CN104425316A - Layer separation apparatus - Google Patents
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Abstract
本发明涉及一种层分离设备,且更明确地说,涉及一种用于在柔性显示器工艺中将涂布层与基础衬底分离的设备。本发明的实施例层分离设备包含:腔室,具有内部空间且在其上壁上设有窗口;激光辐射单元,经配置以通过所述窗口将激光束辐射到所述内部空间上;光源传感器,经配置以朝向所述内部空间中所设置的装置衬底发射光且接收从其反射的所述光;显示单元,经配置以显示从所述光源传感器测量的光接收值;以及衬底传递板,经配置以在所述腔室的所述内部空间中支撑所述装置衬底以在激光束辐射工艺期间传递所述装置衬底以在所述窗口下方滑动且在已完成所述激光束辐射工艺后传递所述装置衬底以在所述光源传感器下方滑动。
The present invention relates to a layer separation apparatus, and more particularly to an apparatus for separating a coating layer from a base substrate in a flexible display process. An embodiment layer separation apparatus of the present invention includes: a chamber having an inner space and a window provided on an upper wall thereof; a laser radiation unit configured to irradiate a laser beam onto the inner space through the window; a light source sensor , configured to emit light toward a device substrate provided in the internal space and receive the light reflected therefrom; a display unit configured to display a light reception value measured from the light source sensor; and a substrate transfer a plate configured to support the device substrate in the inner space of the chamber to pass the device substrate to slide under the window during a laser beam irradiation process and to pass the device substrate after the laser beam has been completed The device substrate is passed to slide under the light source sensor after the irradiation process.
Description
技术领域technical field
本发明涉及一种层分离设备,且更明确地说,涉及一种用于在柔性显示器工艺中将涂布层与基础衬底分离的设备。The present invention relates to a layer separation apparatus, and more particularly to an apparatus for separating a coating layer from a base substrate in a flexible display process.
背景技术Background technique
单晶或多晶硅晶体管由于因高电子移动性所致的优良开关特性而已广泛用于显示器。需要在氮气氛围下在预定温度或更高的温度下执行热处理以用于制造具有优良的开关特性的硅晶体管,且由于高处理温度,在高温下具有低热变形的玻璃衬底被用作基础衬底以用于形成硅晶体管的膜。Monocrystalline or polycrystalline silicon transistors have been widely used in displays due to their excellent switching characteristics due to high electron mobility. It is necessary to perform heat treatment at a predetermined temperature or higher in a nitrogen atmosphere for manufacturing a silicon transistor having excellent switching characteristics, and a glass substrate having low thermal deformation at a high temperature is used as a base substrate due to the high processing temperature The bottom is used to form the film of the silicon transistor.
作为下一代显示器,已广泛对以各种形式制造的柔性显示器(例如,不仅薄且轻而且抗冲击、柔性且可弯曲的柔性显示器)进行研究。由于硅晶体管的低柔性特性和在基础衬底中的限制,难以将硅晶体管应用于柔性显示器。近年来,作为一种用于制造柔性半导体装置的方法,已对一种用于将薄玻璃板用作衬底的方法、一种用于将金属板用作衬底的方法和一种用于使用塑料衬底的方法进行研究。As next-generation displays, flexible displays manufactured in various forms (for example, flexible displays that are not only thin and light but also shock-resistant, flexible and bendable) have been extensively researched. It is difficult to apply silicon transistors to flexible displays due to their low flexibility characteristics and limitations in the base substrate. In recent years, as a method for manufacturing a flexible semiconductor device, a method for using a thin glass plate as a substrate, a method for using a metal plate as a substrate, and a method for The study was carried out using a plastic substrate method.
图1的(a)到(f)说明一种用于制造AMOLED柔性半导体装置的方法的实例。(a) to (f) of FIG. 1 illustrate an example of a method for manufacturing an AMOLED flexible semiconductor device.
如图1的(a)所说明提供基础衬底11,且如图1的(b)所说明,在基础衬底11的顶表面上薄薄地涂布塑料涂布层12。塑料涂布层12由可持续用于热处理工艺的聚酰亚胺(polyimide,PI)制成。接着,如图1的(c)所说明,在塑料涂布层12的顶表面上形成多个半导体装置13,即,已经受激光低温多晶硅(laser low-temperature polysilicon,LTPS)工艺的有源矩阵有机发光二极管(active matrix organic light emitting diode,AMOLED)装置。在塑料涂布层12的顶表面上形成多个半导体装置13后,如图1的(d)所说明,在最上表面上形成上层保护膜14。在形成上层保护膜14后,如图1的(e)所说明,将形成于基础衬底11的顶表面上的塑料涂布层12与基础衬底11分离。此后,如图1的(f)所说明,在与基础衬底11分离的塑料涂布层12的底表面上形成下层保护膜15,如此获得最终的柔性OLED装置。A base substrate 11 is provided as illustrated in (a) of FIG. 1 , and a plastic coating layer 12 is thinly coated on the top surface of the base substrate 11 as illustrated in (b) of FIG. 1 . The plastic coating layer 12 is made of polyimide (PI) which can be continuously used in heat treatment process. Next, as illustrated in (c) of FIG. 1, a plurality of semiconductor devices 13, that is, active matrices that have been subjected to a laser low-temperature polysilicon (LTPS) process, are formed on the top surface of the plastic coating layer 12. Organic light emitting diode (active matrix organic light emitting diode, AMOLED) device. After forming a plurality of semiconductor devices 13 on the top surface of the plastic coating layer 12, as illustrated in FIG. 1(d), an upper protective film 14 is formed on the uppermost surface. After the upper protective film 14 is formed, the plastic coating layer 12 formed on the top surface of the base substrate 11 is separated from the base substrate 11 as illustrated in (e) of FIG. 1 . Thereafter, as illustrated in (f) of FIG. 1 , an underlayer protective film 15 is formed on the bottom surface of the plastic coating layer 12 separated from the base substrate 11, thus obtaining a final flexible OLED device.
