CN104528853A - Double-chimney embedded type solar seawater desalination system and desalination method thereof - Google Patents
Double-chimney embedded type solar seawater desalination system and desalination method thereof Download PDFInfo
- Publication number
- CN104528853A CN104528853A CN201410737281.9A CN201410737281A CN104528853A CN 104528853 A CN104528853 A CN 104528853A CN 201410737281 A CN201410737281 A CN 201410737281A CN 104528853 A CN104528853 A CN 104528853A
- Authority
- CN
- China
- Prior art keywords
- seawater
- chimney
- heat
- shed
- solar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013535 sea water Substances 0.000 title claims abstract description 131
- 238000010612 desalination reaction Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000013505 freshwater Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 238000005338 heat storage Methods 0.000 claims abstract description 14
- 238000003860 storage Methods 0.000 claims description 6
- 230000007423 decrease Effects 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 230000033228 biological regulation Effects 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000012267 brine Substances 0.000 abstract description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000005192 partition Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/14—Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/138—Water desalination using renewable energy
- Y02A20/141—Wind power
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/138—Water desalination using renewable energy
- Y02A20/142—Solar thermal; Photovoltaics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/208—Off-grid powered water treatment
- Y02A20/212—Solar-powered wastewater sewage treatment, e.g. spray evaporation
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
Abstract
本发明公开了一种内嵌双烟囱型太阳能海水淡化系统及其淡化方法,水平布置的集热棚与内烟囱连接;倾斜布置的线性菲涅尔式聚光集热器与外烟囱连接;外烟囱高度高于内烟囱高度;内烟囱底部有风力透平;内外烟囱间壁内有分液器;外烟囱内有冷凝器。太阳能加热水平集热棚产生空气流;空气流推动内烟囱底部的风力透平以提供系统所需部分电能;线性菲涅尔式聚光集热器加热海水产生水蒸汽;内烟囱内的空气流引射水蒸气流向冷凝器后冷凝成淡水;淡水沿外烟囱壁流入淡水罐;较高温度的浓盐水流入水平集热棚底部蓄热层储存能量。本发明结构紧凑,将动力源和能量源合理地分离开,可更好地利用和管理太阳能,提高淡水产率。
The invention discloses a built-in double-chimney solar seawater desalination system and a desalination method thereof. A horizontally arranged heat collection shed is connected to the inner chimney; an obliquely arranged linear Fresnel type light concentrating heat collector is connected to the outer chimney; The height of the chimney is higher than that of the inner chimney; there is a wind turbine at the bottom of the inner chimney; there is a liquid separator in the partition wall of the inner and outer chimneys; and a condenser is arranged in the outer chimney. The solar-heated horizontal heat collection shed generates air flow; the air flow pushes the wind turbine at the bottom of the inner chimney to provide part of the power required by the system; the linear Fresnel-type concentrator heats seawater to generate water vapor; the air flow in the inner chimney The injected water vapor flows to the condenser and condenses into fresh water; the fresh water flows into the fresh water tank along the outer chimney wall; the higher temperature brine flows into the heat storage layer at the bottom of the horizontal heat collection shed to store energy. The invention has a compact structure, rationally separates the power source and the energy source, can better utilize and manage solar energy, and improves fresh water production rate.
Description
技术领域 technical field
本发明属于海水淡化技术领域,涉及一种太阳能热法海水淡化方法,特别涉及一种内嵌双烟囱型的太阳能海水淡化系统和淡化方法。 The invention belongs to the technical field of seawater desalination, and relates to a solar thermal seawater desalination method, in particular to a solar seawater desalination system and a desalination method with embedded double chimneys.
背景技术 Background technique
我国淡水资源人均占有量约2200m3,为世界平均水平的四分之一,被联合国列为十三个最缺水的国家之一。我国是海洋大国,海岸线漫长,可利用太阳能进行海水淡化。现有太阳能海水淡化技术已达20余种,其主要有两种方式:一是利用太阳能发电以驱动反渗透过程;二是利用太阳能产生热能来蒸馏海水使其相变蒸发。太阳能反渗透法需要高压泵、反渗透膜、换热器、冷凝器等部件,因而系统复杂,初投资成本较高。而太阳能蒸馏法简单、应用广泛、技术成熟,且无需额外电能的输入。 China's per capita freshwater resources are about 2200m 3 , which is a quarter of the world's average level, and is listed by the United Nations as one of the thirteen most water-deficient countries. Our country is a big ocean country with a long coastline, and we can use solar energy to desalinate seawater. There are more than 20 types of solar desalination technologies, and there are two main methods: one is to use solar power to drive the reverse osmosis process; the other is to use solar energy to generate heat to distill seawater to make it evaporate through phase change. The solar reverse osmosis method requires high-pressure pumps, reverse osmosis membranes, heat exchangers, condensers and other components, so the system is complex and the initial investment cost is high. The solar distillation method is simple, widely used, mature technology, and does not require additional power input.
