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CN104388849A - Quick molding method of metal-matrix composite part - Google Patents

Quick molding method of metal-matrix composite part Download PDF

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Publication number
CN104388849A
CN104388849A CN201410762728.8A CN201410762728A CN104388849A CN 104388849 A CN104388849 A CN 104388849A CN 201410762728 A CN201410762728 A CN 201410762728A CN 104388849 A CN104388849 A CN 104388849A
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fibers
layer
powder
matrix composite
metal matrix
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单忠德
刘丰
杨东霞
战丽
张群
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Advanced Manufacture Technology Center China Academy of Machinery Science and Technology
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Advanced Manufacture Technology Center China Academy of Machinery Science and Technology
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Abstract

本发明公开一种金属基复合材料零部件的快速成形方法。该方法将零部件三维CAD模型沿Z向分层,逐层铺设纤维,并紧随纤维进行激光融敷,完成一层打印后,下降一个层厚,层层打印,直至完成零部件制造。该成形方法柔性高,能成形复杂形状零部件,适合复杂梯度复合材料的快速制备。

The invention discloses a rapid prototyping method for metal matrix composite parts. In this method, the three-dimensional CAD model of the part is layered along the Z direction, the fibers are laid layer by layer, and laser fusion is carried out following the fibers. After one layer of printing is completed, the thickness of one layer is reduced and printed layer by layer until the part is manufactured. The forming method has high flexibility, can form parts with complex shapes, and is suitable for the rapid preparation of complex gradient composite materials.

Description

一种金属基复合材料零部件的快速成形方法A Rapid Prototyping Method for Metal Matrix Composite Parts

技术领域 technical field

本发明属于制造技术领域,特别涉及一种连续纤维增强金属基复合材料零部件的快速成形方法。 The invention belongs to the field of manufacturing technology, in particular to a rapid prototyping method for continuous fiber reinforced metal matrix composite parts.

背景技术 Background technique

连续纤维增强金属基复合材料是利用高强度、高模量、低密度的硼纤维、氧化铝纤维、碳化硅纤维、碳纤维等作为增强体,与相应的金属基体复合而成的。与短纤维增强连续纤维增强金属基复合材料相比,连续纤维增强复合材料的机械强度、压缩强度、耐疲劳性能都得到很大的提高,因此在先进武器、航空航天等领域有着更加广阔的应用前景。传统的连续纤维增强金属基复合材料的制备方法可以分为固态法(FFF)和液态法两类。固态法是将金属箔或金属粉末与纤维按设计要求以一定的含量、分布、方向混合排布在一起,再经加压、加热,将金属基体与增强物复合黏结在一起,形成复合材料的制备方法。该方法工艺复杂,特别是基体合金箔的制造,严重限制其广泛应用。液态法是先把纤维增强相预制成型,然后将基体熔体倾入,在加压或负压条件下使其浸渗到纤维间隙而达到复合化的目的。这种方法只用于熔点较低的材料,如镁、铝和锌合金等,对于熔点高的钛基和镍基复合材料应用较少。 Continuous fiber-reinforced metal matrix composites are made of high-strength, high-modulus, low-density boron fibers, alumina fibers, silicon carbide fibers, carbon fibers, etc. as reinforcements, combined with the corresponding metal matrix. Compared with short-fiber reinforced continuous fiber-reinforced metal matrix composites, continuous fiber-reinforced composites have greatly improved mechanical strength, compressive strength, and fatigue resistance, so they have wider applications in advanced weapons, aerospace and other fields prospect. The traditional preparation methods of continuous fiber reinforced metal matrix composites can be divided into two categories: solid state method (FFF) and liquid state method. The solid-state method is to mix and arrange metal foil or metal powder and fibers together in a certain content, distribution, and direction according to the design requirements, and then pressurize and heat to bond the metal matrix and reinforcement together to form a composite material. Preparation. The process of this method is complex, especially the manufacture of the matrix alloy foil, which seriously limits its wide application. The liquid method is to prefabricate the fiber-reinforced phase first, then pour the matrix melt into it, and make it infiltrate into the fiber gap under pressure or negative pressure to achieve the purpose of compounding. This method is only used for materials with lower melting points, such as magnesium, aluminum and zinc alloys, and is less used for titanium-based and nickel-based composite materials with high melting points.

