CN104311845A - Production method for moisture-proof agent for plants in mechanical industry - Google Patents
Production method for moisture-proof agent for plants in mechanical industry Download PDFInfo
- Publication number
- CN104311845A CN104311845A CN201410629171.0A CN201410629171A CN104311845A CN 104311845 A CN104311845 A CN 104311845A CN 201410629171 A CN201410629171 A CN 201410629171A CN 104311845 A CN104311845 A CN 104311845A
- Authority
- CN
- China
- Prior art keywords
- moisture
- water
- resin
- proof agent
- blushing thinner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 55
- 229920005989 resin Polymers 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 239000002250 absorbent Substances 0.000 claims abstract description 28
- 239000000178 monomer Substances 0.000 claims abstract description 25
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000035699 permeability Effects 0.000 claims abstract description 14
- 229920006037 cross link polymer Polymers 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000010521 absorption reaction Methods 0.000 claims description 30
- 230000002745 absorbent Effects 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 12
- 239000011802 pulverized particle Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 16
- 238000004132 cross linking Methods 0.000 abstract description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000000463 material Substances 0.000 description 16
- 239000007870 radical polymerization initiator Substances 0.000 description 11
- 230000000630 rising effect Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000209149 Zea Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000413 hydrolysate Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a production method for a moisture-proof agent for plants in the mechanical industry. The moisture-proof agent is a granular moisture-proof agent prepared from powdered water-absorbent resin and an assistant used for improving liquid permeability, wherein the powdered water-absorbent resin is irregularly-shaped smashed particles obtained from further surface cross-linking treatment of a cross-linked polymer of methacrylic acid monomers and/or methylacrylate monomers. The production method includes the following specific steps: ethyl alcohol, the water-absorbent resin and the mixed assistant are mixed, and the obtained mixture is illuminated by a light wave within the waveband of 300 nanometers to 400 nanometers while maintaining the flowing status of the mixture, so as to obtain the moisture-proof agent. The granular moisture-proof agent includes large particle-diameter (400 to 500 microns) powdered particles. Therefore, the moisture-proof agent achieves remarkable social and economic benefits.
Description
Technical field
The present invention relates to a kind of production method of mechanical industry factory building non-blushing thinner.
Background technology
Along with the progress of science and technology and the development of economic construction; the problem of energy dilemma has become the matter of utmost importance hindering world's every country Economic development and construction; by the impact of resource; crude oil in China disparities between supply and demand become increasingly conspicuous; from 1993; China becomes net import of oil state, needs every year to spend a large amount of foreign exchange Imported oils and petroleum products.Develop the oil substitutes such as fuel alcohol, take measures to save petroleum resources.In recent years, about these sanitary materials as disposable diaper and sanitary towel, its high functionalization and slimming make progress, so there is the water-absorbing resin amount increasing and use in every a slice sanitary material, and water-absorbing resin is relative to the trend of the quality % of the whole absorbing structure be made up of such as water-absorbing resin and hydrophilic fibre.
Specifically, by reducing the consumption of hydrophilic fibre (it has low bulk density) and increasing the consumption of water-absorbing resin (it has excellent water-absorbent and large bulk density), the ratio of water-absorbing resin in absorbing structure is improved.Thus, achieve the object of sanitary material slimming and do not reduce water regain.
A kind of known method, wherein uses a kind of absorbing polymeric forming hydrogel, and saline flow conductivity (SFC) value of this polymkeric substance is at least about 30 (10-7cm 3sg-1); The receptivity value (PUP) by pressure performance under 0.7psi (5kPa) locking pressure is at least 23 grams/gram; About 10gsm is at least with basis weight;
Known a kind of absorbing structure, its water-absorbent resin concentration is at least 40%; Saline flow conductivity (SFC) value is at least about 30 (10-7cm 3sg-1); The receptivity value by pressure performance (PUP) under 0.7psi (5kPa) locking pressure is at least 23 grams/grams;
As the object lesson of absorbent resin, hydrolysate and its cross-linking products of the hydrolysate of starch-acrylonitrile graft polymkeric substance, the starch-methacrylic acid graftomer of neutralization, the vinyl acetate-acrylate copolymer of saponification, acrylonitrile copolymer or acrylamide copolymer can be enumerated, and the crosslinked methacrylic acid of part neutralization.These absorbent resin all have the structure of internal crosslinking and show as insoluble in water.
A kind of known method, wherein: in absorbing structure, gel layer permeability (GLP) is that the water-absorbing resin of at least 4 (10-7g-1) is used to upper strata, and the water-absorbing resin that the receptivity under loads (AAP) under 50g/cm 2 load is at least 15 (grams/gram) is used to lower floor;
Expect that characteristic that these absorbent resin have comprises the such as with no pressure or necessary suction that absorbs water from medium that adds the high-selenium corn multiplying power of pressure, excellent absorption rate, high-gel strength and be entirely satisfactory.Because water-absorbent is subject to the impact of cross-linking density, therefore they need not show positive correlation each other, as cross-linking density increase cause gel-strength increase but absorb water amount reduce the fact show.Especially, such as absorbency and absorption rate, gel-strength and suction are contradictory relation.Therefore, when water-absorbent besin particles contacts with water, the absorbent resin having obtained the absorbency of raising may be avoided the absorption of uniform water and form the part of itself moiety aggregation, thus causes absorption rate extremely to reduce because water does not spread the whole volume throughout water-absorbent besin particles.
