CN1045104C - Commonly-used internal combustion engine oil composition - Google Patents
Commonly-used internal combustion engine oil composition Download PDFInfo
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- CN1045104C CN1045104C CN96109061A CN96109061A CN1045104C CN 1045104 C CN1045104 C CN 1045104C CN 96109061 A CN96109061 A CN 96109061A CN 96109061 A CN96109061 A CN 96109061A CN 1045104 C CN1045104 C CN 1045104C
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Abstract
The present invention relates to a universal internal combustion engine oil composition. The composition is characterized in that the composition contains a proper amount of dinonyl dianiline; the performance of high temperature oxidation is improved, and particularly, the problem that engine oil becomes thick at a high temperature in an IIID engine test is favorably solved. The composition also contains a proper quantity of esters as an ashless additive, sulfonate, sulfurized calcium alkyl phenate, polyisobutene butyl diimide and zinc dialkyldithiophosphate; therefore, when the composition improves the antioxygenic property, the properties comprising the high temperature detergent property, the dispersivity, etc. are improved. The composition has the advantages of simple formula, convenient preparation and low cost.
Description
The present invention relates to a kind of commonly-used internal combustion engine oil composition, especially a kind ofly can satisfy the lubricating oil compositions that medium-to-high grade vehicle vapour bavin is general, the summer in winter is general such as the car that uses in most of area and high-power supercharged diesel car.And performance with excellent especially inhibition oil product high temperature retrogradation.
As everyone knows, a kind of internal combustion (IC) engine oil composition is provided, make engine avoid causing accident such as can't run well because of machine oil retrogradation, serious wear, piston deposit too much are directed at sticking ring etc., and prolong engine work-ing life simultaneously, reducing maintenance cost is to improve a big task of oil product.
U.S. Pat 3243370 relates to a kind of internal combustion (IC) engine oil composition that can improve performances such as extreme pressure, wear-resistant, antioxygen.The feature of said composition is the material that contains following structure:
N=0-2 wherein, m=0-100; Y contains the functional group of one of array structure down :=P-, ≡ P=, ≡ P=S; R and R contain the functional group of array structure down: alkyl, halo alkyl, oxygen-containing hydrocarbon base, sulfur-bearing alkyl, sulfur-bearing halo alkyl; R and R " are to contain the down group of array structure: alkyl, haloalkyl, aryl, halogenated aryl, contain oxyalkyl, contain the oxygen haloalkyl; Z contains the down group of array structure: hydrogen and alkyl, and it is a unsaturated hydrocarbon radical, contains 1-17 carbon atom when n=2, contains 1-10 carbon atom when n＜2; Z ' contains the group of array structure down: saturated hydrocarbyl, and when Z was the alkyl of 1-2 carbon atom, Z ' was a methyl, Z and Z ' are combined on the ring of hexanaphthene together by carbon atom when n=2.
Chinese patent CN 87 1 00331 A relate to a kind of internal combustion (IC) engine oil composition that contains transition metal that is used to control viscosity.Be characterised in that the oil soluble that used a kind of trace or the metal composites of oil-dispersing property in the said composition, its consumption is to be enough to block the speed that is caused by cigarette ash, its viscosity increases when oil is used for diesel engine, and metallide wherein contains a kind of metal that is selected from manganese, titanium, cobalt, chromium, vanadium, nickel, tungsten, copper and composition thereof.This patent has used aniline, phenylenediamine, thiazine, aniline-beta-naphthylamine, amino dodecane etc. as " promotor " of sneaking into excess metal.
Chinese patent CN 85 1 01591 A relate to and a kind ofly concoct the IC engine oil additive component that forms by a certain percentage by alkyl sodium salicylate, polyisobutene sulphur barium phosphate, polyisobutene succinimide and four kinds of additives of zinc dialkyl dithiophosphate.This component adds in the mineral oil of deep refining by a certain percentage can produce gasoline engine oil and pressurized diesel engine oil, but can not modulate the multi-grade oil that meets international norm.
As seen, the internal combustion (IC) engine oil composition of prior art, its high temperature oxidation resistance is dissatisfactory.And prescription is complicated, the inconvenience modulation.
