CN104470489B - Cosmetic composition including scattering filler and mother-of-pearl - Google Patents

Abstract

The present invention relates to a kind of cosmetic composition for nurse and/or make up keratin material, particularly facial skin, the following components being included in physiologically acceptable medium：(a) at least one scattering filler, particle size is less than 35 microns, preferably 2 microns to 35 microns, more preferable 11 microns to 17 microns, (b) at least at least one blue mother-of-pearl of red or pink mother-of-pearl and (c).

Description

Cosmetic composition comprising scattering filler and nacre

technical field

The present invention relates to compositions for caring for and/or making up the skin, which are especially intended to impart radiance and a healthy glow.

The terms "shine" and "light effect" are understood according to the invention to mean the characteristic of light reflection, diffusion and continuous reflection on the skin. In fact, the skin naturally reflects a portion of incident light. The "light effect" according to the invention makes it possible to increase this reflection, which gives the make-up a shinier and more luminous appearance. The compositions according to the invention can also impart a healthy glow effect.

The expression "healthy glow effect" is understood to mean the natural coloring of the skin, improving the dull appearance of the complexion (desaturated or colored and anti-dull complexion effect).

The expression "composition for the care and/or makeup of keratin materials" according to the invention is understood to mean a composition other than a rinse-off cleansing composition.

In particular, they will be compositions for caring for and/or making up the skin of the face and/or body, especially the facial skin.

Background technique

For centuries, consumers all over the world, especially in Asia, have been looking for new cosmetic products to improve the appearance of keratinous materials, especially skin, especially surface appearance (visible and/or tactile unevenness) And/or skin complexion, a healthy glow, external signals of health and youth.

Furthermore, in order to impart a radiant and healthy glow to keratin materials, especially the skin, it is necessary to hide imperfections on the skin, while at the same time scatters the light in order to give the skin a luminous and at the same time non-shiny appearance.

It is well known in the prior art to use pigments in cosmetic compositions in order to conceal skin imperfections and lighten the skin. However, pigment particles with strong light scattering and absorption tend to accumulate inside the pores and increase their visibility. US2005163730 to Unilever describes a combination of silicone elastomers, ZnO nanopigments and scattering fillers such as TiO2 coated mica or bismuth oxychloride.

Therefore, there is still a need to find new care and/or make-up products, especially for the complexion, which impart a luminous effect rather than sparkle, which do not mark unevenness while covering imperfections (skin discolouration, marks) or which impart a uniform color to the face, Especially the face has a natural and uniform color and, advantageously, a healthy glow.

Contents of the invention

The inventors have found that scattering fillers, especially bismuth compounds, in combination with nacre, show very good light reflection and making up effects, which fulfill the object of the present invention.

The hydrophilic nature of the scattering compound contributes to the skin affinity of the composition of the invention and improves the adhesion of the composition of the invention.

According to a specific embodiment, cluster structure scattering fillers are used in the present invention. The composition thus becomes cohesive and less transparent due to the structure of the scattering filler. Thus, the composition brings a light-scattering effect to the skin in order to impart a glow but not shiny appearance and at the same time cover skin imperfections.

Furthermore, the composition of the present invention is capable of absorbing sebum on the skin after application due to the structure of the above-mentioned scattering filler.

In one aspect, the present invention provides a cosmetic composition for the care and/or makeup of keratinous materials, in particular facial skin, comprising the following components in a physiologically acceptable medium:

(a) at least one scattering filler having a particle size of less than 35 microns, preferably from 2 microns to 35 microns, more preferably from 11 microns to 17 microns,

(b) at least red or pink mother-of-pearl, and

(c) At least blue mother-of-pearl.

According to a preferred embodiment, the present invention provides a cosmetic composition for the care and/or makeup of keratinous materials, in particular facial skin, comprising the following components in a physiologically acceptable medium:

(a) at least one bismuth oxychloride, preferably in the form of cluster crystals, having a particle size of less than 35 microns, preferably from 2 microns to 35 microns, more preferably from 11 microns to 17 microns,

(b) at least red or pink mother-of-pearl, and

(c) At least blue mother-of-pearl.

The present invention as described above provides a good balance between at least one diffusing filler and nacre so that the composition of the invention is able to bring about coverage of skin imperfections, as well as a lightening and glowing effect on the skin, especially the facial skin.

According to the invention, the compositions may be in various forms, in particular in the form of anhydrous compositions, dispersions or emulsions, such as water/oil or oil/water emulsions or multiple emulsions, among others.

The compositions of the invention are preferably emulsions, in particular direct or inverse emulsions, or anhydrous compositions.

Preferably, the composition is an emulsion.

Emulsions can have an oil or water continuous phase. Such emulsions may be, for example, inverse (W/O) emulsions or direct (O/W) emulsions, or alternatively multiple emulsions (W/O/W or O/W/O).

According to another embodiment, the composition according to the invention also comprises at least one additional colorant selected from angular difference colorants, photochromic colorants, fluorescent agents, optical brighteners, lakes, organic pigments, composite Pigments, and mixtures thereof.

According to yet another particular embodiment, the composition of the invention also comprises at least one additional filler. According to yet another embodiment, the composition of the invention also comprises at least one organic UV sunscreen ingredient, which is organic, and/or an inorganic UV sunscreen ingredient.

In yet another aspect, the present invention relates to a method of caring for and/or making up keratinous materials, comprising applying to said keratinous materials, in particular to the skin, a composition according to the invention, for example an application of a composition to facial skin. In the form of a composition of layers or several layers, used alone or in combination with another composition (two-step application), said composition according to the invention is used in care compositions or cosmetic compositions such as foundations To be administered before and/or after administration.

In particular, application of the composition to the skin, especially the facial skin, provides the former with a radiant and healthy glow.

The object of the present invention is also to include in cosmetic compositions in the form of emulsions, as defined according to the invention, at least one scattering filler with a particle size of less than 35 microns, preferably 2 microns to 35 microns, more preferably 11 microns to 17 microns, at least Use of a combination of red or pink nacre, and at least blue nacre, as an agent for improving the radiance of the complexion.

Detailed ways

Scattering filler

The composition according to the invention comprises at least one scattering filler having a particle size of less than 35 microns, preferably from 2 microns to 35 microns, and more preferably from 11 microns to 17 microns.

Particle size is expressed as mean volume diameter (D[0.5]).

In particular, the refractive index of the scattering filler is 1.6 to 2.5, preferably 1.7 to 2.3, and more preferably 1.7 to 2.2.

In particular, the scattering filler is selected from boron nitride, barium sulphate, bismuth oxychloride, aluminum oxide and materials based on titanium oxide with substrates such as talc, mica, barium sulphate, boron nitride, bismuth oxychloride, aluminum oxide, mixtures thereof Composite powder.

