CN104311045B - Tundish light paint of a kind of resin-bonded and preparation method thereof - Google Patents
Tundish light paint of a kind of resin-bonded and preparation method thereof Download PDFInfo
- Publication number
- CN104311045B CN104311045B CN201410512572.8A CN201410512572A CN104311045B CN 104311045 B CN104311045 B CN 104311045B CN 201410512572 A CN201410512572 A CN 201410512572A CN 104311045 B CN104311045 B CN 104311045B
- Authority
- CN
- China
- Prior art keywords
- resin
- magnesia
- weight part
- equal
- tundish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003973 paint Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 232
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 116
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 92
- 239000000835 fiber Substances 0.000 claims abstract description 84
- 150000007524 organic acids Chemical class 0.000 claims abstract description 37
- 238000005245 sintering Methods 0.000 claims abstract description 37
- 239000006185 dispersion Substances 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 33
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000003756 stirring Methods 0.000 claims abstract description 26
- 229910052839 forsterite Inorganic materials 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 9
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 30
- 238000010276 construction Methods 0.000 claims description 29
- 239000002131 composite material Substances 0.000 claims description 26
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 15
- -1 polyethylene Polymers 0.000 claims description 15
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 12
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 10
- 229920000647 polyepoxide Polymers 0.000 claims description 10
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 9
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 claims description 9
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 claims description 9
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 9
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 9
- 229920003987 resole Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 239000004567 concrete Substances 0.000 claims description 4
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 claims description 4
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 4
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- 229940083542 sodium Drugs 0.000 claims description 2
- 235000015424 sodium Nutrition 0.000 claims description 2
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 229940001593 sodium carbonate Drugs 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 2
- 239000001433 sodium tartrate Substances 0.000 claims description 2
- 229960002167 sodium tartrate Drugs 0.000 claims description 2
- 235000011004 sodium tartrates Nutrition 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 2
- 229940038773 trisodium citrate Drugs 0.000 claims description 2
- 235000019263 trisodium citrate Nutrition 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 45
- 238000000576 coating method Methods 0.000 abstract description 45
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000002474 experimental method Methods 0.000 description 13
- 208000034189 Sclerosis Diseases 0.000 description 9
- 235000005985 organic acids Nutrition 0.000 description 9
- 239000003643 water by type Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000003245 working effect Effects 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019357 lignosulphonate Nutrition 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000003351 stiffener Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000013100 final test Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Products (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention's tundish light paint disclosing a kind of resin-bonded and preparation method thereof, tundish light paint is made up of the component of following weight part: the granularity of 85 ~ 95 weight parts is greater than 0mm and is less than or equal to magnesia and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part and 0.01 ~ 0.2 weight part sodium salt dispersion agent of 0.5mm.Preparation method comprise prepare raw material, according to order by raw material mix and blend and the steps such as stirring that add water.Tundish light paint of the present invention has that volume density is little, intensity is high, good fluidity, setting rate are fast and the advantage such as coating structure is even.
Description
Technical field
The present invention relates to unshape refractory technical field, particularly a kind of tundish light paint and preparation method thereof of resin-bonded.
Background technology
Tundish paint mainly with magnesia and/or forsterite for raw material, be disposable product, Year's consumption is very large.Along with the active demand of exhaustion and the national energy-saving Environmental Protection Strategy day by day of the fire-resistant resources such as magnesia, tundish paint has gradually from heavy (1.8 ~ 2.4g/cm
3) to lightweight (1.2 ~ 1.8/cm
3) trend of future development, its porosity is high, pore size large, and heat insulation effect is excellent.But, light paint in the market generally makes bonding agent or stiffening agent with one or more in silicon powder, clay, cement, water glass, poly-phosphate etc., in order to increase adhesivity, the plasticity-and intensity etc. of coating, addition is generally even higher 2 ~ 6%.This type of coating at high temperature interacts with infiltration slag and produces a large amount of liquid phase, and cause refractoriness significantly to reduce on the one hand, resistance to fouling is deteriorated; Sintering is serious on the other hand, bonds and causes turning over difficulty of wrapping or disintegrate, add the labour intensity of workman with permanent liner.
In addition, in lighting, traditional tundish paint extensively adopts sulfonated lignin, alkylsulfonate or vitriol etc. as air entrapment agent, its advantage is that significantly to reduce the body of coating close, have good water-reducing effect, but also there is the problem of following several aspect: (1) coating is comparatively large by churning time, amount of water, the impact of shelf-time, number of bubbles and size are difficult to control, cause the close poor stability of body, coating structure is uneven; (2) a large amount of micro bubbles improves dope viscosity, adds material adhesion resistance in the duct, and the most conventional domestic piston pump spraying machine cannot be used to carry out construction operation; (3) sulfonated lignin, alkylsulfonate or vitriol etc. have stronger delayed coagulation while bleed, and coating application post-hardening is slow, easily slump, directly affects construction speed.
Summary of the invention
For the deficiencies in the prior art, the object of the present invention is to provide that a kind of eutectic content is few, volume density is little, intensity is high, refractoriness is high, the tundish light paint of resin-bonded that resistance to fouling and sintering resistance can be good and preparation method thereof, tundish light paint of the present invention not only body close stable, coating structure is even, construction post-hardening speed is fast, intensity is high, not easily slump, and can carry out construction operation with the most conventional domestic piston pump spraying machine.
Technical scheme of the present invention is achieved in that a kind of tundish light paint of resin-bonded, is made up of the component of following weight part: the granularity of 85 ~ 95 weight parts is greater than 0mm and is less than or equal to magnesia and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part and 0.01 ~ 0.2 weight part sodium salt dispersion agent of 0.5mm.
The tundish light paint of above-mentioned resin-bonded, described magnesia and/or forsterite be greater than 0.2mm by the granularity of 25 ~ 35 weight parts and be less than or equal to the magnesia of 0.5mm and/or forsterite, the granularity of 30 ~ 50 weight parts is greater than 0.088mm and the granularity of the magnesia and/or forsterite and 25 ~ 40 weight parts that are less than or equal to 0.2mm is greater than 0mm and is less than or equal to the magnesia of 0.088mm and/or forsterite forms.
The tundish light paint of above-mentioned resin-bonded, the mass ratio of described organic acid and described resin-oatmeal is 1:3 ~ 3:1.
The tundish light paint of above-mentioned resin-bonded, in described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass is more than or equal to 85%.
The tundish light paint of above-mentioned resin-bonded, described organic acid be in citric acid, oxysuccinic acid, tartrate and oxalic acid one or both and two or more; Described resin-oatmeal be in resol, epoxy resin, Precondensed UreaFormaldehyde Resin, melmac, Modified Water Soluble Phenolic Resin, modified soluble epoxy resin, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac one or both and two or more; Described magnesia sintering agent be in light burned magnesite powder, attaclay, magnesium chloride hexahydrate and magnesium sulfate heptahydrate one or both and two or more; Described sodium salt dispersion agent be in Sodium hexametaphosphate 99, tripoly phosphate sodium STPP, sodium tetrapolyphosphate, five sodium polyphosphates, hexapolyphosphate sodium, Trisodium Citrate, sodium carbonate, sodium tartrate and trisodium phosphate one or both and two or more.
The tundish light paint of above-mentioned resin-bonded, described hollow organic fibre is hollow polyethylene fibre or hollow polypropylene fibres, and the diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
The preparation method of the tundish light paint of resin-bonded, concrete steps are as follows:
(1) be greater than 0mm according to the tundish light paint of resin-bonded by the granularity of 85 ~ 95 weight parts and be less than or equal to the magnesia of 0.5mm and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part and 0.01 ~ 0.2 weight part sodium salt dispersion agent form, preparing raw material;
(2) ready magnesia in step (1) and/or forsterite are loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2) and/or forsterite, add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 20 ~ 30% of the quality of the middle gained mixture of step (4) used in construction, manually smears or machine spraying after stirring.
A tundish light paint for resin-bonded, is made up of the component of following weight part: the granularity of 85 ~ 95 weight parts is greater than 0mm and is less than or equal to the magnesia of 0.5mm and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part and 0.01 ~ 0.2 weight part sodium salt dispersion agent, 0.5 ~ 2 weight part composite anti-penetrating agent.
The tundish light paint of above-mentioned resin-bonded, composite anti-penetrating agent is made up of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate, the mass ratio of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate is 2:4:1, and the granularity of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate is 1 ~ 5nm.
The preparation method of the tundish light paint of resin-bonded, concrete steps are as follows:
(1) be greater than 0mm according to the tundish light paint of resin-bonded by the granularity of 85 ~ 95 weight parts and be less than or equal to the magnesia of 0.5mm and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part, 0.01 ~ 0.2 weight part sodium salt dispersion agent and 0.5 ~ 2 weight part composite anti-penetrating agent form, preparing raw material;
(2) ready magnesia in step (1) and/or forsterite are loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2) and/or forsterite, add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 20 ~ 30% of the quality of the middle gained mixture of step (4) used in construction, and then add composite anti-penetrating agent, manually smear after stirring or machine spraying.
The invention has the beneficial effects as follows:
1. resin-oatmeal or its water soluble resin are used for tundish light paint, only add a small amount of magnesia sintering agent, namely can be coating and sufficiently high low temperature, middle temperature and hot strength are provided, decrease the generation of liquid phase under product high temperature; The carbon net be simultaneously decomposed to form under resin high temperature to slag and molten steel nonwetting.Thus, compared with the light paint combined with general silicon powder, clay, cement, water glass or poly-phosphate, the resistance to fouling of product and sintering resistance can more excellent, longer service life.
2. composite between the void content that product is high and the close hollow organic fibre mainly coming from the less critical granularity of system, reasonably grain composition, the resin-oatmeal of high dispersive, high dispersive of low body, and not by churning time and the restriction of shelf-time.Compared with existing traditional bleed formulation light paint, the close stability of product body is better, coating structure is more even, better heat preservation.
3. organic acid and resin-oatmeal are composite in proportion, can ensure that product has high mobility, plasticity-and enough setting times, no matter meet coating stirring at normal temperatures, pumping and deposit needs, be spiral pump or piston pump spraying machine, all can operation smoothly; When temperature is more than 60 DEG C, organic acid, then as the stiffening agent of resin-oatmeal, can ensure that the coating being sprayed into permanent liner surface hardens and not slump at short notice, thus accelerating construction progress.
4. in product, with the addition of that low melting point, low body are close, the hollow organic fibre of polymolecularity, in bake process, water vapour except can from the fiber melting or shrink gap discharge except, directly therefrom can also have in vain in the axial hollow pipeline of organic fiber and ooze out, compare and only add traditional paper fiber or glass fibre, the permeability of the coating adopting light paint of the present invention to smear is better, and anti-spalling is more excellent.
5. Strontium carbonate powder, Strontium Sulphate, calcium sulfate are heavy material, and itself is fine and close, has and stops osmosis preferably, and the material of employing nano level degree can make again the doubtful gap between its abundant light filling material, makes material body fine and close and antiseepage; And the compound action of nano strontium carbonate, nanometer Strontium Sulphate, nanometer calcium sulfate, permeability-thickness can be controlled preferably and realize lower cost, but also the compressive strength of coating can be improved.In addition Strontium carbonate powder, Strontium Sulphate still de-S, the de-P agent preferably when high temperature, plays clean acting on to molten steel.After adopting composite anti-penetrating agent, in the experiment of crucible method anti-erosion, and not with compared with composite anti-penetrating, permeation layer thickness reduces about 30%.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
In the examples below, degree of mobilization testing method in prior art is adopted to measure the mobility of the tundish light paint of resin-bonded of the present invention: truncated cone-shaped mould bottom surface diameter is 100 millimeters, upper bottom surface diameter is 70 millimeters, height is 50 millimeters, mould is placed on shaking table, vertically mould is removed after putting coating, vibrate 20 seconds (vibrational flow), test material cake diameter is as yield point value index (unit mm).Measure once every 120 degree, getting the mean value measured for three times is the final testing result of vibration flowability.The test of compressive strength adopts the national standard of refractory product technical field to test the compressive strength of the tundish light paint of resin-bonded of the present invention.
Embodiment 1
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent and 0.2 kilogram of sodium salt dispersion agent.
Described magnesia be greater than 0.2mm by the granularity of 25 kilograms and be less than or equal to the magnesia of 0.3mm, the granularity of 35 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm and the granularity of 25 kilograms and be greater than 0mm and the magnesia being less than or equal to 0.078mm forms.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.03mm accounts for described resin-oatmeal total mass equals 85%.The diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is citric acid; Described resin-oatmeal is resol; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
The tundish light paint preparation method of the present embodiment resin-bonded comprises the steps:
(1) according to the said ratio of each component in the tundish light paint of resin-bonded, raw material is prepared;
(2) magnesia ready in step (1) is loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2), add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 25% of the quality of the middle gained mixture of step (4) used in construction, manually smears or machine spraying after stirring.
