CN104312376A - High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof - Google Patents
High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof Download PDFInfo
- Publication number
- CN104312376A CN104312376A CN201410467568.4A CN201410467568A CN104312376A CN 104312376 A CN104312376 A CN 104312376A CN 201410467568 A CN201410467568 A CN 201410467568A CN 104312376 A CN104312376 A CN 104312376A
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- sand
- added
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- 239000003973 paint Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 6
- 239000003063 flame retardant Substances 0.000 title abstract description 6
- 239000004576 sand Substances 0.000 claims abstract description 34
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000010426 asphalt Substances 0.000 claims abstract description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 20
- -1 alicyclic amine Chemical class 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 16
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims abstract description 7
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims abstract description 7
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims abstract description 7
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 239000002023 wood Substances 0.000 claims abstract description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001289 polyvinyl ether Polymers 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims description 21
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 235000019353 potassium silicate Nutrition 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 14
- 239000002351 wastewater Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 238000009826 distribution Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 6
- 229940063655 aluminum stearate Drugs 0.000 claims description 6
- 229910052586 apatite Inorganic materials 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 6
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 235000021388 linseed oil Nutrition 0.000 claims description 6
- 239000000944 linseed oil Substances 0.000 claims description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 6
- 239000011976 maleic acid Substances 0.000 claims description 6
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 6
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- CUXSAAMWQXNZQW-UHFFFAOYSA-N acetic acid;butan-1-ol Chemical class CC(O)=O.CCCCO CUXSAAMWQXNZQW-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 3
- 238000000703 high-speed centrifugation Methods 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 3
- 235000019792 magnesium silicate Nutrition 0.000 claims description 3
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 3
- 230000010355 oscillation Effects 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000008213 purified water Substances 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 235000019355 sepiolite Nutrition 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- FDPPRGFSWMXMAW-UHFFFAOYSA-K aluminum butyl(methyl)phosphinate Chemical compound [Al+3].CCCCP(C)([O-])=O.CCCCP(C)([O-])=O.CCCCP(C)([O-])=O FDPPRGFSWMXMAW-UHFFFAOYSA-K 0.000 abstract 2
- CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 abstract 1
- XSWKLHINRKWMTD-UHFFFAOYSA-L cobalt(2+);3-(3-ethylcyclopentyl)propanoate Chemical compound [Co+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)C1 XSWKLHINRKWMTD-UHFFFAOYSA-L 0.000 abstract 1
- 239000000539 dimer Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001693 poly(ether-ester) Polymers 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 28
- 230000003628 erosive effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000009972 noncorrosive effect Effects 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000011214 refractory ceramic Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses high temperature-resistant flame-retardant modified bituminous paint for ships. The high temperature-resistant flame-retardant modified bituminous paint is prepared from 32-35 parts by weight of E12 epoxy resin, 1-2 parts by weight of polycarbodiimide, 1-2 parts by weight of poly(ether ester), 3-4 parts by weight of graphene, 1-2 parts by weight of nickel-doped nanometer titanium dioxide, 0.3-0.7 parts by weight of cobaltous naphthenate, 1-2 parts by weight of dimer acid, 2-4 parts by weight of alicyclic amine, 2-3 parts by weight of cardanol, 2-4 parts by weight of cresyl glycidyl ether, 8-13 parts by weight of modified waste sodium silicate sand, 9-14 parts by weight of modified asphalt, 3-5 parts by weight of wood wax oil, 1-2 parts by weight of hexabromo-benzene, 2-3 parts by weight of polyvinyl ether, 8-11 parts by weight of xylene, 6-9 parts by weight of glycol, 0.5-1.0 part by weight of aluminum methylbutylphosphinate and 1-2 parts by weight of talcum powder. The used modified asphalt in the paint solves the problem that epoxy resin paint is pulverized easily at a high temperature and improves paint weatherability, corrosion resistance, moisture resistance and water resistance. The used aluminum methylbutylphosphinate has strong flame retardation. The used modified waste sodium silicate sand realizes environmental protection and improves paint heat resistance and flame resistance. The high temperature-resistant flame-retardant modified bituminous paint has a low production cost, a wide application range and excellent performances and is worthy of popularization use.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of heat-resistant fireproof type ship modifying asphalt paint and preparation method thereof.
Background technology
Boats and ships are among ocean environment for a long time; ocean and land natural condition difference very large; there is salt fog ocean and band slight alkalinity, wherein seawater is more much harder than land to corrosion of metal, in ocean, also have diversified marine attaching organism; they can above alow adhere to; affect the ship speed of a ship or plane, increase fuel consumption, also have strong ultraviolet etc. simultaneously; if do not take sfgd., the work-ing life of boats and ships is very short.Marine paint is the tailor-(made) coating on ships; be used for protecting ship, naval vessels, offshore oil to adopt platform, harbour piling bar and offshore steel iron construction not by sea-water corrosion; marine paint must have excellent water tolerance, rust-preventing characteristic, erosion resistance etc., little to human toxicity during construction.
Sodium silicate sand is formed by silica sand, water glass and additional thing mixed preparing.Water glass is colourless, odorless, nontoxic, in casting cycle, all do not have the spilling of pungency or toxic gas, but the add-on of water past glass is large, collapsibility is poor, on-the-spot in sand removal, silica dust flies upward, and causes silica dust to pollute, regenerating used difficulty, goes out of use in a large number, causes the alkaline pollution of environment.Widely, be used to manufacture the various silicates products such as silica gel, metasilicate pentahydrate sodium, silicon sol, sodium-potassium silicate at chemical system, be the basic raw material of silicon compound to the purposes of water glass; Being indispensable raw material in the washing composition such as washing powder, soap in light industry, is also water softener, settling agent; For helping dye, bleaching and sizing in textile industry; Casting, emery wheel manufacture and anticolodal etc. are widely used in machinery industry; For the manufacture of rapid hardening cement, soil-solidified-agent, refractory materials etc. in building trade; Agriculturally can manufacture silicon element fertilizer material; Be used as the high temperature material such as filler, laboratory crucibles of soap, anticolodal, water-softening agent, detergent builder, refractory materials and ceramic raw material, waterproof, leak stopping, fire retarding wood protection, food antiseptic and preparing adhesive etc. in addition.
Bituminous varnish has excellent erosion resistance, to have excellent weather resistance, but poor heat resistance, the present invention is directed to this situation and waste water glass sand and pitch are all carried out modification be prepared into paint, not only reduce environmental pollution, and enhance acid resistance, thermotolerance, the advantage such as dispersiveness and fire line of paint.
Summary of the invention
The object of this invention is to provide a kind of heat-resistant fireproof type ship modifying asphalt paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of heat-resistant fireproof type ship modifying asphalt paint, is made up of the raw material of following weight part: E12 epoxy resin 32-35, polycarbodiimide 1-2, polyether ester 1-2, Graphene 3-4, nickel doped nano titanium dioxide 1-2, cobalt naphthenate 0.3-0.7, dimeracid 1-2, aliphatic cyclic amine 2-4, cardanol 2-3, toluene glycidyl ether 2-4, modified abandoned sodium silicate sand 8-13, modifying asphalt 9-14, wood wax oil 3-5, hexabromobenzene 1-2, polyvinyl ether 2-3, dimethylbenzene 8-11, ethylene glycol 6-9, methyl butyl phospho acid aluminium 0.5-1.0, talcum powder 1-2;
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resistant fireproof type ship modifying asphalt paint of the present invention, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Advantage of the present invention is: the modifying asphalt that paint of the present invention adds overcomes the shortcoming of the easy efflorescence of epoxy resin-based paint high temperature; and improve the functions such as the weathering resistance of paint, erosion resistance, moisture resistivity and water tolerance; the methyl butyl phospho acid aluminium added has very strong flame retardant properties; and the modified abandoned sodium silicate sand utilization of waste material added; protect environment; add thermotolerance and the flame retardant resistance of paint; paint of the present invention has low production cost; of many uses; excellent performance, is worth of widely use.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of heat-resistant fireproof type ship modifying asphalt paint, is made up of the raw material of following weight part (kilogram): E12 epoxy resin 35, polycarbodiimide 1, polyether ester 1, Graphene 3, nickel doped nano titanium dioxide 1, cobalt naphthenate 0.4, dimeracid 1, aliphatic cyclic amine 3, cardanol 2, toluene glycidyl ether 2, modified abandoned sodium silicate sand 8, modifying asphalt 9, wood wax oil 3, hexabromobenzene 1, polyvinyl ether 2, dimethylbenzene 8, ethylene glycol 9, methyl butyl phospho acid aluminium 0.6, talcum powder 1;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): pitch 82, aluminum stearate 0.5, C9 petroleum resin 5, carboxymethyl cellulose 1, thermoplastic elastomer 0.6, nano montmorillonite powder 2, polyethylene wax 0.4, dioctyl phthalate (DOP) 0.4, ester gum 0.7, isocaprylic acid zinc 0.3, fibrous magnesium silicate 1, polyoxyethylene gather fatty alcohol-ether 0.6, linseed oil 7, maleic acid 0.7, water 12, acetic acid butanols 2; Maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely; By asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resistant fireproof type ship modifying asphalt paint of the present invention, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Paint paint film flat smooth of the present invention, shock-resistance (/cm) 50, snappiness (mm) 2, sticking power (Mpa) 5, artificial accelerated aging (1000h) paint film without efflorescence, without variable color, flawless, salt spray resistance (1000h) paint film is non-foaming, does not come off, non-corrosive, water tolerance (27 ° of C ± 6 ° C, 500h) paint film is non-foaming, does not come off, non-corrosive, time of drying (25 ° of C) surface drying 2h, does solid work 24h, and high temperature resistant (130 ° of C) is greater than 600h.
Claims (3)
1. a heat-resistant fireproof type ship modifying asphalt paint, it is characterized in that, be made up of the raw material of following weight part: E12 epoxy resin 32-35, polycarbodiimide 1-2, polyether ester 1-2, Graphene 3-4, nickel doped nano titanium dioxide 1-2, cobalt naphthenate 0.3-0.7, dimeracid 1-2, aliphatic cyclic amine 2-4, cardanol 2-3, toluene glycidyl ether 2-4, modified abandoned sodium silicate sand 8-13, modifying asphalt 9-14, wood wax oil 3-5, hexabromobenzene 1-2, polyvinyl ether 2-3, dimethylbenzene 8-11, ethylene glycol 6-9, methyl butyl phospho acid aluminium 0.5-1.0, talcum powder 1-2,
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of heat-resistant fireproof type ship modifying asphalt paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned sodium silicate sand according to claim 1, it is characterized in that, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
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| CN201410467568.4A CN104312376A (en) | 2014-09-15 | 2014-09-15 | High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof |
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| CN108699382A (en) * | 2016-02-25 | 2018-10-23 | 中国涂料株式会社 | Anticorrosion coating composition, anticorrosion coating film, substrate with anticorrosion coating film, and manufacturing method thereof |
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