In a particular embodiment, the scattering filler is bismuth oxychloride.

In a preferred embodiment, the scattering filler is cluster crystal bismuth oxychloride having a particle size of less than 35 microns, preferably 2 microns to 35 microns, and more preferably 11 microns to 17 microns.

The clustered bismuth oxychloride as mentioned in the present invention can scatter light and thus help to further impart a luminous and glow effect to the skin without a shiny appearance.

As examples of commercial products of bismuth oxychloride we can use the following products: Ronaflair™ ESQ from Merck, Ronaflair LF™-2000 from Merck, Mearlite GLS and Mearlite LBU from BASF Corporation, POL LO from George Uhe Company, Inc., Pearl I and II, and Pearl Supreme UVS, available from Presperse LLC, Pearl-Glo 1085, Pearl-Glo M 1098, Pearl-Glo SF 1099, and Pearl-Glo SF UVR 1060, available from BASF Corporation.

As preferred bismuth oxychloride we use the following products: Ronaflair™ ESQ from Merck, Ronaflair LF™-2000 from Merck, more preferably Ronaflair™ ESQ from Merck.

The content of at least one scattering filler as described above in the composition of the invention is 0.5 to 15 wt%, preferably 1 to 10 wt%, and more preferably 2 to 5 wt%, based on the total weight of the composition.

mother of pearl

The term "nacres" should be understood to mean any form of iridescent or non- iridescent colored particles, especially produced or alternatively synthesized by certain molluscs in their shells, which have a color effect by optical interference .

The composition includes at least red or pink nacre and blue nacre.

Red or pink nacre is nacre that has a red or pink reflective color.

Blue mother-of-pearl is mother-of-pearl with a blue reflective color.

Nacre can be selected from pearlescent pigments such as mica coated with iron oxide, mica coated with bismuth oxychloride, mica coated with titanium oxide or titanium dioxide, mica coated with chromium oxide, mica coated with tin oxide Mica, mica coated with SnO2, mica coated with BaSO4, mica coated with organic dyes, and pearlescent pigments based on bismuth oxychloride. They can also be mica particles on whose surface at least two successive layers of metal oxides and/or organic colorants are superimposed. Preferably, the nacres are white in their appearance, they are preferably formed of mica coated with at least titanium dioxide.

Examples of nacres that may also be mentioned include natural mica coated with titanium oxide, iron oxide, natural pigments or bismuth oxychloride.

As preferred nacres we use mica coated with titanium oxide or titanium dioxide, and mica coated with titanium dioxide and tin oxide.

Among the commercially available nacres, mention may be made of Timica, Flamenco and Duochrome (mica-based) nacres sold by the company BASF, Timiron nacres sold by the company MERCK, Prestige mica-based nacres sold by the company Eckart Nacres, the following nacres based on natural mica: Sunpearl from Sun Chemical, KTZ from Kobo and Sunprizma from Sun Chemical, Sunshine and Sunprizma nacres sold by Sun Chemical based on synthetic mica, and based on The synthetic mica is Timiron Synwhite mother of pearl sold by the company MERCK.

The mother-of-pearl may more particularly have a pink, red, bronze, orange, blue, brown, gold and/or coppery color or reflection.

As examples of nacres that can be used in the context of the present invention, mention may be made of pink-coloured nacres, especially sold by the company BASF under the names Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), sold under the names Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze mother-of-pearl, especially by the company MERCK under the names Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company BASF under the name marketed under the name Super bronze (Cloisonne); orange mother-of-pearl, especially under the names Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) by the company BASF and Passion orange (Colorona) and Matte orange (17449) by the company MERCK ( Microna); red mother-of-pearl, sold especially by the company BASF under the name Summit Red 30D (Flamenco); blue mother-of-pearl, sold especially by the company MERCK under the name Silk Blue (Timiron); hazel Mother-of-pearl, sold especially under the names Nuantique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite) by the company BASF; Red mother-of-pearl, sold especially under the name Sienna fine (17386) (Colorona) by the company MERCK; reddish mother-of-pearl with a light gold color, sold especially under the name Sunstone G012 (Gemtone) by the company BASF; pink pearl mother-of-pearl, sold especially by the company BASF under the name Tan opale G005 (Gemtone); black mother-of-pearl with a light gold color, sold especially by the company BASF under the name Nu antique bronze 240 AB (Timica); blue mother-of-pearl, especially marketed by the company MERCK under the name Matte blue (17433) (Microna); white mother-of-pearl with a light silver tint, sold especially by the company MERCK under the name Xirona Silver; and gold-green-pink-orange mother-of-pearl, sold especially by MERCK company to Indian marketed under the name summer (Xirona), and mixtures thereof.

As an example of red or pink nacre, we can use mother of pearl of pink color, especially manufactured by BASF company as Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and sold under the name Monarch gold 233X (Cloisonne); red mother-of-pearl, sold especially by the company BASF under the name Summit Red 30D (Flamenco); mother-of-pearl with a reddish color, especially sold under the name Sienna fine (17386) (Colorona ) sold under the name ); light red mother-of-pearl with a light gold color, especially sold under the name Sunstone G012 (Gemtone) by the company BASF; pink mother-of-pearl, sold especially under the name Tan opale G005 (Gemtone) by the company BASF ; and mixtures thereof.

As preferred red or pink nacre, we use red nacre, sold in particular under the name Summit Red 30D (Flamenco) by the company BASF.

As an example of blue mother-of-pearl, we can use blue mother-of-pearl, sold especially by the company MERCK under the name SilkBlue (Timiron); blue mother-of-pearl, sold especially under the name Matte blue (17433) (Microna) by the company MERCK marketed; and mixtures thereof.

As preferred blue nacre, we use blue nacre, sold especially under the name Silk Blue (Timiron) by the company MERCK.

Typically, the content of nacre in the composition of the present invention is 1 to 10 wt%, preferably 2 to 8 wt% and more preferably 3 to 6 wt%, based on the total weight of the composition.

Typically, the content of red or pink nacre in the composition of the present invention is 1 to 10 wt%, preferably 2 to 8 wt% and more preferably 3 to 6 wt%, based on the total weight of the composition.

Usually, the content of blue nacre in the composition of the present invention is 0.1 to 1 wt%, preferably 0.2 to 0.5 wt%, based on the total weight of the composition.

For the purposes of the present invention, the weight ratio of said at least one scattering filler to said at least red or pink nacre is from about 20:1 to about 1:20, preferably from about 5:1 to about 1:5.

The weight ratio of the at least red or pink nacre to the at least blue nacre is from about 10:1 to about 1:10, preferably from about 5:1 to about 1:3.

In a particular embodiment, the scattering filler and nacre are greater than 80% by weight of the total amount of colored particles of the composition, in particular greater than 90%, greater than 95%, greater than 98% , by weight of the total amount of colored particles of the composition.

Galenic form

The present invention relates to a cosmetic composition, especially of emulsion type, which may be in the form of a composition for the care and/or makeup of keratinous materials, in particular the skin, or in the form of a sun protection composition.

It may then be in colorless or low-color form, optionally containing cosmetically or dermatologically active agents. It can then be used as a care or makeup base for keratinous materials, especially skin.

The composition according to the invention may also be in the form of colored products for making up keratin materials, especially for making up the skin, such as foundations, concealers, skin tones, especially applied to the face or neck Complexion corrector, tinted cream or body makeup composition.

In particular, the composition of the invention is in the form of a low color value, preferably a cosmetic base.

The compositions according to the invention may be in various forms, in particular in the form of anhydrous compositions, dispersions or emulsions, such as water/oil or oil/water emulsions or multiple emulsions, among others.

The compositions of the invention are preferably emulsions, in particular direct or inverse emulsions, or anhydrous compositions.

Preferably it is an emulsion.

Dispersions can be made into an aqueous phase or into an oily phase.

Emulsions can have an oil or water continuous phase. Such emulsions may be, for example, inverse (W/O) emulsions or direct (O/W) emulsions, or alternatively multiple emulsions (W/O/W or O/W/O).

In the case of emulsions, direct (O/W) emulsions are preferred.

In particular, the composition according to the invention may be in the form of an oil-in-water (O/W) emulsion, a water-in-oil (W/O) emulsion, or a multiple emulsion, preferably an oil-in-water (O/W) emulsion.

The composition according to the invention can form a makeup base composition, or a care and/or make-up composition, or a composition to be applied under or on top of another make-up and/or care composition, with a small amount of touching way to unify the complexion.

In the case where the composition according to the invention is a care and/or makeup base, it will advantageously be unpigmented or to a very low degree pigmented, which allows the use of A combination of scattering filler and nacre according to the invention is used. This care and/or make-up base can be applied to the entire face, followed by the care composition and/or make-up composition. According to another embodiment, before (bottom) or after (top) application of a layer of care or makeup composition (foundation) or after application of a layer of care or makeup composition (foundation), The treatment and/or makeup base is applied as a touch makeup.

According to a particular embodiment, the composition is applied in touches to areas of the face showing skin defects; this application may be performed before or after the subsequent application of foundation . According to another particular embodiment, it can be applied around the eyes to brighten the eye area, or above the lips, on Cupid's bow to give curves a shape.

According to a particular embodiment, said composition is applied to a person whose skin has visible and/or tactile unevenness and/or heterogeneity of skin tone.

According to a particular embodiment of the invention, said composition is applied to persons with oily skin.

According to another particular embodiment of the invention, said composition is applied to persons with aged or mature skin.

According to another particular embodiment of the invention, said composition is applied to a person with Asian skin.

Physiologically acceptable medium

In addition to the previously indicated compounds, the compositions according to the invention comprise a physiologically acceptable medium.

The term "physiologically acceptable medium" is intended to mean a medium which is particularly suitable for applying the composition according to the invention to the skin.

The physiologically acceptable medium is generally suitable to the nature of the vehicle on which the composition will be administered, and to the form in which the composition is packaged.

The compositions of the invention may be dispersions or emulsions.

Dispersions can be made into an aqueous phase or into an oily phase.

Emulsions can have an oil or water continuous phase. Such emulsions may be, for example, inverse (W/O) emulsions or direct (O/W) emulsions, or alternatively multiple emulsions (W/O/W or O/W/O).

In the case of emulsions, direct (O/W) emulsions are preferred.

water box

Compositions according to the invention may comprise an aqueous phase.

The aqueous phase includes water. Water suitable for use in the present invention may be flower water such as cornflower water and/or mineral water such as Vittel water, Lucas water or La Roche Posay water and/or spring water.

The aqueous phase may also comprise water-miscible organic solvents (at room temperature: 25° C.), such as monohydric alcohols containing 2 to 6 carbon atoms, such as ethanol or isopropanol; polyols, especially containing 2 to 20 carbon atoms , preferably containing 2 to 10 carbon atoms and preferably containing 2 to 6 carbon atoms, such as glycerol, propylene glycol, butanediol, pentanediol, hexanediol, dipropylene glycol or diethylene glycol; glycol ethers ( Especially containing 3 to 16 carbon atoms) such as propylene glycol, dipropylene glycol, tripropylene glycol (C1-C4) alkyl ethers, mono-, di- or triethylene glycol (C1-C4) alkyl ethers, and mixtures thereof.

The aqueous phase may also include stabilizers such as sodium chloride, magnesium dichloride or magnesium sulfate.

The aqueous phase may also include any water-soluble or water-dispersible compound compatible with the aqueous phase, for example, gelling agents, film-forming polymers, thickeners or surfactants, and mixtures thereof.

In particular, the composition of the invention may comprise an aqueous phase in an amount of 1% to 80% by weight, especially 5% to 50% by weight, more particularly 10% to 45% by weight, relative to the total weight of the composition.

fatty phase

The cosmetic composition according to the invention may comprise at least one liquid and/or solid fatty phase.

According to one embodiment, the composition according to the invention is in the form of an emulsion.

In particular, the composition of the invention may comprise at least one liquid fatty phase, especially at least one oil listed below.

The term "oil" refers to any fatty substance which is liquid at room temperature (20-25°C) and at atmospheric pressure.

The composition of the present invention may comprise a liquid fatty phase in an amount of 1% to 90%, in particular 5% to 80%, in particular 10% to 70%, more in particular 20% to 50%, by weight, relative to in the total weight of the composition.

The oil phase suitable for the preparation of cosmetic compositions according to the invention may comprise hydrocarbon-based oils, silicone oils, fluorinated or non-fluorinated oils, or mixtures thereof.

Oils can be volatile or non-volatile.

They can be of animal, vegetable, inorganic or synthetic origin.

The term "fixed oil" refers to an oil which remains on the skin or keratin fibers at room temperature and atmospheric pressure. More specifically, the evaporation rate of the fixed oil is strictly less than 0.01 mg/cm2/min.

To measure this evaporation rate, 15 grams of the oil or oil mixture to be tested are placed in a 7 cm diameter crystallization dish, which is placed on a balance in a large chamber of about 0.3 cubic meters, the temperature of which is regulated To a temperature of 25°C, the humidity was adjusted to 50% relative humidity. The liquid is allowed to evaporate freely without stirring it, while ventilation is provided by a fan (Papst-Motoren, reference 8550 N, rotating at 2700 rpm) placed in the air containing the oil or the mixture In the vertical position above the crystallization dish, the fan blades are facing the crystallization dish, 20 cm away from the bottom of the crystallization dish. Periodically measure the mass of oil remaining in the crystallization dish. Evaporation rate is expressed in milligrams of oil evaporated per unit area (cm2) and per unit time (minutes).

The term "volatile oil" refers to any non-aqueous medium which is capable of evaporating when in contact with the skin or lips in less than 1 hour at room temperature and atmospheric pressure. Essential oils are cosmetic volatile oils which are liquid at room temperature. More specifically, the evaporation rate of the volatile oil is 0.01 to 200 mg/cm2/min inclusive.

For the purposes of the present invention, the term "silicone oil" means an oil comprising at least one silicon atom, and especially at least one Si-O group.

The term "fluorinated oil" refers to an oil that includes at least one fluorine atom.

The term "hydrocarbon-based oil" refers to an oil which mainly contains hydrogen and carbon atoms.

The oil may optionally include oxygen, nitrogen, sulfur and/or phosphorus atoms, for example in the form of hydroxyl or acid groups.

Volatile oil

The volatile oil may be selected from hydrocarbon-based oils containing 8 to 16 carbon atoms, and especially C8-C16 branched chain alkanes (also known as isoparaffins), such as isododecane (also known as 2,2,4,4,6-penta methylheptane), isodecane and isohexadecane, such as the oils sold under the trade names Isopar® or Permethyl®.

Volatile oils which may also be used include volatile silicones, such as volatile linear or cyclic silicone oils, especially those having a viscosity less than or equal to 8 centistokes (cSt) (8 x ^10-6 square meters per second), and especially those containing 2 These siloxanes optionally contain alkyl or alkoxy groups having 1 to 10 carbon atoms, and in particular 2 to 7 silicon atoms. As volatile silicone oils that can be used in the present invention, mention may be made especially of polydimethylsiloxane with a viscosity of 5 to 6 cSt, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecylcyclopentasiloxane, Methylcyclohexyltrisiloxane, Heptamethylhexyltrisiloxane, Heptamethyloctyltrisiloxane, Hexamethyldisiloxane, Octamethyltrisiloxane, Decamethyltetrasiloxane and dodecamethylpentasiloxane, and mixtures thereof.

According to one embodiment, the composition of the present invention may comprise 1 wt % to 80 wt %, or even 5 wt % to 70 wt %, or even 10 wt % to 60 wt % and especially 15 wt % to 50 wt %, relative to the total weight.

non-volatile oil

The non-volatile oil may especially be chosen from non-volatile hydrocarbon-based oils, fluorinated oils and/or silicone oils.

Non-volatile hydrocarbon-based oils which may especially be mentioned include:

- hydrocarbon-based oils of animal origin, such as perhydrosqualene,

- Hydrocarbon-based oils of vegetable origin, such as phytosterol esters, such as phytosterol oleate, phytosterol isostearate and lauryl/octyldodecyl/phytosterol glutamate (Ajinomoto, Eldew PS203), triglycerides formed from fatty acid esters of glycerol, in particular where the fatty acids may have chain lengths from C4 to C36, especially C18 to C36, these oils may be linear or branched, and saturated or unsaturated ; these oils may be, inter alia, heptanoic or caprylic triglycerides, shea butter, alfalfa oil, poppy seed oil, winter squash oil, millet oil, barley oil, quinoa oil, rye oil, candal oil, tomato Lotus Oil, Shea Butter, Aloe Vera Oil, Sweet Almond Oil, Peach Kernel Oil, Peanut Oil, Argan Oil, Avocado Oil, Kapok Oil, Borage Seed Oil, Broccoli Oil, Calendula Oil, Camelina Oil, Mustard Flower Oil, Carrot Oil, Safflower Oil, Flaxseed Oil, Canola Oil, Cottonseed Oil, Coconut Oil, Marrow Seed Oil, Wheat Germ Oil, Jojoba Oil, Lily Flower Oil, Macadamia Oil, Corn Oil, White Pond Seed Oil , St. John's Wort Oil, Gardenia Oil, Hazelnut Oil, Almond Oil, Walnut Oil, Olive Oil, Evening Primrose Oil, Palm Oil, Black Currant Seed Oil, Kiwi Seed Oil, Grape Seed Oil, Pistachio Seed oil, winter squash oil, pumpkin oil, musk rose oil, sesame oil, soybean oil, sunflower oil, castor oil and watermelon seed oil, and mixtures thereof, or alternatively caprylic/capric triglycerides, such as sold by the company Stearineries Dubois or those marketed by the company Dynamit Nobel under the name Miglyol 810®, 812® and 818®,

- linear or branched hydrocarbons of inorganic or synthetic origin, such as liquid paraffins and their derivatives, petrolatum, polydecene, polybutene, hydrogenated polyisobutene such as Parleam, and squalane;

- synthetic ethers containing 10 to 40 carbon atoms;

- synthetic esters, such as oils of formula R1COOR2, wherein R1 is a linear or branched fatty acid residue containing 1 to 40 carbon atoms, R2 is a hydrocarbyl chain, especially branched, containing 1 to 40 carbon atoms, Provided that the sum of the number of carbon atoms in chains R1 and R2 is greater than or equal to 10. Esters may be chosen especially from fatty acid esters of alcohols, such as cetearyl caprylate, isopropanol esters, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate , isopropyl stearate, isopropyl isostearate, isostearyl isostearate, octyl stearate, hydroxylated esters such as isostearyl lactate, octyl hydroxystearate, Diisopropyl adipate, enanthate, and especially isostearyl heptanoate, alcohol or polyol caprylate, caprate, or ricinoleate, such as propylene glycol dicaprylate, cetyl caprylate Alcohol Esters, Tridecyl Octanoate, 2-Ethylhexyl 4-Diheptanoate, 2-Ethylhexyl Palmitate, Alkyl Benzoate, Polyethylene Glycol Di Heptanoate, Propylene Glycol 2-Diethylhexanoate, and mixtures thereof, C12-C15 Alcohol Benzoate, Hexyl Laurate, Neopentanoate, such as Isodecyl Neopentanoate, Isotridecyl Neopentanoate Alkyl esters, isostearyl neopentanoate, octyldodecyl neopentanoate, isononanoates such as isononyl isononanoate, isotridecyl isonononanoate, octyl isonononanoate Esters, hydroxylated esters such as isostearyl lactate and diisostearyl malate,

- polyol and pentaerythritol esters, such as dipentaerythritol tetrahydroxystearate/tetraisostearate,

- Esters of diol dimers and diacid dimers, such as Lusplan DD-DA5® and Lusplan DD-DA7®, sold by Nippon Fine Chemical and described in patent application US 2004-175 338,

- Copolymers of diol dimer and diacid dimer and their esters, such as dilinoleyl diol dimer/dilinoleic dimer (dilinoleyl diol dimer/dilinoleic dimer) copolymers and their esters , such as Planool-G,

- copolymers of polyols and diacid dimers, and esters thereof, such as Hailuscent ISDA or dilinoleic acid/butylene glycol copolymers,

- fatty alcohols which are liquid at room temperature and have a branched and/or unsaturated carbon-based chain containing 12 to 26 carbon atoms, for example 2-octyldodecanol, isostearyl alcohol, oleyl alcohol , 2-hexyldecanol, 2-butyloctanol and 2-undecylpentadecanol;

- C12-C22 higher fatty acids, such as oleic acid, linoleic acid or linolenic acid, and mixtures thereof,

- dialkyl carbonates, the two alkyl chains may be the same or different, such as dioctyl carbonate, sold by Cognis under the name Cetiol CC®,

- oils of high molar mass, in particular a molar mass of from about 400 to about 10000 g/mol, especially from about 650 to about 10000 g/mol, especially from about 750 to about 7500 g/mol, more particularly from about 1000 to About 5000 g/mol. As high molar oils which can be used according to the invention, mention may especially be made of oils selected from the group consisting of:

* lipophilic polymers,

*Linear fatty acid esters with a total carbon number of 35 to 70,

*Hydroxylated esters,

*aromatic esters,

*C24-C28 branched fatty acid or fatty alcohol ester,

*Silicone oil,

* Oils of vegetable origin, and

* mixtures thereof;

- optionally partially hydrocarbyl and/or silicone fluorinated oils, such as fluorosilicone oils, fluoropolyethers and fluorosilicones, as described in document EP-A-847752;

- Silicone oils, such as linear or cyclic non-volatile polydimethylsiloxanes (PDMS); polydimethylsiloxanes, including alkyl, alkoxy or phenyl, which are pendant or in silicon The end of the ketone chain, these groups contain 2 to 24 carbon atoms; phenylsiloxane polymers such as phenyl trimethicone, phenyl dimethicone, phenyl trimethicone Siloxydiphenylsiloxane, Diphenyldimethicone, Diphenylmethyldiphenyltrisiloxane, and 2-Phenylethyltrimethylsiloxysilicate, and

- mixtures thereof.

According to a particular embodiment, the fatty phase of the composition according to the invention may comprise only volatile compounds.

additive

In a particular embodiment, the cosmetic composition according to the invention also comprises at least one compound selected from the group consisting of water, hydrophilic solvents, lipophilic solvents, oils, and mixtures thereof.

The cosmetic composition according to the invention may also comprise any additives usually used in the field concerned, for example selected from gums, anionic, cationic, amphoteric or nonionic surfactants, silicone surfactants, resins , thickeners, structuring agents such as waxes, dispersants, antioxidants, essential oils, preservatives, fragrances, neutralizers, preservatives, UV-screening agents, cosmetic active agents such as vitamins, humectants, emollients Skin agents or collagen-protecting agents, and mixtures thereof.

It is a matter of routine for a person skilled in the art to adjust the nature and amount of additives present in the compositions according to the invention so as not to thereby affect their desired cosmetic and stabilizing properties.

additional colorants

The compositions according to the invention may also comprise at least one colorant. The cosmetic composition according to the invention may advantageously incorporate at least one colorant selected from the group consisting of organic or inorganic colorants, in particular pigments as conventionally used in cosmetic compositions, which may be fat-soluble or water-soluble , and mixtures thereof.

In particular, an additional inorganic colorant is titanium dioxide, which is used to improve the coverage properties on the skin.

In particular, additional organic pigments are used to give a better appearance to the product.

The content of additional colorants may be 0.001 to 5%, preferably 0.01 to 2%, and more preferably 0.5 to 2%.

The term "pigments" is understood to mean white or colored, inorganic or organic particles, which are insoluble in aqueous solutions and which are intended to impart color and/or opacity to the resulting film.

As inorganic pigments that can be used in the present invention, mention may be made of titanium oxide or titanium dioxide, zirconium oxide or cerium oxide, but also zinc oxide, iron oxide or chromium oxide, ferric blue, manganese violet, ultramarine blue and chromium hydrate. As preferred inorganic pigments, mention may be made of titanium dioxide, iron oxides and mixtures thereof.

Preferably, the inorganic pigment is titanium dioxide.

The titanium dioxide can be, for example, surface-treated titanium dioxide. A non-limiting example of a surface-treated titanium dioxide suitable for use in the present invention may be titanium dioxide surface-treated with a C9-15 fluoroalcohol phosphate and/or further treated with a metal oxide.

Preferably, mention may be made of titanium dioxide surface-treated with C9-C15 fluoroalcohol phosphate, sold by Daito Kasei Kogyo under the trade name PF-5 TiO2 CR-50, or surface-treated with C9-C15 fluoroalcohol phosphate Titanium dioxide sold under the tradename PFX-5 TiO2 CR-50 by Daito Kasei Kogyo.

Among the organic pigments that can be used in the present invention, mention may be made of carbon black, pigments of the D&C type, lakes based on cochineal carmine or on barium, strontium, calcium or aluminum, or alternatively diketones Dipyrrolopyrrole (DPP) as described in documents EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/08537.

Those with the following names are among the organic pigments which may especially be mentioned: D&C Blue No. 4, D&C Brown No. 1, D&C Green No. 5, D&C Green No. 6, D&C Orange No. 4, D&C Orange No. . 5, D&C Orange No. 10, D&C Orange No. 11, D&C Red No. 6, D&C Red No. 7, D&C Red No. 17, D&C Red No. 21, D&C Red No. 22, D&C Red No. 27 , D&C Red No. 28, D&C Red No. 30, D&C Red No. 31, D&C Red No. 33, D&C Red No. 34, D&C Red No. 36, D&C Purple No. 2, D&C Yellow No. 7, D&C Yellow No. 8, D&C Yellow No. 10, D&C Yellow No. 11, FD&C Blue No. 1, FD&C Green No. 3, FD&C Red No. 40, FD&C Yellow No. 5, FD&C Yellow No. 6, D&C Black 2 (carbon black) and phthalocyanine blue, and mixtures thereof.

