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CN104403226A - Deodorizing medical material and preparation method thereof - Google Patents

Deodorizing medical material and preparation method thereof Download PDF

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Publication number
CN104403226A
CN104403226A CN201410624299.8A CN201410624299A CN104403226A CN 104403226 A CN104403226 A CN 104403226A CN 201410624299 A CN201410624299 A CN 201410624299A CN 104403226 A CN104403226 A CN 104403226A
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CN
China
Prior art keywords
medical material
deodorizing
preparation
parts
deodorizing medical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410624299.8A
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Chinese (zh)
Inventor
金仲恩
全春兰
张帆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Cosmetic New Materials Co Ltd
Original Assignee
Suzhou Cosmetic New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Cosmetic New Materials Co Ltd filed Critical Suzhou Cosmetic New Materials Co Ltd
Priority to CN201410624299.8A priority Critical patent/CN104403226A/en
Publication of CN104403226A publication Critical patent/CN104403226A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a deodorizing medical material and a preparation method thereof. The deodorizing medical material is composed of the following components: PVC, PET, propoxylated dodecanol, 1,2,4-tricarboxylic acid-2-phosphorylbutane, isopropanol, sodium bicarbonate, sodium silicate, ammonium sulfate, talcum powder, permethrin, ferric sulfate, critic acid, polycarbonate, antioxidant, epoxy chloropropane, and ammonium persulfate. The preparation method comprises the following steps: stirring and mixing the components mentioned above in a mixing machine, and then transferring the mixture to a double-screw extruder to carry out extrusion moulding so as to obtain the deodorizing medical material. The provided deodorizing medical material has good physical properties and a deodorizing performance, wherein the tensile strength can reach 38 MPa or more, the break elongation rate can reach 51% or more, furthermore through deodorizing experiments, people find that the provided deodorizing medical material can well remove the odors given off by the medical garbage, and thus the provided material can be widely used in the medical and hygiene fields.

