CN104449175A - Water-based environment-friendly paint and preparation method thereof - Google Patents
Water-based environment-friendly paint and preparation method thereof Download PDFInfo
- Publication number
- CN104449175A CN104449175A CN201410801642.1A CN201410801642A CN104449175A CN 104449175 A CN104449175 A CN 104449175A CN 201410801642 A CN201410801642 A CN 201410801642A CN 104449175 A CN104449175 A CN 104449175A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- vinylbenzene
- paint
- methacrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000003973 paint Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 32
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 230000007613 environmental effect Effects 0.000 claims description 18
- 230000001681 protective effect Effects 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000005030 aluminium foil Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses water-based environment-friendly paint. The water-based environment-friendly paint is prepared from the following components in parts by weight: 5-10 parts of methylacrylic acid, 10-20 parts of hydroxyethyl methylacrylate, 10-30 parts of styrene, 8-20 parts of butyl methacrylate, 5-30 parts of methyl methacrylate, 3-5 parts of an emulsifier and 50-70 parts of water. The water-based environment-friendly paint is simple to manufacture, good in using effect and environmentally friendly; the adopted production raw materials are non-toxic.
Description
Technical field
The present invention relates to a kind of medical aluminium foil packing and plastics, particularly relate to a kind of Environmental Protective Water-paint and preparation method thereof.
Background technology
At present in medical aluminium foil packing industry, widely used is the solvent based coating invented decades ago, the annual solvent based coating that consumes is at 2000 tons, and the poisonous and harmful solvent to airborne release is 1800 tons, severe contamination environment.In medical aluminium foil packing industry, China becomes world's factory gradually, and domestic consumption is only 1/10 of world's consumption, and following global medical aluminium foil packing will be all made in China, and this will bring serious environmental hazard by China.
Summary of the invention
Object of the present invention: provide a kind of Environmental Protective Water-paint, removes poisonous and harmful solvent completely to the destruction of China's environment.
To achieve these goals, technical scheme of the present invention is:
A kind of Environmental Protective Water-paint, comprises the component of following weight part: methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part.
Above-mentioned Environmental Protective Water-paint, wherein, comprises the component of following weight part: methacrylic acid 5 parts, hydroxyethyl methylacrylate 10 parts, vinylbenzene 10 parts, butyl methacrylate 8 parts, methyl methacrylate 15 parts, emulsifying agent 3 parts and 50 parts, water.
Above-mentioned Environmental Protective Water-paint, wherein, comprises the component of following weight part: methacrylic acid 8 parts, hydroxyethyl methylacrylate 15 parts, vinylbenzene 15 parts, butyl methacrylate 15 parts, methyl methacrylate 22 parts, emulsifying agent 4 parts and 60 parts, water.
Above-mentioned Environmental Protective Water-paint, wherein, comprises the component of following weight part: methacrylic acid 10 parts, hydroxyethyl methylacrylate 20 parts, vinylbenzene 30 parts, butyl methacrylate 20 parts, methyl methacrylate 30 parts, emulsifying agent 5 parts and 70 parts, water.
A making method for Environmental Protective Water-paint, the method at least comprises the steps:
Step 1: by methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part add in reactor, and are uniformly mixed;
Step 2: by the heating raw materials of mixing in step 1 to 90 degree, and with 120 revs/min of reactions 2 hours in reactor.
The present invention makes simply, and the raw materials for production of employing are selected avirulent, and the result of use of coating is good, environmental protection.
Embodiment
A kind of Environmental Protective Water-paint, comprises the component of following weight part:
Methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part.
A making method for Environmental Protective Water-paint, the method at least comprises the steps:
Step 1: by methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part add in reactor, and are uniformly mixed.
Step 2: by the heating raw materials of mixing in step 1 to 90 degree, and with 120 revs/min of reactions 2 hours in reactor.
Embodiment 1:
By methacrylic acid 5 parts, hydroxyethyl methylacrylate 10 parts, vinylbenzene 10 parts, butyl methacrylate 8 parts, methyl methacrylate 15 parts, emulsifying agent 3 parts and 50 parts, water, do not stop in a kettle. to be uniformly mixed post-heating to 90 degree, get product after 2 hours with 120 revs/min of reactions.
Embodiment 2:
By methacrylic acid 8 parts, hydroxyethyl methylacrylate 15 parts, vinylbenzene 15 parts, butyl methacrylate 15 parts, methyl methacrylate 22 parts, emulsifying agent 4 parts and 60 parts, water, do not stop in a kettle. to be uniformly mixed post-heating to 90 degree, get product after 2 hours with 120 revs/min of reactions.
Embodiment 3:
By methacrylic acid 10 parts, hydroxyethyl methylacrylate 20 parts, vinylbenzene 30 parts, butyl methacrylate 20 parts, methyl methacrylate 30 parts, emulsifying agent 5 parts and 70 parts, water, do not stop in a kettle. to be uniformly mixed post-heating to 90 degree, get product after 2 hours with 120 revs/min of reactions.
In sum, the present invention makes simply, and the raw materials for production of employing are selected avirulent, and the result of use of coating is good, environmental protection.According to mix proportion scheme of the present invention, can according to different construction requirements, different geographic climates produces the product that different performance requires.
The foregoing is only the preferred embodiments of the present invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure transformation utilizing description of the present invention to do; or directly or indirectly use the technical field being attached to other related productss, be all in like manner included in scope of patent protection of the present invention.
Claims (5)
1. an Environmental Protective Water-paint, is characterized in that: the component comprising following weight part: methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part.
2. Environmental Protective Water-paint according to claim 1, is characterized in that: the component comprising following weight part: methacrylic acid 5 parts, hydroxyethyl methylacrylate 10 parts, vinylbenzene 10 parts, butyl methacrylate 8 parts, methyl methacrylate 15 parts, emulsifying agent 3 parts and 50 parts, water.
3. Environmental Protective Water-paint according to claim 1, is characterized in that: the component comprising following weight part: methacrylic acid 8 parts, hydroxyethyl methylacrylate 15 parts, vinylbenzene 15 parts, butyl methacrylate 15 parts, methyl methacrylate 22 parts, emulsifying agent 4 parts and 60 parts, water.
4. Environmental Protective Water-paint according to claim 1, is characterized in that: the component comprising following weight part: methacrylic acid 10 parts, hydroxyethyl methylacrylate 20 parts, vinylbenzene 30 parts, butyl methacrylate 20 parts, methyl methacrylate 30 parts, emulsifying agent 5 parts and 70 parts, water.
5. a making method for Environmental Protective Water-paint, is characterized in that: the method at least comprises the steps:
Step 1: by methacrylic acid 5-10 part, hydroxyethyl methylacrylate 10-20 part, vinylbenzene 10-30 part, butyl methacrylate 8-20 part, methyl methacrylate 5-30 part, emulsifying agent 3-5 part and water 50-70 part add in reactor, and are uniformly mixed;
Step 2: by the heating raw materials of mixing in step 1 to 90 degree, and with 120 revs/min of reactions 2 hours in reactor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410801642.1A CN104449175A (en) | 2014-12-22 | 2014-12-22 | Water-based environment-friendly paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410801642.1A CN104449175A (en) | 2014-12-22 | 2014-12-22 | Water-based environment-friendly paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104449175A true CN104449175A (en) | 2015-03-25 |
Family
ID=52895955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410801642.1A Pending CN104449175A (en) | 2014-12-22 | 2014-12-22 | Water-based environment-friendly paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104449175A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5819301A (en) * | 1981-07-16 | 1983-02-04 | ヘキスト・アクチエンゲゼルシヤフト | Manufacture of copolymer aqueous dispersion and use |
| CN101597355A (en) * | 2009-05-27 | 2009-12-09 | 彭文表 | A kind of water-based room temperature crosslinking acrylic acid emulsion and preparation method thereof |
| CN101704930A (en) * | 2009-09-29 | 2010-05-12 | 上海东升新材料有限公司 | Styrene-acrylate emulsion for surface coatings of coated paper |
| CN102002125A (en) * | 2009-08-31 | 2011-04-06 | 无锡市金箭造漆有限公司 | Acrylic resin emulsion for fingerprint-resistant paint and preparation method thereof |
| CN102250281A (en) * | 2011-06-21 | 2011-11-23 | 上海三瑞高分子材料有限公司 | Cation acrylate emulsion |
| CN102585084A (en) * | 2011-12-23 | 2012-07-18 | 上海奇想青晨新材料科技股份有限公司 | Coating emulsion and preparation method thereof |
-
2014
- 2014-12-22 CN CN201410801642.1A patent/CN104449175A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5819301A (en) * | 1981-07-16 | 1983-02-04 | ヘキスト・アクチエンゲゼルシヤフト | Manufacture of copolymer aqueous dispersion and use |
| CN101597355A (en) * | 2009-05-27 | 2009-12-09 | 彭文表 | A kind of water-based room temperature crosslinking acrylic acid emulsion and preparation method thereof |
| CN102002125A (en) * | 2009-08-31 | 2011-04-06 | 无锡市金箭造漆有限公司 | Acrylic resin emulsion for fingerprint-resistant paint and preparation method thereof |
| CN101704930A (en) * | 2009-09-29 | 2010-05-12 | 上海东升新材料有限公司 | Styrene-acrylate emulsion for surface coatings of coated paper |
| CN102250281A (en) * | 2011-06-21 | 2011-11-23 | 上海三瑞高分子材料有限公司 | Cation acrylate emulsion |
| CN102585084A (en) * | 2011-12-23 | 2012-07-18 | 上海奇想青晨新材料科技股份有限公司 | Coating emulsion and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150325 |