The cosmetic compositions according to the invention may also comprise water-soluble or fat-soluble dyes. Fat-soluble dyes, for example, Sudan Red, DC Red 17, DC Green 6, β-Carotene, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5, and Quinoline Yellow. Water-soluble dyes are, for example, beetroot juice and caramel. According to a particular embodiment, the composition according to the invention comprises at least one particular colorant selected from the group consisting of: goniochromatic colorants, photochromic colorants, fluorescent agents, optical brighteners, lakes , organic pigments, composite pigments, and mixtures thereof.

filler

The composition according to the invention may also comprise at least one filler of organic or inorganic nature.

Typically, fillers are present in the compositions of the invention in an amount of 0.1 to 20 wt%, preferably 0.5 to 10 wt%, and more preferably 1 to 5 wt%, by weight of the composition.

In a particular embodiment, the filler is present in an amount of less than 5 wt%, preferably less than 3 wt%, by weight of the composition.

The term "filler" is understood to mean colorless or white solid particles of any shape, which are insoluble and dispersed in the medium of the composition. They are inorganic or organic in nature and make it possible to impart softness and matteness to the composition and a uniform cosmetic result.

The fillers used in the composition according to the invention may be in the form of flakes, pellets or spheres, in the form of fibers or in any other intermediate form between these specified forms.

The fillers according to the invention may or may not be surface-coated, in particular they may be surface-treated with siloxanes, amino acids, fluorinated derivatives or any other substance which facilitates the dispersion and compatibility of the filler in the composition.

Among the inorganic fillers that can be used in the composition according to the invention, mention may be made of talc, mica, silica, trimethylsiloxysilicate, kaolin, bentonite, calcium carbonate, magnesium bicarbonate, hydroxyphosphorus Limestone, boron nitride, hollow silica microspheres (silica beads, from Maprecos), glass or ceramic microcapsules, silica-based fillers such as Aerosil 200 or Aerosil 300; Sunsphere H-33 and Sunsphere H- 51, sold by Asahi Glass; Chemicelen sold by Asahi Chemical; composite materials of silica and titanium dioxide, such as TSG series sold by Nippon SheetGlass, and mixtures thereof.

Fillers suitable for the present invention may preferably be talc, silica, or mixtures thereof.

Among the organic fillers that can be used in the composition according to the invention, mention may be made of polyamide powders (Nylon® Orgasol from Atochem), poly-beta-alanine and polyethylene powders, polytetrafluoroethylene (Teflon® ) powder, lauroyl lysine, starch, tetrafluoroethylene polymer powder, hollow polymer microspheres, such as Expancel (Nobel Industrie), derived from 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms Metal soaps of organic carboxylic acids, such as zinc stearate, magnesium stearate or lithium stearate, zinc laurate, magnesium myristate, Polypore® L 200 (Chemdal Corporation), silicone resin microbeads (Tospearl®, obtained from From Toshiba, for example), powders of polyurethanes, in particular of crosslinked polyurethanes comprising copolymers comprising trimethylol caprolactone, for example hexamethylene diisocyanate/trimethylol Caprolactone polymers, sold by the company Toshiki under the names Plastic Powder D-400® or Plastic Powder D-800®, carnauba microcrystalline waxes, such as those sold under the name MicroCare 350® by the company Micro Powders, synthetic waxes microcrystalline waxes such as those sold by Micro Powders under the name MicroEase 114S®, microcrystalline waxes consisting of a mixture of carnauba wax and polyethylene wax, such as those sold by MicroPowders under the names MicroCare 300® and 310® Microcrystalline waxes consisting of a mixture of carnauba wax and synthetic waxes, such as that sold under the name MicroCare 325® by the company MicroPowders, polyethylene microcrystalline waxes, such as Micropoly 200®, 220®, 220L® and 250S® those sold by the company Micro Powders; and mixtures thereof.

UV sunscreen ingredients

The screening compositions according to the invention comprise organic and/or inorganic UV sunscreen ingredients, which are active in the UV-A and/or UV-B region, which are hydrophilic and/or lipophilic.

Hydrophilic and/or lipophilic organic UV sunscreen ingredients are chosen in particular from dibenzoylmethane derivatives; cinnamic derivatives; salicylic derivatives; benzophenone derivatives; - Diphenylacrylate derivatives; p-aminobenzoic acid (PABA) derivatives; and mixtures thereof.

As examples of organic UV sunscreen ingredients, mention may be made of the following, indicated by their INCI names:

- p-aminobenzoic acid derivatives:

-PABA,

- Ethyl PABA,

-Ethyldihydroxypropyl PABA,

- Ethylhexyldimethyl PABA, sold in particular by ISP under the trademark "Escalol 507",

- Glyceryl PABA,

-Dibenzoylmethane derivatives:

- Butylmethoxydibenzoylmethane, sold in particular under the trademark "Parsol 1789" by Hoffmann-LaRoche,

- Isopropyldibenzoylmethane,

- Salicylic acid derivatives:

- Homosalate, sold under the trademark "Eusolex HMS" by Rona/EM Industries,

- Ethylhexyl salicylate, marketed under the trademark "Neo Heliopan OS" by Haarmann and Reimer,

- dipropylene glycol salicylate, marketed under the trademark "Dipsal" by Scher,

- Triethanolamine salicylate, marketed under the trademark "Neo Heliopan TS" by Haarmann and Reimer,

- Cinnamon Derivatives:

- ethylhexyl methoxycinnamate, sold in particular by Hoffmann-LaRoche under the trademark "Parsol MCX",

- Isopropyl methoxycinnamate,

- Isoamyl methoxycinnamate, sold under the trademark "Neo Heliopan E 1000" by Haarmann and Reimer,

- Cinoxate,

-Methoxycinnamic acid DEA salt,

-Diisopropyl Methylcinnamate,

- Glyceryl Ethylhexanoate Dimethoxycinnamate,

-β,β-Diphenylacrylate derivatives:

- Otoquire, marketed in particular by BASF under the trademark "Uvinul N539",

- Relying on LEELIN, especially marketed by BASF under the trademark "Uvinul N35",

- Benzophenone derivatives:

- Benzophenone-1, marketed by BASF under the trademark "Uvinul 400",

- Benzophenone-2, marketed by BASF under the trademark "Uvinul D50",

- benzophenone-3 or oxybenzone, marketed by BASF under the trademark "Uvinul M40",

- Benzophenone-4, marketed by BASF under the trademark "Uvinul MS40",

- Benzophenone-5,

- Benzophenone-6, marketed by Norquay under the trademark "Helisorb 11",

and its mixture.

Preferred UV sunscreen ingredients are selected from cinnamic acid derivatives, β,β-diphenylacrylate derivatives, salicylic acid derivatives, and mixtures thereof.

Preferred UV sunscreen ingredients are especially selected from the group consisting of ethylhexyl methoxycinnamate, otocquirel and ethylhexyl salicylate, and mixtures thereof.

Mention may especially be made of: ethylhexyl methoxycinnamate, sold under the trade name UVINUL MC 80® by the company BASF; ethylhexyl salicylate, sold under the trade name NEO HELIOPAN OS® by the company SYMRISE and Otoquire, marketed under the tradename NEO HELIOPAN 303® by the company SYMRISE.

Compositions according to the invention may comprise 0.1 to 30 wt%, such as 0.5 to 20 wt%, such as 1 to 15 wt%, and such as at least 1 wt%, of UV sunscreen ingredients, relative to the total weight of the composition.

Example

Example 1: Emulsion O/W with combination of the invention.

Good examples, after research, are pinkish-white in appearance, capable of delivering a very healthy glowing optical effect.

Mutually INCI name Raw material % by weight A water Qsp 100 A Glycerol (glycerol, 99.8% PF from Emery Oleochemicals LLC) 8 A preservative 0.8 A Propylene Glycol (Propylene Glycol USP/EP from Dow Chemical) 8 A Disodium EDTA (Versene™ Na2 crystals from Dow Chemical) 0.05 A Potassium Cetyl Phosphate (Amphisol® K from DSM Nutritional Products, Inc.) 1 A Carbopol (Carbopol® 980 polymer from Lubrizol) 0.3 A Xanthan Gum (Keltrol® CG from CG-T Kelco) 0.1 A Cyclohexasiloxane (Xiameter® PMX-0246 Cyclohexasiloxane from Dow Corning®) 6 A Triethanolamine (Tirethanolamine 99% (TEA 99) from Dow Chemical) 0.3 B Stearic acid (Palmera® B1802CG from Klk Oleo) 2 B Glyceryl Stearate (and) PEG-100 Stearate (Simulsol™ 165 from Seppic) 1.5 B Cetyl alcohol (Ecorol 16/98 from Ecogreen Oleochemicals) 0.7 B Polydimethylsiloxane (Viscosity: 350cSt, Xiameter® PMX-200 Silicon Fluid 350CS from DowCorning®) 0.5 B Octyldodecanol (Eutanol® G from Cognis (BASF)) 4 B Ethylhexyl methoxycinnamate (Parsol® MCX from DSM Nutritional Products) 7.5 B Triethanolamine (Tirethanolamine 99% (TEA 99) from Dow Chemical) 0.4 B Phenoxyethanol (Sepicide LD from Seppic) 0.7 B Cyclohexasiloxane (Xiameter® PMX-0246 Cyclohexasiloxane from Dow Corning®) 1 B Titanium dioxide (and) C9-15 fluoroalcohol phosphate (and) aluminum hydroxide (PFX-5 TiO2 CR-50 from Daito KaseiKogyo) 1 C Mica (and) titanium dioxide (Flamenco® Summit Red R30D from BASF) 4 C Titanium dioxide (and) mica (Timiron® Silk Blue from Merck) 0.3 C Bismuth oxychloride (RonaFlair™ ESQ from Merck) 2.7 C Talc (Luzenac® Pharma M from Luzenac) 0.5 C Silica (Solesphere® H-51 from AGC SI-TECH) 0.5 D. Red 4 (Unicert red 07004-J from Sensient Cosmetic Technologies) 0.005 D. Yellow 5 (Unicert yellow 08005-J from Sensient Cosmetic Technologies) 0.0038 E. spices 0.25

Preparation.

Heating Phase A to about 75°C and combining the ingredients therein;

Prepare Phase B and heat to about 75°C;

Mix phases A and B and stir the mixture with a Rayneri until a homogeneous emulsion is obtained;

The remaining phases were combined into the emulsion and the mixture was stirred until it cooled.

Evaluation Methodology and Results

The composition of the present invention of Example 1 was applied to the skin of 30 Asian women. The results after application were evaluated by 3 experts immediately after application of the composition.

evaluation result

Immediately after application, the results showed:

- Significant improvement in luminosity +29.5%(p<0.01); - Significant improvement in clarity (brightness) +15.5%(p<0.01); -- Significantly improved transparency +8.5%(p<0.01); - significantly reduced olive component -7.1% (p<0.01) - Significantly reduced yellow component -18.9% (p<0.01); - Significantly increased pink component +16.9% (p<0.01).

Changes in other color components that mainly represent skin tone are as follows:

-Significant change in brown component -11.0% (p<0.01); -Significant change in beige component -10.6% (p<0.01); - Significant change in beige component -10.4% (p<0.01);

These changes indicate that the composition of Example 1 significantly brightens skin tone immediately after application.

All these data already show a significant improvement in skin luminosity immediately after application of the composition of Example 1.

All studied indicators (L, B, T, olive, yellow, and pink) are in the desired direction.

Example 2: Effect of the combination of the invention.

Three comparative examples were prepared in order to evaluate the effects, compared with the present invention of Example 1.

