CN104559018A - Environmental-friendly TPE - Google Patents
Environmental-friendly TPE Download PDFInfo
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- CN104559018A CN104559018A CN201310471273.XA CN201310471273A CN104559018A CN 104559018 A CN104559018 A CN 104559018A CN 201310471273 A CN201310471273 A CN 201310471273A CN 104559018 A CN104559018 A CN 104559018A
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- parts
- tpe
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- friendly type
- stir
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- 239000002480 mineral oil Substances 0.000 claims abstract description 4
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 4
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 12
- 229920001155 polypropylene Polymers 0.000 abstract description 10
- -1 polypropylene Polymers 0.000 abstract description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- 238000011161 development Methods 0.000 abstract description 3
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract 1
- 235000013539 calcium stearate Nutrition 0.000 abstract 1
- 239000008116 calcium stearate Substances 0.000 abstract 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 abstract 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 43
- 239000000463 material Substances 0.000 description 12
- 229920001971 elastomer Polymers 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000004636 vulcanized rubber Substances 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to environmental-friendly TPE. The TPE comprises following components by weight: 105-110 parts of SEBS, 50-300 parts of mineral oil, 50-150 parts of polypropylene (PP), 50-90 parts of polyurethane, 10-50 parts of EVA, 10-80 parts of calcium carbonate, 0.5-2.5 parts of calcium stearate, 10-15 parts of talcum powder, 1-15 parts of ethylene propylene diene monomer, 1-10 parts of titanium dioxide, 0.2-1 part of an antioxidant and 3.5-4.5 parts of maleic anhydride grafted polypropylene. The TPE is low in cost, convenient to manufacture, good in toughness, high in plasticity, not liable to volatile when being heated, recyclable, and capable of being circulated and reutilized, and capable of largely saving the cost and saving energy. The TPE has a function of environment protection, and has important meaning for sustainable development.
Description
Technical field
The invention belongs to polymer modification material produce processing technique field, especially a kind of environment-friendly type TPE(thermoplastic elastomer).
Background technology
TPE(Thermoplastic Elastomer, thermoplastic elastomer) be a kind of snappiness with rubber, high strength, high resilience, having again can the material of feature of injection molding.There is environment-protecting asepsis safety, durometer level is wide, has excellent tint permanence, soft-touch, weathering resistance, fatigue resistance and temperature tolerance, processing characteristics is superior, need not sulfuration, can recycle and reduce costs, both can secondary injection molding, with body material coating and bondings such as PP, PE, PC, PS, ABS, also can be shaping separately.Thermoplastic elastomer had both had the processing characteristics of thermoplastics, had again the physicals of vulcanized rubber, was the advantageous combination of plastics and rubber advantage.But current TPE mostly can not recycling, not only causes a large amount of wastes of resource, and causes serious pollution to environment, bring detrimentally affect to Sustainable development.
By retrieval, find following several sections of patent publication us relevant to patent application of the present invention:
1, a kind of halogen-free flame-retardant thermoplastic elastomer TPE material and preparation method thereof (CN102424712A), disclose a kind of halogen-free flame-retardant thermoplastic elastomer TPE material and preparation method thereof, described TPE material by weight, composed of the following components: PP resin 18 ~ 22 parts, first TPE elastomer 23 ~ 27 parts, second TPE elastomer 3 ~ 7 parts, 8 ~ 12 parts, POE elastomerics, solid halogen-free flame retardants 13 ~ 17 parts, liquid halogen-free flame retardants 13 ~ 17 parts, silica powder 3 ~ 5 parts, EPDM3 ~ 5 part, vulcanizing agent 0.6 ~ 1.0 part, linking agent 0.1 ~ 0.3 part, coupling agent 0.4 ~ 0.6 part, 0.1 ~ 0.3 part, oxidation inhibitor, first photostabilizer 0.1 ~ 0.2 part, second photostabilizer 0.1 ~ 0.2 part.Halogen-free flame-retardant thermoplastic elastomer TPE material prepared by the present invention has the elastomeric property of conventional rubber and the thermoplastic processability of resin concurrently, has good adaptability, economy, can repeatedly process and recycling.