在此状况下,通过使用激光剥离(laser lift-off,LLO)工艺移除基础衬底11而执行在图1的(e)中的基础衬底与塑料涂布层之间的界面分离的方法。换句话说,通过激光(L)的辐射来降低基础衬底11与塑料涂布层12之间的粘合强度,进而将基础衬底11与塑料涂布层12分离且移除基础衬底11。In this case, a method of performing interface separation between the base substrate and the plastic coating layer in (e) of FIG. 1 by removing the base substrate 11 using a laser lift-off (LLO) process . In other words, the bonding strength between the base substrate 11 and the plastic coating layer 12 is reduced by irradiation of the laser (L), thereby separating the base substrate 11 from the plastic coating layer 12 and removing the base substrate 11 .
然而,在相关技术中,基础衬底11与塑料涂布层12之间的界面分离仅通过裸眼来检验,且不存在用于使用数据来检验界面分离的状态的方法。因此,对界面分离的检验是不可靠且不准确的。However, in the related art, the interface separation between the base substrate 11 and the plastic coating layer 12 is inspected only by the naked eye, and there is no method for inspecting the state of the interface separation using data. Therefore, the test for interfacial separation is unreliable and inaccurate.
[相关技术文献][Related technical literature]
[专利文献][Patent Document]
专利文献1:第10-2011-0131017号韩国专利申请公开案Patent Document 1: Korean Patent Application Publication No. 10-2011-0131017
发明内容Contents of the invention
本发明提供一种用于将基础衬底和塑料涂布层彼此分离的设备。本发明还提供一种用于检验基础衬底和塑料涂布层是否分离的设备。本发明还增强对检验基础衬底和塑料涂布层是否分离的可靠性。The present invention provides an apparatus for separating a base substrate and a plastic coating layer from each other. The present invention also provides an apparatus for inspecting whether a base substrate and a plastic coating layer are separated. The present invention also enhances the reliability of the detection of separation of the base substrate and the plastic coating layer.
根据示范性实施例,一种层分离设备包含:腔室,具有内部空间且在其上壁上设有窗口;激光辐射单元,经配置以通过所述窗口将激光束辐射到所述内部空间上;光源传感器,经配置以朝向设置在所述内部空间中的装置衬底发射光且接收从装置衬底反射的光;显示单元,经配置以显示从所述光源传感器测量的光接收值;以及衬底传递板,经配置以在所述腔室的所述内部空间中支撑所述装置衬底以在激光束辐射工艺期间传递所述装置衬底以在所述窗口下方滑动且在已完成所述激光束辐射工艺后传递所述装置衬底以在所述光源传感器下方滑动。According to an exemplary embodiment, a layer separation apparatus includes: a chamber having an inner space and a window provided on an upper wall thereof; a laser radiation unit configured to irradiate a laser beam onto the inner space through the window a light source sensor configured to emit light toward a device substrate disposed in the internal space and receive light reflected from the device substrate; a display unit configured to display a light reception value measured from the light source sensor; and a substrate transfer plate configured to support the device substrate in the inner space of the chamber to transfer the device substrate to slide under the window during a laser beam irradiation process and to The device substrate is transferred to slide under the light source sensor after the laser beam irradiation process.
且,所述层分离设备可还包含:检验处理单元,经配置以确定所述光接收值是否落在参考值范围内,且在所述光接收值落在参考值范围内时产生界面分离成功的警报,且在所述光接收值在参考值范围之外时产生界面分离失败的警报。And, the layer separation apparatus may further include: an inspection processing unit configured to determine whether the light reception value falls within a reference value range, and generate interface separation success when the light reception value falls within the reference value range and an alarm of interface separation failure is generated when the light-receiving value is outside the range of the reference value.
且,当所述光接收值在所述参考值范围之外时,所述装置衬底可再次被传递且用激光束辐射。And, when the light reception value is outside the reference value range, the device substrate may be transferred again and irradiated with a laser beam.
且,所述装置衬底可包含依序堆叠的基础衬底、塑料涂布层、半导体装置和保护膜,且被辐射激光束的表面为基础衬底的表面。Also, the device substrate may include a base substrate, a plastic coating layer, a semiconductor device, and a protective film stacked in sequence, and the surface to which the laser beam is irradiated is the surface of the base substrate.
且,所述塑料涂布层可为选自以下各个的任一个:聚萘二甲酸乙二醇酯(polyethylenenaphthelate,PEN)、聚对苯二甲酸乙二醇酯(polyethyleneterephthalate,PET)、聚碳酸酯(polycarbonate,PC)、聚苯砜(polyethylene sulfone,PES)、聚酰亚胺(polyimide,PI)、聚烯丙基化物(polyallylate,PAR)、多环烯烃(polycyclicolefin,PCO)、聚甲基丙烯酸甲酯(polymethylmethacrylate,PMMA)、交联型环氧树脂(cross-linking type epoxt)和交联型聚氨酯膜(cross-linking type urethane film)。And, the plastic coating layer can be any one selected from the following: polyethylene naphthalate (polyethylenenaphthelate, PEN), polyethylene terephthalate (polyethyleneterephthalate, PET), polycarbonate (polycarbonate, PC), polyphenylene sulfone (polyethylene sulfone, PES), polyimide (polyimide, PI), polyallylate (polyallylate, PAR), polycyclic olefin (polycyclic olefin, PCO), polymethacrylic acid Methyl ester (polymethylmethacrylate, PMMA), cross-linking type epoxy resin (cross-linking type epoxy) and cross-linking type polyurethane film (cross-linking type urethane film).