Mutually INCI name Raw material % by weight Raw material % by weight Raw material % by weight Comparative Example 1 Comparative Example 2 Comparative Example 3 A water Qsp 100 Qsp 100 Qsp 100 A Glycerol (glycerol, 99.8% PF from EmeryOleochemicals LLC) 8 8 8 A preservative 0.8 0.8 0.8 A Propylene Glycol (Propylene Glycol USP/EP from DowChemical) 8 8 8 A Disodium EDTA (Versene™ Na2 crystals from Dow Chemical) 0.05 0.05 0.05 A Potassium cetyl phosphate (Amphisol® K from DSM Nutritional Products, Inc.) 1 1 1 A Carbopol (Carbopol® 980 polymer from Lubrizol) 0.3 0.3 0.3 A Xanthan Gum (Keltrol® CG from CG-T Kelco) 0.1 0.1 0.1 A Cyclohexasiloxane (Xiameter® PMX-0246Cyclohexasiloxane from Dow Corning®) 6 6 6 A Triethanolamine (Tirethanolamine 99% (TEA99) from Dow Chemical) 0.3 0.3 0.3 B Stearic acid (Palmera® B1802CG from KlkOleo) 2 2 2 B Glyceryl Stearate (and) PEG-100 Stearate (Simulsol™ 165 from Seppic) 1.5 1.5 1.5 B Cetyl alcohol (Ecorol 16/98 from EcogreenOleochemicals) 0.7 0.7 0.7 B Polydimethylsiloxane (Viscosity: 350cSt, Xiameter® PMX-200 Silicon Fluid 350CS from Dow Corning®) 0.5 0.5 0.5 B Octyldodecanol (Eutanol® G from Cognis (BASF)) 4 4 4 B Ethylhexyl methoxycinnamate (Parsol® MCX from DSM Nutritional Products) 7.5 7.5 7.5 B Triethanolamine (Tirethanolamine 99% (TEA99) from Dow Chemical) 0.4 0.4 0.4 B Phenoxyethanol (Sepicide LD from Seppic) 0.7 0.7 0.7 B Cyclohexasiloxane (Xiameter® PMX-0246 Cyclohexasiloxane from Dow Corning®) 1 1 1 B Titanium dioxide (and) C9-15 fluoroalcohol phosphate (and) aluminum hydroxide (PFX-5 TiO2 CR-50 from DaitoKasei Kogyo) 6.993 1 1 B Iron oxide (and) C9-15 fluoroalcohol phosphate (PFX-5Sunpuro yellow C33-9001 obtained from Daito KaseiKogyo) 0.805 0 0 B Iron oxide (and) C9-15 fluoroalcohol phosphate (PFX-5Sunpuro black C33-7001 from Daito KaseiKogyo) 0.042 0 0 B Iron oxide (and) C9-15 fluoroalcohol phosphate (PFX-5Sunpuro red C33-8001, obtained from Daito KaseiKogyo) 0.16 0 0 C Mica (and) titanium dioxide (Flamenco® SummitRed R30D from BASF) 0 0 4 C Titanium dioxide (and) mica (Timiron® SilkBlue from Merck) 0 0 0 C Bismuth oxychloride (RonaFlair™ ESQ from Merck) 0 2.7 2.7 C Talc (Luzenac® Pharma M from Luzenac) 0.5 0.5 0.5 C Silica (Solesphere® H-51 from AGCSI-TECH) 0.5 0.5 0.5 D. Red 4 (Unicert red 07004-J from Sensient Cosmetic Technologies) 0.005 0.005 0.005 D. Yellow 5 (Unicert yellow 08005-J obtained from Sensient Cosmetic Technologies) 0.0038 0.0038 0.0038 E. spices 0.25 0.25 0.25

Preparation.

Heating Phase A to about 75°C and combining the ingredients therein;

Prepare Phase B and heat to about 75°C;

Mix phases A and B and stir the mixture with a Rayneri until a homogeneous emulsion is obtained;

The remaining phases were combined into the emulsion and the mixture was stirred until it cooled.

Evaluation Methodology and Results

The compositions of Example 1, Comparative Examples 1, 2 and 3 were applied to the skin of 6 Asian women. The results after application were evaluated by 2 experts.

The brightening and healthy glow effect produced by the present invention is the total effect of lightening, anti-yellowing and whitening effects on the skin.

The test results are shown in the table below.

Test Results Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Brightening effect on the skin 3 3 4 3 Anti-yellowing skin tone 3 2 1 1 Brightening effect on the skin 4 2 4 4 Brightening and healthy glowing effect on the skin 4 2 2 3

5: very high effect;

4: High effect;

3: medium effect;

2: low effect;

1: No effect.

Claims (16)

1. A cosmetic composition for the care and/or makeup of keratinous materials comprising the following components in a physiologically acceptable medium: (a) at least one scattering filler which is a cluster-structured scattering filler with a particle size of less than 35 micrometers, (b) at least red or pink mother-of-pearl, and (c) at least one blue mother-of-pearl, Wherein said at least one red nacre or blue nacre is selected from mica coated with iron oxide, mica coated with bismuth oxychloride, mica coated with chromium oxide, mica coated with _SnO2 , Mica coated with BaSO ₄ , mica coated with titanium oxide or titanium dioxide, mica coated with organic dyes and pearlescent pigments based on bismuth oxychloride, superposed on its surface at least two successive layers of metal oxides and/or Mica particles of organic colorants, and mixtures thereof, wherein the weight ratio of said at least one scattering filler to said at least red nacre is 20:1 to 1:20, Wherein the weight ratio of the at least red nacre to the at least blue nacre is 10:1 to 1:10. 2. The cosmetic composition of claim 1, wherein the scattering filler has a refractive index of 1.6 to 2.5. 3. The composition according to claim 1, wherein said at least one scattering filler is selected from the group consisting of boron nitride, barium sulfate, bismuth oxychloride, aluminum oxide and composite powders based on titanium dioxide and a substrate, and mixtures thereof. 4. The composition according to claim 3, wherein said substrate is selected from the group consisting of talc, mica, barium sulfate, boron nitride, bismuth oxychloride, aluminum oxide. 5. The cosmetic composition of claim 1, wherein said at least one scattering filler is bismuth oxychloride. 6. The cosmetic composition of claim 1, wherein the content of the at least one scattering filler in the composition is 0.5% to 15%, based on the total amount of the composition. 7. The cosmetic composition of claim 1, wherein the content of the at least red or pink nacre in the composition is 1 to 10% by weight, based on the total amount of the composition. 8. The cosmetic composition of claim 1, wherein said at least blue nacre is present in the composition in an amount of 0.05 to 1% by weight, based on the total amount of said composition. 9. Cosmetic composition according to claim 1, characterized in that it is in the form of an emulsion. 10. The cosmetic composition of claim 1, further comprising at least one additional colorant. 11. The cosmetic composition of claim 10, wherein said at least one additional colorant is selected from the group consisting of angular difference colorants, photochromic colorants, fluorescers, optical brighteners, lakes, organic pigments, composite pigments, and its mixture. 12. Cosmetic composition according to claim 10 or 11, wherein said at least one colorant is present in the composition in an amount of 0.001 to 5%. 13. The cosmetic composition of claim 1, further comprising at least one additional filler. 14. The cosmetic composition of claim 1, further comprising at least one UV sunscreen ingredient. 15. Method for caring for and/or making up keratinous materials, comprising applying to keratinous materials a composition as defined in any one of claims 1-14. 16. Use of a combination of at least a cluster structure scattering filler with a particle size of less than 35 microns, at least a red nacre, and at least a blue nacre in a cosmetic composition for improving the radiance and luminous effect of skin color, wherein the at least A red nacre or blue nacre selected from mica coated with iron oxide, mica coated with bismuth oxychloride, mica coated with chromium oxide, mica coated with _SnO2 , mica coated with BaSO ₄ mica, mica coated with titanium oxide or titanium dioxide, mica coated with organic dyes and pearlescent pigments based on bismuth oxychloride, metal oxides and/or organic colorants superimposed on their surface in at least two consecutive layers Mica particles, and mixtures thereof, wherein the weight ratio of said at least one scattering filler to said at least red nacre is 20:1 to 1:20, Wherein the weight ratio of the at least red nacre to the at least blue nacre is 10:1 to 1:10.