A kind of known method, wherein polycation is incorporated on water-absorbing resin by conjugated link(age); Known a kind of absorbent material, it comprises the mixture of following component: can be formed gel, containing the absorbing particles of the polymkeric substance of water-insoluble and water-swellable; With can with the absorbefacient polymkeric substance of improvement of contained at least one component reaction in urine;
For alleviating this phenomenon and obtaining the object with the absorbent resin of high-selenium corn multiplying power and more gratifying absorption rate, the method for giving the surface of water-absorbent besin particles tensio-active agent or fixed hydrocarbon coating is available.The method improves the dispersiveness of the initial water absorbed really, but does not bring sufficient effect to the absorption rate and suction improving single resin particle.
Summary of the invention
In order to solve the problems of the technologies described above, technical scheme of the present invention:
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the high diameter powders shape particle of 400-500 micron.
Because method of the present invention does not use any being considered to light wave activation with the water-soluble radical polymerization initiator causing formation table crosslinked or ethylenically unsaturated monomer, and any heat reactivity surface crosslinking agent, therefore, it is possible to reduce material cost.
About the character of material, because it does not use any surface crosslinking agent, it only can significantly improve the absorbency adding pressure of produced non-blushing thinner, and with no pressure under absorbency without any reduction.
In addition, the formation of incidental aggregate when method of the present invention can suppress to mix absorbent resin and water under mixed aid exists, and make while the flow state keeping mixture by becoming possibility with the homogeneous surface modification of light-wave irradiation gained mixture.
Embodiment
Embodiment 1
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner be comprise Powdered absorption moisture resin and improve the auxiliary agent of hydraulic permeability and the particulate state non-blushing thinner made, the resin of wherein said Powdered absorption moisture be the monomer comprising methacrylic acid and/or its salt cross-linked polymer by after further surface-crosslinked process in erose pulverized particles, concrete grammar comprises mixed ethanol, absorbent resin, mixed aid, to keep while this mix flow state with this gained mixture of light-wave irradiation of 300-400nm wave band and get final product, wherein said particulate state non-blushing thinner has the high diameter powders shape particle of 400-500 micron.
Embodiment 2
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of 400nm light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 400 μm.
Embodiment 3
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 394 μm.
Embodiment 4
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of 300nm light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 500 μm.
Embodiment 5
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 294 μm.
Embodiment 6
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 344 μm.
Embodiment 7
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 255 μm.
Embodiment 8
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 257 μm.
Embodiment 9
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 259 μm.
Embodiment 10
A kind of production method of mechanical industry factory building non-blushing thinner, non-blushing thinner comprises the resin of Powdered absorption moisture and the particulate state non-blushing thinner of hydraulic permeability rising agent (β), the resin of wherein said Powdered absorption moisture is that the cross-linked polymer of the monomer comprising methacrylic acid and/or its salt is comprised mixing absorbent resin in erose pulverized particles after further surface-crosslinked process, water and mixed aid and do not add the step of water-soluble radical polymerization initiator and ethylenically unsaturated monomer, with the step material with this gained mixture of light-wave irradiation while keeping this mix flow state, wherein said particulate state non-blushing thinner has the mass median diameter of 265 μm.
Claims (1)
1. the production method of a mechanical industry factory building non-blushing thinner, non-blushing thinner be comprise Powdered absorption moisture resin and improve the auxiliary agent of hydraulic permeability and the particulate state non-blushing thinner made, the resin of wherein said Powdered absorption moisture be the monomer comprising methacrylic acid and/or its salt cross-linked polymer by after further surface-crosslinked process in erose pulverized particles, concrete grammar comprises mixed ethanol, absorbent resin, mixed aid, to keep while this mix flow state with this gained mixture of light-wave irradiation of 300-400nm wave band and get final product, wherein said particulate state non-blushing thinner has the high diameter powders shape particle of 400-500 micron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410629171.0A CN104311845A (en) | 2014-11-10 | 2014-11-10 | Production method for moisture-proof agent for plants in mechanical industry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410629171.0A CN104311845A (en) | 2014-11-10 | 2014-11-10 | Production method for moisture-proof agent for plants in mechanical industry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104311845A true CN104311845A (en) | 2015-01-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410629171.0A Pending CN104311845A (en) | 2014-11-10 | 2014-11-10 | Production method for moisture-proof agent for plants in mechanical industry |
Country Status (1)
| Country | Link |
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| CN (1) | CN104311845A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927914A (en) * | 2002-12-06 | 2007-03-14 | 株式会社日本触媒 | Continuous production method of water absorbing resin product and ater absorbing resin product |
| CN101143909A (en) * | 2006-09-14 | 2008-03-19 | 台湾塑胶工业股份有限公司 | Method for producing high-performance high-water-absorptivity resin |
| CN101262943A (en) * | 2005-09-16 | 2008-09-10 | 株式会社日本触媒 | Method for production of water absorbing agent |
-
2014
- 2014-11-10 CN CN201410629171.0A patent/CN104311845A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927914A (en) * | 2002-12-06 | 2007-03-14 | 株式会社日本触媒 | Continuous production method of water absorbing resin product and ater absorbing resin product |
| CN101262943A (en) * | 2005-09-16 | 2008-09-10 | 株式会社日本触媒 | Method for production of water absorbing agent |
| CN101143909A (en) * | 2006-09-14 | 2008-03-19 | 台湾塑胶工业股份有限公司 | Method for producing high-performance high-water-absorptivity resin |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |
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