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CN104482757A - Tilting high-temperature rotary tube furnace for continuous heat treatment - Google Patents

Tilting high-temperature rotary tube furnace for continuous heat treatment Download PDF

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Publication number
CN104482757A
CN104482757A CN201410721018.0A CN201410721018A CN104482757A CN 104482757 A CN104482757 A CN 104482757A CN 201410721018 A CN201410721018 A CN 201410721018A CN 104482757 A CN104482757 A CN 104482757A
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furnace
heat treatment
temperature
pipe
furnace body
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CN201410721018.0A
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Inventor
王跃忠
张荣实
甘硕文
杨勇
田猛
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8358 Research Institute of 3th Academy of CASC
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8358 Research Institute of 3th Academy of CASC
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Abstract

The invention belongs to the industry and field of high-temperature heat treatment electric furnaces and particularly relates to a tilting high-temperature rotary tube furnace for continuous heat treatment. The furnace mainly comprises a furnace body, a rotating mechanism and a tilting device. The furnace body is provided with an airtight heart; the upper end of the furnace body is provided with a feeding device; the lower end of the furnace body is provided with a receiving device; the rotating mechanism disposed within the furnace body is connected with a high-temperature-resistant liner and drives the same to rotate, thereby driving material within the high-temperature-resistant liner to move. A heating and insulating device and a temperature measurer are disposed within the furnace body. The feeding device is used for conveying material, to be subjected to heat treatment, into the liner by the aid of the tilting device; after heat treatment at a target temperature is complete, the receiving device delivers out the material by the aid of the tilting device. The furnace allows uniform heat treatment, is capable of heating and cooling the material fast, is available for continuous operation, has high applicable temperature and is low in manufacturing cost.

Description

Tilting high-temperature rotary continuous heat treatment tube furnace
Technical Field
The invention belongs to the field of high-temperature heat treatment electric furnace industry, and particularly relates to an inclined high-temperature rotary continuous heat treatment tubular furnace.
Background
In order to improve the heat treatment efficiency of materials, a continuous heat treatment furnace is generally used industrially. At present, an electric Furnace for continuous heat treatment operation is mainly a Belt Furnace (Belt Furnace), and the structure of the electric Furnace is characterized in that the electric Furnace comprises a gradient temperature rise and drop interval, so that the electric Furnace is large in size, large in occupied area, high in manufacturing cost, difficult to popularize and apply comprehensively, applicable temperature is generally below 1600 ℃, and in order to improve the applicable temperature, a gradient temperature zone needs to be further amplified, so that the structure is more complex and the size is larger. Although the belt furnace can realize continuous operation, the effect of material heat treatment uniformity is not as good as that of the rotary furnace. In the heat treatment stage, the rotation is beneficial to improving the uniformity of the material. At present, the commercial rotary tube furnace can improve the uniformity of material heat treatment, but is difficult to realize continuous heat treatment function, mainly stays in periodic operation, and the applicable temperature is basically not more than 1500 ℃.
For this reason, there is a related practitioner to develop a rotary furnace like a belt furnace, i.e., a tubular rotary continuous furnace, combining both advantages. The continuous rotary furnace reported in patent CN202582157U uses metal screw blade rods to convey materials to realize continuous operation function. U.S. cabert company has announced a continuous high temperature rotary tube furnace scheme, and patent WO099/67588, CN1312903A, regard high temperature alloy container as the boiler tube, the inner wall is equipped with the thread tooth, can drive the material to move, and then realize the function of feeding in and discharging in succession, this design scheme has selected high temperature alloy container for use, except that the cost is expensive, so a series of problems still exist: the heavy container causes easy loss of the bearing, the applicable temperature of the material is low, generally not more than 1700 ℃, the metal is easy to embrittle, the service life of the container is low, and the like. In order to reduce the manufacturing cost, high-temperature resistant non-metallic materials such as graphite, BN and the like are often adopted and can also be suitable for high temperature, the scheme of the rotary tube furnace of the American Centorr Vacuum Industries company can meet the use requirement of continuous operation at high temperature (more than or equal to 1600 ℃), and the equipment adopts the scheme similar to the thread-tooth furnace tube scheme in the structural design so as to realize continuous heat treatment.
