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CN104382758A - Zero-added emulsion and preparation method thereof - Google Patents

Zero-added emulsion and preparation method thereof Download PDF

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Publication number
CN104382758A
CN104382758A CN201410695958.7A CN201410695958A CN104382758A CN 104382758 A CN104382758 A CN 104382758A CN 201410695958 A CN201410695958 A CN 201410695958A CN 104382758 A CN104382758 A CN 104382758A
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China
Prior art keywords
emulsion
deionized water
zero
pectin
adds
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Granted
Application number
CN201410695958.7A
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Chinese (zh)
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CN104382758B (en
Inventor
邓伟健
熊洁
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GUANGZHOU SHENCAI COSMETICS Co Ltd
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GUANGZHOU SHENCAI COSMETICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by GUANGZHOU SHENCAI COSMETICS Co Ltd filed Critical GUANGZHOU SHENCAI COSMETICS Co Ltd
Priority to CN201410695958.7A priority Critical patent/CN104382758B/en
Publication of CN104382758A publication Critical patent/CN104382758A/en
Priority to HK15105694.1A priority patent/HK1204957A1/en
Priority to TW104119707A priority patent/TWI604855B/en
Application granted granted Critical
Publication of CN104382758B publication Critical patent/CN104382758B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention provides a zero-added emulsion, which is characterized by comprising the following components in percentage by weight: 8.0-14.0% of isononyl isononanoate, 0.5% of tocopheryl acetate, 3.0-8.0% of olive oil, 0.8% of pectin, 0.3-0.5% of xanthan gum, 0.4-0.6% of gellan gum, 6% of glycerinum, 0.8% of caprylyl glycol, 2.0% of beta-glucan, 0.05% of sodium hydroxide, and the balance of deionized water. Because of no any emulsifier, the emulsion disclosed by the invention is natural, environmental friendly and good in stability.