The viscosity of the present embodiment coating is good, sclerosis is fast, plasticity-is strong, without slump phenomenon, volume density is 1.6g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 15Mpa, and vibration flowability is 280 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 30 minutes; Experiment proves, this coating mean life is 85 stoves, on average connects and waters time 85h.
Embodiment 2
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent and 0.2 kilogram of sodium salt dispersion agent.
Described magnesia is greater than 0.2mm by the granularity of 10 kilograms and is less than or equal to the magnesia of 0.3mm, the granularity of 15 kilograms is more than or equal to 0.35mm and is less than or equal to the magnesia of 0.5mm, the granularity of 5 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm, the granularity of 30 kilograms is more than or equal to 0.13mm and is less than or equal to the magnesia of 0.2mm, the granularity of 14 kilograms is greater than 0mm and is less than or equal to the magnesia of 0.04mm and the granularity of 11 kilograms and is more than or equal to 0.05mm and the magnesia composition being less than or equal to 0.088mm.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.02mm accounts for described resin-oatmeal total mass equals 30%, granularity is more than or equal to 0.025mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass equals 65%.The diameter of described hollow organic fibre is 10 ~ 20 μm, and the length of described hollow organic fibre is greater than 3mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is citric acid; Described resin-oatmeal is resol; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 1.The viscosity of the present embodiment coating is good, sclerosis fast, plasticity-is strong, without slump phenomenon, volume density 1.5g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 20Mpa, and vibration flowability is 285 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 30 minutes; Experiment proves, this coating mean life is 96 stoves, on average connects and waters time 96h.
Embodiment 3
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent and 0.2 kilogram of sodium salt dispersion agent.
Described magnesia be greater than 0.2mm by the granularity of 25 kilograms and be less than or equal to the magnesia of 0.3mm, the granularity of 35 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm and the granularity of 25 kilograms and be greater than 0mm and the magnesia being less than or equal to 0.078mm forms.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.03mm accounts for described resin-oatmeal total mass equals 85%.The diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is oxysuccinic acid and tartaric mixture, and oxysuccinic acid and tartaric mass ratio are 1:1.5; Described resin-oatmeal is the mixture of Precondensed UreaFormaldehyde Resin, melmac, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac, and the mass ratio of Precondensed UreaFormaldehyde Resin, melmac, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac is 1:1.5:0.5:3; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 1.The viscosity of the present embodiment coating is good, sclerosis fast, plasticity-is strong, without slump phenomenon, volume density 1.6g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 15Mpa, and vibration flowability is 303 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 25 minutes; Experiment proves, this coating work-ing life is 86 stoves, connects and waters time 86h.
Embodiment 4
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent and 0.2 kilogram of sodium salt dispersion agent.
Described magnesia is greater than 0.2mm by the granularity of 10 kilograms and is less than or equal to the magnesia of 0.3mm, the granularity of 15 kilograms is more than or equal to 0.35mm and is less than or equal to the magnesia of 0.5mm, the granularity of 5 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm, the granularity of 30 kilograms is more than or equal to 0.13mm and is less than or equal to the magnesia of 0.2mm, the granularity of 14 kilograms is greater than 0mm and is less than or equal to the magnesia of 0.04mm and the granularity of 11 kilograms and is more than or equal to 0.05mm and the magnesia composition being less than or equal to 0.088mm.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.02mm accounts for described resin-oatmeal total mass equals 30%, granularity is more than or equal to 0.025mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass equals 65%.The diameter of described hollow organic fibre is 10 ~ 20 μm, and the length of described hollow organic fibre is greater than 3mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is the mixture of citric acid and oxalic acid, and the mass ratio of citric acid and oxalic acid is 1:1; Described resin-oatmeal is the mixture of resol, epoxy resin, Modified Water Soluble Phenolic Resin and modified soluble epoxy resin, and the mass ratio of resol, epoxy resin, Modified Water Soluble Phenolic Resin and modified soluble epoxy resin is 1:1:1.5:2.5; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 1.The viscosity of the present embodiment coating is good, sclerosis fast, plasticity-is strong, without slump phenomenon, volume density 1.5g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 20.4Mpa, and vibration flowability is 320 millimeters.This coating of the coating of the present embodiment is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 20 minutes; Experiment proves, this coating work-ing life is 96 stoves, connects and waters time 96h.
