CN104338560A - A composite metal complex catalyst for the synthesis of vinyl chloride - Google Patents
A composite metal complex catalyst for the synthesis of vinyl chloride Download PDFInfo
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- CN104338560A CN104338560A CN201310328771.9A CN201310328771A CN104338560A CN 104338560 A CN104338560 A CN 104338560A CN 201310328771 A CN201310328771 A CN 201310328771A CN 104338560 A CN104338560 A CN 104338560A
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- metal complex
- catalyst
- complex compound
- chloride
- synthesizing chloroethylene
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- 239000003054 catalyst Substances 0.000 title claims abstract description 57
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 150000004696 coordination complex Chemical class 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title description 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 239000010931 gold Substances 0.000 claims abstract description 28
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 18
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052737 gold Inorganic materials 0.000 claims abstract description 11
- -1 metal complex compound Chemical class 0.000 claims description 21
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 claims description 12
- 229910003771 Gold(I) chloride Inorganic materials 0.000 claims description 9
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 8
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 6
- 244000060011 Cocos nucifera Species 0.000 claims description 6
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 6
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 5
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims description 2
- 229910001626 barium chloride Inorganic materials 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 2
- TYJJOEBQRJABJG-UHFFFAOYSA-K gold(3+);pyridine;trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Au+3].C1=CC=NC=C1 TYJJOEBQRJABJG-UHFFFAOYSA-K 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 2
- IYRGXJIJGHOCFS-UHFFFAOYSA-N neocuproine Chemical compound C1=C(C)N=C2C3=NC(C)=CC=C3C=CC2=C1 IYRGXJIJGHOCFS-UHFFFAOYSA-N 0.000 claims description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 25
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract description 21
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 5
- 230000002829 reductive effect Effects 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 10
- 229910052753 mercury Inorganic materials 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 7
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 7
- 238000007038 hydrochlorination reaction Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000009257 reactivity Effects 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229960002523 mercuric chloride Drugs 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention provides a composite metal complex catalyst for synthesizing chloroethylene. The catalyst comprises an active metal complex, an auxiliary metal compound and a carrier. The gold element in the active metal complex accounts for 0.01-1% of the total weight of the catalyst, the auxiliary metal compound accounts for 0.1-15% of the total weight of the catalyst, and the balance is carrier active carbon. The invention adopts a gold complex as an active component, Au3+The electrode potential is greatly reduced, and the electrode is not easy to be reduced by an active carbon carrier and reductive gas acetylene and always keeps a high oxidation state. The composite metal complex catalyst prepared by the invention has acetylene conversion rateHigh efficiency, long service life, no loss of components, high safety and reliability, and no environmental pollution.
Description
Technical field
The invention belongs to catalyst technical field, be specifically related to a kind of composition metal complex compound catalyst of acetylene method synthesizing chloroethylene.
Background technology
Vinyl chloride is important organic synthesis raw material, and main purposes produces polyvinyl chloride.At present, method for synthesizing chloroethylene mainly contains two kinds: acetylene method and ethylene process.VC in China monomer is main mainly with acetylene method greatly.
At present, acetylene method vinyl chloride makees catalyst mainly with activated carbon supported mercury chloride greatly, carries out in fixed bed reactors, and mercury chloride load capacity is 10.5% ~ 12.5%.This catalyst stability is very poor, and the easy sublimation of mercury chloride, and strong toxicity, cause environmental pollution.For solving the problem, Some Domestic enterprise and R&D institution have carried out some improvement work containing mercury catalyst, to reduce the use amount of mercury, but still can not thoroughly solve mercury pollution problem.Along with the enhancing of people's environmental consciousness and the increasing of international upper limit mercury pressure, the exploitation of catalyst without mercury is imperative.
For acetylene hydrochlorination reaction, existing large quantity research report both at home and abroad, the standard electrode EMF of metal is associated with acetylene hydrochlorination reactivity by Hutchings, and find that metal master electrode potential is higher, the acetylene hydrochlorination reactivity of its catalysis is higher.Wherein Hg
2+standard electrode EMF be 0.851V, Au
3+standard electrode EMF be 1.498V, thus Au
3+present higher acetylene hydrochlorination reactivity, become the focus of non-mercury catalyst research in recent years.Research shows, the acetylene hydrochlorination reactivity species of golden catalysis are Au
3+, but have very high electrode potential due to it, stability is very poor, is easy to loaded body active carbon and reaction raw materials Acetylene Reduction becomes Au
0and lose activity.At present, the golden non-mercury catalyst active component presoma that contains of report mainly adopts gold chloride, and the halide electrode potential of gold is higher, is easy to be reduced to elemental gold and produce reunion.And containing n-donor ligand and Au
3+can form stable complex compound, can effectively reduce its electrode potential, make it be not easy to be reduced at reaction conditions, remain high oxidation state, catalyst life extends greatly.
Summary of the invention
The mercuric chloride catalyst strong toxicity, the environmental pollution that the object of the invention is to use in the production of solution acetylene method synthesizing chloroethylene are serious, and the existing problem containing golden non-mercury catalyst less stable, and then provide the composition metal complex compound catalyst of a kind of synthesizing chloroethylene that a kind of reactivity is high, stability is strong.
The present invention is achieved by the following technical solutions:
A composition metal complex compound catalyst for synthesizing chloroethylene, this catalyst comprises active metal complex compound, assistant metal compound and carrier.
Described active metal complex compound is selected from (pyridine) gold trichloride (Au (py) Cl
3), (double salicylaldehyde contracting ethylenediamine) chlorauride ([Au (salen)] Cl), (2,2 '-bipyridyl) chlorauride ([AuCl
2(bipy)] Cl), (1,10-phenanthroline) chlorauride ([AuCl
2(phen)] Cl), (Neocuproine) chlorauride ([AuCl
2(CH
3)
2(phen)] Cl) in one or more.
Described assistant metal compound is one or more in potassium chloride, barium chloride, iron chloride, cobalt chloride, nickel chloride, copper chloride, zinc chloride.
Described carrier is one or more in ature of coal, wooden, cocoanut active charcoal, and specific area is greater than 300m
2/ g.
In described active metal complex compound, gold element accounts for 0.01% ~ 1% of total catalyst weight.
Described assistant metal compound accounts for 0.1% ~ 15% of total catalyst weight.
Compared with prior art, the invention has the beneficial effects as follows:
This invention, based on the existing problem containing the easy inactivation of golden non-mercury catalyst, adopts containing n-donor ligand and Au
3+form stable comple, reduce Au
3+electrode potential, higher oxidation state can be kept, and component does not run off, safe and reliable, environmentally safe.This composition metal complex compound catalyst is used for the reaction of acetylene method synthesizing chloroethylene, conversion of alkyne is high, long service life, avoids the pollution produced environment containing mercury catalyst.
Detailed description of the invention
Below by way of specific embodiment, the present invention will be described in more detail.Embodiment is only illustrate one of the present invention, and is not construed as limiting the invention.
Test condition:
Evaluating catalyst adopts internal diameter to be the fixed bed reactors of 10mm, long 400mm, electric heating temperature control, be warming up to reaction temperature required after, pass into hydrogen chloride gas activation 1h, then pass into acetylene, unstripped gas ratio is
v(HCl) ︰
v(C
2h
2)=1.0 ~ 1.3, acetylene air speed 30 ~ 1000h
-1, reaction pressure 0.1MPa.Reaction end gas passes into sodium hydroxide solution to carry out absorbing to remove unreacted hydrogen chloride, and online gas-chromatography carries out product composition analysis.
embodiment 1
Gold presoma is [AuCl
2(bipy)] Cl, assistant metal compound is FeCl
3, ZnCl
2, carrier is cocoanut active charcoal, and wherein, Au accounts for 0.05%, FeCl of total catalyst weight
3account for 0.5%, ZnCl of total catalyst weight
2account for 3% of total catalyst weight.
Utilize this catalyst to carry out synthesizing chloroethylene reaction, reaction condition is: reaction temperature is 180 DEG C, and unstripped gas ratio is
v(HCl) ︰
v(C
2h
2)=1.2:1, acetylene air speed 30h
-1, reaction pressure 0.1MPa.Catalytic performance is in table 1.
embodiment 2
Gold presoma is [AuCl
2(phen)] Cl, assistant metal compound is KCl, NiCl
2, ZnCl
2, carrier is cocoanut active charcoal, wherein, Au account for that 0.05%, KCl of total catalyst weight accounts for total catalyst weight 1.0%, NiCl
2account for 2.0%, ZnCl of total catalyst weight
2account for 3% of total catalyst weight.
Utilize this catalyst to carry out synthesizing chloroethylene reaction, reaction condition is: reaction temperature is 180 DEG C, and unstripped gas ratio is
v(HCl) ︰
v(C
2h
2)=1.2:1, acetylene air speed 30h
-1, reaction pressure 0.1MPa.Catalytic performance is in table 1.
embodiment 3
Gold presoma is [AuCl
2(CH
3)
2(phen)] Cl, assistant metal compound is BaCl
2, CoCl
2, carrier is cocoanut active charcoal, and wherein, Au accounts for 0.05%, BaCl of total catalyst weight
2account for 1.5%, CoCl of total catalyst weight
2account for 2.0% of total catalyst weight.
Utilize this catalyst to carry out synthesizing chloroethylene reaction, reaction condition is: reaction temperature is 180 DEG C, and unstripped gas ratio is
v(HCl) ︰
v(C
2h
2)=1.2:1, acetylene air speed 30h
-1, reaction pressure 0.1MPa.Catalytic performance is in table 1.
embodiment 4
Gold presoma is [Au (salen)] Cl, and assistant metal compound is NiCl
2, CuCl
2, BaCl
2, carrier is cocoanut active charcoal, and wherein, Au accounts for 0.05%, NiCl of total catalyst weight
2account for 1.0%, CuCl of total catalyst weight
2account for 1%, BaCl of total catalyst weight
2account for 10% of total catalyst weight.
Utilize this catalyst to carry out synthesizing chloroethylene reaction, reaction condition is: reaction temperature is 180 DEG C, and unstripped gas ratio is
v(HCl) ︰
v(C
2h
2)=1.2:1, acetylene air speed 30h
-1, reaction pressure 0.1MPa.Catalytic performance is in table 1.
comparative example 1 ~ 4
Catalyst activity component presoma is gold chloride, and other is identical with embodiment 1 ~ 4.Catalytic performance is in table 1.
table 1 different catalysts acetylene hydrochlorination reaction result
| Project | Reaction time (h) | Conversion of alkyne (%) | Vinyl chloride selective (%) | Project |
| Embodiment 1 | 100 | 99.48 | 99.67 | Embodiment 1 |
| Embodiment 2 | 100 | 99.76 | 99.52 | Embodiment 2 |
| Embodiment 3 | 100 | 99.37 | 99.89 | Embodiment 3 |
| Embodiment 4 | 500 | 98.67 | 99.37 | Embodiment 4 |
| Comparative example 1 | 100 | 88.24 | 99.63 | Comparative example 1 |
| Comparative example 2 | 100 | 92.73 | 99.43 | Comparative example 2 |
| Comparative example 3 | 100 | 90.08 | 99.36 | Comparative example 3 |
| Comparative example 4 | 500 | 82.38 | 99.58 | Comparative example 4 |
As can be seen from Table 1, adopting gold complex to be active component presoma, is that the catalyst stability that active component presoma obtains obviously strengthens than gold chloride.
Claims (6)
1. a composition metal complex compound catalyst for synthesizing chloroethylene, is characterized in that, this catalyst comprises active metal complex compound, assistant metal compound and carrier.
2. the composition metal complex compound catalyst of a kind of synthesizing chloroethylene according to claim 1, is characterized in that, described active metal complex compound is selected from (pyridine) gold trichloride (Au (py) Cl
3), (double salicylaldehyde contracting ethylenediamine) chlorauride ([Au (salen)] Cl), (2,2 '-bipyridyl) chlorauride ([AuCl
2(bipy)] Cl), (1,10-phenanthroline) chlorauride ([AuCl
2(phen)] Cl), (Neocuproine) chlorauride ([AuCl
2(CH
3)
2(phen)] Cl) in one or more.
3. the composition metal complex compound catalyst of a kind of synthesizing chloroethylene according to claim 1, it is characterized in that, described assistant metal compound is one or more in potassium chloride, barium chloride, iron chloride, cobalt chloride, nickel chloride, copper chloride, zinc chloride.
4. the composition metal complex compound catalyst of a kind of synthesizing chloroethylene according to claim 1, is characterized in that, described carrier is one or more in ature of coal, wooden, cocoanut active charcoal, and specific area is greater than 300m
2/ g.
5. the composition metal complex compound catalyst of a kind of synthesizing chloroethylene according to claim 1,2, is characterized in that, in described active metal complex compound, gold element accounts for 0.01% ~ 1% of total catalyst weight.
6. the composition metal complex compound catalyst of a kind of synthesizing chloroethylene according to claim 1, is characterized in that, described assistant metal compound accounts for 0.1% ~ 15% of total catalyst weight
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310328771.9A CN104338560A (en) | 2013-07-31 | 2013-07-31 | A composite metal complex catalyst for the synthesis of vinyl chloride |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310328771.9A CN104338560A (en) | 2013-07-31 | 2013-07-31 | A composite metal complex catalyst for the synthesis of vinyl chloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104338560A true CN104338560A (en) | 2015-02-11 |
Family
ID=52495506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310328771.9A Pending CN104338560A (en) | 2013-07-31 | 2013-07-31 | A composite metal complex catalyst for the synthesis of vinyl chloride |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104338560A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104801345A (en) * | 2015-03-31 | 2015-07-29 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Supported type mercury-free catalyst for chloroethylene production with acetylene hydrochlorination method |
| CN107803222A (en) * | 2017-09-29 | 2018-03-16 | 浙江工业大学 | A kind of catalyzed by ruthenium complexes agent for acetylene hydrochlorination reaction |
| CN109865534A (en) * | 2019-03-11 | 2019-06-11 | 陕西开达化工有限责任公司 | A kind of Nano type Au base catalyst and preparation method and application |
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|---|---|---|---|---|
| CN102631942A (en) * | 2012-04-17 | 2012-08-15 | 清华大学 | Composite metal salt catalyst for hydrochlorination reaction of acetylene |
| CN102631947A (en) * | 2012-04-01 | 2012-08-15 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Gold complex catalyst for hydrochlorinating acetylene |
| GB2492888A (en) * | 2011-07-11 | 2013-01-16 | Johnson Matthey Plc | Catalyst and method for its preparation |
-
2013
- 2013-07-31 CN CN201310328771.9A patent/CN104338560A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2492888A (en) * | 2011-07-11 | 2013-01-16 | Johnson Matthey Plc | Catalyst and method for its preparation |
| CN102631947A (en) * | 2012-04-01 | 2012-08-15 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Gold complex catalyst for hydrochlorinating acetylene |
| CN102631942A (en) * | 2012-04-17 | 2012-08-15 | 清华大学 | Composite metal salt catalyst for hydrochlorination reaction of acetylene |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104801345A (en) * | 2015-03-31 | 2015-07-29 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Supported type mercury-free catalyst for chloroethylene production with acetylene hydrochlorination method |
| CN107803222A (en) * | 2017-09-29 | 2018-03-16 | 浙江工业大学 | A kind of catalyzed by ruthenium complexes agent for acetylene hydrochlorination reaction |
| CN107803222B (en) * | 2017-09-29 | 2020-06-09 | 浙江工业大学 | A kind of ruthenium complex catalyst for acetylene hydrochlorination reaction |
| CN109865534A (en) * | 2019-03-11 | 2019-06-11 | 陕西开达化工有限责任公司 | A kind of Nano type Au base catalyst and preparation method and application |
| CN109865534B (en) * | 2019-03-11 | 2021-10-26 | 陕西开达化工有限责任公司 | Nano Au-based catalyst, preparation method and application |
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Application publication date: 20150211 |