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CN104326539A - Sewage treatment agent - Google Patents

Sewage treatment agent Download PDF

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Publication number
CN104326539A
CN104326539A CN201410555732.7A CN201410555732A CN104326539A CN 104326539 A CN104326539 A CN 104326539A CN 201410555732 A CN201410555732 A CN 201410555732A CN 104326539 A CN104326539 A CN 104326539A
Authority
CN
China
Prior art keywords
sewage
polyacrylamide
sewage treatment
treating agent
flyash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410555732.7A
Other languages
Chinese (zh)
Inventor
吴彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU FUQINUO WATER TREATMENT EQUIPMENT CO Ltd
Original Assignee
SUZHOU FUQINUO WATER TREATMENT EQUIPMENT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU FUQINUO WATER TREATMENT EQUIPMENT CO Ltd filed Critical SUZHOU FUQINUO WATER TREATMENT EQUIPMENT CO Ltd
Priority to CN201410555732.7A priority Critical patent/CN104326539A/en
Publication of CN104326539A publication Critical patent/CN104326539A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a sewage treatment agent which is composed of the following components in percentage by mass: 20-45% of polyferric sulfate, 10-20% of polyacrylamide, 5-15% of polyethyleneimine, 10-20% of bentonite and 10-25% of fly ash. The polyferric sulfate has the characteristics of high water solubility, excellent coagulation effect, favorable product stability, wide pH value application range and the like. By using the inorganic matters and organic matters as the synergic coagulating agents, the sewage treatment agent has excellent flocculation effect and has the advantages of high purification speed, favorable effect, environmental protection, no toxicity and the like. The sewage treatment agent also has the advantages of wide manufacturing raw material sources, low cost, lower manufacturing cost, high component decontamination capacity and favorable sewage treatment effect.

Description

A kind of sewage-treating agent
Technical field
The present invention relates to a kind of chemical reagent, particularly relate to a kind of novel sewage-treating agent of sewage disposal aspect.
Background technology
Due to population growth and Economic development, the series of problems affecting resource quality produced the excessive exploitation of resource and unreasonable development day by day highlights, and these problems have directly threatened the existence of we and descendants.China is faced with these problems equally, and China is the country of a water resources shortage, how to alleviate the problem such as water resources shortage and pollution and has become an instant problem.
Along with industrialized development, subsidiary production waste also gets more and more, any discharge can make a very bad impression to environment, for environmental protect, sewage disposal technology arises at the historic moment, sewage disposal refers to the water quality requirement for making sewage reach a certain water body of draining or reuse, and to the process that it purifies, sewage disposal is widely used in building, agricultural, the every field such as traffic, the energy, petrochemical industry, environmental protection, urban look, medical treatment, food and drink, also come into the daily life of common people more and more.
At present, process water resource pollution problem has physics, chemistry, biology, the multiple method such as comprehensive, but to there is treatment effect not good more for physical method, the problems such as processing rate is unstable; Biological method processing cost is too high, is not suitable for promoting the use of; More adopt chemical process to dispose of sewage, but existing sewage-treating agent, there is secondary pollution problem in its agent formulations, also can have a certain impact to environment, such as application number is 201310569471.X, denomination of invention is a kind of patent of sewage-treating agent, containing Tai-Ace S 150 and aluminum phosphate in its composition.Both at home and abroad the biological action research of aluminium is confirmed, human body takes in that too much aluminium can disturb alcium and phosphor metabolization, causes Secondary cases hyperthyroidism, porphyria and Altheimer ' s sick, i.e. presenile dementia etc.It is reported that inorganic aluminate is for after purifying waste water, in water, Aluminium residual is at 0.6 ~ 36mg/L, greatly exceed the recommended value of WHO.This, concerning the mankind of long-term drinking tap water, is the problem of significant.Existing sewage-treating agent result of use is bad in addition, such as application number is 201110355978.6, denomination of invention is the patent of sewage-treating agent, containing polyferric chloride in its composition, and the effect of polyferric chloride in its invention uses as inorganic coagulant, but when polyferric chloride uses as inorganic coagulant, its effect is also bad.
Summary of the invention
The technical problem to be solved in the present invention is for above-mentioned the deficiencies in the prior art, and provides the low evil of a kind of low toxicity, decontamination good purification and the sewage-treating agent of low cost.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 20-45; Polyacrylamide 10-20; Polymine 5-15; Wilkinite 10-20; Flyash 10-25.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 20; Polyacrylamide 20; Polymine 15; Wilkinite 20; Flyash 25.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 25; Polyacrylamide 15; Polymine 15; Wilkinite 20; Flyash 25.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 30; Polyacrylamide 15; Polymine 10; Wilkinite 20; Flyash 25.
The each moiety mass percent of a kind of sewage-treating agent is: bodied ferric sulfate 35; Polyacrylamide 10; Polymine 15; Wilkinite 20; Flyash 20.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 40; Polyacrylamide 10; Polymine 12; Wilkinite 15; Flyash 23.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 45; Polyacrylamide 10; Polymine 10; Wilkinite 15; Flyash 20.
A kind of sewage-treating agent, each moiety mass percent is: bodied ferric sulfate 45; Polyacrylamide 15; Polymine 10; Wilkinite 10; Flyash 20.
After the present invention adopts technique scheme, there is following technique effect:
The present invention has that purification speed is fast, good purification, the bodied ferric sulfate that the present invention adopts has that hydrolysis rate is fast, cohesive force is strong, floc density that is that generate is large, settling velocity is fast, good processed water quality, applicable pH range sludge volume that is wide, that produce is little and be easy to the advantages such as dehydration, be a kind of new and effective water purification agent, the inorganic water purification agent such as polyaluminium sulfate, iron trichloride being all better than in Organic substance in water, colourity, removal colloidal silicon etc. commonly using at present removed by bodied ferric sulfate.
The present invention has the advantages such as flocculating effect excellence, environment-protecting asepsis.The making raw material sources of this sewage-treating agent are extensive, with low cost, therefore cost of manufacture reduces, and component dirty removal capacities is strong, good sewage processing effect.
The present invention adopts flyash and wilkinite as the raw material of disposing of sewage, the cost reducing sewage disposal is low, and the absorption of flyash and flocculation ability strong, settling time is shorter, mud is less, improve effect and the efficiency of sewage disposal further, and in water after treatment, can not chemical residue preparation.
The polyacrylamide itself that the present invention adopts is substantially nontoxic, and after it enters human body, the overwhelming majority excretes in a short time, and little digested road absorbs.
Embodiment
For making the object of the embodiment of the present invention and technical scheme clearly, be clearly and completely described below in conjunction with the technical scheme of the embodiment of the present invention to the embodiment of the present invention.Obviously, described embodiment is a part of embodiment of the present invention, instead of whole embodiments.Based on described embodiments of the invention, the every other embodiment that those of ordinary skill in the art obtain under without the need to the prerequisite of creative work, all belongs to the scope of protection of the invention.
In municipal administration, industry and civilian water and wastewater treatment, coagulation technology is one of technology of widespread use the most.Coagulating agent is one of key link of coagulation technology, can district be inorganic coagulant and organic coagulants by its chemical property.The kind of inorganic coagulant, mainly molysite, aluminium salt and hydrating polymer thereof.Inorganic polymer coagulant is the novel water-treatment medicament grown up after the sixties in 20th century.In recent years, development and application polymeric aluminum, iron, silicon and various composite type inorganic polymer coagulating agent become focus.At present, the production of Japan, Russia, West Europe inorganic polymeric class coagulating agent has accounted for 30 % ~ 60 % of coagulating agent ultimate production.Because Al-based coagulant exists toxicity problem, so just become the emphasis of inorganic polymer coagulant development to the development of iron system kind, exploitation.
The present invention adopts inorganic coagulant and organic floculant exactly, then adds inorganic coagulant aids and be combined to form a kind of sewage-treating agent, utilizes coagulation technology to carry out the principle of sewage purification.
Embodiment 1
A kind of sewage-treating agent, each moiety mass percent is:
Bodied ferric sulfate 20-45; Polyacrylamide 10-20; Polymine 5-15; Wilkinite 10-20; Flyash 10-25.
The relative density of bodied ferric sulfate of the present invention is 1.45, acid, soluble in water.It is fast that bodied ferric sulfate has hydrolysis rate, cohesive force is strong, the floc density generated is large, settling velocity is fast, good processed water quality, applicable pH range is wide, the sludge volume produced is little and be easy to the advantages such as dehydration, it is a kind of new and effective water purification agent, to the suspended substance in water, organism, sulfide and heavy metal ion have very strong removal ability, be widely used in domestic water, the purifying treatment of process water and municipal effluent, also can be used for papermaking, printing and dyeing, food-processing, the temperature of the trade effluents such as machinofacture coagulates precipitation process and air supporting clarifying treatment, bodied ferric sulfate is at removal Organic substance in water, colourity, remove the aspects such as colloidal silicon and be all better than polyaluminium sulfate conventional at present, the inorganic water purification agent such as iron trichloride.
Embodiment 2
Further, described a kind of sewage-treating agent, each moiety mass percent is:
Bodied ferric sulfate 20; Polyacrylamide 20; Polymine 15; Wilkinite 20; Flyash 25.
The present invention and aluminum salt flocculant residual aluminum bring the problems such as the bio-toxicity of serious harm and aluminium and compared with the deficiency such as Ferric Salt Flocculants coagulation effect is poor, product stability is bad to human body, it is wide that this chemical composition has applicable pH value range, after process, the pH of water reduces little, do not increase the colourity of water, the features such as treatment effect is excellent.When the water temperature processed is lower, effect is more obvious.
Embodiment 3
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 25; Polyacrylamide 15; Polymine 15; Wilkinite 20; Flyash 25.
Polyacrylamide is methacrylamide homopolymer or is referred to as with the polymkeric substance of other monomer copolymerizations, and polyacrylamide (PAM) is one of most widely used kind in water-soluble polymer.Polyacrylamide is widely used in the industries such as oil production, papermaking, water treatment, weaving, medicine, agricultural.According to statistics, in the ultimate production of global polyacrylamide 37% for wastewater treatment, and 27% for petroleum industry, and 18% for paper industry.And the most important thing is that polyacrylamide itself is substantially nontoxic, after it enters human body, the overwhelming majority excretes in a short time, little digested road absorbs.
Polymine is the polymkeric substance containing amido, in current material, have the highest positive ion density, hyperergy and water-soluble.For in Water warfare field, as flocculation agent, the fine-grained solids disperseed in liquid can be made to form the high molecular polymer of throw out.
Embodiment 4
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 30; Polyacrylamide 15; Polymine 10; Wilkinite 20; Flyash 25.
The making raw material sources of this sewage-treating agent are extensive, with low cost, therefore cost of manufacture reduces, and component dirty removal capacities is strong, good sewage processing effect.The present invention adopts flyash and wilkinite as the raw material of disposing of sewage, the cost reducing sewage disposal is low, and the absorption of flyash and flocculation ability strong, settling time is shorter, mud is less, improve effect and the efficiency of sewage disposal further, and in the water of process meeting, can not chemical residue preparation.
Embodiment 5
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 35; Polyacrylamide 10; Polymine 15; Wilkinite 20; Flyash 20.
As the wilkinite of inorganics composition, flyash and jointly used in combination as the polyacrylamide of organic components, polymine, inorganics is as coagulating agent, organism is flocculation agent, both collaborate, and coagulating agent can well promote flocculation agent treatment effect.
Embodiment 6
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 40; Polyacrylamide 10; Polymine 12; Wilkinite 15; Flyash 23.
Embodiment 7
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 45; Polyacrylamide 10; Polymine 10; Wilkinite 15; Flyash 20.
Embodiment 7
As to further improvement of the present invention, described a kind of sewage-treating agent, each percentage composition content is:
Bodied ferric sulfate 45; Polyacrylamide 15; Polymine 10; Wilkinite 10; Flyash 20.
The present invention can be applicable to the trade effluents such as process dyestuff, weaving, chemical industry, is also applicable to domestic water and produces the purifying treatment fed water.
The bodied ferric sulfate that the present invention selects is soluble in water, coagulation effect is excellent, product stability is good, be suitable for pH value range wide, use inorganics and organic components to work in coordination with as coagulating agent simultaneously, the present invention is made to have the effect of excellent flocculation, it is fast that the present invention has purification speed, effective, the advantages such as environment-protecting asepsis.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, and all terms used herein (comprising technical term and scientific terminology) have the meaning identical with the general understanding of the those of ordinary skill in field belonging to the present invention.Should also be understood that those terms defined in such as general dictionary should be understood to have the meaning consistent with the meaning in the context of prior art, unless and define as here, can not explain by idealized or too formal implication.
The implication of the "and/or" described in the present invention refers to respective Individual existence or both simultaneous situations include interior.
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.

Claims (8)

1. a sewage-treating agent, is characterized in that, each moiety mass percent is: bodied ferric sulfate 20-45; Polyacrylamide 10-20; Polymine 5-15; Wilkinite 10-20; Flyash 10-25.
2. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 20; Polyacrylamide 20; Polymine 15; Wilkinite 20; Flyash 25.
3. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 25; Polyacrylamide 15; Polymine 15; Wilkinite 20; Flyash 25.
4. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 30; Polyacrylamide 15; Polymine 10; Wilkinite 20; Flyash 25.
5. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 35; Polyacrylamide 10; Polymine 15; Wilkinite 20; Flyash 20.
6. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 40; Polyacrylamide 10; Polymine 12; Wilkinite 15; Flyash 23.
7. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 45; Polyacrylamide 10; Polymine 10; Wilkinite 15; Flyash 20.
8. a kind of sewage-treating agent as claimed in claim 1, is characterized in that, each moiety mass percent is: bodied ferric sulfate 45; Polyacrylamide 15; Polymine 10; Wilkinite 10; Flyash 20.
CN201410555732.7A 2014-10-20 2014-10-20 Sewage treatment agent Pending CN104326539A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104891585A (en) * 2015-05-05 2015-09-09 邱林 Industrial sewage treatment agent
CN105439268A (en) * 2015-12-16 2016-03-30 无锡吉进环保科技有限公司 Preparation method of novel sewage processing agent
CN105481031A (en) * 2015-12-16 2016-04-13 无锡吉进环保科技有限公司 Novel sewage treatment agent
CN106186241A (en) * 2016-09-27 2016-12-07 合肥天翔环境工程有限公司 Flocculant for Acid Dye Wastewater
CN106430361A (en) * 2016-11-25 2017-02-22 南宁市黑晶信息技术有限公司 Special efficient low-cost sewage treatment agent for domestic sewage and preparation method of sewage treatment agent

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103101999A (en) * 2011-11-11 2013-05-15 沈阳创达技术交易市场有限公司 Novel sewage treatment agent

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103101999A (en) * 2011-11-11 2013-05-15 沈阳创达技术交易市场有限公司 Novel sewage treatment agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
秦安荣: "聚硫酸铁的絮凝特性及其在环境保护中的应用", 《上海环境科学》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104891585A (en) * 2015-05-05 2015-09-09 邱林 Industrial sewage treatment agent
CN105439268A (en) * 2015-12-16 2016-03-30 无锡吉进环保科技有限公司 Preparation method of novel sewage processing agent
CN105481031A (en) * 2015-12-16 2016-04-13 无锡吉进环保科技有限公司 Novel sewage treatment agent
CN106186241A (en) * 2016-09-27 2016-12-07 合肥天翔环境工程有限公司 Flocculant for Acid Dye Wastewater
CN106430361A (en) * 2016-11-25 2017-02-22 南宁市黑晶信息技术有限公司 Special efficient low-cost sewage treatment agent for domestic sewage and preparation method of sewage treatment agent

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Application publication date: 20150204