In general, the common characteristics of the tubular rotary continuous furnace are that the material is driven to move forward by adopting a thread tooth transmission structure so as to complete feeding and discharging, the structural defects are that material residues are difficult to avoid, and the material is easy to be solidified on a furnace tube and difficult to remove after high-temperature treatment. If an inclined structure is adopted, the problem of material residue can be avoided. Although there are also commercial tiltable tube furnaces, there are structural limitations and continuous heat treatment operations have not been achieved. Therefore, based on the limitations of the prior art solutions, there is a need to provide a tilting rotary tube furnace with a new structure to realize the coexistence of no material residue, rotation and continuous operation.
Disclosure of Invention
Technical problem to be solved
The technical problem to be solved by the invention is as follows: how to provide a tilting type high-temperature rotary continuous heat treatment tube furnace.
(II) technical scheme
In order to solve the above technical problems, the present invention provides an inclined high-temperature rotary continuous heat treatment tube furnace, comprising: a furnace body, a rotating mechanism and a tilting device;
the furnace body is provided with an airtight furnace chamber, the upper end of the furnace body is provided with a feeding device, the lower end of the furnace body is connected with a material receiving device, and the rotating mechanism is arranged in the furnace body and connected with a high-temperature-resistant furnace pipe to rotate so as to drive materials in the furnace pipe to move; the furnace body is additionally provided with a heating and heat insulation device and a temperature measuring device, materials to be thermally treated are conveyed into the furnace pipe under the assistance of the tilting device through the feeding device, and after the thermal treatment is finished at a target temperature, the materials are conveyed out for standby by the material receiving device under the assistance of the tilting device, so that the functions of uniform thermal treatment, rapid material temperature rise and fall and continuous operation are achieved;
the feed arrangement connects on the furnace body, and it includes: a raw material box, a feed valve, a feed pipe and a vacuum/atmosphere pipeline interface; the material is placed in a raw material box, and when the material conveying device works, the material can be conveyed into a pipeline of a feeding pipe by opening a feeding valve; the vacuum/atmosphere pipeline interface is used for pre-vacuumizing and filling gas into the furnace body;
the tilting device includes: a hand wheel and a rotating shaft; during operation, the hand wheel is rotated to drive the furnace body to perform integral inclined motion along the rotating shaft, so that materials in the feeding device are conveyed into the furnace pipe, and the materials are poured out through inclination after heat treatment is completed.
The furnace body shell is of a two-half structure or an integrated structure; for the two-half structure, the radians of the cross sections of the upper furnace shell and the lower furnace shell respectively account for 90-150 degrees and 210-270 degrees, and sealing rings are arranged at the closed positions; for the integrated furnace shell, the structure is designed to be cylindrical or cuboid.
The furnace pipe is used for material containing heat treatment, structurally comprises a horn cylinder body and a cylindrical cylinder in an end-to-end connection mode, and has an opening at the end opening of the furnace pipe, so that the furnace pipe has the function of facilitating feeding and discharging.
The inner wall of the furnace pipe is provided with a convex groove or a concave groove, and the furnace pipe can drive materials to move when rotating, so that the heat treatment uniformity of the materials can be improved.
The shape of the convex groove is a cuboid or a triangular prism.
The furnace body is provided with an airtight furnace chamber, and the two ends of the furnace liner are respectively provided with an air inlet and an air outlet, so that the furnace is suitable for operation under vacuum/atmosphere conditions.
When used under the above atmospheric conditions, the gas is preferably N2, Ar, or H2.
The material receiving mechanism comprises a material receiving guide pipe and a heat-resistant material receiving bottle; the heat-resistant material receiving bottle is a double-layer water-cooled device and is formed by combining a high-purity graphite or stainless steel lining, a heat-insulating carbon felt and a stainless steel double-layer water-cooled outer barrel from inside to outside in sequence, receives high-temperature materials and rapidly cools the high-temperature materials.
The furnace pipe is made of light high-temperature-resistant material.
The heating body material is graphite or tungsten.
(III) advantageous effects
The invention provides an inclined high-temperature rotary continuous heat treatment tube furnace with high applicable temperature (less than or equal to 2000 ℃), low manufacturing cost and small volume load, which can simultaneously meet the use requirements of uniform heat treatment and continuous operation and can avoid the problems of material residue and the like.