Purpose of the present invention be intended to overcome the deficiencies in the prior art and provide a kind of high temperature oxidation resistance good, suppress the strong commonly-used internal combustion engine oil composition of high temperature retrogradation ability.
The object of the present invention is achieved like this: add an amount of dinonyldiphenylamine in base oil, can improve high-temperature oxidation resistance, strengthen the ability that suppresses the high temperature retrogradation.
What said base oil was a viscosity index at the paraffin base mineral oil of 80-100 and an amount of pour point depressant, kilfoam, viscosity index improver is compound.
The structure of dinonyldiphenylamine used in the present invention is:
It is the product by the reaction of pentanoic and nonene, wherein 4,4 '-content of dinonyldiphenylamine is not less than 70%.
Add the dinonyldiphenylamine of different amounts in HVI 200 base oils, the data that obtain are as shown in table 1.As seen the high-temperature oxidation resistance of the add-on of dinonyldiphenylamine and internal combustion (IC) engine oil composition has definite relation.Oxidation induction period is long more, shows that the oil oxidation performance is good more, and the ability that suppresses the retrogradation of oil product high temperature is strong more.
Table 1
| Comparative example | Embodiment | ||
| Component (m%) | Dinonyldiphenylamine HVI 200 | 0 100 | 0.10 0.25 0.50 1.0 1.5 2.0 surplus surplus surplus surplus surplus surplus |
| Test-results | Oxidation induction period (SH/T0913 method), min | 72 | 142 220 268 286 290 296 |
Dinonyldiphenylamine is a Lanzhou oil-refining chemical head factory product, and its add-on is the 0.1-2.0m% of internal combustion (IC) engine oil composition, the surplus base oil.
After adding dinonyldiphenylamine oxidation inhibitor, the oxide thin layer of oil product is significantly increased inductive phase, thereby satisfied of the requirement of III D testing of engine the high temperature oxidation polishing machine.
Further purpose of the present invention is when continuing raising high temperature oxidation polishing machine, to improve performances such as high temperature detergency, dispersiveness, provides a kind of and can satisfy the commonly-used internal combustion engine oil composition that diesel motor can satisfy the lubricated needs of petrol engine again.For this reason, in base oil, add following an amount of additive:
(A) dinonyldiphenylamine;
(B) the ester class is ashless;
(C) sulfonate;
(D) calcium sulfenyl phenolate;
(E) polyisobutene succinimide;
(F) zinc dialkyl dithiophosphate.
The high temperature oxidation polishing machine of the add-on of dinonyldiphenylamine and commonly-used internal combustion engine oil composition has definite relation; The adding that the ester class is ashless not only makes the dispersiveness of said composition improve, and the high-temperature behavior of said composition also is further improved; The adding of sulfonate and calcium sulfenyl phenolate is to have enough detergency, alkali retentivity and certain rustless property in order to ensure composition; The adding of polyisobutene succinimide is to have enough antioxygens, anticorrosive and abrasion resistance in order to ensure composition.
Zinc dialkyl dithiophosphate in the composition is the carrying out that stops oxidation by its degradation production, dinonyldiphenylamine then be with oxidation reaction process in the chain carrier reaction of transfer chain, make it become the torpescence material, play the effect that stops oxidizing reaction.Therefore dinonyldiphenylamine cooperatively interacts with the different mechanism of action with zinc dialkyl dithiophosphate and has stoped the high temperature oxidation of lubricating oil jointly, has given the high-temperature oxidation resistance of composition excellence.
The ester class that the present invention uses is ashless to be the mixture that polyisobutene dicarboxylic anhydride and tetramethylolmethane reaction generate.The structure of primary product is as follows:
The I dibasic acid esters
II half ester (acid ester)
The III cyclic ester
The IV polyester
Wherein R-is a polyisobutene, and number-average molecular weight is between 800-1200.This material of this structures shape not only gives composition certain dispersing property, and has guaranteed that said composition has excellent high-temperature behavior, thereby makes said composition both satisfy the use properties of diesel engine oil, and the while has been satisfied the use properties of gasoline engine oil again.
In the sufficient oil product of preparation, the consumption such as the table 2 of these binder components (A), (B), (C), (D), (E), (F) and pour point depressant, viscosity index improver, kilfoam.
