CN104313913A - Penetrating agent with high adsorption capacity for leather - Google Patents
Penetrating agent with high adsorption capacity for leather Download PDFInfo
- Publication number
- CN104313913A CN104313913A CN201410575552.5A CN201410575552A CN104313913A CN 104313913 A CN104313913 A CN 104313913A CN 201410575552 A CN201410575552 A CN 201410575552A CN 104313913 A CN104313913 A CN 104313913A
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- CN
- China
- Prior art keywords
- parts
- penetrating agent
- leather
- adsorption capacity
- moss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000010985 leather Substances 0.000 title claims abstract description 14
- 238000001179 sorption measurement Methods 0.000 title abstract description 8
- 230000000149 penetrating effect Effects 0.000 title abstract 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000004048 modification Effects 0.000 claims abstract description 10
- 238000012986 modification Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- AWIJHZIZSALXDG-UHFFFAOYSA-N 2-(2-phenylethyl)naphthalen-1-ol Chemical compound C1=CC2=CC=CC=C2C(O)=C1CCC1=CC=CC=C1 AWIJHZIZSALXDG-UHFFFAOYSA-N 0.000 claims abstract description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 6
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims abstract description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004280 Sodium formate Substances 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 6
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 6
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 235000019254 sodium formate Nutrition 0.000 claims abstract description 6
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims abstract description 4
- 230000000740 bleeding effect Effects 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000009837 dry grinding Methods 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 230000003254 anti-foaming effect Effects 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 230000003204 osmotic effect Effects 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- -1 sodium alkyl benzene Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a penetrating agent with high adsorption capacity for leather. The penetrating agent with high adsorption capacity for leather is prepared from the following raw materials in parts by weight: 40-50 parts of phenethyl naphthol polyoxyethylene ether, 6-8 parts of ethylene glycol monobutyl ether, 25-30 parts of rosin resin, 4-5 parts of linear alkyl benzene sulphonic acid, 8-10 parts of phthalic anhydride, 2-4 parts of cyclohexanone, 4-6 parts of sodium formate, 7-8 parts of p-tert-butyl benzoic acid, 15-20 parts of modified moss and 45-55 parts of water. The penetrating agent with high adsorption capacity for leather has a good osmotic effect and an emulsifying effect and also has low-foam and anti-foaming functions, so that the penetrating agent with high adsorption capacity is environmentally friendly; the obtained penetrating agent does not contain environmentally harmful substances and also has good penetration performance; and the prepared penetrating agent has large specific surface area and strong adsorption capacity by virtue of modification treatment on the moss.
Description
Technical field
The present invention relates to textile printing and dyeing technology, be specifically related to a kind of high absorption capacity leather bleeding agent.
Background technology
More in current bleeding agent is adopt the surfactant of anionic, nonionic surface active agent and different ions type to carry out composite use, to reach comparatively ideal synergy; But great majority are in order to consider cost and result of use, sodium alkyl benzene sulfonate (ABS) and the alkylphenol polyoxyethylene (APEO) of anion is mostly have employed in formula, everyly need chemosmotic place and all will add bleeding agent, its Main Function reduces interfacial tension, is applied to all trades and professions such as weaving, printing and dyeing, leather, papermaking, agricultural chemicals, chemical industry.
Summary of the invention
The object of the present invention is to provide a kind of high absorption capacity leather bleeding agent.
The present invention adopts following technical scheme to achieve these goals:
High absorption capacity leather bleeding agent, the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 40-50, different glycol monobutyl ether 6-8, abietic resin 25-30, linear alkyl benzene sulphonic acid 4-5, phthalic anhydride 8-10, cyclohexanone 2-4, sodium formate 4-6, p-tert-butyl benzoic acid 7-8, modification moss 15-20 and water 45-55.
High absorption capacity leather bleeding agent, the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
The preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate again, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven.
Beneficial effect of the present invention:
High absorption capacity bleeding agent provided by the invention not only has good osmosis and emulsifying effectiveness, and also having low bubble, press down bubble function, is a kind of environmental type bleeding agent; The bleeding agent of gained is not containing environmentally harmful material and permeance property is good, and by the modification to moss, made bleeding agent specific area is large, high adsorption capacity.
Detailed description of the invention
Embodiment 1: high absorption capacity leather bleeding agent, the weight portion (kg) of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
The preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 5% acrylic acid, 2.5% ammonium persulfate again, stir 3-4h at 85 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2 times amount, after mixing, be placed on 105 DEG C of oven dry 35min in baking oven.
Bleeding agent pH value of the present invention is 6.8, cloud point is 34.8 DEG C, water-soluble and the organic solvent of energy, sedimentation time is 65s, and there is very high adsorption capacity and permeability, bleeding agent of the present invention mixes formation dye liquor, in whole dyeing course with water, KOH, dyestuff etc., obvious lamination is there is not, the fabric uniform in color dyed in dye vat.
Claims (3)
1. a high absorption capacity leather bleeding agent, is characterized in that the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 40-50, different glycol monobutyl ether 6-8, abietic resin 25-30, linear alkyl benzene sulphonic acid 4-5, phthalic anhydride 8-10, cyclohexanone 2-4, sodium formate 4-6, p-tert-butyl benzoic acid 7-8, modification moss 15-20 and water 45-55.
2. high absorption capacity leather bleeding agent according to claim 1, is characterized in that the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
3. high absorption capacity leather bleeding agent according to claim 1, it is characterized in that: the preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, then put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575552.5A CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575552.5A CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104313913A true CN104313913A (en) | 2015-01-28 |
Family
ID=52369214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410575552.5A Pending CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104313913A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521992A (en) * | 2016-11-24 | 2017-03-22 | 肇庆高新区飞越信息科技有限公司 | High temperature resistant penetrant for leather dyeing |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827668A (en) * | 1994-07-13 | 1996-01-30 | Sanyo Chem Ind Ltd | Penetrant |
| US20020198287A1 (en) * | 2001-03-12 | 2002-12-26 | Seiko Epson Corporation | Ink for ink jet printing process and printed matter obtained using the same |
| CN103030966A (en) * | 2012-12-24 | 2013-04-10 | 建德市顺发化工助剂有限公司 | Preparation method of high-efficiency penetrant for PU synthetic leather |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
| CN104109470A (en) * | 2014-06-25 | 2014-10-22 | 武汉黑豹防漏技术开发有限公司 | Strong permeability waterproof agent and preparation method thereof |
-
2014
- 2014-10-25 CN CN201410575552.5A patent/CN104313913A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827668A (en) * | 1994-07-13 | 1996-01-30 | Sanyo Chem Ind Ltd | Penetrant |
| US20020198287A1 (en) * | 2001-03-12 | 2002-12-26 | Seiko Epson Corporation | Ink for ink jet printing process and printed matter obtained using the same |
| CN103030966A (en) * | 2012-12-24 | 2013-04-10 | 建德市顺发化工助剂有限公司 | Preparation method of high-efficiency penetrant for PU synthetic leather |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
| CN104109470A (en) * | 2014-06-25 | 2014-10-22 | 武汉黑豹防漏技术开发有限公司 | Strong permeability waterproof agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521992A (en) * | 2016-11-24 | 2017-03-22 | 肇庆高新区飞越信息科技有限公司 | High temperature resistant penetrant for leather dyeing |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |