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CN104479438A - Thinner added in coating layer for automobile sheet metal part stretch forming - Google Patents

Thinner added in coating layer for automobile sheet metal part stretch forming Download PDF

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Publication number
CN104479438A
CN104479438A CN201410845790.3A CN201410845790A CN104479438A CN 104479438 A CN104479438 A CN 104479438A CN 201410845790 A CN201410845790 A CN 201410845790A CN 104479438 A CN104479438 A CN 104479438A
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CN
China
Prior art keywords
parts
thinner
diethylene glycol
gasoline
sheet metal
Prior art date
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Granted
Application number
CN201410845790.3A
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Chinese (zh)
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CN104479438B (en
Inventor
程迎春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Kemiteer Surface Treatment Material Co ltd
Original Assignee
WUHU XIECHENG METAL PRODUCTS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by WUHU XIECHENG METAL PRODUCTS CO Ltd filed Critical WUHU XIECHENG METAL PRODUCTS CO Ltd
Priority to CN201410845790.3A priority Critical patent/CN104479438B/en
Publication of CN104479438A publication Critical patent/CN104479438A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a thinner added in a coating layer for automobile sheet metal part stretch forming, and belongs to the technical field of automobile sheet metal part working. The thinner added in the coating layer for the automobile sheet metal part stretch formatting comprises gasoline and an X-4 amino paint thinner, wherein the parts by mass of the gasoline and the X-4 amino paint thinner are as follows: 100 parts of gasoline and 20-25 parts of the X-4 amino paint thinner; the thinner further comprises zinc dialkyl dithiophosphate, diethylene glycol monomethylether, methyl isobutyl ketone, isopropanol, pyrrole, polyvinyl alcohol, diethylene glycol dimethyl ether, and ethylene dichloride. With the adoption of the technical scheme disclosed by the invention, the surface scratch problem in the sheet metal part stamping and stretch forming process can be solved fundamentally, furthermore the bottleneck problems of surface cast repair and finishing work procedure for the part production in the later period can be solved, and the sheet metal part stretch forming quality can be improved.

