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CN104513588A - Nitrogen-containing flame retardant epoxy resin abrasion proof and water proof coating - Google Patents

Nitrogen-containing flame retardant epoxy resin abrasion proof and water proof coating Download PDF

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Publication number
CN104513588A
CN104513588A CN201410781228.9A CN201410781228A CN104513588A CN 104513588 A CN104513588 A CN 104513588A CN 201410781228 A CN201410781228 A CN 201410781228A CN 104513588 A CN104513588 A CN 104513588A
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CN
China
Prior art keywords
parts
water
fire retarding
epoxide resin
retarding epoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410781228.9A
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Chinese (zh)
Inventor
董宝财
李艳艳
李义国
甄建云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEBEI KELAIDA BUILDING MATERIAL CO., LTD.
Original Assignee
Hebei Ke Lai Changes In Temperature Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Ke Lai Changes In Temperature Engineering Co Ltd filed Critical Hebei Ke Lai Changes In Temperature Engineering Co Ltd
Priority to CN201410781228.9A priority Critical patent/CN104513588A/en
Publication of CN104513588A publication Critical patent/CN104513588A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a nitrogen-containing flame retardant epoxy resin abrasion proof and water proof coating, which comprises the following components by weight: 65-70 parts of a nitrogen-containing flame retardant epoxy resin, 20-30 parts of alkyd resin, 30-40 parts of sodium formaldehyde sulfoxylate, 20-30 parts of polyamide resin, 10-15 parts of urea, 1-3 parts of methyl fiber, 3-9 parts of acrylic emulsion, 5-10 parts of a mica pigment, 4-8 parts of propylene glycol, 2-4 parts of sodium silicate, 0.4-0.6 part of ethylene diamine, 0.2-0.3 part of a defoaming agent and 140-150 parts of water. The enhanced abrasion proof and water proof coating provided by the invention can be widely used in indoor and outdoor decoration; the coating not only has good heat resistance, moisture resistance, corrosion resistance and good abrasion resistance, but also has good waterproof performance, can effectively isolate the outside water; the adhesive coating process is simple, and the coating uniformly coats on the surfaces of wall body, woodware or steel products; the invention has the advantages of no high technical requirements on the construction personnel, convenient construction, and low requirement on the site.

Description

A kind of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint
Technical field
The present invention relates to a kind of coating, specifically a kind of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint.
Background technology
Buildings generally uses concrete structure when building, easy seepage, particularly at roofing and vault, the many place of underground water or rainy time very easily seepage, therefore many positions of buildings need to carry out WATER REPELLENT, the kitichen and toilet metope ground of general house ornamentation also needs to do WATER REPELLENT, building inside and outside wall coating common in the market, paint, waterproof paint, terrace all uses talcum powder, titanium dioxide, coarse whiting, fine particle calcium carbonate kaolin etc. are as color stuffing, after these coating use for some time in severe environment, paint film can produce a lot of drawback, as weathering, be full of cracks comes off, HUMAN HEALTH is affected in indoor, environment is affected in outdoor, and for the paint that makes woodenware coating and coating, usually there is corrosion-resistant, resistance of aging is looked into and the defect of poor adhesive force, time one grows up to sheet be full of cracks and comes off, work-ing life is short, have impact on the attractive in appearance of various goods.
Summary of the invention
The object of the present invention is to provide a kind of wear-resisting and nitrogenous fire retarding epoxide resin abrasionproof waterproof paint of waterproof, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
1. a nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, comprises the component of following weight part: nitrogenous fire retarding epoxide resin 65 ~ 70 parts, Synolac 20 ~ 30 parts, rongalite 30 ~ 40 parts, polyamide resin 20 ~ 30 parts, 10 ~ 15 parts, urea, methylcellulose gum 1 ~ 3 part, ACRYLIC EMULSION 3 ~ 9 parts, pigments, mica 5 ~ 10 parts, propylene glycol 4 ~ 8 parts, water glass 2 ~ 4 parts, quadrol 0.4 ~ 0.6 part, defoamer 0.2 ~ 0.3 part, 140 ~ 150 parts, water.
The preparation method of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint comprises the steps:
(1) each amounts of components is taken according to weight part; (2) load weighted rongalite, urea, water glass and methylcellulose gum being put into successively temperature is that the reactor of 110 ~ 130 DEG C carries out stirring 4 ~ 6min; (3) load weighted nitrogenous fire retarding epoxide resin, Synolac, polyamide resin and pigments, mica are put into reactor successively to stir rapidly; (4) load weighted ACRYLIC EMULSION, propylene glycol, defoamer, quadrol and water are put into reactor successively to stir rapidly; (5) go out reactor after being incubated 10 ~ 12h be cooled to room temperature and pack.
As the further scheme of the present invention: described nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, comprises the component of following weight part: nitrogenous fire retarding epoxide resin 68 parts, Synolac 25 parts, rongalite 35 parts, polyamide resin 25 parts, 12 parts, urea, methylcellulose gum 2 parts, ACRYLIC EMULSION 6 parts, pigments, mica 8 parts, propylene glycol 6 parts, water glass 3 parts, quadrol 0.5 part, defoamer 0.25 part, 145 parts, water.
As the present invention's further scheme: by the two contracting Ursol D Schiff's base of p-Hydroxybenzaldehyde and epoxy chloropropane, condensation in sodium hydroxide solution obtains described nitrogenous fire retarding epoxide resin.
Compared with prior art, the invention has the beneficial effects as follows:
Reinforced abrasionproof waterproof paint of the present invention, the decoration of indoor and outdoor can be widely used in, its coating not only heat-resisting, moistureproof, anticorrosive, abrasion resistance is good, and water resistance is fine, effectively can completely cut off extraneous water, snearing technique is simple, only need by the surface of coating even application in body of wall, woodenware or steel work, to workmen without higher technical requirements, easy construction, low to site requirements.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
A kind of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, comprises the component of following weight part: nitrogenous fire retarding epoxide resin 65 parts, Synolac 20 parts, rongalite 30 parts, polyamide resin 20 parts, 10 parts, urea, methylcellulose gum 1 part, ACRYLIC EMULSION 3 parts, propylene glycol 4 parts, pigments, mica 5 parts, water glass 2 parts, quadrol 0.4 part, defoamer 0.2 part, 140 parts, water.
The preparation method of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint comprises the steps:
(1) each amounts of components is taken according to weight part; (2) load weighted rongalite, urea, water glass and methylcellulose gum being put into successively temperature is that the reactor of 110 DEG C carries out stirring 4min; (3) load weighted nitrogenous fire retarding epoxide resin, Synolac, polyamide resin and pigments, mica are put into reactor successively to stir rapidly; (4) load weighted ACRYLIC EMULSION, propylene glycol, defoamer, quadrol and water are put into reactor successively to stir rapidly; (5) go out reactor after being incubated 10h be cooled to room temperature and pack.
Embodiment 2
A kind of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, comprises the component of following weight part: nitrogenous fire retarding epoxide resin 68 parts, Synolac 25 parts, rongalite 35 parts, polyamide resin 25 parts, 12 parts, urea, methylcellulose gum 2 parts, ACRYLIC EMULSION 6 parts, pigments, mica 8 parts, propylene glycol 6 parts, water glass 3 parts, quadrol 0.5 part, defoamer 0.25 part, 145 parts, water.
The preparation method of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint comprises the steps:
(1) each amounts of components is taken according to weight part; (2) load weighted rongalite, urea, water glass and methylcellulose gum being put into successively temperature is that the reactor of 120 DEG C carries out stirring 5min; (3) load weighted nitrogenous fire retarding epoxide resin, Synolac, polyamide resin and pigments, mica are put into reactor successively to stir rapidly; (4) load weighted ACRYLIC EMULSION, propylene glycol, defoamer, quadrol and water are put into reactor successively to stir rapidly; (5) go out reactor after being incubated 11h be cooled to room temperature and pack.
Embodiment 3
A kind of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, comprises the component of following weight part: nitrogenous fire retarding epoxide resin 70 parts, Synolac 30 parts, rongalite 40 parts, polyamide resin 30 parts, 15 parts, urea, methylcellulose gum 3 parts, ACRYLIC EMULSION 9 parts, pigments, mica 10 parts, propylene glycol 8 parts, water glass 4 parts, quadrol 0.6 part, defoamer 0.3 part, 150 parts, water.
The preparation method of nitrogenous fire retarding epoxide resin abrasionproof waterproof paint comprises the steps:
(1) each amounts of components is taken according to weight part; (2) load weighted rongalite, urea, water glass and methylcellulose gum being put into successively temperature is that the reactor of 130 DEG C carries out stirring 4min; (3) load weighted nitrogenous fire retarding epoxide resin, Synolac, polyamide resin and mica eye pigment are put into reactor successively to stir rapidly; (4) load weighted ACRYLIC EMULSION, propylene glycol, defoamer, quadrol and water are put into reactor successively to stir rapidly; (5) go out reactor after being incubated 12h be cooled to room temperature and pack.
Reinforced abrasionproof waterproof paint of the present invention, the decoration of indoor and outdoor can be widely used in, its coating not only heat-resisting, moistureproof, anticorrosive, abrasion resistance is good, and water resistance is fine, effectively can completely cut off extraneous water, snearing technique is simple, only need by the surface of coating even application in body of wall, woodenware or steel work, to workmen without higher technical requirements, easy construction, low to site requirements.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.

Claims (4)

1. a nitrogenous fire retarding epoxide resin abrasionproof waterproof paint, it is characterized in that, comprise the component of following weight part: nitrogenous fire retarding epoxide resin 65 ~ 70 parts, Synolac 20 ~ 30 parts, rongalite 30 ~ 40 parts, polyamide resin 20 ~ 30 parts, 10 ~ 15 parts, urea, methylcellulose gum 1 ~ 3 part, ACRYLIC EMULSION 3 ~ 9 parts, pigments, mica 5 ~ 10 parts, propylene glycol 4 ~ 8 parts, water glass 2 ~ 4 parts, quadrol 0.4 ~ 0.6 part, defoamer 0.2 ~ 0.3 part, 140 ~ 150 parts, water.
2. nitrogenous fire retarding epoxide resin abrasionproof waterproof paint according to claim 1, it is characterized in that, comprise the component of following weight part: nitrogenous fire retarding epoxide resin 68 parts, Synolac 25 parts, rongalite 35 parts, polyamide resin 25 parts, 12 parts, urea, methylcellulose gum 2 parts, ACRYLIC EMULSION 6 parts, pigments, mica 8 parts, propylene glycol 6 parts, water glass 3 parts, quadrol 0.5 part, defoamer 0.25 part, 145 parts, water.
3. nitrogenous fire retarding epoxide resin abrasionproof waterproof paint according to claim 1 and 2, is characterized in that, by the two contracting Ursol D Schiff's base of p-Hydroxybenzaldehyde and epoxy chloropropane, condensation in NaOH liquid obtains described nitrogenous fire retarding epoxide resin.
4. adopt a preparation method for the nitrogenous fire retarding epoxide resin abrasionproof waterproof paint as described in one of claim 1-3, it is characterized in that, comprise the steps: that (1) takes each amounts of components according to weight part; (2) load weighted rongalite, urea, water glass and methylcellulose gum being put into successively temperature is that the reactor of 110 ~ 130 DEG C carries out stirring 4 ~ 6min; (3) load weighted nitrogenous fire retarding epoxide resin, Synolac, polyamide resin and pigments, mica are put into reactor successively to stir rapidly; (4) load weighted ACRYLIC EMULSION, propylene glycol, defoamer, quadrol and water are put into reactor successively to stir rapidly; (5) go out reactor after being incubated 10 ~ 12h be cooled to room temperature and pack.
CN201410781228.9A 2014-12-18 2014-12-18 Nitrogen-containing flame retardant epoxy resin abrasion proof and water proof coating Pending CN104513588A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105255282A (en) * 2015-10-28 2016-01-20 自贡市华尔美科技有限公司 Flame-retardant waterproof coating for house decoration
CN109895484A (en) * 2019-02-18 2019-06-18 滁州卷烟材料厂 A kind of water proof fire retardant corrugated case
CN117070130A (en) * 2023-08-16 2023-11-17 黄山天马新材料科技有限公司 Preparation method of epoxy resin-based powder coating with texture effect
CN117070130B (en) * 2023-08-16 2025-04-15 黄山天马新材料科技有限公司 A method for preparing epoxy resin-based powder coating with texture effect

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11166153A (en) * 1997-12-02 1999-06-22 Shinto Paint Co Ltd Normal temperature-curable two-component aqueous epoxy resin coating composition
CN1752163A (en) * 2005-10-20 2006-03-29 同济大学 A kind of aqueous epoxide resin paint and preparation method thereof
CN103214655A (en) * 2013-03-27 2013-07-24 杭州日耀科技有限公司 Modified epoxy resin and high-solid anticorrosive coating prepared therewith
CN103242740A (en) * 2013-05-23 2013-08-14 苏州富通高新材料科技股份有限公司 Flame-retardant coating for wood floors
CN103342935A (en) * 2013-06-27 2013-10-09 虞城县非凡涂料有限公司 Epoxy modified water-soluble tape coating and preparation method thereof
CN103865350A (en) * 2014-03-19 2014-06-18 湖州百胜涂料有限公司 Waterproof coating for outer wall

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11166153A (en) * 1997-12-02 1999-06-22 Shinto Paint Co Ltd Normal temperature-curable two-component aqueous epoxy resin coating composition
CN1752163A (en) * 2005-10-20 2006-03-29 同济大学 A kind of aqueous epoxide resin paint and preparation method thereof
CN103214655A (en) * 2013-03-27 2013-07-24 杭州日耀科技有限公司 Modified epoxy resin and high-solid anticorrosive coating prepared therewith
CN103242740A (en) * 2013-05-23 2013-08-14 苏州富通高新材料科技股份有限公司 Flame-retardant coating for wood floors
CN103342935A (en) * 2013-06-27 2013-10-09 虞城县非凡涂料有限公司 Epoxy modified water-soluble tape coating and preparation method thereof
CN103865350A (en) * 2014-03-19 2014-06-18 湖州百胜涂料有限公司 Waterproof coating for outer wall

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Title
徐伟箭等: "新型含氮阻燃环氧树脂的合成与性能", 《湖南大学学报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105255282A (en) * 2015-10-28 2016-01-20 自贡市华尔美科技有限公司 Flame-retardant waterproof coating for house decoration
CN109895484A (en) * 2019-02-18 2019-06-18 滁州卷烟材料厂 A kind of water proof fire retardant corrugated case
CN117070130A (en) * 2023-08-16 2023-11-17 黄山天马新材料科技有限公司 Preparation method of epoxy resin-based powder coating with texture effect
CN117070130B (en) * 2023-08-16 2025-04-15 黄山天马新材料科技有限公司 A method for preparing epoxy resin-based powder coating with texture effect

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Address after: 050000 Hebei Province, Shijiazhuang city Gaocheng District Yang Macun Airport Road East

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