It has the following beneficial effects:
(1) can realize the function of quickly heating and cooling the material, and the material is not easy to remain. The specific implementation way is as follows: through heating device, heat the stove courage to the target temperature earlier, rethread feed arrangement carries the material of pending to the stove courage under the assistance of tilting device in, can realize the quick intensification function of material. After the heat treatment is finished at the target temperature, the material is conveyed to a collecting bottle with water cooling by the material receiving device under the assistance of the tilting device, and the function of quickly cooling the material can be realized. The problem of material residue can be solved by inclined discharging;
(2) the uniformity of the heat treatment of the material can be effectively improved. The specific implementation way is as follows: during heat treatment operation, the furnace pipe is driven to move through the rotating mechanism, so that the material is driven to move, and the uniform heat treatment function of the material can be realized;
(3) can realize continuous operation at high temperature. The specific implementation way is as follows: on the basis of the beneficial effect (1), after the heat treatment and the discharge of the previous batch of materials are finished, the feeding, the heat treatment and the discharge of the next batch of materials can be carried out without secondary temperature rise and drop, thereby achieving the function of continuous operation;
(4) in structural design, the bearing is arranged outside the heat preservation layer for isolation, so that the loss of radiation and heat conduction to the bearing can be effectively reduced, and the bearing can be used under the condition of high temperature (less than or equal to 2000 ℃); the furnace pipe is made of light high-temperature-resistant material (preferably high-purity graphite or BN), so that the bearing load can be reduced, and the service life of the bearing is prolonged.
Drawings
FIG. 1 is a schematic sectional view of a tilting type high temperature rotary continuous heat treatment tube furnace in example 1.
FIG. 2 is a schematic sectional view of a tilting type high temperature rotary continuous heat treatment tube furnace in example 1.
FIG. 3 is a schematic sectional view of a tilting type high temperature rotary continuous heat treatment tube furnace in example 2.
FIG. 4 is a schematic sectional view of a tilting type high temperature rotary continuous heat treatment tube furnace in example 1.
Detailed Description
In order to make the objects, contents, and advantages of the present invention clearer, the following detailed description of the embodiments of the present invention will be made in conjunction with the accompanying drawings and examples.
In order to solve the problems of the prior art, the invention provides a tilting type high-temperature rotary continuous heat treatment tube furnace, which comprises: a furnace body, a rotating mechanism and a tilting device;
the furnace body is provided with an airtight furnace chamber, the upper end of the furnace body is provided with a feeding device, the lower end of the furnace body is connected with a material receiving device, and the rotating mechanism is arranged in the furnace body and connected with a high-temperature-resistant furnace pipe to rotate so as to drive materials in the furnace pipe to move; the furnace body is additionally provided with a heating and heat insulation device and a temperature measuring device, materials to be thermally treated are conveyed into the furnace pipe under the assistance of the tilting device through the feeding device, and after the thermal treatment is finished at a target temperature, the materials are conveyed out for standby by the material receiving device under the assistance of the tilting device, so that the functions of uniform thermal treatment, rapid material temperature rise and fall and continuous operation are achieved; wherein,
the feed arrangement connects on the furnace body, and it includes: a raw material box, a feed valve, a feed pipe and a vacuum/atmosphere pipeline interface; the material is placed in a raw material box, and when the material conveying device works, the material can be conveyed into a pipeline of a feeding pipe by opening a feeding valve; the vacuum/atmosphere pipeline interface is used for pre-vacuumizing and filling gas into the furnace body;
the tilting device includes: a hand wheel and a rotating shaft; when the furnace is in operation, the hand wheel is rotated to drive the furnace body to integrally tilt along the rotating shaft, so that materials in the feeding device can be conveyed into the furnace, and after the heat treatment is finished, the materials are poured out through tilting again;
the furnace body shell is of a two-half structure or an integrated structure. For the two-half structure, the radians of the cross sections of the upper furnace shell and the lower furnace shell respectively account for 90-150 degrees and 210-270 degrees, and sealing rings are arranged at the closed positions; for the integrated furnace shell, the structural design is preferably cylindrical or cuboid;
the furnace pipe is used for material containing heat treatment, structurally comprises a horn cylinder body and a cylindrical cylinder which are connected end to end, and has an opening at the end opening, so that the furnace pipe has the function of facilitating feeding and discharging;
the inner wall of the furnace pipe can be processed with a convex groove or a concave groove, and the furnace pipe can drive materials to move when rotating, so that the uniformity of heat treatment of the materials is improved; preferably, the shape of the convex groove is a cuboid or a triangular prism;
the furnace body is provided with an airtight furnace chamber, and the two ends of the furnace liner are respectively provided with an air inlet and an air outlet, so that the furnace is suitable for operation under vacuum/atmosphere conditions; when used under atmospheric conditions, the gas is preferably N2, Ar, H2;
the material receiving mechanism comprises a material receiving guide pipe and a heat-resistant material receiving bottle; the heat-resistant material receiving bottle is a double-layer water-cooled device and is formed by combining a high-purity graphite or stainless steel lining, a heat-insulating carbon felt and a stainless steel double-layer water-cooled outer barrel from inside to outside in sequence, so that high-temperature materials can be received and rapidly cooled;
the rotating mechanism is provided with a high-temperature-resistant bearing, and the material is preferably SiC, Si3N4 or graphite;
the furnace pipe is made of a light high-temperature-resistant material, preferably high-purity graphite or BN, and the purity is not lower than 99.999 percent;
the heating body material is preferably graphite or tungsten;
the temperature measuring device is preferably a tungsten-rhenium thermocouple or an infrared thermometer, or a combination of the tungsten-rhenium thermocouple and the infrared thermometer.
The present invention will be described in detail with reference to specific examples.
Example 1
The inclined high-temperature rotary continuous heat treatment tube furnace (hereinafter referred to as "tube furnace") has the structure as described above, and as shown in fig. 1 and 2, the tube furnace mainly includes a furnace body 1, a rotary mechanism 2, and an inclined device 3. The furnace body 1 is provided with an airtight hearth, the upper end of the furnace body is provided with a feeding device 4, and the lower end of the furnace body is provided with a receiving device 5. The rotating mechanism 2 is connected with the graphite furnace pipe 6 and rotates to drive the material A in the furnace pipe to move. The furnace body 1 is additionally provided with a heating body and a heat insulation device which are composed of a graphite heating body 7 and a graphite soft felt heat shield 8, and a temperature measuring device which is composed of a thermocouple 9, so that the temperature of a hearth can be raised to a target temperature, a material B to be thermally treated is conveyed into a furnace pipe 6 by the aid of a feeding device 4 under the aid of an inclining device 3, and after the thermal treatment is completed at the target temperature, the material B is conveyed out for standby by a material receiving device 5 under the aid of the inclining device 3. After the material of the previous batch is discharged after the heat treatment, the feeding, the heat treatment and the discharging of the material of the next batch can be carried out without secondary temperature rise and drop, thereby achieving the function of continuous operation.
Further, the feeding device 4 is mainly composed of a charging box 10, a feeding valve 11, a feeding pipe 12, and the like. The charging box 11 is of a funnel-shaped structure, and is internally provided with material containing grids which are equally divided and independent, so that the quality of materials entering the furnace pipe every time can be ensured to be equal; when feeding, firstly opening the feed valve 11 to enable the material B to enter the port of the furnace pipe 6 through the feed pipe 12, and inclining the furnace body 1 to enable the material B to enter the graphite furnace pipe 6;
further, the furnace shell 13 is of an integrated cylindrical barrel structure and is of a side-surface cover-opening structure;
further, the furnace shell 13 is provided with a hole in the center of an axial end face seal plate for installing the SiC bearing 14;
furthermore, a thermocouple 9, a vacuum/atmosphere pipeline interface and the like are arranged on the furnace shell;
further, the graphite furnace pipe 6 is formed by connecting a horn-shaped graphite 15, a cylindrical graphite barrel 16, a horn-shaped graphite 17 and a cylindrical graphite barrel 18 end to end, and the purity of the graphite is 99.999 percent;
furthermore, an opening 19 is formed in the pipe wall of the cylindrical graphite barrel 18, and when the opening is turned downwards, the material A can be poured out of the furnace pipe 6 conveniently by inclining the furnace body 1;
furthermore, a cuboid convex groove is axially processed on the inner wall of the cylindrical graphite 16, and the material A can be driven to move when the furnace pipe rotates;
further, the SiC bearing 14 is positioned on the furnace shell 13 and outside the graphite soft felt heat shield 8, so that the loss of the bearing caused by heat conduction can be effectively reduced;
further, the material receiving mechanism 5 is provided with a stainless steel double-layer water-cooling outer cylinder 20 which can receive the high-temperature materials after heat treatment and quickly cool the high-temperature materials;
further, the tilting device 3 is constituted by a hand wheel 21 (with a positioning function), a rotation bearing 22, and the like. The furnace shell is driven to integrally tilt by rotating a hand wheel 21 so as to facilitate feeding and discharging;
further, if the heat treatment is to be performed under atmospheric conditions, gas may be introduced through the gas inlet pipe 23.
Example 2
The inclined high-temperature rotary continuous heat treatment tube furnace (hereinafter referred to as "tube furnace") is constructed as described above, and as shown in fig. 3 and 4, the tube furnace is mainly composed of a furnace body 24, a rotary mechanism 25, and an inclined device 26. The furnace body 24 is provided with an airtight hearth, the upper end of the furnace body is provided with a feeding device 27, and the lower end of the furnace body is provided with a receiving device 28. The rotating mechanism 25 is connected with the high-purity BN furnace pipe 29 and rotates to drive the material C in the furnace pipe to move. The furnace body 24 is additionally provided with a heating body and a heat insulation device which are composed of a graphite heating body 30 and a graphite soft felt heat shield 31, and a temperature measuring device which is composed of a thermocouple 32 and an infrared thermometer 33, the temperature of the furnace hearth can be raised to a target temperature, the material D to be heat-treated is conveyed into the furnace pipe 29 by the aid of the tilting device 26 through the feeding device 27, and after the heat treatment is finished at the target temperature, the material D is conveyed out for standby by the material receiving device 28 by the aid of the tilting device 26. After the material of the previous batch is discharged after the heat treatment, the feeding, the heat treatment and the discharging of the material of the next batch can be carried out without secondary temperature rise and drop, thereby achieving the function of continuous operation.
Further, the feeding device 27 is mainly composed of a charging box 34, a feeding valve 35, a feeding pipe 36, and the like. The charging box 34 is of a funnel-shaped structure, and is internally provided with material containing grids which are equally divided and independent, so that the quality of materials entering the furnace pipe every time can be ensured to be equal; opening the feeding valve 35 to allow the material D to enter the furnace pipe 29 through the feeding pipe 36;
further, the furnace shell 37 is of a double-half structure, the cross section of the upper end cover 38 is of a small arc (100 degrees) structure, and the lower furnace body 39 is of a large arc (260 degrees) structure and is of an upper open cover type structure;
further, the cross section of the heating element 30 is a 245-degree large arc structure;
further, the furnace shell 37 is provided with a hole in the center of an axial end face seal plate for installing the isostatic pressing graphite bearing 40;
furthermore, a thermocouple 32, an infrared thermometer 33, a vacuum/atmosphere pipeline interface 41 and the like are arranged on the furnace shell;
further, the furnace pipe 29 is composed of a cylindrical BN cylinder 42, a horn-shaped BN cylinder 43 and a cylindrical BN cylinder 44 which are connected end to end, and the BN purity is 99.99%;
further, the tube wall of the cylindrical BN tube 44 is provided with an opening 45, and when the opening is turned downwards, the material C is favorably poured out of the furnace pipe 29 by inclining the furnace body 24;
furthermore, a triangular prism convex groove is axially processed on the inner wall of the cylindrical BN cylinder 42, and the furnace pipe can drive the material C to move when rotating;
furthermore, the isostatic pressing graphite bearing 40 is positioned on the furnace shell 37 and outside the graphite soft felt heat shield 31, so that the loss of the bearing caused by heat conduction can be effectively reduced;
further, the material receiving mechanism 28 is provided with a stainless steel double-layer water-cooling outer cylinder 46 which can receive the high-temperature materials after heat treatment and quickly cool the high-temperature materials;
further, the tilting device 26 is constituted by a hand wheel 47 (with a positioning function), a rotation bearing 48, and the like. The furnace shell is driven to integrally tilt by rotating the hand wheel 48 so as to facilitate feeding and discharging;
further, if the heat treatment is to be performed under atmospheric conditions, gas may be introduced through the gas inlet pipe 49.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (9)

1. A tilting high-temperature rotary continuous heat treatment tube furnace, comprising: a furnace body, a rotating mechanism and a tilting device;
the furnace body is provided with an airtight furnace chamber, the upper end of the furnace body is provided with a feeding device, the lower end of the furnace body is connected with a material receiving device, and the rotating mechanism is arranged in the furnace body and connected with a high-temperature-resistant furnace pipe to rotate so as to drive materials in the furnace pipe to move; the furnace body is additionally provided with a heating and heat insulation device and a temperature measuring device, materials to be thermally treated are conveyed into the furnace pipe under the assistance of the tilting device through the feeding device, and after the thermal treatment is finished at a target temperature, the materials are conveyed out for standby by the material receiving device under the assistance of the tilting device, so that the functions of uniform thermal treatment, rapid material temperature rise and fall and continuous operation are achieved;
the feed arrangement connects on the furnace body, and it includes: a raw material box, a feed valve, a feed pipe and a vacuum/atmosphere pipeline interface; the material is placed in a raw material box, and when the material conveying device works, the material can be conveyed into a pipeline of a feeding pipe by opening a feeding valve; the vacuum/atmosphere pipeline interface is used for pre-vacuumizing and filling gas into the furnace body;
the tilting device includes: a hand wheel and a rotating shaft; during operation, the hand wheel is rotated to drive the furnace body to perform integral inclined motion along the rotating shaft, so that materials in the feeding device are conveyed into the furnace pipe, and the materials are poured out through inclination after heat treatment is completed.
2. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 1, wherein the furnace body shell is of a two-half structure or an integrated structure; for the two-half structure, the radians of the cross sections of the upper furnace shell and the lower furnace shell respectively account for 90-150 degrees and 210-270 degrees, and sealing rings are arranged at the closed positions; for the integrated furnace shell, the structure is designed to be cylindrical or cuboid.
3. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 1, wherein the furnace pipe is used for material-containing heat treatment and is structurally formed by combining a horn cylinder body and a cylindrical cylinder body in an end-to-end manner, and an opening is formed at the end of the furnace pipe, so that the furnace pipe has the function of facilitating feeding and discharging.
4. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 3, wherein the inner wall of the furnace pipe is provided with a convex groove or a concave groove, so that the furnace pipe can drive the material to move when rotating, thereby improving the uniformity of the heat treatment of the material.
5. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 4, wherein the shape of the convex groove is a rectangular parallelepiped or a triangular prism.
6. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 1, wherein the furnace body is provided with an airtight hearth, and the two ends of the furnace pipe are respectively provided with an air inlet and an air outlet, so that the furnace is suitable for operation under vacuum/atmosphere conditions.
7. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 6, wherein when used under the atmospheric conditions, the gas is preferably N2, Ar, H2.
8. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 1, wherein the material receiving mechanism comprises a material receiving guide tube and a heat-resistant material receiving bottle; the heat-resistant material receiving bottle is a double-layer water-cooled device and is formed by combining a high-purity graphite or stainless steel lining, a heat-insulating carbon felt and a stainless steel double-layer water-cooled outer barrel from inside to outside in sequence, receives high-temperature materials and rapidly cools the high-temperature materials.
9. The inclined high-temperature rotary continuous heat treatment tube furnace as claimed in claim 1, wherein the furnace pipe is made of light high-temperature resistant material.
CN201410721018.0A 2014-12-02 2014-12-02 Tilting high-temperature rotary tube furnace for continuous heat treatment Pending CN104482757A (en)

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CN106109234A (en) * 2016-07-26 2016-11-16 温玉桂 Moxibustion device
CN106216695A (en) * 2016-08-25 2016-12-14 宁波英纳特新材料有限公司 A kind of high-voltage capacitor preparation method of spherical tantalum powder
CN109721106A (en) * 2019-01-23 2019-05-07 广西大学 A kind of method and device thereof preparing inorganic fullerene-like disulphide nanoparticle
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CN106216695A (en) * 2016-08-25 2016-12-14 宁波英纳特新材料有限公司 A kind of high-voltage capacitor preparation method of spherical tantalum powder
CN109721106A (en) * 2019-01-23 2019-05-07 广西大学 A kind of method and device thereof preparing inorganic fullerene-like disulphide nanoparticle
CN110171824A (en) * 2019-04-15 2019-08-27 石门县顺超科技发展有限公司 A kind of graphite purification equipment and its method of purification
CN110207489A (en) * 2019-06-05 2019-09-06 江苏凤谷节能科技有限公司 Metallic rotary kiln barrel temperature-detecting device

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Application publication date: 20150401