Description

A kind of deodorizing medical material and preparation method thereof
Technical field
The invention belongs to field of medical materials, be specifically related to a kind of deodorizing medical material and preparation method thereof.
Background technology
The stink of rubbish is produced by bacterial degradation because of the organic composition in rubbish, 75-80% is had to be organism in domestic refuse, mainly contain pericarp, dish leaf vegetables obstructs, leftovers/dish, poultry, the skin of animal and fish, hair, internal organ, fat, ight soil, tankage/watery blood, leaf, waste paper, the body of flowers and plants and animal etc. and certain moisture. in the process of digestion naturally, under the effects such as aerobic/anaerobically fermenting, produce stench, especially when heat, because fermentative action is accelerated, it is more serious that foul smell becomes. and the stink of domestic refuse has ammonia, hydrogen sulfide, organic amine, organosulfur, voltaile fatty acid etc.And medical waste refers to contacted patient blood, the human body etc., and the contaminative rubbish produced by hospital.As used cotton balls, Sha Bu, adhesive plaster, waste water, disposable medical appliance, postoperative waste products, expired medicine etc.Medical examining report according to national health department shows, because medical waste has space-pollution, the features such as acute infection and latent pollution, its virus, the hazardness of germ be common domestic refuse tens, hundreds of even thousands of times.If dealt with improperly, will the severe contamination to environment be caused, also may become the source of pestilence.Process at present for medical waste has had a set of perfect Convention Mechanism, but will inevitably cause in the generation and treating processes of medical waste that people's is unhappy, therefore just need a kind of can the material of deodorizing as the container of these rubbish, can reduce this kind of rubbish generation, deposit with treating processes in bring negative impact.
Summary of the invention
The object of the invention is to provide a kind of deodorizing medical material and preparation method thereof to overcome above the deficiencies in the prior art, this material can well remove the stink in medical waste.
The present invention is realized by following technique means:
A kind of deodorizing medical material, comprises in components by weight percent: PVC40-50 part, PET20-30 part, propoxylation lauryl alcohol 10-20 part; 1,2,4-tricarboxylic acid-2-phosphoryl butane 3-8 part; Virahol 5-10 part, sodium bicarbonate 1-4 part, water glass 2-6 part; ammonium sulfate 0.5-1 part, talcum powder 0.2-1 part, permethrin 0.2-1 part; ferric sulfate 0.5-1 part, citric acid 1-5 part, polycarbonate 2-6 part; oxidation inhibitor 0.5-1 part, epoxy chloropropane 1-4 part, ammonium persulphate 1-3 part.
Described deodorizing medical material, can preferably comprise in components by weight percent: PVC43-47 part, PET22-26 part, propoxylation lauryl alcohol 13-16 part; 1,2,4-tricarboxylic acid-2-phosphoryl butane 6-8 part; Virahol 7-9 part, sodium bicarbonate 2-4 part, water glass 3-5 part; ammonium sulfate 0.6-0.8 part, talcum powder 0.4-0.8 part, permethrin 0.4-0.6 part; ferric sulfate 0.7-1 part, citric acid 2-4 part, polycarbonate 3-5 part; oxidation inhibitor 0.6-0.8 part, epoxy chloropropane 2-4 part, ammonium persulphate 2-3 part.
Above-described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, obtains deodorizing medical material.
The preparation method of described deodorizing medical material, the condition mixed in step 2 can be temperature 40-50 DEG C, and the speed of being uniformly mixed is 200-300 rev/min.
The preparation method of described deodorizing medical material, the condition of extrusion moulding in step 3 can be temperature 180-210 DEG C, and screw slenderness ratio is 15:1, screw speed 35-45 rev/min.
Deodorizing medical material provided by the invention has good physicals and deodoriging properties, wherein tensile strength reaches more than 38MPa, elongation at break reaches more than 51%, can be found out by deodorizing test simultaneously, material provided by the invention can well remove the stink of medical waste, can be widely used in medicine and hygiene fields.
Embodiment
Embodiment 1
A kind of deodorizing medical material, comprises in components by weight percent: PVC40 part, PET20 part, propoxylation lauryl alcohol 10 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 3 parts; Virahol 5 parts, sodium bicarbonate 1 part, water glass 2 parts; 0.5 part, ammonium sulfate, talcum powder 0.2 part, permethrin 0.2 part; 0.5 part, ferric sulfate, citric acid 1 part, polycarbonate 2 parts; antioxidant BHT 0.5 part, epoxy chloropropane 1 part, ammonium persulphate 1 part.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 40 DEG C, and the speed of being uniformly mixed is 200 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 180 DEG C, and screw slenderness ratio is 15:1, and screw speed 35 revs/min, obtains deodorizing medical material.
Embodiment 2
A kind of deodorizing medical material, for comprising in components by weight percent: PVC43 part, PET22 part, propoxylation lauryl alcohol 13 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 6 parts; Virahol 7 parts, sodium bicarbonate 2 parts, water glass 3 parts; 0.6 part, ammonium sulfate, talcum powder 0.4 part, permethrin 0.4 part; 0.7 part, ferric sulfate, citric acid 2 parts, polycarbonate 3 parts; antioxidant BHT 0.6 part, epoxy chloropropane 2 parts, ammonium persulphate 2 parts.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 42 DEG C, and the speed of being uniformly mixed is 220 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 185 DEG C, and screw slenderness ratio is 15:1, and screw speed 38 revs/min, obtains deodorizing medical material.
Embodiment 3
A kind of deodorizing medical material, for comprising in components by weight percent: PVC46 part, PET25 part, propoxylation lauryl alcohol 15 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 7 parts; Virahol 8 parts, sodium bicarbonate 3 parts, water glass 4 parts; 0.7 part, ammonium sulfate, talcum powder 0.6 part, permethrin 0.5 part; 0.9 part, ferric sulfate, citric acid 3 parts, polycarbonate 4 parts; antioxidant BHT 0.7 part, epoxy chloropropane 3 parts, ammonium persulphate 3 parts.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 46 DEG C, and the speed of being uniformly mixed is 260 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 200 DEG C, and screw slenderness ratio is 15:1, and screw speed 40 revs/min, obtains deodorizing medical material.
Embodiment 4
A kind of deodorizing medical material, for comprising in components by weight percent: PVC47 part, PET26 part, propoxylation lauryl alcohol 16 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 8 parts; Virahol 9 parts, sodium bicarbonate 4 parts, water glass 5 parts; 0.8 part, ammonium sulfate, talcum powder 0.8 part, permethrin 0.6 part; 1 part, ferric sulfate, citric acid 4 parts, polycarbonate 5 parts; antioxidant BHT 0.8 part, epoxy chloropropane 4 parts, ammonium persulphate 3 parts.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 50 C, and the speed of being uniformly mixed is 280 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 200 DEG C, and screw slenderness ratio is 15:1, and screw speed 42 revs/min, obtains deodorizing medical material.
Embodiment 5
A kind of deodorizing medical material, comprises in components by weight percent: PVC48 part, PET28 part, propoxylation lauryl alcohol 17 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 7 parts; Virahol 6 parts, sodium bicarbonate 4 parts, water glass 4 parts; 0.8 part, ammonium sulfate, talcum powder 0.6 part, permethrin 0.9 part; 0.7 part, ferric sulfate, citric acid 3 parts, polycarbonate 6 parts; antioxidant BHT 0.8 part, epoxy chloropropane 3 parts, ammonium persulphate 3 parts.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 48 DEG C, and the speed of being uniformly mixed is 290 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 205 DEG C, and screw slenderness ratio is 15:1, and screw speed 45 revs/min, obtains deodorizing medical material.
Embodiment 6
A kind of deodorizing medical material, comprises in components by weight percent: PVC50 part, PET30 part, propoxylation lauryl alcohol 20 parts; 1,2,4-tricarboxylic acid-2-phosphoryl butane 8 parts; Virahol 10 parts, sodium bicarbonate 4 parts, water glass 6 parts; 1 part, ammonium sulfate, talcum powder 1 part, permethrin 1 part; 1 part, ferric sulfate, citric acid 5 parts, polycarbonate 6 parts; antioxidant BHT 1 part, epoxy chloropropane 4 parts, ammonium persulphate 3 parts.
Described deodorizing medical material, described oxidation inhibitor can be antioxidant BHT.
The preparation method of the deodorizing medical material described in more than one, comprises the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, and condition is temperature 50 C, and the speed of being uniformly mixed is 300 revs/min, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, and extrusion moulding condition is temperature 210 DEG C, and screw slenderness ratio is 15:1, and screw speed 45 revs/min, obtains deodorizing medical material.
Performance test is carried out to the deodorizing medical material that above embodiment prepares, wherein deodorizing test is for make packing bag by this material, medical waste is loaded wherein, close certain hour, test the deodoriging properties of this material, wherein garbage odor is divided into 10 grades, the corresponding corresponding mark of each grade, 10 are divided into the initial undressed state of rubbish, and 1 is divided into the state be destitute of smell, and test result is as follows:
As can be seen from above test-results, deodorizing medical material provided by the invention has good physicals and deodoriging properties, wherein tensile strength reaches more than 38MPa, elongation at break reaches more than 51%, can be found out by deodorizing test simultaneously, material provided by the invention can well remove the stink of medical waste, can be widely used in medicine and hygiene fields.