1982年,德国斯图加特大学的Schlaich博士设计并建立了第一座太阳能烟囱示范电站,该电站由水平布置的圆形集热棚、位于集热棚中心位置的烟囱以及布置在集热棚与烟囱的连接部位的透平发电机组三个主要部件构成,其中烟囱高度为194.6m、烟囱半径为5.08m、集热棚面积46000m2,理论发电功率为50kW。其工作过程为太阳光照射集热棚,加热棚内的空气和棚下的土壤,受热空气温度升高,密度下降,在太阳能烟囱的抽吸作用下形成一股强大的上升气流,驱动风力涡轮机发电,同时集热棚周围的冷空气补充进入棚内,形成持续不断的空气循环流动。现有研究表明太阳能热气流发电系统电效率极低,MW级电站电效率仅为1%级别。但是,该系统热效率较高,一般能达到50%以上。 In 1982, Dr. Schlaich of the University of Stuttgart in Germany designed and built the first solar chimney demonstration power station. The turbine generator set at the connection part is composed of three main components, among which the height of the chimney is 194.6m, the radius of the chimney is 5.08m, the area of the heat collecting shed is 46000m 2 , and the theoretical power generation is 50kW. Its working process is that sunlight irradiates the heat-collecting shed, heating the air in the shed and the soil under the shed, the temperature of the heated air rises, the density decreases, and a strong updraft is formed under the suction of the solar chimney to drive the wind turbine to generate electricity At the same time, the cold air around the heat collecting shed is supplemented into the shed to form a continuous air circulation. Existing studies have shown that the electrical efficiency of solar thermal airflow power generation systems is extremely low, and the electrical efficiency of MW-level power stations is only 1%. However, the thermal efficiency of the system is relatively high, generally reaching more than 50%.
将太阳能烟囱系统与太阳能蒸馏法海水淡化结合,将从太阳处获得的热能用于蒸发海水将能充分发挥两者的优势,具有结构简单、较高效率的优势。现有专利中已有将太阳能烟囱系统与太阳能蒸馏法海水淡化结合的案例,分别为:公告号CN1331764C,公告日为2007年8月15日和公开号是CN101358578A,公告日为2009年2月4日的中国发明专利。然而这些专利均在集热棚下直接布置盐水池,太阳能在加热集热棚时将会有大量能量消耗在盐水蒸发上,从而损失了大量的能量,同时也使得集热棚内蒸汽的密度变化降低,进而影响了进入烟囱的气流速度从而降低了淡水产率。 Combining the solar chimney system with the desalination of seawater by solar distillation, and using the heat energy obtained from the sun to evaporate seawater will give full play to the advantages of both, and has the advantages of simple structure and high efficiency. There have been cases of combining solar chimney system with solar distillation seawater desalination in the existing patents, respectively: the announcement number CN1331764C, the announcement date is August 15, 2007 and the publication number is CN101358578A, the announcement date is February 4, 2009 Japan's Chinese invention patent. However, in these patents, the brine pool is directly arranged under the heat collection shed. When the solar energy heats the heat collection shed, a large amount of energy will be consumed in the evaporation of brine, thereby losing a lot of energy, and at the same time reducing the change in the density of the steam in the heat collection shed. , thereby affecting the airflow velocity into the chimney and reducing the freshwater production rate.
发明内容 Contents of the invention
为了克服上述现有技术的不足,本发明所要解决的技术问题是提供了一种新型基于太阳能烟囱的海水淡化系统,该系统采用太阳能分别提供能量源和动力源的系统方案。具体地:能量源主要用于聚光加热海水使得其蒸发,动力源主要是加热空气从而在烟囱内产生高速流动气流,蒸发所得蒸汽与上升气流进入内嵌式的太阳能烟囱后经冷凝器冷却为淡水。同时本发明还引入预热、能量回收和蓄热系统。 In order to overcome the deficiencies of the prior art above, the technical problem to be solved by the present invention is to provide a new type of seawater desalination system based on solar chimneys, which uses solar energy to provide energy source and power source respectively. Specifically: the energy source is mainly used to concentrate light to heat seawater to evaporate it, and the power source is mainly to heat the air to generate high-speed flowing airflow in the chimney. The evaporated steam and updraft enter the built-in solar chimney and are cooled by the condenser. freshwater. At the same time, the present invention also introduces preheating, energy recovery and thermal storage systems.
本发明为实现上述目的,采用如下技术方案: In order to achieve the above object, the present invention adopts the following technical solutions:
一种内嵌双烟囱型太阳能海水淡化系统,包括内烟囱(1)、外烟囱(2)、线性菲涅尔式聚光集热器(3)、透明集热棚(5)、海水预热器(6)、冷凝器(7)、海水输入管(8)、接水罐(10)、淡水罐(11)、集热棚底面吸热板(12)、浓海水储热罐(13)、支撑组(17)、淡水连接管(18);所述内烟囱(1)内嵌于外烟囱(2)内,内烟囱(1)出口下方设置海水预热器(6),外烟囱(2)内置冷凝器(7);所述内烟囱(1)的底部连接透明集热棚(5),所述连接处设置接水罐(10),所述接水罐(10)通过淡水连接管(18)连接淡水罐(11),所述透明集热棚(5)底部通过多组支撑组(17)支撑,所述支撑组(17)位于环形设置的集热棚底面吸热板(12)的上方,所述支撑组(17)上端还斜向设置线性菲涅尔式聚光集热器(3),所述集热棚底面吸热板(12)下方设置浓海水储热罐(13),所述浓海水储热罐(13)下方设置水平海水输入管(8)。 A built-in double-chimney solar desalination system, including inner chimney (1), outer chimney (2), linear Fresnel concentrator (3), transparent heat collection shed (5), seawater preheating Condenser (6), condenser (7), seawater input pipe (8), water receiving tank (10), fresh water tank (11), heat absorbing plate on the bottom of heat collecting shed (12), concentrated seawater heat storage tank (13) , support group (17), fresh water connecting pipe (18); the inner chimney (1) is embedded in the outer chimney (2), and a seawater preheater (6) is arranged below the outlet of the inner chimney (1), and the outer chimney ( 2) A built-in condenser (7); the bottom of the inner chimney (1) is connected to a transparent heat collection shed (5), and a water receiving tank (10) is provided at the connection, and the water receiving tank (10) is connected by fresh water The pipe (18) is connected to the fresh water tank (11), and the bottom of the transparent heat-collecting shed (5) is supported by multiple sets of support groups (17), and the support groups (17) are located on the heat-absorbing plate on the bottom of the heat-collecting shed ( 12), the upper end of the support group (17) is also obliquely provided with a linear Fresnel-type concentrating heat collector (3), and a concentrated seawater heat storage tank is provided under the heat-absorbing plate (12) on the bottom of the heat-collecting shed (13), a horizontal seawater input pipe (8) is arranged below the concentrated seawater heat storage tank (13).
上述内烟囱(1)底部设置风力透平(4)。 A wind turbine (4) is arranged at the bottom of the inner chimney (1).
上述线性菲涅尔式聚光集热器(3)由菲涅尔透镜(19)和涂黑吸热面(20)组成,所述菲涅尔透镜(19)比涂黑吸热面(20)宽。 The above-mentioned linear Fresnel type concentrating heat collector (3) is composed of a Fresnel lens (19) and a blackened heat-absorbing surface (20), and the Fresnel lens (19) is smaller than the blackened heat-absorbing surface (20). )Width.
上述涂黑吸热面(20)采用黑漆,且为阶梯形。 The above-mentioned blackened heat-absorbing surface (20) adopts black paint and is stepped.
上述外烟囱(2)内设置海水周向分液器(9),所述海水周向分液器(9)与涂黑吸热面(20)相连。 A seawater circumferential liquid separator (9) is arranged inside the outer chimney (2), and the seawater circumferential liquid separator (9) is connected to the blackened heat-absorbing surface (20).
上述淡水罐(11)水平设置淡水输出管(15),所述浓海水储热罐(13)水平设置浓海水输出管(16)。 The fresh water tank (11) is horizontally provided with a fresh water output pipe (15), and the concentrated seawater heat storage tank (13) is horizontally provided with a concentrated seawater output pipe (16).
上述冷凝器(7)高于内烟囱(1)出口,且为倾斜对称布置。 The above-mentioned condenser (7) is higher than the outlet of the inner chimney (1), and is arranged obliquely and symmetrically.
上述透明集热棚(5)设置通风口(14)。 The above-mentioned transparent heat collecting shed (5) is provided with vents (14).
一种内嵌式双烟囱型太阳能海水淡化方法,利用上述的系统,包括如下步骤: A method for desalination of seawater with built-in double-chimney solar energy, using the above-mentioned system, includes the following steps:
(1)、海水经过初级过滤后由泵输送至海水预热器(6),在该处与外界的湿蒸汽换热而提高温度,而后由海水周向分液管(9)缓缓流入涂黑吸热面(20)上,在吸热面上形成海水液膜,从而由菲涅尔透镜(19)聚光加热涂黑吸热面(20),进而使得吸热面上方的海水薄膜蒸发,产生水蒸气,浓海水则流入浓海水罐(13)内,在该处蓄积热能留作无太阳时候使用,浓海水罐水储满后由浓海水输出管(16)流出; (1) After primary filtration, the seawater is pumped to the seawater preheater (6), where it exchanges heat with the external wet steam to increase the temperature, and then slowly flows into the coating from the seawater circumferential liquid pipe (9). On the black heat-absorbing surface (20), a seawater liquid film is formed on the heat-absorbing surface, so that the Fresnel lens (19) concentrates and heats the black heat-absorbing surface (20), and then evaporates the seawater film above the heat-absorbing surface , water vapor is generated, and the concentrated seawater flows into the concentrated seawater tank (13), where heat energy is accumulated for use when there is no sun, and the concentrated seawater tank is filled with water and flows out from the concentrated seawater output pipe (16);
(2)、空气分两路,一路从线性菲涅尔聚光集热器(3)内流入,另一路从透明集热棚(5)和集热棚底面吸热板(12)之间进入内烟囱(1),在线性菲涅尔聚光集热器(3)内,空气从海水薄膜上方吹扫过,在海水薄膜快速蒸发时空气湿度大量增加,湿空气在浮升力作用和内烟囱(1)射流引射作用下进入内外烟囱壁间,继而流向海水预热器(6),在该处湿空气流动空间突然增大加之海水预热器(6)作用从而凝结为淡水滴落进入下方的接水罐(10)而后存入淡水罐(11);在透明集热棚(5)和集热棚底面吸热板(12)之间,空气流过透明集热棚(5)时被加热,从而温度升高密度降低,在烟囱浮升力作用下进入内烟囱(1),而后流向外烟囱(2)。 (2), the air is divided into two paths, one path flows in from the linear Fresnel concentrating heat collector (3), and the other path enters from between the transparent heat collecting shed (5) and the heat absorbing plate (12) on the bottom surface of the heat collecting shed In the inner chimney (1), in the linear Fresnel concentrator (3), the air is blown from above the seawater film, and the air humidity increases greatly when the seawater film evaporates rapidly, and the moist air is affected by the buoyancy force and the inner chimney (1) Under the action of jet ejection, it enters the inner and outer chimney walls, and then flows to the seawater preheater (6), where the humid air flow space suddenly increases and the action of the seawater preheater (6) condenses into fresh water dripping into the The lower water receiving tank (10) is then stored in the fresh water tank (11); between the transparent heat collecting shed (5) and the heat absorbing plate (12) on the bottom of the heat collecting shed, when the air flows through the transparent heat collecting shed (5) It is heated, so that the temperature rises and the density decreases, and enters the inner chimney (1) under the action of chimney buoyancy, and then flows to the outer chimney (2).