Table 2
| Component | Optional value m% | Optimum value m% |
| (A) dinonyldiphenylamine (B) ester class ashless (C) sulfonate (D) calcium sulfenyl phenolate (E) polyisobutene succinimide (F) zinc dialkyl dithiophosphate pour-point depressant viscosity index improver anti-foaming agent paraffin base mineral oil | 0.1-2.0 0.3-1.5 2.0-6.0 0.5-2.0 1.0-3.0 1.0-1.5 0.01-5.0 4-20 0.001-0.1 surplus | 0.1-1.5 0.3-1.5 2.0-4.5 0.5-1.5 1.0-3.0 1.0-1.5 0.1-1.0 6-15 0.001-0.002 surplus |
Above-mentioned each component was fully stirred 4 hours under 85 ± 5 ℃ of conditions; Can obtain the general service oil of the different viscosity trade mark.
The ratio of various additives is determined by heat pipe oxidation test, the test of board-like coking device, oxide thin layer test (TFOUT), four ball oxidative wear tests etc. in the composition among the present invention.The actual applying working condition of lubricating oil has been simulated in these tests effectively.
Adopt technical scheme of the present invention, it is good to modulate high-temperature oxidation resistance, and it is strong to suppress high temperature retrogradation ability, improved petrol engine of performances such as high temperature detergency, dispersiveness and the general internal combustion (IC) engine oil composition of diesel motor; Not only single-stage oil can be modulated, and multi-grade oil can be modulated; Other desirable performance and effect of adding lubricating oil after the dinonyldiphenylamine, for example suitability, resistance to abrasion, rust-preventing characteristic, high temperatrue stability etc. are not therefore and impaired; Prescription is simple, and modulation is convenient, and cost is lower.
Below in conjunction with embodiment technical scheme of the present invention and effect thereof are done further statement.
Embodiment 1
Prepare a total composition 10W/30SF/CD general service oil, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 3.
Table 3
Annotating (1) is Lanzhou oil-refining chemical head factory product.(2) be that Lanzhou oil-refining chemical head factory product ester class is ashless, hydroxyl valency 1.71%, cl content 0.20%.(3 are ETHYL company product calcium alkylbenzenesulfonate.(4) be Lanzhou oil-refining chemical head factory product, calcium contents 8.9%, total basicnumber 256mg KOH/g.(5) be that Lanzhou oil-refining chemical head factory produces LAN152A, total nitrogen content 1.64%.(6) be that Lanzhou oil-refining chemical head factory produces zinc dialkyl dithiophosphate, zinc content 8.7%, phosphorus content 7.18%, pH value 5.2.
| Comparative example | Embodiment | Test method | ||
| Component (m%) | Dinonyldiphenylamine (1) ester class is ashless (2) sulfonate (3) calcium sulfenyl phenolate (4) polyisobutene succinimide (5) zinc dialkyl dithiophosphate (6) base oil | 0 0.7 2.8 1.2 2.1 1.4 surpluses | 0.5 0.7 2.8 1.2 2.1 1.2 surpluses | |
| The oil viscosity trade mark of transferring | 10W/30SF/CD | 10W/30SF/CD | ||
| Test-results | Oxide thin layer test (TFOUT), min | 144 | 195 | SH/T0074 |
| Detergency test (heat pipe oxidation test method), grading | 1.5 | 1.0 | Q/LZJS.2002 | |
| Low temperature dispersity test (SDT) | 86.0 | 84.8 | Q/LZJ.0011 | |
Embodiment 2
Prepare a total composition 15W/40SF/CD general service oil, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 4.
Table 4
| Embodiment | Test method | ||
| Component (m%) | Dinonyldiphenylamine ester class ashless sulfonate calcium sulfenyl phenolate polyisobutene succinimide zinc dialkyl dithiophosphate | 0.5 0.7 2.8 1.2 2.1 1.2 | |
| The oil viscosity trade mark of transferring | 15W/40SF/CD | ||
| Test-results | Oxide thin layer test (TFOUT), min | 220 | SH/T0074 |
| Detergency test (heat pipe oxidation test method), grading | 1.0 | Q/LZJS.2002 | |
| Low temperature dispersity test (SDT) | - | Q/LZJ.0011 | |
| Testing of engine 1135D 2Total weighted scoring apical ring groove carbon-filling rate, v% Lay Buick L-38 bearing shell weightlessness, mg piston ring skirt section paint film scoring | 298.8 40.0 38.3 ＞9.0 | SH/T0265 | |
Embodiment 3
Prepare a total composition 10W/30SF/CD general service oil, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 5.