快速成形(Rapid Prototyping)技术兴起于20世纪90年代,是集计算机技术、激光加工技术、新型材料技术于一体的零件原型制造技术。不同于传统的去除材料制造零件的方法,快速成形技术是依靠CAD软件,在计算集中建立三维实体模型,并将其离散化成一系列平面几何信息,通过控制激光束或电子束等热源的扫描方向和速度,采用粘结、烧结、聚合或化学与反应等手段逐层有选择的加工原材料,从而快速堆积出实体模型的增材制造方法。目前常用的快速成形方法有:光固化成型(SLA)、分层实体制造(LOM)、选取激光烧结(SLS)、三维打印(3DP)和熔融沉积制造(FDM)。这些方法一般采用光敏树脂、塑料薄膜、蜡、尼龙、金属或陶瓷粉末作为成形材料,因此只能制造相应材料的金属或非金属零件。对于市场需求旺盛、应用前景广阔的复合材料,特别是连续纤维增强金属基复合材料的快速制造,上述方法都很难实现。 Rapid prototyping (Rapid Prototyping) technology emerged in the 1990s. It is a part prototype manufacturing technology that integrates computer technology, laser processing technology, and new material technology. Different from the traditional method of removing material to manufacture parts, rapid prototyping technology relies on CAD software to establish a three-dimensional solid model in the calculation set, and discretize it into a series of plane geometric information, by controlling the scanning direction of heat sources such as laser beams or electron beams And speed, using methods such as bonding, sintering, polymerization or chemical and reaction to selectively process raw materials layer by layer, so as to quickly accumulate a solid model additive manufacturing method. Currently commonly used rapid prototyping methods are: stereolithography (SLA), layered solid manufacturing (LOM), selective laser sintering (SLS), three-dimensional printing (3DP) and fused deposition manufacturing (FDM). These methods generally use photosensitive resin, plastic film, wax, nylon, metal or ceramic powder as forming materials, so only metal or non-metal parts of corresponding materials can be manufactured. For composite materials with strong market demand and broad application prospects, especially the rapid manufacturing of continuous fiber-reinforced metal matrix composites, the above methods are difficult to achieve.

激光熔覆技术是20世纪70年代兴起的一种新的激光加工技术,它是利用激光辐照作用将合金粉末或陶瓷粉末与基体表面迅速加热并熔化,随后冷却形成稀释率极低,与基体材料呈冶金结合的表面涂层一种表面强化方法。由于激光熔敷层的冷却速度快,容易得到细晶组织或产生平衡态所无法得到的新相,如非稳相、非晶态,因此具有优异的耐磨、耐蚀、耐热、抗氧化及电气特性。 Laser cladding technology is a new laser processing technology that emerged in the 1970s. It uses laser irradiation to rapidly heat and melt alloy powder or ceramic powder and the surface of the substrate, and then cools to form a very low dilution rate. Surface coating of materials that are metallurgically bonded A method of surface strengthening. Due to the fast cooling rate of the laser cladding layer, it is easy to obtain a fine-grained structure or a new phase that cannot be obtained in an equilibrium state, such as an unstable phase and an amorphous state, so it has excellent wear resistance, corrosion resistance, heat resistance, and oxidation resistance. and electrical characteristics.

发明内容 Contents of the invention

本发明的目的在于提供一种精度高、性能好、自动化程度高的连续纤维增强金属基复合材料零部件的快速制造方法。 The purpose of the present invention is to provide a rapid manufacturing method of continuous fiber reinforced metal matrix composite parts with high precision, good performance and high degree of automation.