2, motion air bag is with transparent blowing TPE material (CN102786738A), relates to a kind of transparent blowing TPE material of motion air bag that can be used for blow molding.It is characterized in that being made up of by weight following component: SEBS50-100, white oil 100-150, polypropylene 200-300, stablizer 0.2-0.4.Wherein, described stablizer is the mixture of primary antioxidant 1010 and auxiliary antioxidant 1681: 1.The transparency, snappiness, the high strength of this TPE material and can blow molding performance combine, make motion air bag Product processing simple, simplify the complete processing of molded vulcanization product, simplify die design, reduce product energy consumption, avoid the shortcoming of vulcanized rubber not recoverable simultaneously, greatly reduce product cost, expanded the range of application of styrene series elastomer.
3, the high temperature resistant TPE material (CN201110139016) of car light sealing, relates to the high temperature resistant TPE material that a kind of car light for injection moulding seals.It is characterized in that being made up of by weight following component: SEBS100-200, white oil 200-300, polypropylene 50-100, calcium carbonate 100-200, polyphenylene oxide 100-200, stablizer 0.2-0.4.Having can injection moulding, and rebound resilience is high, good airproof performance, and high thermal resistance is good, the advantage of recoverable.
4, a kind of high-performance odorlessness is without colour-change thermoplastic elastomer TPE and preparation method thereof (CN102070834A), disclose a kind of high-performance odorlessness without colour-change thermoplastic elastomer TPE and preparation method thereof, this thermoplastic elastomer TPE comprises the raw material of following weight percent: the polypropylene of 1-30%, the styrenic rubbers of 10-20%, the RUBBER PROCESS OIL of 20-50%, the ethylene-octene copolymer of 0-40%, the inorganic filler of 0-40%, the oxidation inhibitor of 0.3-1%, the lubricant of 0.5-5%, the compatilizer of 0-10%; Wherein, described polypropylene selects Co-polypropylene or homo-polypropylene.The present invention by adding scentless maleic anhydride inoculated polypropylene to improve the dispersiveness of filler and polypropylene affinity and filler, thus improves stretching and the shock strength of filled polypropylene.Thermoplastic elastomer TPE provided by the invention has good mechanical property, and odorlessness, without colour-change, can be used for the fields such as electronic apparatus, automobile, household electrical appliances, sports goods, medicine equipment.
By contrast, there are the different of essence in patent application of the present invention and above-mentioned patent publication us.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art part, provide a kind of recoverable, with low cost, easy to make, saved the environment-friendly type TPE of the energy widely.
The technical scheme that the present invention realizes object is:
A kind of environment-friendly type TPE, its moiety and parts by weight as follows:
And, described environment-friendly type TPE, its moiety and parts by weight as follows:
The preparation method of environment-friendly type TPE as above, step is as follows:
(1) pour SEBS into agitator;
(2) pour white mineral oil into agitator again, stir 10 ~ 15 minutes, stir;
(3) pour other raw materials remaining into agitator in the lump again, then stir 10 ~ 15 minutes, the raw mixture that must stir;
(4) again the raw mixture stirred is poured in twin screw extruder, namely obtain environment-friendly type TPE through melt extruding at 150 ~ 200 DEG C, cooling, after granulation.
Advantage of the present invention and beneficial effect are:
TPE of the present invention is with low cost, easy to make, and snappiness is good, and plasticity-is high, is heated not volatile, and recyclable cycling and reutilization, has saved cost widely, has saved the energy, and had the function of environmental protection, had great importance to Sustainable development.
Embodiment
Below by specific embodiment, the invention will be further described, and following examples are descriptive, is not determinate, can not limit protection scope of the present invention with this.
If no special instructions, the reagent used in the present invention is conventional reagent; If no special instructions, the method used is ordinary method.
Embodiment 1
A kind of environment-friendly type TPE, its moiety and parts by weight as follows:
The preparation method of environment-friendly type TPE as above, step is as follows:
(1) pour SEBS into agitator;
(2) pour white mineral oil into agitator again, stir 10 ~ 15 minutes, stir;
(3) pour other raw materials remaining into agitator in the lump again, then stir 10 ~ 15 minutes, the raw mixture that must stir;
(4) again the raw mixture stirred is poured in twin screw extruder, namely obtain environment-friendly type TPE through melt extruding at 150 ~ 200 DEG C, cooling, after granulation.
Embodiment 2
A kind of environment-friendly type TPE, its moiety and parts by weight as follows:
The preparation method of above-mentioned environment-friendly type TPE is with embodiment 1.
Embodiment 3
A kind of environment-friendly type TPE, its moiety and parts by weight as follows:
The preparation method of above-mentioned environment-friendly type TPE is with embodiment 1.
Claims (3)
1. an environment-friendly type TPE, is characterized in that: its moiety and parts by weight as follows:
2. environment-friendly type TPE according to claim 1, is characterized in that: its moiety and parts by weight as follows:
3. a preparation method of the environment-friendly type TPE as described in any one of claim 1 or 2, is characterized in that: step is as follows:
(1) pour SEBS into agitator;
(2) pour white mineral oil into agitator again, stir 10 ~ 15 minutes, stir;
(3) pour other raw materials remaining into agitator in the lump again, then stir 10 ~ 15 minutes, the raw mixture that must stir;
(4) again the raw mixture stirred is poured in twin screw extruder, namely obtain environment-friendly type TPE through melt extruding at 150 ~ 200 DEG C, cooling, after granulation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310471273.XA CN104559018A (en) | 2013-10-09 | 2013-10-09 | Environmental-friendly TPE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310471273.XA CN104559018A (en) | 2013-10-09 | 2013-10-09 | Environmental-friendly TPE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104559018A true CN104559018A (en) | 2015-04-29 |
Family
ID=53076138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310471273.XA Pending CN104559018A (en) | 2013-10-09 | 2013-10-09 | Environmental-friendly TPE |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104559018A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331032A (en) * | 2015-11-06 | 2016-02-17 | 安徽雄亚塑胶科技有限公司 | TPE composition and automobile protective film prepared through same |
| CN105542442A (en) * | 2016-01-21 | 2016-05-04 | 盛嘉伦橡塑(深圳）股份有限公司 | Thermoplastic elastomer material for smart wristband and preparation method of thermoplastic elastomer material |
| CN105694334A (en) * | 2016-03-08 | 2016-06-22 | 安徽韧达高分子材料有限公司 | TPE (thermal plastic elastomer) material for coating nylon and preparation method of TPE material |
| CN107286558A (en) * | 2017-08-09 | 2017-10-24 | 邓韵 | A kind of TPE material for the colour developing that heats up |
| CN108314833A (en) * | 2018-02-05 | 2018-07-24 | 广东远华新材料实业有限公司 | A kind of TPE material and the preparation method and application thereof |
-
2013
- 2013-10-09 CN CN201310471273.XA patent/CN104559018A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331032A (en) * | 2015-11-06 | 2016-02-17 | 安徽雄亚塑胶科技有限公司 | TPE composition and automobile protective film prepared through same |
| CN105542442A (en) * | 2016-01-21 | 2016-05-04 | 盛嘉伦橡塑(深圳）股份有限公司 | Thermoplastic elastomer material for smart wristband and preparation method of thermoplastic elastomer material |
| CN105694334A (en) * | 2016-03-08 | 2016-06-22 | 安徽韧达高分子材料有限公司 | TPE (thermal plastic elastomer) material for coating nylon and preparation method of TPE material |
| CN107286558A (en) * | 2017-08-09 | 2017-10-24 | 邓韵 | A kind of TPE material for the colour developing that heats up |
| CN108314833A (en) * | 2018-02-05 | 2018-07-24 | 广东远华新材料实业有限公司 | A kind of TPE material and the preparation method and application thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150429 |