附图说明Description of drawings
可结合附图从以下描述更详细地理解示范性实施例。Exemplary embodiments can be understood in more detail from the following description in conjunction with the accompanying drawings.
图1的(a)到(f)说明一种用于制造有源矩阵有机发光二极管(AMOLED)柔性半导体装置的方法的实例。(a) to (f) of FIG. 1 illustrate an example of a method for manufacturing an active matrix organic light emitting diode (AMOLED) flexible semiconductor device.
图2说明根据示范性实施例的层分离设备,其中将激光束辐射到半导体装置衬底上。FIG. 2 illustrates a layer separation apparatus in which a laser beam is irradiated onto a semiconductor device substrate according to an exemplary embodiment.
图3说明根据示范性实施例的层分离设备,其中通过光源传感器来检验半导体装置衬底的层分离。FIG. 3 illustrates a layer separation apparatus in which layer separation of a semiconductor device substrate is inspected by a light source sensor according to an exemplary embodiment.
图4说明根据示范性实施例的衬底台。Figure 4 illustrates a substrate table according to an exemplary embodiment.
图5说明根据示范性实施例的衬底传递板上的半导体装置衬底。FIG. 5 illustrates a semiconductor device substrate on a substrate transfer plate according to an exemplary embodiment.
图6是说明根据示范性实施例的由RGB传感器配置的光源传感器的概念性横截面图。FIG. 6 is a conceptual cross-sectional view illustrating a light source sensor configured by RGB sensors according to an exemplary embodiment.
图7说明根据示范性实施例在将激光束辐射到基础衬底的表面上后由光源传感器发射和接收的光。FIG. 7 illustrates light emitted and received by a light source sensor after irradiating a laser beam onto a surface of a base substrate according to an exemplary embodiment.
图8是根据示范性实施例的用于检验层分离设备的分离是否成功的概念性框图。FIG. 8 is a conceptual block diagram for verifying whether separation of a layer separation device is successful, according to an exemplary embodiment.
图9是展示根据示范性实施例的具有输入构件的额外显示单元的图像。FIG. 9 is an image showing an additional display unit with an input member according to an exemplary embodiment.
图10说明根据示范性实施例将激光束辐射在双处理腔室中的情形。FIG. 10 illustrates a situation in which laser beams are irradiated in a dual processing chamber according to an exemplary embodiment.
图11说明根据示范性实施例在双处理腔室中使用光源传感器来执行层分离的检验的情形。FIG. 11 illustrates a scenario in which inspection of layer separation is performed using a light source sensor in a dual processing chamber according to an exemplary embodiment.
主要元件标号说明:Explanation of main component labels:
10:衬底10: Substrate
10a:第一半导体装置衬底10a: First semiconductor device substrate
10b:第二半导体装置衬底10b: Second semiconductor device substrate
11:基础衬底11: Base substrate
12:塑料涂布层12: Plastic coating layer
13:半导体装置13: Semiconductor device
14:上层保护膜14: Upper protective film
15:下层保护膜15: Lower protective film
100:腔室100: chamber
100a:上壁100a: upper wall
100b:主体100b: subject
200:衬底台200: substrate table
210:线性马达导轨210: Linear Motor Guide
220:Y轴传递板220: Y-axis transmission plate
230:衬底传递板230: substrate transfer plate
300:窗口300: window
400:光源传感器400: light source sensor
400a:光源传感器400a: light source sensor
400b:光源传感器400b: Light source sensor
400c:光源传感器400c: light source sensor
410:光发射部分410: light emitting part
420:光接收部分420: Light receiving part
500:激光辐射单元500: laser radiation unit
600:显示单元600: display unit
700:检验处理单元700: Check processing unit
具体实施方式Detailed ways
下文中,将参看附图来详细地描述示范性实施例。然而,本发明可按照许多不同形式体现,且不应被解释为限于本文中所陈述的实施例;而是,提供这些实施例以使得本发明将彻底且完整,且将向所属领域的技术人员完全地传达本发明的概念。此外,本发明仅由权利要求的范围界定。图中相似参考数字表示相似装置。Hereinafter, exemplary embodiments will be described in detail with reference to the accompanying drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will convey to those skilled in the art fully convey the concept of the invention. Furthermore, the present invention is limited only by the scope of the claims. Like reference numerals in the figures indicate like devices.
下文中,装置衬底是指一种衬底,其中塑料涂布层涂布在基础衬底上且多个装置沉积在塑料涂布层上。所述装置可包含半导体装置等。在以下描述中,半导体装置衬底将被描述为装置衬底的实例;然而,本发明可应用于除了半导体装置衬底之外的各种装置衬底。Hereinafter, a device substrate refers to a substrate in which a plastic coating layer is coated on a base substrate and a plurality of devices are deposited on the plastic coating layer. The devices may include semiconductor devices and the like. In the following description, a semiconductor device substrate will be described as an example of the device substrate; however, the present invention is applicable to various device substrates other than the semiconductor device substrate.
图2说明根据示范性实施例的层分离设备,其中将激光束辐射到半导体装置衬底上,且图3说明根据示范性实施例的层分离设备,其中通过光源传感器来检验半导体装置衬底的层分离。2 illustrates a layer separation apparatus according to an exemplary embodiment in which a laser beam is irradiated onto a semiconductor device substrate, and FIG. 3 illustrates a layer separation apparatus according to an exemplary embodiment in which the semiconductor device substrate is inspected by a light source sensor. Layer separation.
腔室100具有衬底台200,衬底台200在腔室100的内部空间中支撑半导体装置衬底10,且层分离通过激光处理而对置于衬底台200上的半导体装置衬底10执行。且,腔室100包含:主体100b,其上部开放;以及上壁100a,其为覆盖所述主体的上部的顶盖且能够打开和闭合。虽然未图示,但腔室100在侧壁上具有门,所述门是直通路径,其中半导体装置衬底10通过所述直通路径而传递到内部空间。The chamber 100 has a substrate table 200 that supports a semiconductor device substrate 10 in an inner space of the chamber 100, and layer separation is performed on the semiconductor device substrate 10 placed on the substrate table 200 by laser processing. . And, the chamber 100 includes: a main body 100b whose upper part is open; and an upper wall 100a which is a top cover covering the upper part of the main body and which can be opened and closed. Although not shown, the chamber 100 has a door on a side wall, which is a through-path through which the semiconductor device substrate 10 is transferred to the inner space.
腔室100在其上壁100a上具有由透明材料制成的窗口300并且例如在腔室100的上壁100a的一部分中具有直通区域,以使得所述直通区域用作窗口。具体来说,窗口保持主体(未图示)安装在腔室100的上壁上的直通区域中,且通过窗口保持主体来保持并支撑窗口300,进而将窗口300置于腔室100的上壁上。窗口300是由石英等制成,且因此允许从激光辐射单元500振荡的激光束通过窗口300且朝向衬底台200上的半导体装置衬底10传播。且,与衬底台200相对地布置的多个光源传感器400(400a、400b、400c)设置在腔室的上壁100a的下部中,且朝向置于衬底台200上的半导体装置衬底10发射,且接收从半导体装置衬底10的表面反射的光,这将在稍后描述。The chamber 100 has a window 300 made of a transparent material on its upper wall 100a and for example has a through-area in a part of the upper wall 100a of the chamber 100 such that the through-area acts as a window. Specifically, a window holding body (not shown) is installed in a straight-through area on the upper wall of the chamber 100, and the window 300 is held and supported by the window holding body, thereby placing the window 300 on the upper wall of the chamber 100. superior. The window 300 is made of quartz or the like, and thus allows the laser beam oscillated from the laser radiation unit 500 to pass through the window 300 and propagate toward the semiconductor device substrate 10 on the substrate stage 200 . And, a plurality of light source sensors 400 (400a, 400b, 400c) arranged opposite to the substrate table 200 are provided in a lower portion of the upper wall 100a of the chamber, and face the semiconductor device substrate 10 placed on the substrate table 200. The light reflected from the surface of the semiconductor device substrate 10 is emitted and received, which will be described later.
如图4所说明的衬底台200具有表面板结构且因此具有衬底传递板230,其中,半导体装置衬底置于衬底传递板230中,以使得衬底传递板230可沿着线性马达(LM)导引件移动。换句话说,Y轴传递板220在X轴方向上沿着LM导轨210移动,且衬底传递板230在Y轴方向上沿着Y轴传递板220移动。因此,置于衬底传递板230上的半导体装置衬底定位在适当的位置处,这是因为所述半导体装置衬底可在激光层分离和检验工艺期间在X轴和Y轴方向且通过水平旋转移动。在本文中,X轴和Y轴可包含形成2维平面的任何轴。X轴和Y轴的定义同样适用于以下描述。且,水平旋转意味着,当被放置衬底的衬底支撑结构(未图示)另外设置在衬底传递板230内时,置于衬底支撑结构上的半导体装置衬底能够通过衬底支撑结构的旋转而旋转。The substrate table 200 as illustrated in FIG. 4 has a surface plate structure and thus has a substrate transfer plate 230 in which semiconductor device substrates are placed such that the substrate transfer plate 230 can move along the linear motor (LM) Guide movement. In other words, the Y-axis transfer plate 220 moves along the LM guide 210 in the X-axis direction, and the substrate transfer plate 230 moves along the Y-axis transfer plate 220 in the Y-axis direction. Therefore, the semiconductor device substrate placed on the substrate transfer plate 230 is positioned at an appropriate position because the semiconductor device substrate can pass horizontally in the X-axis and Y-axis directions and through the horizontal during the laser layer separation and inspection process. Rotate to move. Herein, the X axis and the Y axis may include any axes forming a 2-dimensional plane. The definitions of the X-axis and the Y-axis also apply to the following description. Also, horizontal rotation means that when a substrate support structure (not shown) on which a substrate is placed is additionally provided in the substrate transfer plate 230, a semiconductor device substrate placed on the substrate support structure can be supported by the substrate. The structure rotates while rotating.
同时,半导体装置衬底10置于衬底台200的衬底传递板230上,其中如图5所说明,示范性实施例中的半导体装置衬底10是指一种衬底,其中塑料涂布层12设置在基础衬底11上,且多个半导体装置13沉积在塑料涂布层12上且用保护膜14覆盖。且,半导体装置衬底10可为没有保护膜14的衬底。Meanwhile, the semiconductor device substrate 10 is placed on the substrate transfer plate 230 of the substrate stage 200, wherein as illustrated in FIG. A layer 12 is arranged on a base substrate 11 and a plurality of semiconductor devices 13 are deposited on the plastic coating layer 12 and covered with a protective film 14 . Also, the semiconductor device substrate 10 may be a substrate without the protective film 14 .
保护膜14放置成与衬底传递板230的上表面接触,且基础衬底11定位成离衬底传递板230最远。因此,激光束辐射到基础衬底11的表面上。类似地,光源传感器还可朝向基础衬底发射光且接收光。The protective film 14 is placed in contact with the upper surface of the substrate transfer plate 230 , and the base substrate 11 is positioned farthest from the substrate transfer plate 230 . Thus, the laser beam is irradiated onto the surface of base substrate 11 . Similarly, the light source sensor can also emit light towards the base substrate and receive light.
以上的基础衬底11可包含玻璃衬底、陶瓷衬底和金属-多晶硅或聚合物衬底;然而,基础衬底不限于此,且因此在高衬底温度下具有热稳定性的各种种类的基础衬底可适用。此外,因为根据示范性实施例的基础衬底在后续工艺中被分离和移除,所以不需要是透明的,而是,各种且廉价的材料可用于衬底,只要这些材料在高温下具有热稳定性即可,而不管其透明度如何。The above base substrate 11 may include glass substrates, ceramic substrates, and metal-polysilicon or polymer substrates; however, base substrates are not limited thereto, and thus have various types of thermal stability at high substrate temperatures. The base substrate is applicable. Also, since the base substrate according to the exemplary embodiment is separated and removed in a subsequent process, it does not need to be transparent, but various and inexpensive materials can be used for the substrate as long as they have Thermal stability is sufficient regardless of its transparency.
因此,涂覆到基础衬底11的塑料涂布层12可由具有柔性的柔性材料制成,且可包含选自以下各个的任一个:聚萘二甲酸乙二醇酯(PEN)、聚对苯二甲酸乙二醇酯(PET)、聚碳酸酯(PC)、聚苯砜(PES)、聚酰亚胺(PI)、聚烯丙基化物(PAR)、多环烯烃(PCO)、聚甲基丙烯酸甲酯(PMMA)、交联型环氧树脂和交联型聚氨酯膜。另外,沉积于塑料涂布层12上的多个半导体装置13可包含已经受低温多晶硅(LTPS)结晶的OLED半导体装置。Therefore, the plastic coating layer 12 applied to the base substrate 11 may be made of a flexible material having flexibility, and may contain any one selected from the following: polyethylene naphthalate (PEN), polyethylene terephthalate Ethylene dicarboxylate (PET), polycarbonate (PC), polyphenylsulfone (PES), polyimide (PI), polyallyl compound (PAR), polycyclic olefin (PCO), polymethylene Acrylic methyl acrylate (PMMA), cross-linked epoxy resin and cross-linked polyurethane film. Additionally, the plurality of semiconductor devices 13 deposited on the plastic coating layer 12 may include OLED semiconductor devices that have been crystallized from low temperature polysilicon (LTPS).
激光辐射单元500使激光束通过窗口300振荡进入腔室的内部空间中,以便将激光束辐射到半导体装置衬底10的表面上。激光辐射单元500可还设有反射镜(未图示)且从激光辐射单元500发射的激光束从所述反射镜反射且因此朝向半导体装置衬底的表面辐射。激光辐射单元500的激光源的实例可包含选自以下各个的至少一个:气体激光器,例如,Ar激光器、Kr激光器和准分子激光器;具有钕(Nd)、镱(Yb)、铬(Cr)、钛(Ti)、钬(Ho)、铒(Er)、铥(Tm)和钽(Ta)中的一种或多种掺杂剂添加到例如YAG、YV04、镁橄榄石(Mg2SiO4)、YA103和GdV04等单晶体或例如YAG、Y203、YV04、YA103和GdV04等多晶体(陶瓷)中的介质的激光器;玻璃激光器;红宝石激光器;翠绿宝石激光器;Ti:蓝宝石激光器;铜蒸汽激光器和金蒸汽激光器。合意的是,激光束可为比共同地辐射衬底的整个表面的表面形光束更容易地集中光束的线形光束。The laser radiation unit 500 oscillates the laser beam into the inner space of the chamber through the window 300 so as to radiate the laser beam onto the surface of the semiconductor device substrate 10 . The laser radiation unit 500 may be further provided with a reflection mirror (not shown) and the laser beam emitted from the laser radiation unit 500 is reflected from the reflection mirror and thus radiated toward the surface of the semiconductor device substrate. Examples of the laser light source of the laser radiation unit 500 may include at least one selected from each of the following: gas lasers, for example, Ar lasers, Kr lasers, and excimer lasers; One or more dopants of titanium (Ti), holmium (Ho), erbium (Er), thulium (Tm) and tantalum (Ta) are added to, for example, YAG, YV04, forsterite (Mg2SiO4), YA103 and Lasers in single crystals such as GdV04 or media in polycrystals (ceramics) such as YAG, Y203, YV04, YA103 and GdV04; glass lasers; ruby lasers; alexandrite lasers; Ti:sapphire lasers; copper vapor lasers and gold vapor lasers. Desirably, the laser beam may be a line-shaped beam that concentrates the beam more easily than a surface-shaped beam that collectively irradiates the entire surface of the substrate.
如图5所说明,被辐射激光束的表面(相反的表面)是基础衬底,且因此在基础衬底、塑料涂布层、半导体装置和保护膜依序堆叠时,激光束辐射到基础衬底11的底表面上。激光束辐射导致基础衬底11与塑料涂布层12之间的界面的改变,进而将基础衬底11与塑料涂布层12彼此分离。激光束降低所述界面的粘合强度,进而将基础衬底与塑料涂布层彼此分离。As illustrated in FIG. 5, the surface (opposite surface) to which the laser beam is irradiated is the base substrate, and thus when the base substrate, plastic coating layer, semiconductor device, and protective film are sequentially stacked, the laser beam is irradiated to the base substrate. on the bottom surface of the bottom 11. Laser beam irradiation causes a change in the interface between base substrate 11 and plastic coating layer 12 , thereby separating base substrate 11 and plastic coating layer 12 from each other. The laser beam reduces the adhesive strength of the interface, thereby separating the base substrate and the plastic coating layer from each other.
同时,为了检验基础衬底11与塑料涂布层12之间的分离是否由于用于层分离的激光束而成功,衬底传递板230移动以允许半导体装置衬底10在光源传感器400下方在Y轴方向上滑动。Meanwhile, in order to check whether the separation between the base substrate 11 and the plastic coating layer 12 was successful due to the laser beam used for layer separation, the substrate transfer plate 230 was moved to allow the semiconductor device substrate 10 to move under the light source sensor 400 at Y slide in the direction of the axis.
光源传感器400设置在腔室的上壁的下部中以便发射和接收光。光源传感器400的实例可包含RGB传感器和红外线传感器,且在光源传感器是由RGB传感器配置时,所述RGB传感器发射可见光且接收从其反射的光。光源传感器400朝向半导体装置衬底发射光且接着接收从半导体装置衬底的表面反射的光。换句话说,所发射的光所到达的表面是基础衬底的表面,且因此在基础衬底、塑料涂布层、半导体装置和保护膜依序堆叠时,激光束辐射到基础衬底11的所述表面上。图6是说明由RGB传感器配置的光源传感器的概念性横截面图。由RGB传感器配置的光源传感器400包含光发射部分410和光接收部分420且从光发射部分410发射可见光,其中所发射的光透射穿过基础衬底11或完全从基础衬底11反射,且所透射的光的一部分再次通过从塑料涂布层12的全反射或折射而被导引。因此,所发射的光的一部分再次从基础衬底11的表面反射。光源传感器400的光接收部分420收集从基础衬底11的表面反射的光。另外,可设置多个光源传感器,且举例来说,成行设置三个光源传感器,即,第一光源传感器400a、第二光源传感器400b和第三光源传感器400c,如图2和图3所说明。因此,可同时在基础衬底的多个部分处发射或接收光。The light source sensor 400 is disposed in a lower portion of the upper wall of the chamber so as to emit and receive light. Examples of the light source sensor 400 may include an RGB sensor and an infrared sensor, and when the light source sensor is configured by the RGB sensor, the RGB sensor emits visible light and receives light reflected therefrom. The light source sensor 400 emits light toward a semiconductor device substrate and then receives light reflected from the surface of the semiconductor device substrate. In other words, the surface to which the emitted light reaches is the surface of the base substrate, and thus when the base substrate, plastic coating layer, semiconductor device, and protective film are sequentially stacked, the laser beam is irradiated to the surface of the base substrate 11. on the surface. FIG. 6 is a conceptual cross-sectional view illustrating a light source sensor configured by RGB sensors. The light source sensor 400 configured by an RGB sensor includes a light emitting part 410 and a light receiving part 420 and emits visible light from the light emitting part 410, wherein the emitted light is transmitted through the base substrate 11 or completely reflected from the base substrate 11, and the transmitted light A part of the light is again guided by total reflection or refraction from the plastic coating layer 12 . Therefore, part of the emitted light is reflected from the surface of base substrate 11 again. The light receiving portion 420 of the light source sensor 400 collects light reflected from the surface of the base substrate 11 . In addition, a plurality of light source sensors may be provided, and for example, three light source sensors are provided in a row, ie, a first light source sensor 400a, a second light source sensor 400b, and a third light source sensor 400c, as illustrated in FIGS. 2 and 3 . Thus, light can be emitted or received at multiple portions of the base substrate simultaneously.
作为参考,图7说明在将激光束辐射到基础衬底的表面上后由光源传感器发射和接收的光。随着基础衬底在窗口下方在Y轴方向上移动,激光束可扫描基础衬底11的整个表面。For reference, FIG. 7 illustrates light emitted and received by the light source sensor after radiating a laser beam onto the surface of the base substrate. The laser beam may scan the entire surface of the base substrate 11 as the base substrate moves in the Y-axis direction under the window.
激光束辐射降低基础衬底11与塑料涂布层12之间的界面的粘合强度,从而导致塑料涂布层12与基础衬底11分离。为了检验层分离是否完全成功,在Y轴方向上传递衬底传递板以允许基础衬底在光源传感器400下方在Y轴方向上缓慢移动。通过所述三个光源传感器400a、400b、400c,可接收从基础衬底的表面上的三个点反射的光。因此,当设置三个光源传感器时,根据基础衬底的移动,对第一线I、第二线II和第三线III的多个点执行扫描,且可实现光发射和接收。Laser beam irradiation reduces the adhesive strength of the interface between base substrate 11 and plastic coating layer 12 , thereby causing separation of plastic coating layer 12 from base substrate 11 . In order to check whether the layer separation was completely successful, the substrate transfer plate was transferred in the Y-axis direction to allow the base substrate to move slowly in the Y-axis direction under the light source sensor 400 . Through the three light source sensors 400a, 400b, 400c, light reflected from three points on the surface of the base substrate may be received. Therefore, when three light source sensors are provided, scanning is performed on a plurality of points of the first line I, the second line II, and the third line III according to the movement of the base substrate, and light emission and reception can be achieved.
同时,由光源传感器400接收的光接收值可取决于基础衬底11与塑料涂布层12之间的界面是否完全分离而改变。以上的光接收值是指所接收的光的RGB比率与作为所接收的光的量的光接收量中的其中一个。作为参考,使用所接收的光的RGB比率与所发射的光的RGB比率进行比较。也就是说,在所发射的光的RGB比率等于R∶G∶B=1∶1∶1的状况下,使用所接收的光的RGB比率来确定所接收的光的RGB比率与所发射的光的RGB比率偏离多少。RGB比率的移位展示界面分离是否成功。Meanwhile, the light reception value received by the light source sensor 400 may vary depending on whether the interface between the base substrate 11 and the plastic coating layer 12 is completely separated. The above light reception value refers to one of the RGB ratio of received light and the light reception amount which is the amount of received light. As a reference, the RGB ratio of the received light is compared to the RGB ratio of the emitted light. That is, under the condition that the RGB ratio of the emitted light is equal to R:G:B=1:1:1, the RGB ratio of the received light is used to determine the ratio of the RGB ratio of the received light to the emitted light. How much the RGB ratio deviates. The shift of the RGB ratio shows whether the interface separation was successful.
且,作为所接收的光的量的光接收量用于通过相对于光发射量检测光接收量来检验界面分离状态。可通过使用以下特性来检验界面分离:在基础衬底与塑料涂布层之间的界面完全附接时,即,处于100%的附接状态下,光接收值最高,且随着界面分离开始导致附接状态变差,光接收值变低。举例来说,假设在基础衬底与塑料涂布层之间的界面完全附接时,即,处于100%的附接状态下,光接收值与光发射值的比率高于90%,在基础衬底与塑料涂布层之间的界面部分分离且界面附接状态的比率减小到低于50%时,光接收值变得减小到低于70%。这是因为在基础衬底与塑料涂布层之间的界面处的粘合强度改变,如此导致光接收量由于界面之间的不同折射率而改变。辐射到基础衬底的表面上的激光束的一部分通过全反射而从表面反射且接着被接收;然而,通过基础衬底的激光束的一部分在基础衬底与塑料涂布层之间的界面处改变其折射率。当界面完全附接时,通过全反射朝向界面的表面反射的光量增加;然而,当界面部分或完全分离而降低粘合强度时,通过塑料涂布层且在界面之间被导引的折射光的量变得大于全反射的光量,这结果减少所反射的光的量。Also, the light reception amount, which is the amount of received light, is used to check the interface separation state by detecting the light reception amount with respect to the light emission amount. The interfacial separation can be checked by using the property that when the interface between the base substrate and the plastic coating layer is fully attached, i.e. at 100% attached, the light acceptance value is highest, and as the interfacial separation begins As a result, the attached state deteriorates and the light reception value becomes low. For example, assuming that when the interface between the base substrate and the plastic coating layer is fully attached, that is, in a 100% attached state, the ratio of the light receiving value to the light emitting value is higher than 90%, at the base When the interface between the substrate and the plastic coating layer is partially separated and the ratio of the interface-attached state is reduced below 50%, the light reception value becomes reduced below 70%. This is because the adhesive strength changes at the interface between the base substrate and the plastic coating layer, thus causing the light reception amount to change due to the different refractive index between the interfaces. A part of the laser beam radiated onto the surface of the base substrate is reflected from the surface by total reflection and then received; however, a part of the laser beam passing through the base substrate is at the interface between the base substrate and the plastic coating layer change its refractive index. When the interfaces are fully attached, the amount of light that is reflected towards the surface of the interface by total reflection increases; however, when the interfaces are partially or completely separated reducing the bond strength, the refracted light that passes through the plastic-coated layer and is guided between the interfaces The amount of becomes larger than the amount of light totally reflected, which in turn reduces the amount of light reflected.
因此,根据示范性实施例,可通过使用光接收值取决于界面是否分离而改变的特性来检验界面是否分离。为此,在图8中说明了说明根据示范性实施例的层分离设备的检验的概念性框图。Therefore, according to an exemplary embodiment, whether the interface is separated may be checked by using a property that a light reception value changes depending on whether the interface is separated. To this end, a conceptual block diagram illustrating inspection of a layer separation device according to an exemplary embodiment is illustrated in FIG. 8 .
由光源传感器400测量的光接收值被递送到在腔室100外所设置的显示单元600且显示在显示单元600上,以使得工艺操作者能够确定界面分离是否成功。显示单元600可由一般显示面板配置,且替代地可由具有如图9所说明的输入构件的额外显示单元配置。The light reception value measured by the light source sensor 400 is delivered to and displayed on the display unit 600 provided outside the chamber 100 so that the process operator can determine whether the interface separation is successful. The display unit 600 may be configured by a general display panel, and alternatively may be configured by an additional display unit having an input member as illustrated in FIG. 9 .
根据示范性实施例,独立地设置检验处理单元700,其确定光接收值是否落在参考值范围内,且在所述光接收值落在参考值范围内时产生界面分离成功的警报,且在所述光接收值在参考值范围之外时产生界面分离失败的警报。举例来说,当参考值范围与光发射值的比率是20%到40%且光接收值与光发射值的比率是32%时,检验处理单元700产生界面分离成功的警报。相比而言,当光接收值与光发射值的比率是55%时,所述比率在参考值范围之外,且因此检验处理单元700产生界面分离失败的警报。参考值范围是一个范围,在所述范围内,基础衬底与塑料涂布层之间的界面分离是成功完成的。参考值范围可以是光接收值与光发射值的比率的范围,但可被设定为光接收量的接收值范围或RGB比率范围。可根据基础衬底的种类来确定参考值范围,且尤其合意的是,根据塑料涂布层的类型来确定参考值范围。According to an exemplary embodiment, a verification processing unit 700 is independently provided, which determines whether the light receiving value falls within a reference value range, and generates an alarm that the interface separation is successful when the light receiving value falls within the reference value range, and at An alarm of interface separation failure is generated when the light reception value is outside a reference value range. For example, when the ratio of the reference value range to the light emission value is 20% to 40% and the ratio of the light reception value to the light emission value is 32%, the verification processing unit 700 generates an alarm that the interface separation is successful. In contrast, when the ratio of the light reception value to the light emission value is 55%, the ratio is outside the reference value range, and thus the inspection processing unit 700 generates an alarm of interface separation failure. The reference value range is a range within which the interface separation between the base substrate and the plastic coating layer is successfully accomplished. The reference value range may be a range of a ratio of a light reception value to a light emission value, but may be set as a reception value range of a light reception amount or an RGB ratio range. The reference value range may be determined according to the kind of the base substrate, and it is particularly desirable to determine the reference value range according to the type of the plastic coating layer.