 本发明的连续纤维增强金属基复合材料零部件的快速制造方法包括以下步骤: The rapid manufacturing method of continuous fiber reinforced metal matrix composite parts of the present invention comprises the following steps:

A.    利用三维CAD造型软件建立零部件的三维实体模型; A. Use 3D CAD modeling software to establish 3D solid models of parts;

B.    将建立的模型Z向离散化; B. Discretize the established model in the Z direction;

C.    对层片进行纤维铺放路径规划; C. Carry out fiber laying path planning for the ply;

D.    根据层片的规划路径连续铺放纤维,并紧随铺放的纤维进行激光熔敷; D. Lay fibers continuously according to the planned path of the ply, and perform laser welding following the laid fibers;

E.     完成层片熔敷后,工作台下降一个工作高度; E. After the layer welding is completed, the workbench is lowered to a working height;

F.     重复步骤D、E,直至零件加工完成。 F. Repeat steps D and E until the part is finished.

所述的纤维的铺放方法为,纤维由导丝嘴导出,并在导丝嘴的带动下移动。 The fiber laying method is as follows: the fiber is led out by the wire guide nozzle and moved under the drive of the wire guide nozzle.

所述的激光熔敷的方法为,紧随铺放的纤维,在其已铺放纤维的路径喷射金属粉末,并采用激光辐照使粉末熔化。喷射的金属粉末可以为铝及铝合金粉末、镁及镁合金粉末、钛及钛合金粉末、镍及镍合金粉末。 The laser cladding method is as follows, following the laid fibers, spraying metal powder on the path where the fibers have been laid, and using laser radiation to melt the powder. The sprayed metal powder can be aluminum and aluminum alloy powder, magnesium and magnesium alloy powder, titanium and titanium alloy powder, nickel and nickel alloy powder.

所述对已铺放纤维激光熔敷时,判断层片是否为第一层,若层片为第一层,则不需要铺放纤维,只进行激光熔敷。熔敷完成后根据层片信息对熔覆层进行层面的去除加工。 When laser cladding the placed fibers, it is judged whether the ply is the first layer. If the ply is the first layer, it is not necessary to lay the fibers, and only laser cladding is performed. After the cladding is completed, the cladding layer is removed according to the layer information.

为了达到更好的熔敷效果,在所述用激光熔敷时采用以下工艺条件:激光功率200-3000W,光斑直径1-8mm,扫描速度10-100mm/s,送粉量5-25g/min。 In order to achieve a better welding effect, the following process conditions are used in the laser welding: laser power 200-3000W, spot diameter 1-8mm, scanning speed 10-100mm/s, powder feeding amount 5-25g/min .

本发明的连续纤维增强金属基复合材料零部件的快速成形方法产生的有益效果是: The beneficial effects produced by the rapid prototyping method of continuous fiber reinforced metal matrix composite parts of the present invention are:

(1)在计算机三维实体模型的基础上,采用二维平面加工直接成形出连续纤维增强金属基复合材料的零部件,降低了制造难度与对数控系统高维制造的要求; (1) On the basis of the computer three-dimensional solid model, two-dimensional plane processing is used to directly form parts of continuous fiber-reinforced metal matrix composite materials, which reduces the manufacturing difficulty and the requirements for high-dimensional manufacturing of the numerical control system;

(2)纤维铺放和激光熔敷同步进行,成形速度快,易于实现连续纤维增强金属基复合材料的快速成形; (2) Fiber laying and laser cladding are carried out simultaneously, the forming speed is fast, and it is easy to realize the rapid prototyping of continuous fiber reinforced metal matrix composites;

(3)通过激光功率的调节,不仅可以实现熔点较低的镁、铝、锌基复合材料的制备,还可以用于高熔点金属如钛基和镍基复合材料的快速成形; (3) Through the adjustment of laser power, not only the preparation of magnesium, aluminum and zinc-based composite materials with low melting point can be realized, but also the rapid prototyping of high-melting point metals such as titanium-based and nickel-based composite materials can be realized;

(4)基体材料采用粉末可以大大增加材料设计的灵活性,使复杂梯度复合材料的快速制备成为可能; (4) The use of powder as the matrix material can greatly increase the flexibility of material design, making it possible to rapidly prepare complex gradient composite materials;

(5)激光熔敷热输入小,熔敷层的变形很小,因此有利于实现大尺寸金属基复合材料的快速制造。 (5) The heat input of laser cladding is small, and the deformation of the cladding layer is small, so it is conducive to the rapid manufacture of large-scale metal matrix composites.

附图说明 Description of drawings

图1是本发明的连续纤维增强金属基复合材料的快速制造工艺流程图; Fig. 1 is the rapid manufacturing process flowchart of continuous fiber reinforced metal matrix composite material of the present invention;

图2是本发明的连续纤维增强金属基复合材料的制造示意图; Fig. 2 is the manufacturing schematic diagram of continuous fiber reinforced metal matrix composite material of the present invention;

图3是实施例1中制造的碳纤维增强铝基复合材料长方体零件示意图; Fig. 3 is the schematic diagram of the cuboid part of carbon fiber reinforced aluminum matrix composite material manufactured in embodiment 1;

图4是实施例1中制造的碳纤维增强钛合金管状零件示意图; Fig. 4 is the schematic diagram of the carbon fiber reinforced titanium alloy tubular part manufactured in embodiment 1;

附图标记 reference sign

1-工作台  2-纤维  3-导丝嘴  4-熔覆头  5-金属粉末  6-激光头  7-铣刀 1-Working table 2-Fiber 3-Wire guide nozzle 4-Cladding head 5-Metal powder 6-Laser head 7-Milling cutter

8-金属基复合材料。 8 - Metal matrix composites.

具体实施方式 Detailed ways

下面通过两个实施例对本发明做详细的说明,但不作为对本发明的限定。 The present invention will be described in detail through two examples below, but not as a limitation of the present invention.

实施例一:利用本发明制造一个40×40×10mm的碳纤维增强铝基复合材料长方体零件; Embodiment 1: Utilize the present invention to manufacture a 40×40×10mm carbon fiber reinforced aluminum matrix composite cuboid part;

(1)利用计算机建立40×40×10mm的立方体模型; (1) Use a computer to build a cube model of 40×40×10mm;

(2)将上述模型进行Z向离散化处理,即将立方体模型分成厚度为1mm的层状模型,共10层,每层为40×40mm的正方形; (2) The above model is discretized in the Z direction, that is, the cube model is divided into a layered model with a thickness of 1mm, a total of 10 layers, and each layer is a square of 40×40mm;

(3)根据层片厚度选择粗细匹配的纤维及匹配的激光熔敷工艺; (3) Select fiber with matching thickness and matching laser cladding process according to the thickness of the layer;

(4) 根据层片模型确定铺放及激光熔敷路径; (4) Determine the laying and laser cladding path according to the ply model;

(5)判断该层是否是第一层,如果是,沿规划路径喷射铝合金粉末,并在激光辐照下实现熔敷,否则进行步骤(6); (5) Determine whether the layer is the first layer, if so, spray aluminum alloy powder along the planned path, and achieve welding under laser irradiation, otherwise proceed to step (6);

(6)利用铣刀将熔敷片层厚度方向1mm以外的部分去除; (6) Use a milling cutter to remove the part other than 1mm in the thickness direction of the welded sheet;

(7)由导丝嘴引导纤维沿规划路径移动,熔覆头和激光头紧随导丝嘴,以同轴送粉的形式在其后方移动; (7) The fiber is guided by the wire guide to move along the planned path, and the cladding head and the laser head follow the wire guide and move behind it in the form of coaxial powder feeding;

(8)层片加工完成后,将工作台下移1mm; (8) After the layer processing is completed, move the workbench down by 1mm;

(9)判断是否所有层片全部加工完成,如果不是,重复步骤(6)~(8),直至所有层片加工完毕。 (9) Determine whether all layers are processed, if not, repeat steps (6)~(8) until all layers are processed.

实施例二:利用本发明制造一个内径36mm,外径40mm,高度10mm的碳纤维增强钛合金管状零件; Embodiment two: Utilize the present invention to manufacture a carbon fiber reinforced titanium alloy tubular part with an inner diameter of 36mm, an outer diameter of 40mm, and a height of 10mm;

(1)利用计算机建立内径36mm,外径40mm,高度10mm的管状模型; (1) Use a computer to build a tubular model with an inner diameter of 36mm, an outer diameter of 40mm, and a height of 10mm;

(2)将上述模型进行Z向离散化处理,即将立方体模型分成厚度为2mm的层状模型,共5层,每层为内径36mm,外径40mm的圆环; (2) The above model is discretized in the Z direction, that is, the cube model is divided into a layered model with a thickness of 2mm, a total of 5 layers, each layer is a ring with an inner diameter of 36mm and an outer diameter of 40mm;

