CN104497600A - Environment-friendly preparation process of warm-mix asphalt cement material - Google Patents
Environment-friendly preparation process of warm-mix asphalt cement material Download PDFInfo
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- CN104497600A CN104497600A CN201410831579.6A CN201410831579A CN104497600A CN 104497600 A CN104497600 A CN 104497600A CN 201410831579 A CN201410831579 A CN 201410831579A CN 104497600 A CN104497600 A CN 104497600A
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- environment
- preparation process
- asphalt cement
- warm
- friendly preparation
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- 239000004568 cement Substances 0.000 title claims abstract description 51
- 239000010426 asphalt Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 title claims abstract description 23
- 239000004033 plastic Substances 0.000 claims abstract description 30
- 229920003023 plastic Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001971 elastomer Polymers 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 235000019830 sodium polyphosphate Nutrition 0.000 claims abstract description 16
- 238000002844 melting Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000012423 maintenance Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000002309 gasification Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000206 moulding compound Substances 0.000 description 3
- 239000011295 pitch Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011339 hard pitch Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002209 Crumb rubber Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/30—Adapting or protecting infrastructure or their operation in transportation, e.g. on roads, waterways or railways
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
The invention discloses an environment-friendly preparation process of a warm-mix asphalt cement material. By adopting the technical formula (w/%), the environment-friendly preparation process comprises the following components: 80%-90% of an asphalt cement material, 2%-18% of a recycled material, 0.5%-5% of sodium polyphosphate and 0.05%-2% of water. The warm-mix asphalt cement material prepared by the preparation process still keeps good liquidity at a relatively low temperature due to the action of a sodium polyphosphate water solution, thus the stirring, paving and storing temperatures of the asphalt cement material are lowered. By introducing a proper amount of water, the viscosity of the asphalt is effectively reduced; meanwhile, gasification and volatilization of organic matters are reduced; the safety of the environment and a human body is protected; recycled plastic and recycled rubber are effectively utilized, so that the problem of plastic pollution is greatly solved; the warm-mix asphalt cement material prepared by the environment-friendly preparation process is stable in property, safe and environment-friendly; and the preparation process is simple and easy to control.
Description
Technical field
The present invention relates to a kind of Warm mixed asphalt cement, particularly a kind of environment-friendly preparation process of Warm mixed asphalt cement, belongs to petrochemical industry.
Background technology
Bituminous pavement, as a kind of continuous pavement, has damping, an advantage such as comfortable, the easy-maintaining of driving a vehicle, and is the major way that high class pavement adopts.Along with the quickening of industrialization, urbanization process, there is great demand to the usage quantity of bituminous cements.Generally use the hard pitch higher than 200 DEG C directly to carry out cooling forming through sieve plate distributor in existing refining of petroleum industry, but there is mixing, transport and in the process that paves, occur thermal ageing, toxic gaseous emission and too much energy consumption problem in hard pitch.Along with the cry of global energy-saving and emission-reduction is surging, scientific workers have made a large amount of effort in the temperature reducing mixing bituminous cements and environmental protection, environmentally friendly Warm-Mix Bitumen Mixture is come out one after another with kinds of processes form, and gets up in ground widespread uses such as Europe, North America, South Africa, East Asia.
" Warm mixed asphalt cement and preparation method thereof " disclosed in CN 201010609465, adds rheological modifiers and high molecular polymer and carries out hybrid reaction and obtain in bituminous cements; " a kind of Warm-Mix Bitumen Mixture and preparation method thereof " disclosed in CN 101302348A adopts Sasobit warm-mixed asphalt additive to carry out warm mix, adopt cracking polyethylene wax and stearic acid as smoke inhibition modifying agent in CN 101649122 disclosed " a kind of SBS modifying asphalt and preparation method thereof ", modification is carried out to SBS modifying asphalt agglutinate, in WO2009137299A2 disclosed " resin modified bituminous cements component ", in bituminous cements, add the resin of 0.01wt% ~ 25wt%.Above-mentioned patent documentation all solves cooling viscosity reduction problem when asphalt mixes and stirs, and improves construction workability, strengthens compactness.In addition in US 006846354B2 disclosed " technique of production warm mix plate form rubber composition and system ", appropriate moisture is introduced in bituminous cements, make pitch by foaming viscosity reduction, realize the warm mix of asphalt preferably, reach the object of energy-saving and emission-reduction.
Plastics are widely used in packaging, furniture, plastic film for agricultural use, Industrial materials because it has good shaping, the feature such as insulativity, acid and alkali-resistance, erosion resistance by people.But increase along with plastics output, price reduces, and renewal frequency is accelerated, and makes plastic products also increasing to the pollution of environment, " white pollution " that waste plastic brings, and having become one today can not unheeded social effects of pollution again.China is one of ten large plastics production and consumption states in the world, the recycling of plastic products in recent years also result in the great attention of country and society, greatly develop plastics recycling industry and not only slow down environmental pollution, facilitate again the fast development of plastic industry.
Current, for the rare report of research and development recycled plastic is applied in bituminous cements.
We study by experiment, by recycled plastic or rubber applications in bituminous cements, develop a kind of environment-friendly preparation process of Warm mixed asphalt cement.
Summary of the invention
Goal of the invention: for the problems of the prior art, a large amount of plastics that the present invention reclaims in being intended to utilize life to produce or rubber item, provide a kind of production technique simple, the environment-friendly preparation process of the Warm mixed asphalt cement that product property is stable.
For achieving the above object, the present invention by the following technical solutions: a kind of environment-friendly preparation process of Warm mixed asphalt cement, comprises the steps:
A, weigh each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the reclaimed materials of weighing to be pulverized; D, the crushed material of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour; The ratio of described each raw material following (
w/ %):
Bituminous cements 80 ~ 90
Reclaimed materials 2 ~ 18
Sodium polyphosphate 0.5 ~ 5
Water 0.05 ~ 2.
As preferably, described bituminous cements is reason pitch or the polymer modified asphalt of each class requirement in satisfied " standard specification for construction and acceptance of highway asphalt pavement " (JTG F40-2004).
As preferably, described reclaimed materials is a kind of in plastics, rubber or both mixtures.
As preferably, described plastics are homogeneous plastic or heterogeneous plastics.
As preferably, described rubber is homogeneity rubber or heterogeneous rubber.
The environment-friendly preparation process of a kind of Warm mixed asphalt cement provided by the invention, compared to existing technology, there is following beneficial effect: the Warm mixed asphalt cement prepared by the present invention is due to the effect of polyphosphoric acid sodium water solution, still good mobility is kept at a lower temperature, thus reduce bituminous cements stirring, pave storing temp; Introduce appropriate water in the present invention, while making the effective viscosity reduction of pitch, reduce organic gasification volatilization, protection of the environment and human-body safety; Effective utilization of recycled plastic and recovery rubber, very big limit solves white pollution problems; The made Warm mixed asphalt cement stable in properties of the present invention, safety and environmental protection, production technique is simple and easy to control.
Specific embodiment
By the following examples the present invention is further explained:
Embodiment 1
Formula A (
w/ %):
Bituminous cements 80
Recycled plastic 15
Sodium polyphosphate 3.5
Water 1.5
An environment-friendly preparation process for Warm mixed asphalt cement, comprises the steps: A, weighs each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the recycled plastic of weighing to be pulverized; D, the synthetic resin moulding compound particle of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour.
Embodiment 2
Formula B (
w/ %):
Bituminous cements 85
Recycled plastic 12
Sodium polyphosphate 2.5
Water 0.5
An environment-friendly preparation process for Warm mixed asphalt cement, comprises the steps: A, weighs each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the recycled plastic of weighing to be pulverized; D, the synthetic resin moulding compound particle of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour.
Embodiment 3
Formula C (
w/ %):
Bituminous cements 90
Recycled plastic 7.5
Sodium polyphosphate 2
Water 0.5
An environment-friendly preparation process for Warm mixed asphalt cement, comprises the steps: A, weighs each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the recycled plastic of weighing to be pulverized; D, the synthetic resin moulding compound particle of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour.
Embodiment 4
Formula D (
w/ %):
Bituminous cements 85
Reclaim rubber 10
Sodium polyphosphate 4
Water 1
An environment-friendly preparation process for Warm mixed asphalt cement, comprises the steps: A, weighs each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the recovery rubber of weighing to be pulverized; D, the rubber powder particle of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour.