Description

A kind of zero adds emulsion and preparation method thereof
Technical field
The invention belongs to cosmetic field, be specifically related to a kind of zero emulsion of adding, and the preparation method of this emulsion.
Background technology
Emulsion cosmetic is also called emulsified body cosmetics, being a kind of liquid white class cosmetics, in fluid state under room temperature, is the mixture mixed by multiple water-soluble component and oil-soluble constitents, there is good skin moistening effect, both can supplement moisture content for skin, also can form oil film at skin surface, and prevent moisture from evaporating, maintain skin appropriate aqueous amount, also can be skin and nutrition is provided, alleviate outside stimulus, delay skin aging.
Generally, in order to form stable emulsion, usually must add emulsifying agent or surfactant, thus reduce the surface tension of biphase liquid, wherein a kind of uniform liquid is stably dispersed in another kind of liquid, avoids the layering of emulsion, sedimentation, flocculation, the problem such as coalescent to occur.But emulsifying agent and surfactant often produce certain zest, sensitive skin is easily made to occur stimulating and dehydration problem.Meanwhile, due to the existence of emulsifying agent, what add emulsion sprawls resistance, and the texture that seems is more thick and heavy and sticky.
Summary of the invention
An object of the present invention is the technical problem for solving above, provide a kind of containing emulsion that is emulsifying agent, natural, green, good stability.
Another object of the present invention is to provide the preparation method of above-mentioned emulsion.
For reaching above object, the invention provides following technical scheme:
A kind of zero adds emulsion, it is characterized in that being made up of the component of following percentage by weight:
Isononyl isononanoate 8.0% ~ 14.0%,
Tocopherol acetas 0.5%,
Olive oil 3.0% ~ 8.0%,
Pectin 0.8%,
Xanthan gum 0.3% ~ 0.5%,
Gellan gum 0.4% ~ 0.6%,
Glycerol 6%,
Caprylyl glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
Preferably, zero interpolation emulsion of the present invention is made up of the component of following percentage by weight:
Isononyl isononanoate 8.0% ~ 12.0%,
Tocopherol acetas 0.5%,
Olive oil 5.0% ~ 8.0%,
Pectin 0.8%,
Xanthan gum 0.3% ~ 0.5%,
Gellan gum 0.4% ~ 0.6%,
Glycerol 6%,
Caprylyl glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
Present invention also offers the preparation method that described zero adds emulsion, its step is as follows:
(1) pectin, xanthan gum and gellan gum are added in isononyl isononanoate, tocopherol acetas and olive oil, add oil phase pot together, open and stir, be warming up to 80 DEG C, be incubated 5 minutes;
(2) reserved appropriate amount of deionized water, remaining deionized water and glycerol are added successively in emulsifying pot, unlatching is uniformly mixed, and be warming up to 80 DEG C, be incubated 20 minutes, by the material of step (1) slowly suction emulsifying pot, homogenizing 10 minutes, cooling;
(3) mixed homogeneously with above-mentioned reserved appropriate amount of deionized water by sodium hydroxide, when pot to be emulsified is cooled to 60 DEG C, adds emulsifying pot, and stir, pH value is 4.5 ~ 6.5;
(4), when stirring is cooled to below 45 DEG C, add caprylyl glycol and beta glucan, homogenizing also stirs; Discharging when being down to 38 DEG C.
Preferably, described step (2) the mass ratio of the appropriate amount of deionized water reserved and sodium hydroxide be 4:1.
Compared with prior art, emulsion of the present invention has the following advantages:
(1) not containing any emulsifying agent and surfactant, compared with traditional oil-in-water type product, there is higher safety;
(2) breach traditional emulsifying technology and theory, make stable, can the oil-in-water type product of suitability for industrialized production;
(3) the suspension thick stabilization system that this product uses is natural, green, environmental protection, renewable and can be degradable;
(4) zero interpolation emulsion skinfeel of the present invention is splendid, merrily and lightheartedly soft and smooth, moistens and is easy to absorb.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme of the present invention is described in further detail, but protection scope of the present invention is not limited in following examples.
Weigh each component according to following percentage by weight, following component is all bought by commercial channel and is obtained.
The emulsion of preparation described in embodiment 1 ~ 3, its step is as follows:
1. pectin, xanthan gum and gellan gum are added in isononyl isononanoate, tocopherol acetas and olive oil, add oil phase pot together, open and stir, be warming up to 80 DEG C, be incubated 5 minutes;
2. added successively in emulsifying pot by the raw material of B component, unlatching is uniformly mixed, and is warming up to 80 DEG C, is incubated 20 minutes, by the raw material of component A slowly suction emulsifying pot, and homogenizing 10 minutes, cooling;
3., by component C mix homogeneously, when emulsifying pot drops to 60 DEG C, add in emulsifying pot, stir; PH value range: 4.5 ~ 6.5;
4., when stirring is cooled to below 45 DEG C, add D component, homogenizing also stirs; Discharging when being down to 38 DEG C.
Product stability is assessed
1. temperature stability test
(1) 48 DEG C of stability test:
