有限公司 | Novel tin-free self-polishing type antifouling paint |
| CN111375535A (en) * | 2020-03-30 | 2020-07-07 | 广西平班水电开发有限公司 | Antifouling coating process for preventing shells from adhering to underwater metal structure of hydropower station and antifouling coating |
| CN111375535B (en) * | 2020-03-30 | 2022-09-06 | 广西平班水电开发有限公司 | Antifouling coating process for preventing shells from adhering to underwater metal structure of hydropower station and antifouling coating |
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