Description

The thinner added in a kind of automobile metal plate work drawing and forming coat
Technical field
The present invention relates to plates of automobile processing technique field, more particularly, relate to the thinner added in a kind of automobile metal plate work drawing and forming coat.
Background technology
Panel beating is for a kind of comprehensive cold machining process of metal sheet (usually at below 6mm), comprises cutting, rushing/cut/compound, folding, welding, riveted joint, splicing, shaping (as body of a motor car) etc.Its significant feature is exactly Same Part consistency of thickness.Can manufacturing is the hinge technology that panel beating technician needs to hold, and is also the important procedure that sheet metal product is shaped.Can manufacturing comprises method and the processing parameters such as traditional cutting stock, punch press process, curved pressing formation, comprises again various cold punching die structure &processes parameter, various equipment work principle and method of operating, also comprise new stamping technology and novel process.
Drawing also claims drawing or calendering, is the processing method for stamping that the plate blank obtained after utilizing Dies ' Blanking becomes the hollow part of opening.Tubular, stepped appearance, taper, spherical, box-like and other erose thin-walled parts can be made with deep-drawing technique, if coordinated with other Sheet Metal Forming Technologies, the part that shape is very complicated can also be manufactured.In the drawing process of rectangular drawpiece, the middle portion of plate becomes the bottom of part, does not substantially deform.And very large compressive plastic deformation will along the circumferential direction occur in outside, and force unnecessary metal to produce flowing along the radial direction of blank, thus form the sidewall of drawing part.A pair kinematic pair in drawing process is different from common mechanical organ, and the side because of their relatively sliding is quenched hard mold, and the opposing party is much softer than mould processing plate, so their very different of being out of shape separately; Along with the change in processing orientation, processing plate also has very large from difference at the distortion speed of each profiled section.Detect by observing the representational drawing part of part, the thickness of discovery drawing part each several part is inconsistent, normally bottom is basic keeps original thickness, side wall upper part thickens, thin down portions, and with slightly upper for the thinnest close to bottom roundings place, this just reflects the discordance of drawing process metal slippage.
The cut that drawing surface occurs and other surface quality defect mainly cause because the contact surface of drawing material and mould produces Relative sliding, and the cut that this slippage creates on article surface because of the inconsistent of friction resistance suffered during some particle place slippage.Cut on article surface is the defect of puzzlement cold stamping deformation technique always, how to reduce, even avoid the generation of this kind of defect, it is an urgent demand constantly moving towards high precision Pressing Deformation part, especially for automobile cold stamping product, after processing, the degree of uniformity of woollen matrix, directly affects safe reliability and the work-ing life of component and even complete machine.
In prior art; cut is produced in automobile metal plate work drawing and forming process; generally before drawing and forming, be coated with last layer coat protect; coat is generally made up of paint material and thinner; but; thinner proportioning in tradition coat is unreasonable, often occurs that part scratches and the problem of coat bonding mould.
Summary of the invention
1. invent the technical problem that will solve
The object of the invention is to overcome the deficiency easily producing cut in prior art in automobile metal plate work drawing and forming process, provide the thinner added in a kind of automobile metal plate work drawing and forming coat, adopt technical scheme of the present invention, fundamentally can solve the surface tear problem in sheet metal component punching press drawing process, thus the surface throwing solving the production of part later stage is repaiied and finishing process bottleneck problem, improves the quality of sheet metal component punching press drawing and forming.
2. technical scheme
For achieving the above object, technical scheme provided by the invention is:
The thinner added in a kind of automobile metal plate work drawing and forming coat of the present invention, this thinner comprises gasoline and X-4 amino paint thinner.
Further, the mass parts of gasoline and X-4 amino paint thinner consists of: 100 parts, gasoline, X-4 amino paint thinner 20 ~ 25 parts.
Further, this thinner also comprises zinc dialkyl dithiophosphate, diethylene glycol ethylmethyl ether, mibk, Virahol, pyrroles, polyvinyl alcohol, diethylene glycol dimethyl ether, ethylene dichloride.
Further, this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 10 ~ 12 parts,
Diethylene glycol ethylmethyl ether 7 ~ 9 parts,
Mibk 4 ~ 7 parts,
Virahol 6 ~ 8 parts,
Pyrroles 5 ~ 9 parts,
Polyvinyl alcohol 5 ~ 9 parts,
Diethylene glycol dimethyl ether 11 ~ 13 parts,
Ethylene dichloride 11 ~ 13 parts.
Further, this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 11 parts,
Diethylene glycol ethylmethyl ether 8 parts,
Mibk 5 parts,
Virahol 7 parts,
Pyrroles 8 parts,
Polyvinyl alcohol 7 parts,
Diethylene glycol dimethyl ether 12 parts,
Ethylene dichloride 12 parts.
Further, this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 10 parts,
Diethylene glycol ethylmethyl ether 7 parts,
Mibk 4 parts,
Virahol 6 parts,
Pyrroles 5 parts,
Polyvinyl alcohol 5 parts,
Diethylene glycol dimethyl ether 11 parts,
Ethylene dichloride 11 parts.
3. beneficial effect
Adopt technical scheme provided by the invention, compared with prior art, there is following unusual effect:
(1) thinner added in a kind of automobile metal plate work drawing and forming coat of the present invention, gasoline and X-4 amino paint mixing diluents is adopted to use, and be configured with specific auxiliary addition agent, the auxiliary addition agent used comprises zinc dialkyl dithiophosphate, diethylene glycol ethylmethyl ether, mibk, Virahol, pyrroles, polyvinyl alcohol, diethylene glycol dimethyl ether, ethylene dichloride, auxiliary addition agent is the technological innovation of key of the present invention, by dispersion and the crosslinked action of auxiliary addition agent, using thinner of the present invention to be mixed and made into coating material with paint material is sprayed on automobile metal plate work, best paint film thickness angle value can be obtained, the lubrication of the coat on automobile metal plate work surface in part drawing process and provide protection effect is enable to reach best, part is prevented to be damaged in drawing process, fundamentally solve the surface tear problem in sheet metal component punching press drawing process.
(2) thinner added in a kind of automobile metal plate work drawing and forming coat of the present invention; be applied in sheet metal component drawing production process; respond well; meet the resist technology requirement of negative clearance and deep drawing; the present invention is once great promotion for sheet metal part surface protection technique, has considerable economic benefit and good social benefit.
Embodiment
For understanding content of the present invention further, below in conjunction with embodiment, the invention will be further described.
embodiment 1
The thinner added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, this thinner is made up of following component, and each component is by following mass parts composition: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 11 parts, diethylene glycol ethylmethyl ether 8 parts, mibk 5 parts, Virahol 7 parts, pyrroles 8 parts, polyvinyl alcohol 7 parts, diethylene glycol dimethyl ether 12 parts, ethylene dichloride 12 parts.Wherein, the gasoline in the present embodiment is mixed according to volume ratio 1:2 by No. 90 gasoline and No. 97 gasoline.
The thinner preparation method added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, its concrete step is:
Step one, prepare each component of thinner by mass fraction: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 11 parts, diethylene glycol ethylmethyl ether 8 parts, mibk 5 parts, Virahol 7 parts, pyrroles 8 parts, polyvinyl alcohol 7 parts, diethylene glycol dimethyl ether 12 parts, ethylene dichloride 12 parts; And X-4 amino paint thinner is joined in gasoline, be uniformly mixed to obtain mixture A;
Step 2, the zinc dialkyl dithiophosphate by preparing in step one, diethylene glycol ethylmethyl ether, mibk, Virahol, pyrroles, polyvinyl alcohol, diethylene glycol dimethyl ether, ethylene dichloride mixing and stirring at normal temperatures, obtain mixture B;
Step 3, mixture A obtained in step one is poured in reactor, again the mixture B obtained in step 2 is poured in reactor, pass into nitrogen purging reactor 18 minutes, purging terminates rear closedown nitrogen and starts to stir, it is 180 rpm that stirring velocity controls, churning time is 32 minutes, stir after terminating and be warmed up to 40 DEG C with the heat-up rate of 2 DEG C/min, static insulation is after 10 minutes, 48 DEG C are warming up to again with the heat-up rate of 2 DEG C/min, react and be warmed up to 57 DEG C with the heat-up rate of 3 DEG C/min after 1.5 hours, static insulation is after 8 minutes, 67 DEG C are warming up to again with the heat-up rate of 2 DEG C/min, react 2.5 hours, continue again to be warming up to 93 DEG C, its heat-up rate is 2 DEG C/min, react 3.5 hours, after cooling, obtain the thinner added in automobile metal plate work drawing and forming coat.Preparation method in the present embodiment, adopt specific technology controlling and process, especially mixture A and mixture B was mixing the control of the temperature in process, made gasoline, X-4 amino paint thinner and auxiliary addition agent be disperseed fully and be cross-linked, greatly improved the final utilization performance of thinner.
The thinner added in the automobile metal plate work drawing and forming coat adopting the present embodiment to prepare and paint material are mixed to get coating material; coating material is sprayed on automobile metal plate work to be processed on the surface; best paint film thickness angle value can be obtained; the lubrication of the coat on automobile metal plate work surface in part drawing process and provide protection effect is enable to reach best; prevent part to be damaged in drawing process, fundamentally solve the surface tear problem in sheet metal component punching press drawing process.The technical problem of the present embodiment key is the thinner composition and ratio cooperation selection thereof that add in coat, the thinner of the present embodiment makes coat can bear deep drawing, the negative clearance pressure within 820 tons and the pressure-pad-force of 170 tons, ensures that part is not scratched in drawing process.
embodiment 2
The thinner added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, this thinner is made up of following component, and each component is by following mass parts composition: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 10 parts, diethylene glycol ethylmethyl ether 7 parts, mibk 4 parts, Virahol 6 parts, pyrroles 5 parts, polyvinyl alcohol 5 parts, diethylene glycol dimethyl ether 11 parts, ethylene dichloride 11 parts.
The thinner preparation method added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, its concrete step is same embodiment 1, and difference is: in step one, each component of thinner prepares by following mass parts: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 10 parts, diethylene glycol ethylmethyl ether 7 parts, mibk 4 parts, Virahol 6 parts, pyrroles 5 parts, polyvinyl alcohol 5 parts, diethylene glycol dimethyl ether 11 parts, ethylene dichloride 11 parts.
The thinner added in the automobile metal plate work drawing and forming coat adopting the present embodiment to prepare and paint material are mixed to get coating material; coating material is sprayed on automobile metal plate work to be processed on the surface; best paint film thickness angle value can be obtained; the lubrication of the coat on automobile metal plate work surface in part drawing process and provide protection effect is enable to reach best; prevent part to be damaged in drawing process, fundamentally solve the surface tear problem in sheet metal component punching press drawing process.The technical problem of the present embodiment key is the thinner composition and ratio cooperation selection thereof that add in coat, the thinner of the present embodiment makes coat can bear deep drawing, the negative clearance pressure within 825 tons and the pressure-pad-force of 168 tons, ensures that part is not scratched in drawing process.
embodiment 3
The thinner added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, this thinner is made up of following component, and each component is by following mass parts composition: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 12 parts, diethylene glycol ethylmethyl ether 9 parts, mibk 7 parts, Virahol 8 parts, pyrroles 9 parts, polyvinyl alcohol 9 parts, diethylene glycol dimethyl ether 13 parts, ethylene dichloride 13 parts.
The thinner preparation method added in a kind of automobile metal plate work drawing and forming coat of the present embodiment, its concrete step is same embodiment 1, and difference is: in step one, each component of thinner prepares by following mass parts: 100 parts, gasoline, X-4 amino paint thinner 23 parts, zinc dialkyl dithiophosphate 12 parts, diethylene glycol ethylmethyl ether 9 parts, mibk 7 parts, Virahol 8 parts, pyrroles 9 parts, polyvinyl alcohol 9 parts, diethylene glycol dimethyl ether 13 parts, ethylene dichloride 13 parts.
The thinner added in the automobile metal plate work drawing and forming coat adopting the present embodiment to prepare and paint material are mixed to get coating material; coating material is sprayed on automobile metal plate work to be processed on the surface; best paint film thickness angle value can be obtained; the lubrication of the coat on automobile metal plate work surface in part drawing process and provide protection effect is enable to reach best; prevent part to be damaged in drawing process, fundamentally solve the surface tear problem in sheet metal component punching press drawing process.The technical problem of the present embodiment key is the thinner composition and ratio cooperation selection thereof that add in coat, the thinner of the present embodiment makes coat can bear deep drawing, the negative clearance pressure within 817 tons and the pressure-pad-force of 165 tons, ensures that part is not scratched in drawing process.