Test sample: 1 or more
Testing time: 4 weeks method of testings: product (content) is loaded in the PET bottle of 30mL, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed in the heat-resistant stability of the biochemical cultivation case test products of 48 DEG C, 24 hours, 1 week, 2 weeks, 4 weeks time, (returning to room temperature) observes the change of the outward appearance of product, abnormal smells from the patient, pH, viscosity respectively, and by the change of day part, be recorded in report.
(2) 40 DEG C of stability tests:
Test sample: 1 or more
Testing time: 12 weeks
Method of testing: product (content) is loaded in the PET bottle of 30ML, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed in the heat-resistant stability of the biochemical cultivation case test products of 40 DEG C, when 24 hours, 1 week, 2 weeks, 4 weeks, 8 weeks and 12 weeks, (returning to room temperature) observed the change of the outward appearance of product, abnormal smells from the patient, pH, viscosity respectively, and by the change of day part, be recorded in report.
(3) room temperature (Ambient) stability test:
Test sample: 1 or more
Testing time: 12 weeks
Method of testing: product (content) is loaded in the PET bottle of 30ML, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed in sample cabinet, respectively 24 hours (survey pH value, viscosimetric), 1 week, 2 weeks, 4 weeks, 8 weeks and 12 weeks (survey pH value) time the outward appearance of observation product, abnormal smells from the patient, pH, viscosity change, and by the change of day part, be recorded in report.
(4)-18 DEG C of stability tests:
Test sample: 1 or more
Testing time: 12 weeks
Method of testing: product (content) is loaded in the PET bottle of 30ML, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed in the cold-resistant stability of-18 DEG C of refrigerator test products, when 24 hours, 1 week, 2 weeks, 4 weeks, 8 weeks and 12 weeks, (returning to room temperature) observed the change of the outward appearance of product, abnormal smells from the patient, pH, viscosity respectively, and by the change of day part, be recorded in report.
(5) 48 DEG C and-18 DEG C of cyclical stability tests
Test sample: 1 or more
Testing time: continuous three loop tests (first place in 48 DEG C of biochemical cultivation cases after 24 hours, place 24 hours at room temperature, be then placed on-18 DEG C of refrigerators 24 hours, and then return to room temperature be a circulation and observed result).
Method of testing: product (content) is loaded in the PET bottle of 30ML, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed in the biochemical cultivation case 24 hours of 48 DEG C, place 24 hours at room temperature, then be placed in-18 DEG C of refrigerators 24 hours, and then return to room temperature.Observe the change of product outward appearance, abnormal smells from the patient, PH, viscosity etc. of product when cold-resistant heat-resisting alternate cycles, and be recorded in report.
2. sunlight stability test
Test sample: 1 or more
Testing time: 4 weeks
Sunlight stability test: product (content) is loaded in the PET bottle of 30ML, labelled, indicate name of product, formula number, the information such as test condition, testDate, be placed on place near the window, west (label facing away from sunlight), 24 hours, 1 week, 2 weeks, 4 weeks time, (returning to room temperature) observes the outward appearance of product, the change of abnormal smells from the patient respectively, and by the change of day part, be recorded in report.
Stability result: use above-mentioned 6 kinds of stability test methods to add emulsion to zero of embodiment 1 to 3 gained and test, through the stability test of 12 weeks, every stability test result display, it is better that zero of embodiment 1 to 3 adds stability of emulsion, meets relevant provisions of laws and regulations completely.
Product Safety assessment (human skin patch result)
1. tested material: cosmetics finished product (emulsion).
2. negative control: blank.
3. experimenter: totally 40 people, male 15 people, female 25 people, at 18 ~ 30 years old age, meets experimenter and volunteers inclusion criteria.
4. speckle method for testing: select qualified speckle examination device, with closed patch test method, tested material being about 0.02ml ~ 0.025ml is applied in speckle examination device, external special adhesive tape sticks in the bent side of experimenter's forearm, tested material is removed after 24 hours, 30min after removal tested material speckle examination device, observes dermoreaction, by its result of dermoreaction grade scale record in " cosmetics health specification " (version in 2007) after impression disappears.
5. evaluation of result: according to the form below (skin adverse reaction grade scale) records reaction result.
6. result of the test (seeing the following form):
Human skin patch result shows: in embodiments of the invention 1 ~ 3, and 40 subjects skin are all negative reaction (grading system: 0 grade).According to " cosmetics health specification " (version in 2007) human body skin class paste test criterion, sample to human body without skin adverse reaction.And reference examples (commercially available domestic famous brand name emulsion) has 2 experimenters to occur 1 order reaction.
According to the reflection of user, zero interpolation emulsion skinfeel of the present invention is splendid, merrily and lightheartedly soft and smooth, moistens and is easy to absorb.