Claims (6)

1. a deodorizing medical material, is characterized in that, comprises in components by weight percent: PVC 40-50 part, PET 20-30 part; propoxylation lauryl alcohol 10-20 part, 1,2,4-tricarboxylic acid-2-phosphoryl butane 3-8 part; Virahol 5-10 part, sodium bicarbonate 1-4 part, water glass 2-6 part; ammonium sulfate 0.5-1 part, talcum powder 0.2-1 part, permethrin 0.2-1 part; ferric sulfate 0.5-1 part, citric acid 1-5 part, polycarbonate 2-6 part; oxidation inhibitor 0.5-1 part, epoxy chloropropane 1-4 part, ammonium persulphate 1-3 part.
2. deodorizing medical material according to claim 1; it is characterized in that, comprise in components by weight percent: PVC 43-47 part, PET 22-26 part; propoxylation lauryl alcohol 13-16 part; 1,2,4-tricarboxylic acid-2-phosphoryl butane 6-8 part; Virahol 7-9 part; sodium bicarbonate 2-4 part, water glass 3-5 part, ammonium sulfate 0.6-0.8 part; talcum powder 0.4-0.8 part; permethrin 0.4-0.6 part, ferric sulfate 0.7-1 part, citric acid 2-4 part; polycarbonate 3-5 part; oxidation inhibitor 0.6-0.8 part, epoxy chloropropane 2-4 part, ammonium persulphate 2-3 part.
3. deodorizing medical material according to claim 1 and 2, is characterized in that, described oxidation inhibitor is antioxidant BHT.
4. the preparation method of the deodorizing medical material described in claim 1 or 2, is characterized in that, comprise the following steps:
Step one, takes each component according to weight part;
Step 2, is uniformly mixed each component in mixing machine, obtains mixture one;
Step 3, carries out extrusion moulding by mixture one in twin screw extruder, obtains deodorizing medical material.
5. the preparation method of deodorizing medical material according to claim 4, is characterized in that, the condition mixed in step 2 is temperature 40-50 DEG C, and the speed of being uniformly mixed is 200-300 rev/min.
6. the preparation method of deodorizing medical material according to claim 4, is characterized in that, the condition of extrusion moulding in step 3 is temperature 180-210 DEG C, and screw slenderness ratio is 15:1, screw speed 35-45 rev/min.
CN201410624299.8A 2014-11-07 2014-11-07 Deodorizing medical material and preparation method thereof Pending CN104403226A (en)

Priority Applications (1)

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CN201410624299.8A CN104403226A (en) 2014-11-07 2014-11-07 Deodorizing medical material and preparation method thereof

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Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131471A (en) * 2015-09-23 2015-12-09 江苏蓝湾生物科技有限公司 Preparation method of acid and alkali resistant medical composite material
CN106221170A (en) * 2016-07-29 2016-12-14 江苏蓝湾生物科技有限公司 A kind of preparation method of high temperature resistant deodorization masterbatch

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131471A (en) * 2015-09-23 2015-12-09 江苏蓝湾生物科技有限公司 Preparation method of acid and alkali resistant medical composite material
CN106221170A (en) * 2016-07-29 2016-12-14 江苏蓝湾生物科技有限公司 A kind of preparation method of high temperature resistant deodorization masterbatch

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Application publication date: 20150311