(3)根据层片模型确定纤维铺放及激光熔敷路径; (3) Determine the fiber placement and laser cladding path according to the ply model;

(4)根据层片厚度选择粗细匹配的纤维及匹配的激光熔敷工艺; (4) Select fiber with matching thickness and matching laser cladding process according to the thickness of the layer;

(5)判断该层是否是第一层,如果是,沿规划路径喷射钛合金粉末,并在激光辐照下实现熔敷,否则进行步骤(6); (5) Determine whether the layer is the first layer, if so, spray titanium alloy powder along the planned path, and achieve cladding under laser irradiation, otherwise proceed to step (6);

(6)利用铣刀将熔敷片层厚度方向2mm以外的部分去除; (6) Use a milling cutter to remove the part other than 2mm in the thickness direction of the welded sheet;

(7)由导丝嘴引导纤维沿规划路径移动,熔覆头和激光头紧随导丝嘴,以旁轴送粉的形式在其后方移动; (7) The fiber is guided by the guide nozzle to move along the planned path, and the cladding head and laser head follow the guide nozzle and move behind it in the form of side-axis powder feeding;

(8)层片加工完成后,将工作台下移2mm; (8) After the layer processing is completed, move the workbench down by 2mm;

(9)判断是否所有层片全部加工完成,如果不是,重复步骤(6)~(8),直至所有层片加工完毕。 (9) Determine whether all layers are processed, if not, repeat steps (6)~(8) until all layers are processed.

以上对本发明及其实施方式的描述是示意性的,没有限制性。所以,如果本领域的普通技术人员受其启示,在不脱离本发明创造宗旨的情况下,进行其他实施例,均应属于本发明的保护范围。 The above description of the present invention and its embodiments is illustrative, not restrictive. Therefore, if those of ordinary skill in the art are inspired by it and carry out other embodiments without departing from the inventive concept of the present invention, all should belong to the protection scope of the present invention.

Claims (8)