Embodiment 5
Formula E (
w/ %):
Bituminous cements 85
Recycled plastic and rubber 11
Sodium polyphosphate 3
Water 1
An environment-friendly preparation process for Warm mixed asphalt cement, comprises the steps: A, weighs each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the recycled plastic of weighing and rubber to be pulverized; D, the crushed material of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. an environment-friendly preparation process for Warm mixed asphalt cement, is characterized in that comprising the steps:
A, weigh each material component by proportioning; B, by bituminous cements heating raw materials to 130 ~ 160 DEG C, make its progressively softening melting; C, the reclaimed materials of weighing to be pulverized; D, the crushed material of step C is added in the molten mass of step B, be stirred to evenly; E, maintenance temperature 130 ~ 160 DEG C, add sodium polyphosphate and water, shear, stir, be slowly warming up to 140 ~ 175 DEG C in the melting mixing body of step D gained, continues stirring reaction and take the dish out of the pot for 0.5 ~ 2 hour; The ratio of described each raw material following (
w/ %):
Bituminous cements 80 ~ 90
Reclaimed materials 2 ~ 18
Sodium polyphosphate 0.5 ~ 5
Water 0.05 ~ 2.
2. the environment-friendly preparation process of a kind of Warm mixed asphalt cement as claimed in claim 1, it is characterized in that, described bituminous cements is reason pitch or the polymer modified asphalt of each class requirement in satisfied " standard specification for construction and acceptance of highway asphalt pavement " (JTG F40-2004).
3. the environment-friendly preparation process of a kind of Warm mixed asphalt cement as claimed in claim 1, is characterized in that, described reclaimed materials is a kind of in plastics, rubber or both mixtures.
4. the environment-friendly preparation process of a kind of Warm mixed asphalt cement as claimed in claim 3, it is characterized in that, described plastics are homogeneous plastic or heterogeneous plastics.
5. the environment-friendly preparation process of a kind of Warm mixed asphalt cement as claimed in claim 3, it is characterized in that, described rubber is homogeneity rubber or heterogeneous rubber.
Priority Applications (1)
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CN201410831579.6A CN104497600A (en) | 2014-12-29 | 2014-12-29 | Environment-friendly preparation process of warm-mix asphalt cement material |
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CN201410831579.6A CN104497600A (en) | 2014-12-29 | 2014-12-29 | Environment-friendly preparation process of warm-mix asphalt cement material |
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Publication Number | Publication Date |
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CN104497600A true CN104497600A (en) | 2015-04-08 |
Family
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---|---|---|---|
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE68900035D1 (en) * | 1988-06-27 | 1991-03-14 | Asphalt Materials Inc | MULTI-GRADE ASPHALT CEMENT PRODUCT AND METHOD FOR PRODUCTION. |
CN101265363A (en) * | 2007-11-29 | 2008-09-17 | 陕西长大博源公路养护科技有限公司 | Waste and old rubber powder modifying asphalt and preparation method thereof |
CN102234432A (en) * | 2010-04-28 | 2011-11-09 | 上海益泰能源科技有限公司 | Anti-stripping warm mix asphalt additive agent comprising surfactant, its preparation method and application |
CN102702600A (en) * | 2012-06-04 | 2012-10-03 | 深圳市科中大高分子材料研究所 | Environment-friendly asphalt pavement anti-rut agent and preparation method thereof |
-
2014
- 2014-12-29 CN CN201410831579.6A patent/CN104497600A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE68900035D1 (en) * | 1988-06-27 | 1991-03-14 | Asphalt Materials Inc | MULTI-GRADE ASPHALT CEMENT PRODUCT AND METHOD FOR PRODUCTION. |
CN101265363A (en) * | 2007-11-29 | 2008-09-17 | 陕西长大博源公路养护科技有限公司 | Waste and old rubber powder modifying asphalt and preparation method thereof |
CN102234432A (en) * | 2010-04-28 | 2011-11-09 | 上海益泰能源科技有限公司 | Anti-stripping warm mix asphalt additive agent comprising surfactant, its preparation method and application |
CN102702600A (en) * | 2012-06-04 | 2012-10-03 | 深圳市科中大高分子材料研究所 | Environment-friendly asphalt pavement anti-rut agent and preparation method thereof |
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