CN104403409A - Antibacterial printing ink composition and preparation method thereof - Google Patents
Antibacterial printing ink composition and preparation method thereof Download PDFInfo
- Publication number
- CN104403409A CN104403409A CN201410714299.7A CN201410714299A CN104403409A CN 104403409 A CN104403409 A CN 104403409A CN 201410714299 A CN201410714299 A CN 201410714299A CN 104403409 A CN104403409 A CN 104403409A
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- parts
- ink composition
- pigment
- antibacterial ink
- antibacterial
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 17
- YSVQGHIOJPVICX-UHFFFAOYSA-N 1-(1-hydroxycyclohexyl)-1-phenylpropan-2-one Chemical compound C1CCCCC1(O)C(C(=O)C)C1=CC=CC=C1 YSVQGHIOJPVICX-UHFFFAOYSA-N 0.000 claims abstract description 9
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 9
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 9
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229920000136 polysorbate Polymers 0.000 claims abstract description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- IEDVJHCEMCRBQM-UHFFFAOYSA-N trimethoprim Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(N)=NC=2)N)=C1 IEDVJHCEMCRBQM-UHFFFAOYSA-N 0.000 claims description 7
- 229960001082 trimethoprim Drugs 0.000 claims description 7
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001219 Polysorbate 40 Polymers 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 claims description 3
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 229940101027 polysorbate 40 Drugs 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 abstract 2
- JRPRCOLKIYRSNH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC2OC2)C=1C(=O)OCC1CO1 JRPRCOLKIYRSNH-UHFFFAOYSA-N 0.000 abstract 2
- 229920001529 polyepoxysuccinic acid Polymers 0.000 abstract 2
- 238000005303 weighing Methods 0.000 abstract 2
- 238000011056 performance test Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 206010011409 Cross infection Diseases 0.000 description 1
- 206010029803 Nosocomial infection Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an antibacterial printing ink composition and a preparation method thereof. The composition is prepared from the following components in parts by weight: 8-11 parts of phthalic diglycidyl ester, 8-11 parts of 1-hydroxycyclohexylphenylacetone, 8-11 parts of epoxypropane butyl ether, 5-8 parts of pigment, 4-7 parts of sodium dibutyl naphthalene sulfonate, 3.5-5 parts of Tween, 2-3 parts of an antibacterial agent, 2-3 parts of polydimethylsiloxane and 1.5-2 parts of polyepoxysuccinic acid. The preparation method comprises the following steps: (1) weighing 5-8 parts of the pigment, adding 2-3 parts of the antibacterial agent, 8-11 parts of phthalic diglycidyl ester, 8-11 parts of 1-hydroxycyclohexylphenylacetone and 8-11 parts of epoxypropane butyl ether in sequence, and uniformly mixing; (2) weighing 4-7 parts of sodium dibutyl naphthalene sulfonate, 2-3 parts of polydimethylsiloxane, 3.5-5 parts of Tween and 1.5-2 parts of polyepoxysuccinic acid, and grinding in a three-roll grinding machine for 10-20 minutes; (3) ultrasonically processing a product in the step (1) and a product in the step (2) at 55-70 DEG C for 15-25 minutes, and defoaming in vacuum for 1-2 hours to obtain the antibacterial printing ink composition.
Description
Technical field
The present invention relates to a kind of ink material field, particularly a kind of antibacterial ink composition and method of making the same.
Background technology
In the modern life, people more and more pay attention to the quality of living environment, to all kinds of directly and the product of contact human skin, all can there is the hidden danger of safety and health, therefore, the security of this series products be had higher requirement.
Stationery topmost use colony is student, and wherein, particularly young student is for frequent with intimate the contacting of stationery, makes the quality of the material of stationery and its security are had higher requirement, and also requires the environmental protection more of its materials simultaneously.
Microorganism can be propagated by all kinds of contact, finally be attached on stationery, when multiple student uses stationery alternately, can respective germ and the microorganism of carrying be stayed on stationery, use the stationery with cooperating microorganisms, wash one's hands in time if do not note, just have the danger of cross infection, thus affect the healthy of people.Therefore, the germ resistance of people to stationery is had higher requirement.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of antibacterial ink composition and method of making the same.
Object of the present invention can be achieved through the following technical solutions:
A kind of antibacterial ink composition, be made up of the component of following weight part:
O-phthalic acid diglycidyl ester 8-11 part,
1-hydroxycyclohexylphenyl acetone 8-11 part,
Epoxy propane butyl ether 8-11 part,
Pigment 5-8 part,
Sodium dibutyl naphthalene sulfonate 4-7 part,
Tween 3.5-5 part,
Antiseptic-germicide 2-3 part,
Polydimethylsiloxane 2-3 part,
Poly-epoxy succinic acid 1.5-2 part.
Described tween is the mixing of one or more in polysorbas20, polysorbate40, polysorbate60 and tween 80.
Described antiseptic-germicide is selected from the mixing of one or more in trimethoprim, nano titanium oxide, nano zine oxide.
In described antiseptic-germicide, the mass ratio of trimethoprim, nano titanium oxide, nano zine oxide is 0.5:1:2.
Described pigment is selected from magenta, carbon black, Pigment Yellow 73 74, Pigment Yellow 73 155, Pigment Yellow 73 213, pigment Yellow 12 8, pigment Blue 15: 3 and pigment Blue 15: one or more mixing in 4.
A preparation method for antibacterial ink composition, comprises the following steps:
(1) take pigment 5-8 part, add antiseptic-germicide 2-3 part, o-phthalic acid diglycidyl ester 8-11 part, 1-hydroxycyclohexylphenyl acetone 8-11 part and epoxy propane butyl ether 8-11 part successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 4-7 part, polydimethylsiloxane 2-3 part, tween 3.5-5 part and poly-epoxy succinic acid 1.5-2 part, add in three-roll grinder and grind 10-20 minute;
(3) the ultrasonic 15-25 minute at 55-70 DEG C by the product of step 1 and the product of step 2, deaeration 1-2 hour under vacuum, obtains antibacterial ink composition.
Compared with prior art, its beneficial effect is in the present invention:
(1) its modest viscosity of antibacterial ink composition of obtaining of the present invention, can ensure good coating or printing effect.
(2) the antibacterial ink preparation method of composition that obtains of the present invention is simple, and cost is low, is applicable to scale operation.
(3) antibacterial ink composition of the present invention has excellent tack, still can have good effect after can ensureing long-term preservation.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) carbon black 5kg is taken, add trimethoprim 0.29kg, nano titanium oxide 0.58kg, nano zine oxide 1.16kg, o-phthalic acid diglycidyl ester 11kg, 1-hydroxycyclohexylphenyl acetone 8kg and epoxy propane butyl ether 11kg successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 6kg, polydimethylsiloxane 3kg, 3.5kg polysorbas20 and poly-epoxy succinic acid 1.5kg, add in three-roll grinder and grind 15 minutes;
(3) by the product of step 1 and the product of step 2 at 55 DEG C ultrasonic 15 minutes, deaeration 1 hour, obtains antibacterial ink composition under vacuum.
The performance test results of obtained antibacterial ink composition is as shown in table 1.
Embodiment 2
(1) take 8kg Pigment Yellow 73 74, add nano titanium oxide 3kg, o-phthalic acid diglycidyl ester 8kg, 1-hydroxycyclohexylphenyl acetone 11kg and epoxy propane butyl ether 8kg successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 4kg, polydimethylsiloxane 3kg, 5kg polysorbate60 and poly-epoxy succinic acid 2kg, add in three-roll grinder and grind 10 minutes;
(3) by the product of step 1 and the product of step 2 at 60 DEG C ultrasonic 20 minutes, deaeration 2 hours, obtains antibacterial ink composition under vacuum.
The performance test results of obtained antibacterial ink composition is as shown in table 1.
Embodiment 3
(1) take 6kg Pigment Yellow 73 155, add trimethoprim 2kg, o-phthalic acid diglycidyl ester 11kg, 1-hydroxycyclohexylphenyl acetone 10kg and epoxy propane butyl ether 9kg successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 7kg, polydimethylsiloxane 2kg, 3.5kg polysorbate40 and poly-epoxy succinic acid 1.5kg, add in three-roll grinder and grind 20 minutes;
(3) by the product of step 1 and the product of step 2 at 70 DEG C ultrasonic 25 minutes, deaeration 2 hours, obtains antibacterial ink composition under vacuum.
The performance test results of obtained antibacterial ink composition is as shown in table 1.
