CN104437083A - Waste gas treating agent - Google Patents
Waste gas treating agent Download PDFInfo
- Publication number
- CN104437083A CN104437083A CN201410851632.9A CN201410851632A CN104437083A CN 104437083 A CN104437083 A CN 104437083A CN 201410851632 A CN201410851632 A CN 201410851632A CN 104437083 A CN104437083 A CN 104437083A
- Authority
- CN
- China
- Prior art keywords
- waste gas
- treating agent
- gas treating
- exhaust gas
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002912 waste gas Substances 0.000 title abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000001648 tannin Substances 0.000 claims abstract description 3
- 235000018553 tannin Nutrition 0.000 claims abstract description 3
- 229920001864 tannin Polymers 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims description 11
- 235000011511 Diospyros Nutrition 0.000 claims description 2
- 244000236655 Diospyros kaki Species 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 33
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 15
- 239000002440 industrial waste Substances 0.000 abstract description 6
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 235000019256 formaldehyde Nutrition 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010805 inorganic waste Substances 0.000 description 2
- 210000004185 liver Anatomy 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 230000007170 pathology Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- RNKMOGIPOMVCHO-SJMVAQJGSA-N 1,3,6-trigalloyl glucose Chemical compound C([C@@H]1[C@H]([C@@H]([C@@H](O)[C@H](OC(=O)C=2C=C(O)C(O)=C(O)C=2)O1)OC(=O)C=1C=C(O)C(O)=C(O)C=1)O)OC(=O)C1=CC(O)=C(O)C(O)=C1 RNKMOGIPOMVCHO-SJMVAQJGSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention relates to the technical field of waste gas treatment, in particular to a waste gas treating agent. The waste gas treating agent comprises by weight, 40-50 parts of papermaking black liquid, 10-20 parts of FeCl3, 5-15 parts of CuO, 7-18 parts of nano SiO2 and 3-12 parts of tannin. The waste gas treating agent can be used for treating multiple kinds of waste gas such as SO2, NO, CO2, CO, methanal, heavy metal and other substances, the papermaking black liquid which is a serious pollutant is comprehensively recovered and reutilized, waste materials are made profitable, and the production cost of products is greatly reduced. The waste gas treating agent is suitable of treating industrial waste gas and automobile exhaust.
Description
Technical field
The present invention relates to technical field of waste gas treatment, particularly a kind of exhaust gas treating agent.
Background technology
Waste gas refers to that the mankind are at the poisonous and hazardous gas produced and discharge in life process.Particularly chemical plant, steel plant, pharmaceutical factory, and coking plant and oil plant etc., the waste gas smell of discharge is large, serious environment pollution and affect health.The industrial waste gas of all kinds of manufacturing enterprises discharge is the important sources of atmosphere pollution.If large capacity industrial waste gas unprocessed up to standard after enter air, atmosphere quality must be made to decline, bring serious harm to health, bring about great losses to national economy.After in industrial waste gas, poisonous and harmful substance enters human body by respiratory tract and skin, long-term low concentration or the contact of short-term high concentration can cause the temporary and permanent pathology of the organs and systems such as the breathing of human body, blood, liver, and especially benzopyrenes polycyclic aromatic hydrocarbon can make human body directly carcinogenic to cause the great attention of the mankind.
Industrial waste gas comprises organic exhaust gas and inorganic waste gases.Organic exhaust gas mainly comprises various hydro carbons, alcohols, aldehydes, acids, ketone and amine etc.; Inorganic waste gases mainly comprises oxysulfide, nitrogen oxide, oxycarbide, halogen and compound thereof etc.China takes pollutant emission control system for atmosphere pollution.Organic exhaust gas is one of main atmosphere pollution, enters human body, cause temporary and permanent pathology to organs and systems such as the breathing of people, blood, livers by respiratory tract and skin.As PTA oxidized tail gas contains a large amount of pernicious gases, as: formaldehyde, benzene,toluene,xylene, methyl acetate, CO etc., its index all exceedes discharging standards, causes serious harm to environment.For preventing pollution, except reducing oil loss, reducing consumption of organic solvent with except the generation reducing organic exhaust gas and discharge, exhaust gas purification is current practicable governance way.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of exhaust gas treating agent, and this exhaust gas treating agent applied range, can process multiple harmful exhaust.
For achieving the above object, the present invention adopts following technical scheme:
A kind of exhaust gas treating agent, be made up of the raw material of following weight portion:
For ensureing the superperformance of exhaust gas treating agent, preferably, black liquid Baume degrees of the present invention is 35 ~ 40 ° of B é.
Tannin of the present invention derives from persimmon.Tannin can Adsorption of Heavy Metal Ions, reduces heavy metal substance content in waste gas.
Preferably, exhaust gas treating agent of the present invention, be made up of the raw material of following weight portion:
Black liquid of the present invention contains a large amount of K
2cO
3, Na
2cO
3, KOH, NaOH and Ca (OH)
2deng, there is desulfidation, alkali wherein can also and CO
2reaction generates salt, thus removing CO
2.
FeCl
3the effect of catalyst can be played, reduce SO
2and NO, play absorbent again simultaneously.
Nano-meter SiO_2
2have very strong adsorption capacity, can adsorb the formaldehyde in waste gas, not only there is physical absorption in its PARA FORMALDEHYDE PRILLS(91,95), and has chemisorbed, defines hydrogen bond or covalent bond with formaldehyde, can be reduced the content of formaldehyde in waste gas.
The CuO that the present invention adds, can react with CO under high temperature and generate Cu and CO
2, thus removing CO, the CO of generation
2with the alkali reaction in black liquid, CO can be prevented
2enter in air.
The usage of exhaust gas treating agent of the present invention: waste gas is contacted with exhaust gas treating agent of the present invention.
Beneficial effect of the present invention is:
1, the present invention can process multiple harmful exhaust, as SO
2, NO, CO
2, CO, the material such as formaldehyde and heavy metal.
2, the black liquid synthetical recovery as high pollution thing is recycled, turn waste into wealth, greatly reduce the production cost of product.
3, the present invention forms simply, and process waste gas Be very effective, product of the present invention is applicable to industrial waste gas and vehicle maintenance service.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited to these embodiments.
Embodiment 1
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 2
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 3
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 4
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 5
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 6
Exhaust gas treating agent, be made up of the raw material of following weight portion:
Embodiment 7
Exhaust gas treating agent, be made up of the raw material of following weight portion:
After tested, during with various embodiments of the present invention exhaust gas treating agent process waste gas, various waste gas clearance situation is as follows:
Unit: %
| Title | SO 2 | NO | CO 2 | CO | Formaldehyde | Heavy metal | Soot particle |
| Embodiment 1 | 65 | 56 | 92 | 89 | 86 | 79 | 79 |
| Embodiment 2 | 84 | 58 | 90 | 85 | 91 | 89 | 78 |
| Embodiment 3 | 76 | 65 | 89 | 90 | 87 | 90 | 85 |
| Embodiment 4 | 89 | 79 | 95 | 92 | 95 | 89 | 83 |
| Embodiment 5 | 70 | 74 | 91 | 91 | 92 | 85 | 75 |
| Embodiment 6 | 73 | 69 | 86 | 88 | 87 | 81 | 86 |
| Embodiment 7 | 69 | 71 | 89 | 87 | 80 | 75 | 80 |
Claims (4)
1. an exhaust gas treating agent, is characterized in that, is made up of the raw material of following weight portion:
2. exhaust gas treating agent according to claim 1, is characterized in that, is made up of the raw material of following weight portion:
3. exhaust gas treating agent according to claim 1 and 2, is characterized in that: described black liquid Baume degrees is 35 ~ 40 ° of B é.
4. exhaust gas treating agent according to claim 1 and 2, is characterized in that: described tannin derives from persimmon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410851632.9A CN104437083A (en) | 2014-12-31 | 2014-12-31 | Waste gas treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410851632.9A CN104437083A (en) | 2014-12-31 | 2014-12-31 | Waste gas treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104437083A true CN104437083A (en) | 2015-03-25 |
Family
ID=52884297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410851632.9A Pending CN104437083A (en) | 2014-12-31 | 2014-12-31 | Waste gas treating agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104437083A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105396450A (en) * | 2015-11-18 | 2016-03-16 | 山东苏势环保能源科技发展有限公司 | Chemical desulfurization and denitrification agent for boiler flue gas and preparation method thereof |
| CN106110881A (en) * | 2016-06-23 | 2016-11-16 | 杨添凯 | A kind of exhaust gas treating agent |
| CN107335412A (en) * | 2017-08-15 | 2017-11-10 | 德阳护球环保科技有限公司 | A kind of efficient compound exhaust gas treating agent |
| CN109621713A (en) * | 2018-12-29 | 2019-04-16 | 浙江工业大学 | A kind of sludge composite denitration agent and its preparation and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5294862A (en) * | 1976-02-05 | 1977-08-09 | Agency Of Ind Science & Technol | Treatment of exhaust gas with industrial waste materials |
| CN1240767A (en) * | 1998-07-03 | 2000-01-12 | 毛呜庆 | Process for treating waste paper-making liquor |
| CN103194295A (en) * | 2013-04-25 | 2013-07-10 | 甘肃黑马石化工程有限公司 | Boiler coal combustion-improving denitrifying agent composition and preparation method thereof |
| CN103816865A (en) * | 2014-03-03 | 2014-05-28 | 艾特克控股集团有限公司 | Organic waste gas adsorption cleaning agent and preparing method thereof |
-
2014
- 2014-12-31 CN CN201410851632.9A patent/CN104437083A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5294862A (en) * | 1976-02-05 | 1977-08-09 | Agency Of Ind Science & Technol | Treatment of exhaust gas with industrial waste materials |
| CN1240767A (en) * | 1998-07-03 | 2000-01-12 | 毛呜庆 | Process for treating waste paper-making liquor |
| CN103194295A (en) * | 2013-04-25 | 2013-07-10 | 甘肃黑马石化工程有限公司 | Boiler coal combustion-improving denitrifying agent composition and preparation method thereof |
| CN103816865A (en) * | 2014-03-03 | 2014-05-28 | 艾特克控股集团有限公司 | Organic waste gas adsorption cleaning agent and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 谢枫等: "柿单宁在重金属吸附中的应用研究进展", 《华中农业大学学报》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105396450A (en) * | 2015-11-18 | 2016-03-16 | 山东苏势环保能源科技发展有限公司 | Chemical desulfurization and denitrification agent for boiler flue gas and preparation method thereof |
| CN106110881A (en) * | 2016-06-23 | 2016-11-16 | 杨添凯 | A kind of exhaust gas treating agent |
| CN107335412A (en) * | 2017-08-15 | 2017-11-10 | 德阳护球环保科技有限公司 | A kind of efficient compound exhaust gas treating agent |
| CN109621713A (en) * | 2018-12-29 | 2019-04-16 | 浙江工业大学 | A kind of sludge composite denitration agent and its preparation and application |
| CN109621713B (en) * | 2018-12-29 | 2022-01-14 | 浙江工业大学 | Sludge composite denitration agent and preparation and application thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |