CN104371518A - Coating with good weather resistance - Google Patents
Coating with good weather resistance Download PDFInfo
- Publication number
- CN104371518A CN104371518A CN201410638012.7A CN201410638012A CN104371518A CN 104371518 A CN104371518 A CN 104371518A CN 201410638012 A CN201410638012 A CN 201410638012A CN 104371518 A CN104371518 A CN 104371518A
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- coating
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- acid
- degree
- good weatherability
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- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims abstract description 24
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000003973 paint Substances 0.000 claims abstract description 13
- 229920000180 alkyd Polymers 0.000 claims abstract description 9
- 239000004203 carnauba wax Substances 0.000 claims abstract description 9
- 235000019386 wax ester Nutrition 0.000 claims abstract description 9
- 239000003921 oil Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003822 epoxy resin Substances 0.000 claims abstract description 5
- 239000000113 methacrylic resin Substances 0.000 claims abstract description 5
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 5
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 5
- 239000002383 tung oil Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 23
- -1 olein ester Chemical class 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 8
- 238000005886 esterification reaction Methods 0.000 claims description 8
- 229940038384 octadecane Drugs 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
- 239000008158 vegetable oil Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 150000002632 lipids Chemical class 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 4
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 4
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 4
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 claims description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 235000021388 linseed oil Nutrition 0.000 claims description 4
- 239000000944 linseed oil Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 150000004666 short chain fatty acids Chemical class 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 229940033355 lauric acid Drugs 0.000 claims description 3
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000002075 anti-alcohol Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
- C08G63/21—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups in the presence of unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a coating, and particularly relates to a coating with good weather resistance. The coating comprises the following components in percentage by weight: 30%-40% of modified alkyd resin, 20%-30% of tung oil, 10%-16% of epoxy resin, 2%-5% of terephthalic acid, 12%-16% of palm wax ester, 5%-8% of methacrylic resin, 1%-3% of acrylic paint, 5%-10% of polyvinyl butyral, 3%-5% of defoaming agents and the balance of thinners. The coating disclosed by the invention has excellent properties. According to the coating, a paint film is difficult to age and has good mineral oil resistance and alcohol solvent resistance by being formed into a high-reticular structure after being dried, a baked paint film is greatly enhanced in water resistance, insulativity and oil resistance and has the advantages of good transparency, fullness and distinctness of image, good weather resistance and lasting luster, and the paint film is flexible, firm and resistant in friction.
Description
Technical field
The present invention relates to a kind of coating, especially a kind of coating of good weatherability.
Background technology
Weathering resistance refers to that film is because being subject to solar radiation, temperature variation, the impact of the ambient conditionss such as wind and weather, and occur fade, variable color, be full of cracks, a series of aging phenomenon such as efflorescence and strength degradation.The weathering resistance of a lot of coating is not strong at present.Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.Belong to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The classification of the Chemicals of passing through according to the modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, and provides a kind of coating of good weatherability, its excellent performance, height of formation reticulated structure after drying varniss, not easily aging, anti-mineral oil, anti-alcoholic solvent are good, and the paint film water tolerance after baking, insulativity, oil-proofness improve all greatly, transparency, fullness ratio and clarity are good, good weatherability, gloss does not move back lastingly, and paint film is pliable and tough strong, rub resistance, its technical scheme adopted is as follows:
A kind of coating of good weatherability, it is characterized in that: its composition weight proportioning is: the modified alkyd resin of 30 ~ 40%, the tung oil of 20 ~ 30%, 10 ~ 16% epoxy resin, the terephthalic acid of 2 ~ 5%, palm wax ester, the methacrylic resin of 5 ~ 8%, acrylic paints, the polyvinyl butyral acetal of 5 ~ 10%, the defoamer of 3 ~ 5% of 1 ~ 3% of 12 ~ 16%, all the other are solvent or diluent.
On technique scheme basis, described palm wax ester is palm grease, palm-kernel ester or palm olein ester.
On technique scheme basis, described defoamer is polysiloxane defoamers.
On technique scheme basis, the preparation method of described modified alkyd resin, it comprises the following steps: a) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filter and obtain modification.
On technique scheme basis, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.
On technique scheme basis, described latting drown low boiling ester kind solvent is vinyl acetic monomer or methylcarbonate.
Tool of the present invention has the following advantages: excellent performance, height of formation reticulated structure after drying varniss, not easily aging, anti-mineral oil, anti-alcoholic solvent are good, and the paint film water tolerance after baking, insulativity, oil-proofness improve all greatly, and transparency, fullness ratio and clarity are good, good weatherability, gloss does not move back lastingly, and paint film is pliable and tough strong, rub resistance.
Embodiment
Embodiment 1
A kind of coating of good weatherability, it is characterized in that: its composition weight proportioning is: the modified alkyd resin of 30%, the tung oil of 20%, 10% epoxy resin, the terephthalic acid of 2%, palm wax ester, the methacrylic resin of 5%, acrylic paints, the polyvinyl butyral acetal of 5%, the defoamer of 3% of 1% of 12%, all the other are solvent or diluent.
Preferably, described palm wax ester is palm grease, and described defoamer is polysiloxane defoamers.
Preferably, the preparation method of described modified alkyd resin, it comprises the following steps:
A) by 8 parts, the lipid acid of short chain, terephthalic acid 2 parts, octadecane alkene vegetable oil acid 6 parts, monopentaerythritol 10 parts, phthalic anhydride 23 parts, glycerine 1 part, dibasic alcohol 6 parts, agent 0.05 part of losing lustre, dimethylbenzene 3 parts of input reactors, be uniformly mixed;
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 degree, insulation esterification 3 hours, be then warming up to 190 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 degree, add latting drown aromatic solvent 20 parts, continue to be cooled to 75 degree, add latting drown low boiling ester kind solvent 4 parts, filter and obtain modification.
On technique scheme basis, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.
On technique scheme basis, described latting drown low boiling ester kind solvent is vinyl acetic monomer or methylcarbonate.
Embodiment 2
A kind of coating of good weatherability, it is characterized in that: its composition weight proportioning is: the modified alkyd resin of 40%, the tung oil of 30%, 16% epoxy resin, the terephthalic acid of 5%, palm wax ester, the methacrylic resin of 8%, acrylic paints, the polyvinyl butyral acetal of 10%, the defoamer of 5% of 3% of 16%, all the other are solvent or diluent.
Preferably, described palm wax ester is palm olein ester, and described defoamer is polysiloxane defoamers.
On technique scheme basis, the preparation method of described modified alkyd resin, it comprises the following steps:
A) by 12 parts, the lipid acid of short chain, terephthalic acid 3 parts, octadecane alkene vegetable oil acid 10 parts, monopentaerythritol 15 parts, phthalic anhydride 28 parts, glycerine 4 parts, dibasic alcohol 10 parts, agent 0.2 part of losing lustre, dimethylbenzene 6 parts of input reactors, be uniformly mixed;
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 190 degree, insulation esterification 4 hours, be then warming up to 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 170 degree, add latting drown aromatic solvent 25 parts, continue to be cooled to 85 degree, add latting drown low boiling ester kind solvent 8 parts, filter and obtain modification.
On technique scheme basis, described short chain fatty acid is cocinic acid, and described octadecane alkene vegetable oil acid is linseed oil fatty acid.
On technique scheme basis, described latting drown low boiling ester kind solvent is vinyl acetic monomer.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.
Claims (6)
1. the coating of a good weatherability, it is characterized in that: its composition weight proportioning is: the modified alkyd resin of 30 ~ 40%, the tung oil of 20 ~ 30%, 10 ~ 16% epoxy resin, the terephthalic acid of 2 ~ 5%, palm wax ester, the methacrylic resin of 5 ~ 8%, acrylic paints, the polyvinyl butyral acetal of 5 ~ 10%, the defoamer of 3 ~ 5% of 1 ~ 3% of 12 ~ 16%, all the other are solvent or diluent.
2. the coating of a kind of good weatherability according to claim 1, is characterized in that: described palm wax ester is palm grease, palm-kernel ester or palm olein ester.
3. the coating of a kind of good weatherability according to claim 1, is characterized in that: described defoamer is polysiloxane defoamers.
4. the coating of a kind of good weatherability according to any one of claims 1 to 3, is characterized in that: the preparation method of described modified alkyd resin, and it comprises the following steps:
A) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filter and obtain modification.
5. the coating of a kind of good weatherability according to claim 4, is characterized in that, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.
6. the coating of a kind of good weatherability according to claim 5, is characterized in that: described latting drown low boiling ester kind solvent is vinyl acetic monomer or methylcarbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410638012.7A CN104371518A (en) | 2014-11-13 | 2014-11-13 | Coating with good weather resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410638012.7A CN104371518A (en) | 2014-11-13 | 2014-11-13 | Coating with good weather resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104371518A true CN104371518A (en) | 2015-02-25 |
Family
ID=52550726
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410638012.7A Pending CN104371518A (en) | 2014-11-13 | 2014-11-13 | Coating with good weather resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104371518A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349084A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Adhesive with good weatherability |
| CN105855747A (en) * | 2016-06-15 | 2016-08-17 | 李孟平 | Anti-corrosion flux and preparation method thereof |
| CN116284702A (en) * | 2023-03-14 | 2023-06-23 | 上海嘉宝莉涂料有限公司 | Polyvinyl butyral modified alkyd resin and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1171450A (en) * | 1997-08-22 | 1999-03-16 | Ciba Specialty Chem Holding Inc | Photogeneration of amine from alpha-aminoacetophenone |
| CN103044668A (en) * | 2012-12-21 | 2013-04-17 | 江苏三木化工股份有限公司 | Matt alkyd resin and preparation method thereof |
| CN103756504A (en) * | 2013-12-20 | 2014-04-30 | 吴江邻苏精密机械有限公司 | Multifunctional rustproof coating agent and preparation method thereof |
| CN103881445A (en) * | 2013-10-29 | 2014-06-25 | 东南大学 | Noctilucent paint |
-
2014
- 2014-11-13 CN CN201410638012.7A patent/CN104371518A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1171450A (en) * | 1997-08-22 | 1999-03-16 | Ciba Specialty Chem Holding Inc | Photogeneration of amine from alpha-aminoacetophenone |
| CN103044668A (en) * | 2012-12-21 | 2013-04-17 | 江苏三木化工股份有限公司 | Matt alkyd resin and preparation method thereof |
| CN103881445A (en) * | 2013-10-29 | 2014-06-25 | 东南大学 | Noctilucent paint |
| CN103756504A (en) * | 2013-12-20 | 2014-04-30 | 吴江邻苏精密机械有限公司 | Multifunctional rustproof coating agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349084A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Adhesive with good weatherability |
| CN105855747A (en) * | 2016-06-15 | 2016-08-17 | 李孟平 | Anti-corrosion flux and preparation method thereof |
| CN116284702A (en) * | 2023-03-14 | 2023-06-23 | 上海嘉宝莉涂料有限公司 | Polyvinyl butyral modified alkyd resin and preparation method and application thereof |
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