Table 5
| Comparative example 1 | Comparative example 2 | Embodiment | Test method | ||
| Component (m%) | Dinonyldiphenylamine ester class ashless sulfonate calcium sulfenyl phenolate polyisobutene succinimide zinc dialkyl dithiophosphate base oil | 0 0.7 3.1 1.2 2.1 1.4 surpluses | 0 0.7 3.2 1.3 2.1 1.2 surpluses | 0.5 0.7 3.1 1.2 2.1 1.2 surpluses | |
| Test-results | Oxide thin layer test (TFOUT), min | 144 | 153 | 194 | SH/T0074 |
| Low temperature dispersity test (SDT) | 86.0 | 76.6 | 84.8 | Q/LZJ.0011 |
Embodiment 4
Use the hydrogenated base oil HVI 125 preparations one total composition 10W/30SF/CD general service oil that Lanzhou oil-refining chemical head factory is produced, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 6.
Table 6
| Embodiment | Test method | ||
| Component (m%) | Dinonyldiphenylamine ester class ashless sulfonate calcium sulfenyl phenolate polyisobutene succinimide zinc dialkyl dithiophosphate base oil | 0.3 0.3 2.0 2.0 2.9 1.0 surpluses | |
| The oil viscosity trade mark of transferring | 10W/30SF/CD | ||
| Test-results | Oxide thin layer test (TFOUT), min | 170 | SH/T0074 |
| Detergency test (heat pipe oxidation test method), grading | 1.5 | Q/LZJS.2002 | |
| Low temperature dispersity test (SDT) | 75.0 | Q/LZJ.0011 | |
| Testing of engine 1135D 2Total weighted scoring apical ring groove carbon-filling rate, v% Lay Buick L-38 bearing shell weightlessness, mg skirt of piston paint film scoring | 249.51 40 5.6 9.5 | SH/T0261 SH/T0265 | |
Embodiment 5
Prepare a total composition general service oil, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 7.
Table 7
| Embodiment | Comparative example | Test method | ||
| Component (m%) | Dinonyldiphenylamine ester class ashless sulfonate calcium sulfenyl phenolate polyisobutene succinimide zinc dialkyl dithiophosphate base oil | 1.0 1.5 6.0 0.5 3.0 1.5 surpluses | Add the Lubrizol LZ8880B of company recombiner 14.0m% surplus | |
| Test-results | Oxide thin layer test (TFOUT), min | ＞300 | 140 | SH/T0074 |
| Detergency test (heat pipe oxidation test method), grading | 0.5 | 2.5 | Q/LZJS.2002 | |
| Low temperature dispersity test (SDT), % | 75.2 | 75.0 | Q/LZJ.0011 | |
| Last non seizure load (four ball method PB values), N | 1029.0 | 882.0 | GB/T3142 |
Embodiment 6
Prepare a total composition general service oil, it contains dinonyldiphenylamine, the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.The data that obtain are thus listed in table 8.
Table 8
| Embodiment | Comparative example | Test method | ||
| Component (m%) | Dinonyldiphenylamine ester class ashless sulfonate calcium sulfenyl phenolate polyisobutene succinimide zinc dialkyl dithiophosphate base oil | 0.3 1.5 3.0 1.5 1.0 1.5 surpluses | Add the Lubrizol LZ8888 of company recombiner 11.2m% surplus | |
| Test-results | Oxide thin layer test (TFOUT), min | 190 | 95 | SH/T0074 |
| Detergency test (heat pipe oxidation test method), grading | 2.5 | 2.5 | Q/LZJS.2002 | |
| Low temperature dispersity test (SDT), % | 75.2 | 70.3 | Q/LZJ.0011 |
Claims (7)
1. a commonly-used internal combustion engine oil composition comprises base oil, it is characterized in that said composition contains dinonyldiphenylamine, and its structure is:
2. by the described commonly-used internal combustion engine oil composition of claim 1, it is characterized in that said dinonyldiphenylamine consumption is 0.1-2.0m%, the surplus base oil.