Claims (6)

1. the thinner added in automobile metal plate work drawing and forming coat, is characterized in that: this thinner comprises gasoline and X-4 amino paint thinner.
2. the thinner added in a kind of automobile metal plate work drawing and forming coat according to claim 1, is characterized in that: the mass parts of gasoline and X-4 amino paint thinner consists of: 100 parts, gasoline, X-4 amino paint thinner 20 ~ 25 parts.
3. the thinner added in a kind of automobile metal plate work drawing and forming coat according to claim 1, is characterized in that: this thinner also comprises zinc dialkyl dithiophosphate, diethylene glycol ethylmethyl ether, mibk, Virahol, pyrroles, polyvinyl alcohol, diethylene glycol dimethyl ether, ethylene dichloride.
4. the thinner added in a kind of automobile metal plate work drawing and forming coat according to claim 3 or 4, is characterized in that: this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 10 ~ 12 parts,
Diethylene glycol ethylmethyl ether 7 ~ 9 parts,
Mibk 4 ~ 7 parts,
Virahol 6 ~ 8 parts,
Pyrroles 5 ~ 9 parts,
Polyvinyl alcohol 5 ~ 9 parts,
Diethylene glycol dimethyl ether 11 ~ 13 parts,
Ethylene dichloride 11 ~ 13 parts.
5. the thinner added in a kind of automobile metal plate work drawing and forming coat according to claim 3, is characterized in that: this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 11 parts,
Diethylene glycol ethylmethyl ether 8 parts,
Mibk 5 parts,
Virahol 7 parts,
Pyrroles 8 parts,
Polyvinyl alcohol 7 parts,
Diethylene glycol dimethyl ether 12 parts,
Ethylene dichloride 12 parts.
6. the thinner added in a kind of automobile metal plate work drawing and forming coat according to claim 3, is characterized in that: this thinner is made up of following component, and each component is by following mass parts composition:
100 parts, gasoline,
X-4 amino paint thinner 23 parts,
Zinc dialkyl dithiophosphate 10 parts,
Diethylene glycol ethylmethyl ether 7 parts,
Mibk 4 parts,
Virahol 6 parts,
Pyrroles 5 parts,
Polyvinyl alcohol 5 parts,
Diethylene glycol dimethyl ether 11 parts,
Ethylene dichloride 11 parts.
CN201410845790.3A 2014-12-31 2014-12-31 A kind of automobile metal plate work drawing and forming is with the diluent added in coat Expired - Fee Related CN104479438B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410845790.3A CN104479438B (en) 2014-12-31 2014-12-31 A kind of automobile metal plate work drawing and forming is with the diluent added in coat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410845790.3A CN104479438B (en) 2014-12-31 2014-12-31 A kind of automobile metal plate work drawing and forming is with the diluent added in coat

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CN104479438A true CN104479438A (en) 2015-04-01
CN104479438B CN104479438B (en) 2017-07-14

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3111101A1 (en) * 1981-03-20 1982-09-30 Georg Scheidel Jr. Gmbh, 8606 Hirschaid Lacquer solvent/diluent
CN1044480A (en) * 1989-01-28 1990-08-08 常州市武进县村前第二化工厂 The preparation technology of the multi-functional thinner of no benzene
CN1047100A (en) * 1990-01-24 1990-11-21 陈二孝 Cryogenic baking finishing preparating process
CN1067438A (en) * 1991-05-31 1992-12-30 王建国 Benzene-free diluent of nitro-finish
CN1130204A (en) * 1995-03-02 1996-09-04 湘潭市南方高新技术研究所 Perlatolic polyester furniture paint
JP2006169307A (en) * 2004-12-14 2006-06-29 Sato Kiyomatsu Shoten:Kk Aerosol lacquer
CN1970652A (en) * 2005-11-23 2007-05-30 黄永平 Environment-friendly health type paint thinner
CN102559041A (en) * 2011-12-30 2012-07-11 株洲南方燃气轮机成套制造安装有限公司 Paint, preparation method thereof and coating moulding method
CN102964897A (en) * 2012-11-15 2013-03-13 青岛保利康新材料有限公司 Paint coating thinner
CN103205152A (en) * 2013-04-10 2013-07-17 吕金海 Green environment-friendly diluent
CN103736638A (en) * 2013-12-20 2014-04-23 河北汉光重工有限责任公司 Metal surface paint spraying quality control process

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3111101A1 (en) * 1981-03-20 1982-09-30 Georg Scheidel Jr. Gmbh, 8606 Hirschaid Lacquer solvent/diluent
CN1044480A (en) * 1989-01-28 1990-08-08 常州市武进县村前第二化工厂 The preparation technology of the multi-functional thinner of no benzene
CN1047100A (en) * 1990-01-24 1990-11-21 陈二孝 Cryogenic baking finishing preparating process
CN1067438A (en) * 1991-05-31 1992-12-30 王建国 Benzene-free diluent of nitro-finish
CN1130204A (en) * 1995-03-02 1996-09-04 湘潭市南方高新技术研究所 Perlatolic polyester furniture paint
JP2006169307A (en) * 2004-12-14 2006-06-29 Sato Kiyomatsu Shoten:Kk Aerosol lacquer
CN1970652A (en) * 2005-11-23 2007-05-30 黄永平 Environment-friendly health type paint thinner
CN102559041A (en) * 2011-12-30 2012-07-11 株洲南方燃气轮机成套制造安装有限公司 Paint, preparation method thereof and coating moulding method
CN102964897A (en) * 2012-11-15 2013-03-13 青岛保利康新材料有限公司 Paint coating thinner
CN103205152A (en) * 2013-04-10 2013-07-17 吕金海 Green environment-friendly diluent
CN103736638A (en) * 2013-12-20 2014-04-23 河北汉光重工有限责任公司 Metal surface paint spraying quality control process

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Address after: 241000 Anhui Province, Wuhu City Fumin Jiujiang Road Economic Development Zone

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