(3)、在外烟囱(2)内与经过海水预热器(6)的湿空气混合一起进入冷凝器(7),在该处继续将部分蒸汽冷凝,而后排入大气; (3) In the outer chimney (2), it is mixed with the humid air passing through the seawater preheater (6) and enters the condenser (7), where it continues to condense part of the steam and then discharges it into the atmosphere;
(4)、风力透平(4)留作调峰使用;风力发电获得的电能经逆变器调频后一起存入蓄电池内,而后驱动泵使得海水流入海水输入管(8),如有电能富余可直接用作电加热海水薄膜或浓海水储液罐(13)。 (4) The wind turbine (4) is reserved for peak regulation; the electric energy obtained by wind power is stored in the battery after frequency modulation by the inverter, and then the pump is driven to make seawater flow into the seawater input pipe (8). If there is surplus electric energy It can be directly used as an electrically heated seawater film or a concentrated seawater liquid storage tank (13).
本发明在工作时: When the present invention works:
线性菲涅尔式聚光器以太阳能外烟囱为中心,周向倾斜分布,海水经过初级过滤后由泵输送至海水预热器,在该处与外烟囱的湿蒸汽和内烟囱的热空气换热而提高温度,而后由周向分液管分流后缓缓进入涂黑吸热面上,形成海水液膜。太阳能被线性菲涅尔式聚集从而加热涂黑吸热面,再由吸热面加热其下表面的海水薄膜从而产生蒸汽。涂黑吸热面为阶梯型,可以有效增加海水蒸发量。海水经过蒸发后产生的浓海水则流入集热棚底面吸热板下方的浓海水罐内,并在该处蓄积热能留作无太阳时候使用。浓海水罐水储满后则由浓海水输出管流出。空气分两路进入该系统,一部分空气经由线性菲涅尔聚光集热器加热产生浮升力,快速从海水薄膜上方吹扫过,使得海水薄膜快速蒸发,并且空气湿度大量增加。湿空气在浮升力作用下进入内外烟囱的夹层内,继而流向海水预热器,在该处湿空气流动空间突然增大加之海水预热器作用从而凝结为淡水滴落进入下方的接水罐而后存入淡水罐。另外一部分空气经由集热棚底面吸热板与集热棚底面吸热板之间形成的空气夹层,在该夹层内空气被集热棚底部的吸热板加热,从而温度升高密度降低,与外部环境形成密度差,从而形成压力差,产生强大的上升气流驱动置于内烟囱底部中央的风力透平,从而带动发电机发电,而后流向外烟囱。而这时的空气仍然是上升的热风,该热风可以引射经过海水预热器的湿空气,在烟囱双通道最终混合一起进入外烟囱后继续上升,经过冷凝器,在该处将湿蒸汽二次冷凝,形成淡水沿外烟囱壁面滴落。该冷凝器为倾斜对称布置,便于淡水能够汇集至外烟囱壁面,并且冷凝器部分伸出烟囱外部,在冷凝器内部形成自然循环,温度高的水会循环至冷凝器在烟囱外部的部分由外部环境进行风冷,温度低的水循环至冷凝器底部,对上升的湿蒸汽进行冷却,同时该冷凝器由于布置位置较高,可以在利用夜间较低的环境温度进行冷却。 The linear Fresnel concentrator is centered on the solar chimney and distributed obliquely in the circumferential direction. After primary filtration, the seawater is pumped to the seawater preheater, where it is exchanged with the wet steam of the outer chimney and the hot air of the inner chimney. The temperature is increased by heat, and then the flow is diverted by the circumferential liquid distribution pipe and then slowly enters the blackened heat-absorbing surface to form a seawater liquid film. Solar energy is concentrated in a linear Fresnel manner to heat the blackened heat absorbing surface, which in turn heats the seawater film below it to generate steam. The blackened heat-absorbing surface is stepped, which can effectively increase the evaporation of seawater. The concentrated seawater produced by the evaporation of seawater flows into the concentrated seawater tank under the heat absorbing plate on the bottom of the heat collection shed, where heat energy is stored for use when there is no sun. After the thick seawater tank is full, it will flow out from the thick seawater output pipe. The air enters the system in two ways, and part of the air is heated by a linear Fresnel concentrator to generate buoyancy, and is quickly swept over the seawater film, causing the seawater film to evaporate rapidly and the air humidity to increase significantly. The moist air enters the interlayer of the inner and outer chimneys under the action of the buoyancy force, and then flows to the seawater preheater, where the flow space of the moist air suddenly increases, coupled with the action of the seawater preheater, condenses into fresh water and drips into the water receiving tank below. Store in fresh water tanks. The other part of the air passes through the air interlayer formed between the heat-absorbing plate on the bottom of the heat-collecting shed and the heat-absorbing plate on the bottom of the heat-collecting shed. The external environment forms a density difference, resulting in a pressure difference, which generates a strong updraft to drive the wind turbine placed in the center of the bottom of the inner chimney, thereby driving the generator to generate electricity, and then flows to the outer chimney. At this time, the air is still rising hot air, which can eject the humid air passing through the seawater preheater, and continue to rise after the two channels of the chimney are finally mixed together and enter the outer chimney. Secondary condensation forms fresh water that drips along the wall of the outer chimney. The condenser is inclined and symmetrically arranged, so that fresh water can be collected to the wall of the outer chimney, and the part of the condenser protrudes out of the chimney to form a natural circulation inside the condenser, and the water with high temperature will circulate to the part of the condenser outside the chimney from the outside The environment is air-cooled, and the low-temperature water circulates to the bottom of the condenser to cool the rising wet steam. At the same time, the condenser can be cooled by using the lower ambient temperature at night due to its high location.
本发明的技术方案与现有技术相比,具有以下有益效果:具有周向布置的倾斜集热棚,在增加吸收的太阳辐射量的同时可增强烟囱的安全性;具有内外两个烟囱,空气分两路进入系统,经过空气分配优化可以使得海水淡化效率提高;在赤道地区,线性菲涅尔式聚光器以太阳能外烟囱为中心,周向均匀倾斜分布,可以增大集热器的集热面积,并且提高其集热效率;使用冷凝器可以有效提高水蒸气冷凝效率;冷凝器为倾斜对称布置,便于淡水能够汇集至外烟囱壁面,并且部分伸出烟囱外部可以使其冷凝器内部形成自然循环,从而不需要额外能源的输入。 Compared with the prior art, the technical solution of the present invention has the following beneficial effects: it has a circumferentially arranged inclined heat collection shed, which can enhance the safety of the chimney while increasing the amount of absorbed solar radiation; it has two chimneys inside and outside, and the air It enters the system in two ways, and the optimization of air distribution can improve the efficiency of seawater desalination; in the equatorial region, the linear Fresnel concentrator is centered on the solar chimney, and is evenly distributed in the circumferential direction, which can increase the concentration of the collector. heat area, and improve its heat collection efficiency; using a condenser can effectively improve the condensation efficiency of water vapor; the condenser is arranged in a tilted symmetry, so that fresh water can be collected to the wall of the outer chimney, and part of it protruding from the outside of the chimney can make the inside of the condenser form a natural cycle, so that no additional energy input is required.
附图说明 Description of drawings
为了使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明作进一步的详细描述,其中: In order to make the purpose, technical solutions and advantages of the present invention clearer, the present invention will be described in further detail below in conjunction with the accompanying drawings, wherein:
图1为本发明内嵌双烟囱型太阳能海水淡化系统原理图。 Fig. 1 is a schematic diagram of the present invention embedded double-chimney solar seawater desalination system.
图2为本发明线性菲涅尔式聚光集热器结构图。 Fig. 2 is a structural diagram of the linear Fresnel type concentrator of the present invention.
图3为外烟囱内冷凝器的剖视图。 Fig. 3 is a sectional view of the condenser in the outer chimney.
图中: In the picture:
1、内烟囱,2、外烟囱,3、线性菲涅尔式聚光集热器,4、风力涡轮机,5、透明集热棚,6、海水预热器,7、冷凝器,8、海水输入管,9、海水周向分液管,10、接水罐,11、淡水罐,12、集热棚底面吸热板,13、浓海水储热罐,14、通风口,15、淡水输出管,16、浓海水输出管,17、支撑组,18、淡水连接管,19、菲涅尔透镜,20、涂黑吸热面。 1. Inner chimney, 2. Outer chimney, 3. Linear Fresnel concentrator, 4. Wind turbine, 5. Transparent heat collection shed, 6. Seawater preheater, 7. Condenser, 8. Seawater Input pipe, 9. Seawater circumferential liquid distribution pipe, 10. Water tank, 11. Fresh water tank, 12. Heat absorbing plate on the bottom of the heat collection shed, 13. Concentrated seawater heat storage tank, 14. Vent, 15. Fresh water output Pipe, 16, dense seawater output pipe, 17, support group, 18, fresh water connecting pipe, 19, Fresnel lens, 20, blackened heat-absorbing surface.
具体实施方式 detailed description
下面结合附图对本发明进一步说明。如图1所示,一种内嵌双烟囱型太阳能海水淡化系统,包括内烟囱1、外烟囱2、线性菲涅尔式聚光集热器3、透明集热棚5、海水预热器6、冷凝器7、海水输入管8、接水罐10、淡水罐11、集热棚底面吸热板12、浓海水储热罐13、支撑组17、淡水连接管18;内烟囱1内嵌于外烟囱2内,内烟囱1出口下方设置海水预热器6,外烟囱2内置冷凝器7;内烟囱1的底部连接透明集热棚5,连接处设置接水罐10,接水罐10通过淡水连接管18连接淡水罐11,透明集热棚5底部通过多组支撑组17支撑,支撑组17位于环形设置的集热棚底面吸热板12的上方,支撑组17上端还斜向设置线性菲涅尔式聚光集热器3,集热棚底面吸热板12下方设置浓海水储热罐13,浓海水储热罐13下方设置水平海水输入管8。 The present invention will be further described below in conjunction with the accompanying drawings. As shown in Figure 1, a built-in double-chimney solar desalination system includes an inner chimney 1, an outer chimney 2, a linear Fresnel concentrator 3, a transparent heat collection shed 5, and a seawater preheater 6 , condenser 7, seawater input pipe 8, water receiving tank 10, fresh water tank 11, heat absorbing plate 12 at the bottom of the heat collection shed, concentrated seawater heat storage tank 13, support group 17, fresh water connecting pipe 18; the inner chimney 1 is embedded in Inside the outer chimney 2, a seawater preheater 6 is installed under the outlet of the inner chimney 1, and a condenser 7 is built in the outer chimney 2; the bottom of the inner chimney 1 is connected to a transparent heat collection shed 5, and a water tank 10 is set at the connection, and the water tank 10 passes through The fresh water connecting pipe 18 is connected to the fresh water tank 11. The bottom of the transparent heat collecting shed 5 is supported by multiple sets of support groups 17. The support group 17 is located above the heat absorbing plate 12 on the bottom surface of the heat collecting shed which is arranged in a ring. The Fresnel type concentrating heat collector 3, the concentrated seawater heat storage tank 13 is arranged under the heat absorbing plate 12 on the bottom surface of the heat collecting shed, and the horizontal seawater input pipe 8 is arranged under the concentrated seawater heat storage tank 13.
上述内烟囱1底部设置风力透平4。 A wind turbine 4 is arranged at the bottom of the above-mentioned inner chimney 1 .
上述线性菲涅尔式聚光集热器3由菲涅尔透镜19和涂黑吸热面20组成,所述菲涅尔透镜19比涂黑吸热面20宽。 The above-mentioned linear Fresnel type concentrating heat collector 3 is composed of a Fresnel lens 19 and a blackened heat absorbing surface 20 , and the Fresnel lens 19 is wider than the blackened heat absorbing surface 20 .
上述涂黑吸热面20采用黑漆,且为阶梯形。 The above-mentioned blackened heat absorbing surface 20 adopts black paint and is stepped.
上述外烟囱2内设置海水周向分液器9,海水周向分液器9与涂黑吸热面20相连。 The seawater circumferential liquid separator 9 is arranged inside the outer chimney 2 , and the seawater circumferential liquid separator 9 is connected to the blackened heat-absorbing surface 20 .
上述淡水罐11水平设置淡水输出管15,浓海水储热罐13水平设置浓海水输出管16。 The fresh water tank 11 is horizontally provided with a fresh water output pipe 15, and the concentrated seawater heat storage tank 13 is horizontally provided with a concentrated seawater output pipe 16.
上述冷凝器7高于内烟囱1出口,且为倾斜对称布置。 The above-mentioned condenser 7 is higher than the outlet of the inner chimney 1, and is arranged obliquely and symmetrically.
上述透明集热棚5设置通风口14。 The above-mentioned transparent heat collecting shed 5 is provided with vents 14 .
