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CN104529286A - Novel concrete artificial fish reef and preparation method thereof - Google Patents

Novel concrete artificial fish reef and preparation method thereof Download PDF

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Publication number
CN104529286A
CN104529286A CN201410776696.7A CN201410776696A CN104529286A CN 104529286 A CN104529286 A CN 104529286A CN 201410776696 A CN201410776696 A CN 201410776696A CN 104529286 A CN104529286 A CN 104529286A
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artificial fish
concrete artificial
preparation
cement
concrete
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李霞
陈海燕
王小梅
李德豪
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Guangdong University of Technology
Guangdong University of Petrochemical Technology
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Guangdong University of Technology
Guangdong University of Petrochemical Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Artificial Fish Reefs (AREA)

Abstract

一种新型混凝土人工鱼礁,它由以下配比的原料制成:水泥:沙:石子:拌合水:牡蛎壳粉:粉媒灰:矿粉的质量比为:1:(1.9~2.6):(2.8~3.9):(0.4~0.6):(0.1~0.2):(0.1~0.3):(0.1~0.5);其制备方法是:将上述原料加入混凝土搅拌机,搅拌后,放到振动台进行振动均匀压实,12-24小时后拆模;拆模后进行标准养护28天即得。本发明在使用过程中不会溶出有害物质,不影响生物附着,对环境无污染,性能更适宜海洋环境,可以改良人工鱼礁的效果。A new type of concrete artificial fish reef, which is made of the following raw materials: cement: sand: gravel: mixing water: oyster shell powder: powder ash: mineral powder The mass ratio is: 1: (1.9~2.6) :(2.8~3.9):(0.4~0.6):(0.1~0.2):(0.1~0.3):(0.1~0.5); the preparation method is: add the above raw materials into the concrete mixer, after stirring, put it on the vibrating table Vibrate and compact evenly, remove the formwork after 12-24 hours; carry out standard maintenance for 28 days after removing the formwork. The invention does not dissolve harmful substances during use, does not affect biological adhesion, has no pollution to the environment, has more suitable performance for the marine environment, and can improve the effect of artificial fish reefs.

Description

一种新型混凝土人工鱼礁及其制备方法A new type of concrete artificial fish reef and its preparation method

技术领域 technical field

本发明涉及废弃材料在海洋渔业中的利用,具体说是一种新型混凝土人工鱼礁及其制备方法,属于环保领域和渔业基础设施技术领域。 The invention relates to the utilization of waste materials in marine fishery, in particular to a novel concrete artificial fish reef and a preparation method thereof, belonging to the field of environmental protection and the technical field of fishery infrastructure.

背景技术 Background technique

人工鱼礁建设是一个复杂的海底工程,往往投资巨大,目前混凝土人工鱼礁被国内外沿海地区广泛使用。但混凝土并不是一劳永逸的耐久材料,在实际工程中的缺点和局限性主要表现在几个方面:(1)混凝土的开裂、塌边等劣化现象会严重威胁混凝土结构的耐久性,导致工程的实际寿命短于设计使用寿命;(2)混凝土人工鱼礁需要消耗大量的水泥、砂、石,原料成本较高,而且浪费资源;(3)普通水泥制备的混凝土人工鱼礁,其表面、内部碱性较强,不利于藻类的附着和鱼类的增殖。如何保证人工鱼礁建设能合理预算及取得预期效果,耐久性的混凝土人工鱼礁的研究相当重要。 The construction of artificial reefs is a complicated submarine project, often requiring huge investment. At present, concrete artificial reefs are widely used in coastal areas at home and abroad. But concrete is not a once-and-for-all durable material. The shortcomings and limitations in actual engineering are mainly manifested in several aspects: (1) Deterioration phenomena such as cracking and edge collapse of concrete will seriously threaten the durability of concrete structures, resulting in the actual engineering The service life is shorter than the designed service life; (2) Concrete artificial fish reef needs to consume a lot of cement, sand, stone, the cost of raw materials is high, and waste resources; (3) The concrete artificial fish reef made of ordinary cement, its surface and internal Strong resistance, not conducive to the attachment of algae and the proliferation of fish. How to ensure that the construction of artificial reefs can have a reasonable budget and achieve the expected results, the research on durable concrete artificial reefs is very important.

近年来,我国牡蛎的养殖发展很快,产量由1990年的8.5万吨增长到2005年的382.6万吨,我国目前对于占牡蛎质量60%以上的牡蛎壳加工却很少,每年约有230万吨的牡蛎壳变成了废弃物或低值资源,占据了一些滩涂和土地,腐败发臭,给环境带来许多不良影响。目前国内外对牡蛎壳等海产壳类物质的利用已作了相关研究,但利用牡蛎等海产壳类作为人工鱼礁的研究和应用还很少。如果能够充分利用这些资源,就近取材作为人工鱼礁的材料,增加仿天然鱼礁岩体的相仿度,不仅可充分利用废料,变废为宝,有环境保护和节省资源的重大意义。 In recent years, my country's oyster farming has developed rapidly, and the output increased from 85,000 tons in 1990 to 3.826 million tons in 2005. At present, my country's oyster shells, which account for more than 60% of oyster quality, are rarely processed, with about 2.3 million oyster shells each year. Tons of oyster shells have become waste or low-value resources, occupying some tidal flats and land, rotten and smelly, and have brought many adverse effects on the environment. At present, relevant research has been done on the utilization of marine shell materials such as oyster shells at home and abroad, but the research and application of using marine shell materials such as oysters as artificial fish reefs is still seldom. If these resources can be made full use of, nearby materials can be used as materials for artificial reefs, and the similarity of natural reef rocks can be increased, which can not only make full use of waste materials, turn waste into treasure, but also have great significance for environmental protection and resource conservation.

材料综合化是目前人工鱼礁的发展趋势之一。牡蛎壳、粉煤灰、矿粉等多种废弃材料,虽然在建材等方面有一定的研究,但在人工鱼礁中的综合应用的研究鲜见报道。 Material integration is one of the development trends of artificial reefs. Oyster shells, fly ash, mineral powder and other waste materials have been studied to some extent in building materials, but there are few reports on their comprehensive application in artificial reefs.

发明内容 Contents of the invention

本发明要解决的技术问题是在普通混凝土人工鱼礁中添加牡蛎壳等废弃材料,并研究其配合比,以制备一种新型混凝土人工鱼礁,以改善人工鱼礁的综合性能。 The technical problem to be solved by the present invention is to add waste materials such as oyster shells to common concrete artificial fish reefs, and study the mix ratio to prepare a new type of concrete artificial fish reefs to improve the comprehensive performance of artificial fish reefs.

为解决上述技术问题,本发明的目的是通过以下技术方案实现: In order to solve the problems of the technologies described above, the object of the present invention is to achieve through the following technical solutions:

一种新型混凝土人工鱼礁,它由以下配比的原料制成: A new type of concrete artificial fish reef is made of the following raw materials:

水泥:沙:石子:拌合水:牡蛎壳粉:粉媒灰:矿粉的质量比为: Cement: sand: gravel: mixing water: oyster shell powder: powder ash: the mass ratio of mineral powder is:

1:(1.9~2.6):(2.8~3.9):(0.4~0.6):(0.1~0.2):(0.1~0.3):(0.1~0.5); 1:(1.9~2.6):(2.8~3.9):(0.4~0.6):(0.1~0.2):(0.1~0.3):(0.1~0.5);

其制备方法是:将上述原料加入混凝土搅拌机,搅拌后,放到振动台进行振动均匀压实,12-24小时后拆模;拆模后进行标准养护7-28天即得。 The preparation method is as follows: adding the above-mentioned raw materials into a concrete mixer, after mixing, putting them on a vibrating table for vibration and uniform compaction, removing the formwork after 12-24 hours; and carrying out standard curing for 7-28 days after the form removal.

上述中,牡蛎壳粉采用下述方法制备: Among the above, oyster shell powder is prepared by the following method:

将牡蛎壳清洗后,干燥,粉碎至约0.5-0.8厘米即得。 Wash the oyster shells, dry them, and crush them to about 0.5-0.8 cm.

