CN104497520A - Composite material used for cellphone shells - Google Patents
Composite material used for cellphone shells Download PDFInfo
- Publication number
- CN104497520A CN104497520A CN201410690181.5A CN201410690181A CN104497520A CN 104497520 A CN104497520 A CN 104497520A CN 201410690181 A CN201410690181 A CN 201410690181A CN 104497520 A CN104497520 A CN 104497520A
- Authority
- CN
- China
- Prior art keywords
- matrix material
- phone housing
- housing according
- parts
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title abstract 4
- 238000005336 cracking Methods 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 6
- 239000011159 matrix material Substances 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 230000002180 anti-stress Effects 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 3
- HIVGXUNKSAJJDN-UHFFFAOYSA-N [Si].[P] Chemical compound [Si].[P] HIVGXUNKSAJJDN-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229920001112 grafted polyolefin Polymers 0.000 claims description 3
- 239000012796 inorganic flame retardant Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 abstract description 9
- 229920000515 polycarbonate Polymers 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A disclosed composite material used for cellphone shells comprises the following compositions in parts by weight: 55-70 parts of PC (polycarbonate), 5-15 parts of ABS, 1-10 parts of a stress-cracking-resistant agent, 1-5 parts of a flexibilizer, 0.1-0.5 part of an anti-oxidant, 2-15 parts of a fire retardant, and 0.1-0.5 part of a toner. On the basis of not large change on mechanical properties of PC, the impact strength of the composite material is improved, the application field is expanded, and the application cost of the composite material is reduced.
Description
Technical field
The present invention relates to a kind of matrix material for phone housing, belong to technical field of polymer materials.
Background technology
PC (polycarbonate) has excellent shock resistance, creep resistance, dimensional stability and electric insulating quality, a kind of engineering plastics of superior performance, be widely used in the fields such as mechanical means, electronic product, automobile making, but also there is poor fluidity, easily stress cracking, the easily aging and shortcoming such as to wear no resistance, its application is in a lot of fields restricted.But, the shell of existing electronic product through be everlasting maintenance dismounting time fracture, be obviously that meanwhile, cost is relatively high because its shock strength index can not meet its needs as electronic product casing.
Summary of the invention
For solving the deficiencies in the prior art, the object of the invention is to the defect overcoming prior art, a kind of impact-resistant matrix material for phone housing is provided.
In order to realize above-mentioned target, the present invention adopts following technical scheme: a kind of matrix material for phone housing, is characterized in that, comprises following component and the parts by weight of each component are:
PC 55-70 part;
ABS 5-15 part;
Anti-stress cracking agent 1-10 part;
Toughner 1-5 part;
Oxidation inhibitor 0.1-0.5 part;
Fire retardant 2-15 part;
Toner 0.1-0.5 part.
Aforesaid a kind of matrix material for phone housing, is characterized in that, described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
Aforesaid a kind of matrix material for phone housing, is characterized in that, described PC is aromatic copolycarbonate.
Aforesaid a kind of matrix material for phone housing, is characterized in that, described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
Aforesaid a kind of matrix material for phone housing, is characterized in that, described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
Aforesaid a kind of matrix material for phone housing, is characterized in that, described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
Beneficial effect of the present invention is: the present invention is changing on little basis the mechanical property of PC, improves its shock strength, expands Application Areas, and reduces its application cost.
embodiment:
Below in conjunction with specific embodiment, the present invention is described further.
The proportioning of each component of table 1 embodiment 1-4 and comparative example
Wherein, described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
Described PC is aromatic copolycarbonate.
Described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
Described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
Described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
The performance test results of each embodiment of table 2 and comparative example
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example | |
| Tensile strength (Mpa) | 58 | 59 | 65 | 60 | 50 |
| Elongation at break (%) | 47 | 42 | 45 | 49 | 39 |
| Flexural strength (Mpa) | 97 | 94 | 95 | 99 | 81 |
| Modulus in flexure (Mpa) | 2655 | 2580 | 2601 | 2549 | 2501 |
| Notched Izod impact strength (kJ/m 2) | 34 | 35 | 38 | 39 | 20 |
Note: reference standard is: GB13525/T-92 and UL94.
As can be seen from Table 2, from notched Izod impact strength, the notched Izod impact strength of embodiment 1-4 is relatively better.For other indexs, embodiment 1-4 also has advantage, and associative list 1 can draw, due to adding of anti-stress cracking agent, its notched Izod impact strength be improved significantly.