当光接收值在参考值范围之外时,除了产生界面分离失败的警报之外,检验处理单元700还控制衬底传递板230以再次将激光束辐射到半导体装置衬底上。换句话说,当光接收值在参考值范围之外时,基础衬底未完全分离。因此,在窗口下方传递衬底传递板以将激光束再次辐射到半导体装置衬底上以进行完整分离。When the light reception value is outside the reference value range, in addition to generating an alarm of interface separation failure, the inspection processing unit 700 controls the substrate transfer plate 230 to irradiate the laser beam onto the semiconductor device substrate again. In other words, when the light reception value is outside the range of the reference value, the base substrate is not completely separated. Therefore, the substrate transfer plate is passed under the window to irradiate the laser beam onto the semiconductor device substrate again for complete separation.
同时,前述层分离设备已通过示范单一处理腔室来描述,但还可应用于双处理腔室。图10和11说明在双处理腔室中辐射激光束且检测光接收值的情形。具体来说,图10说明根据示范性实施例在双处理腔室中辐射激光束的情形,且图11说明根据示范性实施例通过使用光源传感器在双处理腔室中检验层分离的情形。作为参考,在图10和图11中省略上面放置且因此传递半导体装置衬底的衬底传递板以用于更好的理解。Meanwhile, the aforementioned layer separation apparatus has been described by exemplifying a single processing chamber, but can also be applied to a double processing chamber. 10 and 11 illustrate the case where a laser beam is irradiated and a light-reception value is detected in a dual processing chamber. Specifically, FIG. 10 illustrates a case of irradiating laser beams in a dual process chamber according to an exemplary embodiment, and FIG. 11 illustrates a case of inspecting layer separation in a dual process chamber by using a light source sensor according to an exemplary embodiment. For reference, the substrate transfer plate on which the semiconductor device substrate is placed and thus transferred is omitted in FIGS. 10 and 11 for better understanding.
如图10所说明,第一半导体装置衬底10a在X轴方向上从第一备用区域A传递到激光束处理区域B,且接着在沿着Y轴传递的同时暴露于激光束。在此状况下,第二半导体装置衬底10b通过门从外部传递到第二备用区域C中或从第二备用区域C传递出。As illustrated in FIG. 10, the first semiconductor device substrate 10a is transferred from the first spare area A to the laser beam processing area B in the X-axis direction, and then exposed to the laser beam while being transferred along the Y-axis. In this state, the second semiconductor device substrate 10b is transferred into or out of the second spare area C from the outside through the gate.
当到第一半导体装置衬底10a上的激光束辐射已如图10所说明完成时,如图11所说明,第一半导体装置衬底10a返回到第一备用区域A,且在光源传感器400下方在Y轴方向上传递,进而检验界面是否分离。此处,置于第二备用区域C中的第二半导体装置衬底10b沿着X轴输入到激光束处理区域B中,且在Y轴方向上传递的同时暴露于激光束。When the laser beam irradiation on the first semiconductor device substrate 10a has been completed as illustrated in FIG. 10, as illustrated in FIG. Transfer in the Y-axis direction, and then check whether the interface is separated. Here, the second semiconductor device substrate 10b placed in the second spare area C is input into the laser beam processing area B along the X axis, and exposed to the laser beam while passing in the Y axis direction.
根据示范性实施例,可检验基础衬底和塑料涂布层是否分离,进而提高检验的可靠性。且,使用光源传感器来取代操作者的裸眼以实现简易和快速检验。此外,在辐射激光束后在相同的腔室中执行检验,这使得可简化制造工艺的整个流程。According to exemplary embodiments, it may be inspected whether the base substrate and the plastic coating layer are separated, thereby improving the reliability of the inspection. Also, a light source sensor is used instead of the operator's naked eyes to realize easy and quick inspection. In addition, inspection is performed in the same chamber after the laser beam is irradiated, which makes it possible to simplify the entire flow of the manufacturing process.
虽然已参考特定实施例描述了层分离设备,但层分离设备不限于此。因此,所属领域的技术人员应易于理解,在不脱离由所附权利要求定义的本发明的精神和范围的情况下可对其进行各种修改和改变。Although the layer separation device has been described with reference to certain embodiments, the layer separation device is not limited thereto. Accordingly, it will be readily understood by those skilled in the art that various modifications and changes can be made therein without departing from the spirit and scope of the present invention as defined by the appended claims.
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US11139358B2 (en) | 2018-08-31 | 2021-10-05 | Wuhan China Star Optoelectronics Semiconductor Display Technology Co., Ltd. | Display panel and manufacturing method thereof |
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TWI577559B (en) | 2017-04-11 |
CN104425316B (en) | 2017-07-25 |
KR101794828B1 (en) | 2017-11-09 |
KR20150025172A (en) | 2015-03-10 |
TW201507859A (en) | 2015-03-01 |
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