1.一种金属基复合材料零部件的快速成形方法,其特征在于,包括如下步骤: 1. A method for rapid prototyping of metal matrix composite parts, characterized in that, comprising the steps: A. 利用三维CAD造型软件建立零部件的三维实体模型; A. Use 3D CAD modeling software to establish 3D solid models of parts; B. 将建立的模型Z向离散化; B. Discretize the established model in the Z direction; C. 对层片进行纤维铺放路径规划; C. Plan the fiber laying path for the layer; D. 根据层片的规划路径连续铺放纤维,并紧随铺放的纤维进行激光熔敷; D. Continuously lay fibers according to the planned path of the ply, and perform laser welding following the placed fibers; E. 完成层片熔敷后,工作台下降一个工作高度; E. After the lamination is completed, the workbench is lowered to a working height; F. 重复步骤D、E,直至零件加工完成。 F. Repeat steps D and E until the part is finished. 2.根据权利要求1所述的连续纤维增强金属基复合材料零部件的快速成形方法,其特征在于,所述的纤维包括硼纤维、氧化铝纤维、碳化硅纤维、碳纤维。 2. The method for rapid prototyping of continuous fiber-reinforced metal matrix composite parts according to claim 1, wherein said fibers include boron fibers, alumina fibers, silicon carbide fibers, and carbon fibers. 3.根据权利要求1所述的连续纤维增强金属基复合材料零部件的快速成形方法,其特征在于,所述纤维的铺放方法为,纤维由导丝嘴导出,并在导丝嘴的带动下移动。 3. The method for rapid prototyping of continuous fiber-reinforced metal matrix composite parts according to claim 1, characterized in that the laying method of the fibers is that the fibers are led out by the guide nozzle, and driven by the guide nozzle Move down. 4.根据权利要求1所述的连续纤维增强金属基复合材料零部件的快速成形方法,其特征在于,所述激光熔敷的方法为,紧随铺放的纤维,在其已铺放纤维的路径喷射金属粉末,并采用激光辐照使粉末熔化。 4. The method for rapid prototyping of continuous fiber-reinforced metal matrix composite parts according to claim 1, characterized in that, the method of laser cladding is, following the laid fibers, on the surface where the fibers have been laid The path sprays metal powder and uses laser irradiation to melt the powder. 5.根据权利要求4所述的激光熔敷的方法,其特征在于,所述的金属粉末喷射方式为同轴送粉或旁轴送粉。 5. The laser cladding method according to claim 4, characterized in that, the metal powder spraying method is coaxial powder feeding or side-axis powder feeding. 6.根据权利要求4所述的在其已铺放的路径喷射金属粉末,其特征在于,所述的金属粉末为铝及铝合金粉末、镁及镁合金粉末、钛及钛合金粉末、镍及镍合金粉末。 6. According to claim 4, spraying metal powder on its laid path, it is characterized in that, described metal powder is aluminum and aluminum alloy powder, magnesium and magnesium alloy powder, titanium and titanium alloy powder, nickel and Nickel alloy powder. 7.根据权利要求1所述的连续纤维增强金属基复合材料零部件的快速成形方法,其特征在于,若层片为第一层,则不需要铺放纤维,只进行激光熔敷,熔敷完成后根据层片信息对熔覆层进行层面的去除加工。 7. The method for rapid prototyping of continuous fiber-reinforced metal matrix composite parts according to claim 1, characterized in that, if the ply is the first layer, it is not necessary to lay fibers, only laser welding is performed, and the welding After completion, layer removal processing is performed on the cladding layer according to the layer information. 8.根据权利要求1所述的连续纤维增强金属基复合材料零部件的快速成形方法,其特征在于,所述激光熔敷所采用的工艺条件为:激光功率200-3000W,光斑直径1-8mm,扫描速度10-100mm/s,送粉量5-25g/min。 8. The method for rapid prototyping of continuous fiber reinforced metal matrix composite parts according to claim 1, characterized in that the process conditions used in the laser cladding are: laser power 200-3000W, spot diameter 1-8mm , scanning speed 10-100mm/s, powder feeding volume 5-25g/min.
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CN105081325A (en) * 2015-08-28 2015-11-25 许昌学院 Surface quality control device for three-dimensional (3D) part formed through metal drop printing and control method of surface quality control device
CN105598441B (en) * 2015-12-23 2017-11-14 罗仙花 A kind of composite for 3D printing engine cylinder cover and preparation method thereof
CN105598441A (en) * 2015-12-23 2016-05-25 成都新柯力化工科技有限公司 Composite material for 3D printing engine cylinder cover and preparation method thereof
CN105970124A (en) * 2016-05-03 2016-09-28 太仓市武锋金属制品有限公司 Lightweight high-strength front fork inner tube of mountain bike
CN106077652A (en) * 2016-08-10 2016-11-09 河北大学 A kind of laser melting coating lamination composite forming apparatus and manufacturing process
CN106515041A (en) * 2016-11-10 2017-03-22 机械科学研究总院先进制造技术研究中心 Three-dimensional printing forming method of long fiber thermoplastic composite material component
CN106756649A (en) * 2016-11-28 2017-05-31 中国科学院金属研究所 A kind of continuous SiC fiber strengthens the laser gain material manufacture method of titanium matrix composite
CN107282924A (en) * 2017-07-10 2017-10-24 香港生产力促进局 3D printing device and method
CN107282924B (en) * 2017-07-10 2019-01-04 香港生产力促进局 3D printing device and method
CN107470619A (en) * 2017-07-12 2017-12-15 北京煜鼎增材制造研究院有限公司 A kind of increasing material manufacturing method of metal parts
CN109482886A (en) * 2019-01-07 2019-03-19 吉林大学 A kind of preparation method of 3D printing ceramic and fiber composite reinforced aluminum base material
CN114013069A (en) * 2021-10-22 2022-02-08 华中科技大学 Automatic laying and fused deposition compounding process of fiber reinforced thermoplastic material
CN114013069B (en) * 2021-10-22 2022-12-02 华中科技大学 A composite process of automatic placement and fused deposition of fiber reinforced thermoplastic materials
CN118122951A (en) * 2024-05-10 2024-06-04 内蒙古工业大学 A 3D printing film-coated reinforced casting mold and preparation method thereof

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