More than show and describe ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, and all drops in protection scope of the present invention.
Claims (6)
1. for a matrix material for phone housing, it is characterized in that, comprise following component and the parts by weight of each component are:
PC 55-70 part;
ABS 5-15 part;
Anti-stress cracking agent 1-10 part;
Toughner 1-5 part;
Oxidation inhibitor 0.1-0.5 part;
Fire retardant 2-15 part;
Toner 0.1-0.5 part.
2. a kind of matrix material for phone housing according to claim 1, is characterized in that, described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
3. a kind of matrix material for phone housing according to claim 1, is characterized in that, described PC is aromatic copolycarbonate.
4. a kind of matrix material for phone housing according to claim 1, is characterized in that, described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
5. a kind of matrix material for phone housing according to claim 1, is characterized in that, described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
6. a kind of matrix material for phone housing according to claim 1, is characterized in that, described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690181.5A CN104497520A (en) | 2014-11-26 | 2014-11-26 | Composite material used for cellphone shells |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690181.5A CN104497520A (en) | 2014-11-26 | 2014-11-26 | Composite material used for cellphone shells |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104497520A true CN104497520A (en) | 2015-04-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410690181.5A Pending CN104497520A (en) | 2014-11-26 | 2014-11-26 | Composite material used for cellphone shells |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497520A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131553A (en) * | 2015-09-18 | 2015-12-09 | 苏州新区佳合塑胶有限公司 | Abrasion-resistant composite material for mobile phone shells |
| CN105323340A (en) * | 2015-10-30 | 2016-02-10 | 苏州天擎电子通讯有限公司 | Novel plastic mobile phone shell |
| CN107083039A (en) * | 2017-04-25 | 2017-08-22 | 福建华塑新材料有限公司 | A kind of control box shell polycarbonate compositions and its preparation technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319875A (en) * | 2013-07-01 | 2013-09-25 | 深圳市兴盛迪新材料有限公司 | Polycarbonate/acrylonitrile-styrene-butadiene alloy and preparation method thereof |
| CN103333483A (en) * | 2013-07-19 | 2013-10-02 | 深圳市兴盛迪新材料有限公司 | Improved PC-ABS (polycarbonate-acrylonitrile-butadiene styrene) resin alloy |
| CN103351591A (en) * | 2013-07-10 | 2013-10-16 | 深圳市兴盛迪新材料有限公司 | Cold-resistant polycarbonate/acrylonitrile-phenethylene-butadiene alloy and preparation method thereof |
| CN103351594A (en) * | 2013-07-19 | 2013-10-16 | 深圳市兴盛迪新材料有限公司 | PC-ABS alloy for computer housing |
-
2014
- 2014-11-26 CN CN201410690181.5A patent/CN104497520A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319875A (en) * | 2013-07-01 | 2013-09-25 | 深圳市兴盛迪新材料有限公司 | Polycarbonate/acrylonitrile-styrene-butadiene alloy and preparation method thereof |
| CN103351591A (en) * | 2013-07-10 | 2013-10-16 | 深圳市兴盛迪新材料有限公司 | Cold-resistant polycarbonate/acrylonitrile-phenethylene-butadiene alloy and preparation method thereof |
| CN103333483A (en) * | 2013-07-19 | 2013-10-02 | 深圳市兴盛迪新材料有限公司 | Improved PC-ABS (polycarbonate-acrylonitrile-butadiene styrene) resin alloy |
| CN103351594A (en) * | 2013-07-19 | 2013-10-16 | 深圳市兴盛迪新材料有限公司 | PC-ABS alloy for computer housing |
Non-Patent Citations (1)
| Title |
|---|
| 潘祖仁: "《高分子化学（第四版）》", 31 January 2009, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131553A (en) * | 2015-09-18 | 2015-12-09 | 苏州新区佳合塑胶有限公司 | Abrasion-resistant composite material for mobile phone shells |
| CN105323340A (en) * | 2015-10-30 | 2016-02-10 | 苏州天擎电子通讯有限公司 | Novel plastic mobile phone shell |
| CN107083039A (en) * | 2017-04-25 | 2017-08-22 | 福建华塑新材料有限公司 | A kind of control box shell polycarbonate compositions and its preparation technology |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150408 |