3. by claim 1 or 2 described commonly-used internal combustion engine oil compositions, it is characterized in that in the said dinonyldiphenylamine that 4,4 ＇-dinonyldiphenylamine content is not less than 70%.
4. by the described commonly-used internal combustion engine oil composition of claim 1, it is characterized in that said composition contains also that the ester class is ashless, sulfonate, calcium sulfenyl phenolate, polyisobutene succinimide, zinc dialkyl dithiophosphate.
5. by the described commonly-used internal combustion engine oil composition of claim 4, it is characterized in that dinonyldiphenylamine accounts for 0.1-2.0% in the said composition, the ester class is ashless to account for 0.3-1.5m%, and sulfonate accounts for 2.0-6.0m%, and calcium sulfenyl phenolate accounts for 0.5-2.0m%, polyisobutene succinimide accounts for 1.0-3.0m%, zinc dialkyl dithiophosphate accounts for 1.0-1.5m%, and pour point depressant accounts for 0.01-5.0m%, and viscosity index improver accounts for 4-20m%, kilfoam accounts for 0.001-0.1m%, the surplus paraffin base mineral oil.
6. by the described commonly-used internal combustion engine oil composition of claim 4, it is characterized in that dinonyldiphenylamine accounts for 0.1-1.5% in the said composition, the ester class is ashless to account for 0.3-1.5m%, and sulfonate accounts for 2.0-4.5m%, and calcium sulfenyl phenolate accounts for 0.5-1.5m%, polyisobutene succinimide accounts for 1.0-3.0m%, zinc dialkyl dithiophosphate accounts for 1.0-1.5m%, and pour point depressant accounts for 0.1-1.0m%, and viscosity index improver accounts for 6-15m%, kilfoam accounts for 0.001-0.002m%, the surplus paraffin base mineral oil.
7. by claim 4,5 or 6 described commonly-used internal combustion engine oil compositions, it is characterized in that each component was fully stirred 4 hours down at 85 ± 5 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96109061A CN1045104C (en) | 1996-08-20 | 1996-08-20 | Commonly-used internal combustion engine oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96109061A CN1045104C (en) | 1996-08-20 | 1996-08-20 | Commonly-used internal combustion engine oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1174228A CN1174228A (en) | 1998-02-25 |
| CN1045104C true CN1045104C (en) | 1999-09-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96109061A Expired - Lifetime CN1045104C (en) | 1996-08-20 | 1996-08-20 | Commonly-used internal combustion engine oil composition |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1108361C (en) * | 1999-03-30 | 2003-05-14 | 恒运集团石油股份有限公司 | Antioxidative compositte of lubricating oil and its application in lubricating oil of internal combustion engine |
| CN105647627B (en) * | 2016-02-23 | 2018-06-01 | 北京雅士科莱恩石油化工有限公司 | Gasoline engine oil of multiple wear-resistant protection a kind of of long-life and preparation method thereof |
| CN108517245A (en) * | 2018-05-15 | 2018-09-11 | 郭健 | Lubricating oil and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0384720A1 (en) * | 1989-02-23 | 1990-08-29 | Exxon Chemical Patents Inc. | Crankcase lubricating oil compositions and additives for use therein |
| CA2105132A1 (en) * | 1992-09-28 | 1994-03-29 | John W. Frankenfeld | Substituted 1, 2, 4-triazole containing lubricants having improved oxidation stability |
| WO1995027022A1 (en) * | 1994-03-31 | 1995-10-12 | Exxon Research & Engineering Company | Lubrication oil composition |
-
1996
- 1996-08-20 CN CN96109061A patent/CN1045104C/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0384720A1 (en) * | 1989-02-23 | 1990-08-29 | Exxon Chemical Patents Inc. | Crankcase lubricating oil compositions and additives for use therein |
| CA2105132A1 (en) * | 1992-09-28 | 1994-03-29 | John W. Frankenfeld | Substituted 1, 2, 4-triazole containing lubricants having improved oxidation stability |
| WO1995027022A1 (en) * | 1994-03-31 | 1995-10-12 | Exxon Research & Engineering Company | Lubrication oil composition |
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|---|---|
| CN1174228A (en) | 1998-02-25 |
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