一种内嵌双烟囱型太阳能海水淡化方法,海水经过初级过滤后由泵输送至海水预热器6,在该处与外界的湿蒸汽换热而提高温度,而后由海水周向分液管9缓缓流入涂黑吸热面20上,在吸热面上形成海水液膜,从而由菲涅尔透镜19聚光加热涂黑吸热面20,进而使得吸热面上方的海水薄膜蒸发,产生水蒸气,浓海水则流入浓海水罐13内,在该处蓄积热能留作无太阳时候使用。浓海水罐水储满后则由浓海水输出管16流出。线性菲涅尔式聚光器3以烟囱为中心周向布置,为使得聚光器效率较高,可根据其放置的位置和太阳位置进行调节。空气分两路,一路从线性菲涅尔聚光集热器3内流入,另一路从透明集热棚5和集热棚底面吸热板12之间进入内烟囱1。在线性菲涅尔聚光集热器3内,空气从海水薄膜上方吹扫过,在海水薄膜快速蒸发时空气湿度大量增加。湿空气在浮升力作用和内烟囱1射流引射作用下进入内外烟囱壁间,继而流向海水预热器6,在该处湿空气流动空间突然增大加之海水预热器6作用从而凝结为淡水滴落进入下方的接水罐10而后存入淡水罐11。在透明集热棚5和集热棚底面吸热板12之间,空气流过集热棚时被加热,从而温度升高密度降低,在烟囱浮升力作用下进入内烟囱1,而后流向外烟囱2。在外烟囱内与经过海水预热器6的湿空气混合一起进入冷凝器7,在该处继续将部分蒸汽冷凝,而后排入大气。风力透平4留作调峰使用。风力发电获得的电能经逆变器调频后一起存入蓄电池内,而后驱动泵使得海水流入海水输入管8。如有电能富余可直接用作电加热海水薄膜或浓海水储液罐13。 A method for desalination of seawater with built-in double-chimney solar energy. After primary filtration, the seawater is pumped to the seawater preheater 6, where it exchanges heat with the external wet steam to increase the temperature, and then the seawater is distributed by the circumferential liquid pipe 9. Slowly flow into the blackened heat-absorbing surface 20, forming a seawater liquid film on the heat-absorbing surface, so that the Fresnel lens 19 condenses and heats the blackened heat-absorbing surface 20, and then evaporates the seawater film above the heat-absorbing surface, resulting in Water vapor and thick seawater then flow into the thick seawater tank 13, where heat energy is accumulated for use when there is no sun. After the thick seawater tank water storage is full, then flow out by the thick seawater output pipe 16. The linear Fresnel concentrator 3 is arranged circumferentially around the chimney, and can be adjusted according to its placement position and the position of the sun in order to make the concentrator more efficient. The air is divided into two paths, one path flows in from the linear Fresnel concentrating heat collector 3, and the other path enters the inner chimney 1 between the transparent heat collecting shed 5 and the heat absorbing plate 12 on the bottom surface of the heat collecting shed. In the linear Fresnel concentrating heat collector 3, the air is swept from above the seawater film, and the air humidity increases greatly when the seawater film evaporates rapidly. The moist air enters the inner and outer chimney walls under the action of the buoyancy force and the jet ejection of the inner chimney 1, and then flows to the seawater preheater 6, where the flow space of the moist air suddenly increases and the action of the seawater preheater 6 condenses into fresh water Drip into the water receiving tank 10 below and then deposit in the fresh water tank 11. Between the transparent heat-collecting shed 5 and the heat-absorbing plate 12 on the bottom of the heat-collecting shed, the air is heated when it flows through the heat-collecting shed, so that the temperature rises and the density decreases. 2. In the outer chimney, it mixes with the humid air passing through the seawater preheater 6 and enters the condenser 7, where it continues to condense part of the steam, and then discharges it into the atmosphere. Wind turbine 4 is reserved for peak regulation. The electric energy obtained by wind power generation is stored in the storage battery after frequency modulation by the inverter, and then the pump is driven to make the seawater flow into the seawater input pipe 8 . Can directly be used as electric heating seawater film or concentrated seawater storage tank 13 if there is electric energy surplus.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410737281.9A CN104528853B (en) | 2014-12-05 | 2014-12-05 | A kind of embedded pair of chimney type solar seawater desalination system and desalination method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410737281.9A CN104528853B (en) | 2014-12-05 | 2014-12-05 | A kind of embedded pair of chimney type solar seawater desalination system and desalination method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104528853A true CN104528853A (en) | 2015-04-22 |
CN104528853B CN104528853B (en) | 2016-08-31 |
Family
ID=52844548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410737281.9A Expired - Fee Related CN104528853B (en) | 2014-12-05 | 2014-12-05 | A kind of embedded pair of chimney type solar seawater desalination system and desalination method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104528853B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105056441A (en) * | 2015-08-17 | 2015-11-18 | 泉港区奇妙工业设计服务中心 | Movement fire protection condenser |
CN106698567A (en) * | 2017-01-18 | 2017-05-24 | 河海大学 | Solar power generation and seawater desalination device of combining condenser and wind turbine |
CN106856699A (en) * | 2017-03-09 | 2017-06-20 | 天津商业大学 | A kind of active desalting salinized soil device of utilization solar energy effect |
CN108870798A (en) * | 2017-05-12 | 2018-11-23 | 浙江大学 | Radiation refrigeration particle and devaporation recyclable device |
CN108911339A (en) * | 2018-08-21 | 2018-11-30 | 吴爱兵 | A method of utilizing seawater preparing fresh |
US10371125B1 (en) | 2017-12-15 | 2019-08-06 | King Fahd University Of Petroleum And Minerals | Solar-concentrating chimney system with inflatable fresnel lens |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1623915A (en) * | 2004-12-14 | 2005-06-08 | 天津大学 | Solar Chimney Indirect Condensation Heat Exchange Preparation of Fresh Water and Wind Power Integrated System |
CN101358578A (en) * | 2008-08-05 | 2009-02-04 | 河海大学 | A device that utilizes solar energy for chimney power generation and seawater desalination |