牡蛎壳为废弃材料,粉碎后可做细骨料。 Oyster shells are waste materials that can be used as fine aggregate after crushing.

本发明具有以下优点:(1)牡蛎壳价格便宜,容易就近取材费用少;牡蛎壳使用过程中不会溶出有害物质,不影响生物附着,对环境无污染,是环保型材料;(2)由于牡蛎壳材料的使用,其主要成份相对稳定,不会产生游离Ca3+,不会影响水泥的稳定性;(3)由于牡蛎壳本身为海洋废弃材料,性能更适宜海洋环境,可以改良人工鱼礁的效果。 The invention has the following advantages: (1) oyster shells are cheap, easy to obtain materials nearby, and cost less; oyster shells will not dissolve harmful substances during use, do not affect biological adhesion, and have no pollution to the environment, and are environmentally friendly materials; (2) due to The use of oyster shell materials, its main components are relatively stable, will not produce free Ca 3+ , and will not affect the stability of cement; (3) Since oyster shells themselves are marine waste materials, their performance is more suitable for marine environments, and artificial fish can be improved. reef effect.

具体实施方式 Detailed ways

实施例1: Example 1:

将牡蛎壳清洗,干燥,粉碎至0.5-0.8厘米后,将水泥:沙:石子:拌合水:牡蛎壳粉:粉媒灰:矿粉按质量比1:1.91:2.89:0.42:0.10:0.17:0.08混合加到混凝土搅拌机,搅拌后,放到振动台进行振动均匀压实,24小时后拆模;拆模后的混凝土人工鱼礁进行标准养护28天。 After cleaning, drying and crushing the oyster shells to 0.5-0.8 cm, mix cement: sand: gravel: mixing water: oyster shell powder: powder ash: mineral powder according to the mass ratio 1: 1.91: 2.89: 0.42: 0.10: 0.17 : 0.08 mixed into the concrete mixer, after mixing, put it on the vibrating table to vibrate and compact evenly, and remove the formwork after 24 hours; after the formwork removal, the concrete artificial fish reef will undergo standard maintenance for 28 days.

实施例2: Example 2:

牡蛎壳清洗,在干燥器中干燥,粉碎至0.5-0.8厘米后,将水泥:沙:石子:拌合水:牡蛎壳:粉媒灰:矿粉按质量比1:2.18:3.31:0.48:0.12:0.21:0.21混合加到混凝土搅拌机,搅拌后,放到振动台进行振动均匀压实,24小时后拆模;拆模后的混凝土人工鱼礁进行标准养护28天。 Wash the oyster shells, dry them in a desiccator, and crush them to 0.5-0.8 cm. Mix cement: sand: gravel: mixing water: oyster shells: powder ash: mineral powder in a mass ratio of 1: 2.18: 3.31: 0.48: 0.12 : 0.21: 0.21 mixed into the concrete mixer, after mixing, put it on the vibrating table to vibrate and compact evenly, remove the formwork after 24 hours; after the formwork removal, the concrete artificial reef will be maintained for 28 days.

实施例3: Example 3:

牡蛎壳清洗,在干燥器中干燥,粉碎至0.5-0.8厘米后,将水泥:沙:石子:拌合水:牡蛎壳:粉媒灰:矿粉按质量比1:2.55:3.86:0.55:0.13:0.22:0.44混合加到混凝土搅拌机,搅拌后,放到振动台进行振动均匀压实,24小时后拆模;拆模后的混凝土人工鱼礁进行标准养护28天。 Wash the oyster shells, dry them in a desiccator, and crush them to 0.5-0.8 cm, mix cement: sand: gravel: mixing water: oyster shells: powder ash: mineral powder according to the mass ratio 1: 2.55: 3.86: 0.55: 0.13 : 0.22: 0.44 mixed into the concrete mixer, after mixing, put it on the vibrating table to vibrate and compact evenly, remove the formwork after 24 hours; after the formwork removal, the concrete artificial fish reef will undergo standard maintenance for 28 days.