Embodiment 4
(1) 8kg pigment Blue 15 is taken: 4, add trimethoprim 0.42kg, nano titanium oxide 0.84kg, nano zine oxide 1.68kg, o-phthalic acid diglycidyl ester 9kg, 1-hydroxycyclohexylphenyl acetone 8kg and epoxy propane butyl ether 11kg successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 4kg, polydimethylsiloxane 2kg, 5kg tween 80 and poly-epoxy succinic acid 2kg, add in three-roll grinder and grind 18 minutes;
(3) by the product of step 1 and the product of step 2 at 58 DEG C ultrasonic 15 minutes, deaeration 2 hours, obtains antibacterial ink composition under vacuum.
The performance test results of obtained antibacterial ink composition is as shown in table 1.
By the antibacterial ink composition of embodiment 1-4 under the condition of relative humidity 75%, place 20 days, all have no sedimentation.
Table 1
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Bonding strength (MPa) | 20.5 | 16.6 | 19.9 | 17.1 |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (6)
1. an antibacterial ink composition, is characterized in that, is made up of the component of following weight part:
2. antibacterial ink composition according to claim 1, it is characterized in that, described tween is the mixing of one or more in polysorbas20, polysorbate40, polysorbate60 and tween 80.
3. antibacterial ink composition according to claim 1, it is characterized in that, described antiseptic-germicide is selected from the mixing of one or more in trimethoprim, nano titanium oxide, nano zine oxide.
4. antibacterial ink composition according to claim 1, it is characterized in that, in described antiseptic-germicide, the mass ratio of trimethoprim, nano titanium oxide, nano zine oxide is 0.5:1:2.
5. antibacterial ink composition according to claim 1, it is characterized in that, described pigment is selected from magenta, carbon black, Pigment Yellow 73 74, Pigment Yellow 73 155, Pigment Yellow 73 213, pigment Yellow 12 8, pigment Blue 15: 3 and pigment Blue 15: one or more mixing in 4.
6. a preparation method for antibacterial ink composition, is characterized in that, comprises the following steps:
(1) take pigment 5-8 part, add antiseptic-germicide 2-3 part, o-phthalic acid diglycidyl ester 8-11 part, 1-hydroxycyclohexylphenyl acetone 8-11 part and epoxy propane butyl ether 8-11 part successively, mix;
(2) take sodium dibutyl naphthalene sulfonate 4-7 part, polydimethylsiloxane 2-3 part, tween 3.5-5 part and poly-epoxy succinic acid 1.5-2 part, add in three-roll grinder and grind 10-20 minute;
(3) the ultrasonic 15-25 minute at 55-70 DEG C by the product of step 1 and the product of step 2, deaeration 1-2 hour under vacuum, obtains antibacterial ink composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410714299.7A CN104403409B (en) | 2014-12-01 | 2014-12-01 | A kind of antibacterial ink compositions and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410714299.7A CN104403409B (en) | 2014-12-01 | 2014-12-01 | A kind of antibacterial ink compositions and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104403409A true CN104403409A (en) | 2015-03-11 |
| CN104403409B CN104403409B (en) | 2016-08-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410714299.7A Expired - Fee Related CN104403409B (en) | 2014-12-01 | 2014-12-01 | A kind of antibacterial ink compositions and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104403409B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802198A (en) * | 2016-04-05 | 2016-07-27 | 吴江市林旺纺织厂 | Waterproof textile material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
| JP4482873B2 (en) * | 2003-06-06 | 2010-06-16 | 昭栄化学工業株式会社 | Conductive paste, circuit board, solar cell, and chip-type ceramic electronic component |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN102942822A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Antimicrobial UV curing printing ink and preparation method thereof |
-
2014
- 2014-12-01 CN CN201410714299.7A patent/CN104403409B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4482873B2 (en) * | 2003-06-06 | 2010-06-16 | 昭栄化学工業株式会社 | Conductive paste, circuit board, solar cell, and chip-type ceramic electronic component |
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN102942822A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Antimicrobial UV curing printing ink and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802198A (en) * | 2016-04-05 | 2016-07-27 | 吴江市林旺纺织厂 | Waterproof textile material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104403409B (en) | 2016-08-31 |
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Granted publication date: 20160831 Termination date: 20161201 |