CN202849107U (en) * | 2012-10-20 | 2013-04-03 | 刘方旭 | Water ring vacuum negative-pressure evaporation solar-powered seawater desalination device |
JP2013063360A (en) * | 2011-09-15 | 2013-04-11 | Japan Aerospace Technology Foundation | Seawater desalination plant |
CN203200053U (en) * | 2013-03-28 | 2013-09-18 | 深圳市和平卧龙科技有限公司 | Solar-powered seawater desalination device |
CN203229394U (en) * | 2013-05-09 | 2013-10-09 | 王博涛 | Seawater desalination system utilizing water circulation characteristics |
-
2014
- 2014-12-05 CN CN201410737281.9A patent/CN104528853B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1623915A (en) * | 2004-12-14 | 2005-06-08 | 天津大学 | Solar Chimney Indirect Condensation Heat Exchange Preparation of Fresh Water and Wind Power Integrated System |
CN101358578A (en) * | 2008-08-05 | 2009-02-04 | 河海大学 | A device that utilizes solar energy for chimney power generation and seawater desalination |
JP2013063360A (en) * | 2011-09-15 | 2013-04-11 | Japan Aerospace Technology Foundation | Seawater desalination plant |
CN202849107U (en) * | 2012-10-20 | 2013-04-03 | 刘方旭 | Water ring vacuum negative-pressure evaporation solar-powered seawater desalination device |
CN203200053U (en) * | 2013-03-28 | 2013-09-18 | 深圳市和平卧龙科技有限公司 | Solar-powered seawater desalination device |
CN203229394U (en) * | 2013-05-09 | 2013-10-09 | 王博涛 | Seawater desalination system utilizing water circulation characteristics |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105056441A (en) * | 2015-08-17 | 2015-11-18 | 泉港区奇妙工业设计服务中心 | Movement fire protection condenser |
CN105056441B (en) * | 2015-08-17 | 2018-02-27 | 泉港区奇妙工业设计服务中心 | One kind motion fire-fighting condenser |
CN106698567A (en) * | 2017-01-18 | 2017-05-24 | 河海大学 | Solar power generation and seawater desalination device of combining condenser and wind turbine |
CN106698567B (en) * | 2017-01-18 | 2019-12-13 | 河海大学 | A solar power generation and seawater desalination device combining condenser and wind turbine |
CN106856699A (en) * | 2017-03-09 | 2017-06-20 | 天津商业大学 | A kind of active desalting salinized soil device of utilization solar energy effect |
CN108870798A (en) * | 2017-05-12 | 2018-11-23 | 浙江大学 | Radiation refrigeration particle and devaporation recyclable device |
CN108870798B (en) * | 2017-05-12 | 2020-07-14 | 浙江大学 | Radiation refrigeration particle and steam condensation recovery device |
US10371125B1 (en) | 2017-12-15 | 2019-08-06 | King Fahd University Of Petroleum And Minerals | Solar-concentrating chimney system with inflatable fresnel lens |
CN108911339A (en) * | 2018-08-21 | 2018-11-30 | 吴爱兵 | A method of utilizing seawater preparing fresh |
Also Published As
Publication number | Publication date |
---|---|
CN104528853B (en) | 2016-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104528853B (en) | A kind of embedded pair of chimney type solar seawater desalination system and desalination method thereof | |
CN105152252B (en) | Comprehensively utilize zero energy consumption sea water desalinating unit of solar energy | |
CN103739029B (en) | Solar concentrating distillation seawater desalination device | |
CN105174339B (en) | Forward optically focused multiple-effect backheat array humidifies dehumidifying solar energy sea water desalination apparatus | |
CN104896769B (en) | A kind of tower type solar chimney salt, water, cogeneration system and its operation method | |
CN111392797A (en) | Solar seawater desalination system and method | |
CN103964526B (en) | Sea water desalination film adopting solar micro condensation and capillary evaporation | |
CN104402078B (en) | A kind of two chimney type motion tracking solar seawater desalination system and desalination method thereof | |
CN104944488B (en) | A kind of solar tracking solar chimney salt, water, cogeneration system and its operation method | |
CN207002313U (en) | A kind of negative pressure ultrasound atomization type solar energy sea water desalination apparatus | |
CN209259726U (en) | An integrated system based on solar desalination and salinity energy generation | |
CN103626247B (en) | A kind of solar energy sea water vaporizer | |
CN101767840A (en) | High-efficiency and energy-saving type solar energy seawater (salt water) desalination technology | |
CN104192930B (en) | Solar energy separate heat pipe desalination plant | |
CN105923677B (en) | The multi-stage falling-film desalination plant that parabolic concentrator is pulsed compound with hot steam | |
CN103359799A (en) | Two-channel chimney device, seawater desalting device and method for forming two airflow channels | |
CN104944487A (en) | Electricity and fresh water co-generation compound solar device | |
KR101994116B1 (en) | Solar thermal collector apparatus in solar updraft tower for distilling seawater and generating electricity | |
CN110104716A (en) | A kind of two-tube opposed type solar energy sea water desalination apparatus based on membrane distillation | |
CN108178219A (en) | Solar seawater desalination system based on MOF materials | |
CN114604923B (en) | A photothermal photoelectric integrated collector tube seawater desalination device | |
CN106517395A (en) | Circular light and heat concentration salt water and fresh water separator | |
CN209383435U (en) | A seawater desalination system | |
CN208500408U (en) | Solar energy optical-thermal thermo-electric generation and sea water desalination integrated system | |
CN203297048U (en) | Water-vapor circulation electricity generating device based on solar energy |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160831 Termination date: 20211205 |