                                                

实施例1~3的新型混凝土人工鱼礁性能见表1: The novel concrete artificial fish reef performance of embodiment 1~3 is shown in Table 1:

表1复合材料性能 Table 1 Composite material properties

 the 实施例1Example 1 实施例2Example 2 实施例3Example 3 水泥cement 11 11 11 sand 1.911.91 2.182.18 2.552.55 石子pebbles 2.892.89 3.313.31 3.863.86 拌合水mixing water 0.420.42 0.480.48 0.550.55 牡蛎壳oyster shell 0.100.10 0.110.11 0.130.13 粉媒灰powder gray 0.170.17 0.210.21 0.220.22 矿粉mineral powder 0.080.08 0.210.21 0.440.44 塌落度(mm)Slump (mm) 170170 180180 205205 28d抗压强度/Mpa28d compressive strength/Mpa 52.252.2 50.250.2 52.652.6 抗渗等级Impermeability grade 满足P8Meet P8 满足P8Meet P8 满足P8Meet P8

以上对本发明所提供的新型混凝土人工鱼礁及其制备方法进行了详细介绍,本文中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的一般技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有所改变,综上所述,本说明书内容不应理解为对本发明的限制。 Above, the novel concrete artificial fish reef provided by the present invention and its preparation method have been introduced in detail. In this paper, specific examples have been used to illustrate the principle and implementation of the present invention. The descriptions of the above examples are only used to help understand the present invention. method and its core idea; at the same time, for those of ordinary skill in the art, according to the idea of the present invention, there will be changes in the specific implementation and scope of application. In summary, the contents of this specification should not be understood as Invention Limitations.

Claims (3)

1. a new concrete artificial marine habitat, is characterized in that, it is made up of the raw material of following proportioning:
Cement: husky: stone: mixing water: oyster shell powder: flyash: the mass ratio of breeze is:
1:(1.9~2.6):(2.8~3.9):(0.4~0.6):(0.1~0.2):(0.1~0.3):(0.1~0.5);
Its preparation method is: above-mentioned raw materials is added concrete mixer, after stirring, is put into shaking table and carries out vibration uniform compaction, form removal after 12-24 hour; The laggard column criterion maintenance of form removal 28 days and get final product.
2. a kind of new concrete artificial marine habitat according to claim 1, is characterized in that, cement: husky: stone: mixing water: oyster shell powder: flyash: the mass ratio of breeze is 1:2.55:3.86:0.55:0.13:0.22:0.44.
3. a kind of new concrete artificial marine habitat according to claim 1 and 2, is characterized in that, oyster shell powder adopts following method to prepare:
Oyster shells is cleaned, dry, pulverize to 0.5-0.8 centimetre and get final product.
CN201410776696.7A 2014-12-17 2014-12-17 Novel concrete artificial fish reef and preparation method thereof Pending CN104529286A (en)

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CN105645862A (en) * 2015-12-31 2016-06-08 福州皇家地坪有限公司 Ecological concrete for water purification
CN106630789A (en) * 2016-11-10 2017-05-10 梅庆波 Preparation method of concrete artificial fish reef material
CN106699059A (en) * 2016-12-25 2017-05-24 吴迪 Preparation method of fishing reef material with high durability
CN107549075A (en) * 2017-09-27 2018-01-09 大连博众轨道交通装备有限公司 A kind of method that structural type fish shelter and building block are made using waste shell
CN110984405A (en) * 2019-12-02 2020-04-10 哈尔滨工程大学 An ecological anti-corrosion method for marine reinforced concrete engineering in service
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CN105645862A (en) * 2015-12-31 2016-06-08 福州皇家地坪有限公司 Ecological concrete for water purification
CN106630789A (en) * 2016-11-10 2017-05-10 梅庆波 Preparation method of concrete artificial fish reef material
CN106630789B (en) * 2016-11-10 2019-01-01 中热科(海南)海洋与农业研究院有限公司 A kind of preparation method of concrete artificial reef material
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