Claims (3)

1. zero adds an emulsion, it is characterized in that the component comprising following percentage by weight:
Isononyl isononanoate 8.0% ~ 14.0%,
Tocopherol acetas 0.5%,
Olive oil 3.0% ~ 8.0%,
Pectin 0.8%,
Xanthan gum 0.3% ~ 0.5%,
Gellan gum 0.4% ~ 0.6%,
Glycerol 6%,
Caprylyl glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
2. according to claim 1 zero adds emulsion, it is characterized in that the component comprising following percentage by weight:
Isononyl isononanoate 8.0% ~ 12.0%,
Tocopherol acetas 0.5%,
Olive oil 5.0% ~ 8.0%,
Pectin 0.8%,
Xanthan gum 0.3% ~ 0.5%,
Gellan gum 0.4% ~ 0.6%,
Glycerol 6%,
Caprylyl glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
3. zero described in claim 1 or 2 adds the preparation method of emulsion, and its step is as follows:
(1) pectin, xanthan gum and gellan gum are added in isononyl isononanoate, tocopherol acetas and olive oil, add oil phase pot together, open and stir, be warming up to 80 DEG C, be incubated 5 minutes;
(2) reserved appropriate amount of deionized water, remaining deionized water and glycerol are added successively in emulsifying pot, unlatching is uniformly mixed, and be warming up to 80 DEG C, be incubated 20 minutes, by the material of step (1) slowly suction emulsifying pot, homogenizing 10 minutes, cooling;
(3) mixed homogeneously with above-mentioned reserved appropriate amount of deionized water by sodium hydroxide, when pot to be emulsified is cooled to 60 DEG C, adds emulsifying pot, and stir, pH value is 4.5 ~ 6.5;
(4), when stirring is cooled to below 45 DEG C, add caprylyl glycol and beta glucan, homogenizing also stirs; Discharging when being down to 38 DEG C.
CN201410695958.7A 2014-11-25 2014-11-25 One kind zero adds emulsion and preparation method thereof Expired - Fee Related CN104382758B (en)

Priority Applications (3)

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CN201410695958.7A CN104382758B (en) 2014-11-25 2014-11-25 One kind zero adds emulsion and preparation method thereof
HK15105694.1A HK1204957A1 (en) 2014-11-25 2015-06-16 Emulsifier-free emulsion and preparation method thereof
TW104119707A TWI604855B (en) 2014-11-25 2015-06-18 Emulsifier-free emulsion and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN104382758B CN104382758B (en) 2017-08-22

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TW (1) TWI604855B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105168080A (en) * 2015-08-27 2015-12-23 广州智媛生物科技有限公司 Double whitening emulsion and preparation method thereof
CN105456052A (en) * 2015-12-25 2016-04-06 肇庆迪彩日化科技有限公司 Skin care composition
CN106214532A (en) * 2016-07-26 2016-12-14 广州智媛生物科技有限公司 There is compositions of control oil bacteriostasis efficacy and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107232581B (en) * 2017-06-29 2020-08-14 河南鼎元食品科技有限公司 A kind of quick-frozen rice noodle food quality improver and preparation method thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101410172A (en) * 2005-11-23 2009-04-15 雀巢技术公司 Oil-in-water emulsion for creating new product consistencies
CN103405379A (en) * 2013-07-29 2013-11-27 广州丹奇日用化工厂有限公司 Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product
US20140271508A1 (en) * 2013-03-15 2014-09-18 Mary Kay Inc. Cosmetic compositions and uses thereof
CN104146922A (en) * 2014-08-26 2014-11-19 广州神采化妆品有限公司 Sun-blocking and moisturizing composition and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101410172A (en) * 2005-11-23 2009-04-15 雀巢技术公司 Oil-in-water emulsion for creating new product consistencies
US20140271508A1 (en) * 2013-03-15 2014-09-18 Mary Kay Inc. Cosmetic compositions and uses thereof
CN103405379A (en) * 2013-07-29 2013-11-27 广州丹奇日用化工厂有限公司 Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product
CN104146922A (en) * 2014-08-26 2014-11-19 广州神采化妆品有限公司 Sun-blocking and moisturizing composition and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105168080A (en) * 2015-08-27 2015-12-23 广州智媛生物科技有限公司 Double whitening emulsion and preparation method thereof
CN105168080B (en) * 2015-08-27 2018-06-19 广州智媛生物科技有限公司 A kind of dual whitening emulsion and preparation method thereof
CN105456052A (en) * 2015-12-25 2016-04-06 肇庆迪彩日化科技有限公司 Skin care composition
CN106214532A (en) * 2016-07-26 2016-12-14 广州智媛生物科技有限公司 There is compositions of control oil bacteriostasis efficacy and preparation method thereof
CN106214532B (en) * 2016-07-26 2019-04-19 广州智媛生物科技有限公司 Composition and preparation method thereof with oil-control bacteriostasis efficacy

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Publication number Publication date
TWI604855B (en) 2017-11-11
TW201622692A (en) 2016-07-01
HK1204957A1 (en) 2015-12-11
CN104382758B (en) 2017-08-22

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