Embodiment 5
A tundish light paint for resin-bonded, is made up of the component of following weight part: the granularity of 90.8 kilograms is greater than 0mm and is less than or equal to the magnesia of 0.5mm and forsterite, 2.3 kilogram resin powder, 2.21 kilograms of organic acids, 2.29 kilograms of hollow organic fibres, 2.29 kilograms of paper fibers, 0.1 kilogram of magnesia sintering agent and 0.01 kilogram of sodium salt dispersion agent.Wherein, magnesia is 40 kilograms, and forsterite is 50.8 kilograms.
Described organic acid is oxalic acid; Described resin-oatmeal is epoxy resin; Described magnesia sintering agent is magnesium sulfate heptahydrate; Described sodium salt dispersion agent is trisodium phosphate.
Wherein the granularity of 30 kilograms of described magnesia is greater than 0.2mm and is less than or equal to 0.5mm; The granularity of 40 kilograms of described forsterites is greater than 0.088mm and is less than or equal to 0.2mm; The granularity of 10 kilograms of magnesia and 10.8 kilograms of forsterites is greater than 0mm and is less than or equal to 0.088mm.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass is more than or equal to 85%.
Described hollow organic fibre is hollow polyethylene fibre or hollow polypropylene fibres, and the diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
The tundish light paint preparation method of the present embodiment resin-bonded comprises the steps:
(1) according to the said ratio of each component in the tundish light paint of resin-bonded, raw material is prepared;
(2) ready magnesia in step (1) and forsterite are loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2), add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 20% of the quality of the middle gained mixture of step (4) used in construction, manually smears or machine spraying after stirring.
The viscosity of the present embodiment coating is good, sclerosis is fast, plasticity-is strong, without slump phenomenon, volume density is 1.6g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 14Mpa, and vibration flowability is 270 millimeters.This coating of the coating of the present embodiment is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 35 minutes; Experiment proves, this coating mean life is 82 stoves, on average connects and waters time 82h.
Embodiment 6
A tundish light paint for resin-bonded, is made up of the component of following weight part: the granularity of 90.8 kilograms is greater than 0mm and is less than or equal to the magnesia of 0.5mm and forsterite, 2.3 kilogram resin powder, 2.21 kilograms of organic acids, 2.29 kilograms of hollow organic fibres, 2.29 kilograms of paper fibers, 0.1 kilogram of magnesia sintering agent and 0.01 kilogram of sodium salt dispersion agent.Wherein, magnesia is 40 kilograms, and forsterite is 50.8 kilograms.
Described organic acid is oxalic acid; Described resin-oatmeal is epoxy resin; Described magnesia sintering agent is magnesium sulfate heptahydrate; Described sodium salt dispersion agent is trisodium phosphate.
Wherein the granularity of 10 kilograms of described magnesia is greater than 0.2mm and is less than or equal to 0.3mm, and the granularity of 20 kilograms of described magnesia is more than or equal to 0.4mm and is less than or equal to 0.5mm; The granularity of 40 kilograms of described forsterites is greater than 0.088mm and is less than or equal to 0.2mm; The granularity of 10 kilograms of magnesia and 10.8 kilograms of forsterites is greater than 0mm and is less than or equal to 0.07mm.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.03mm accounts for described resin-oatmeal total mass is 40%, and granularity is greater than 0.03mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass is 50%.
Described hollow organic fibre is hollow polyethylene fibre or hollow polypropylene fibres, and the diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 5mm and is less than or equal to 8 ㎜.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 5.The viscosity of the present embodiment coating is good, sclerosis is fast, plasticity-is strong, without slump phenomenon, volume density is 1.53g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 18Mpa, and vibration flowability is 271 millimeters.This coating of the coating of the present embodiment is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 35 minutes; Experiment proves, this coating mean life is 84 stoves, on average connects and waters time 84h.
Embodiment 7
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent, 0.2 kilogram of sodium salt dispersion agent and 1.75 kilograms of composite anti-penetrating agent.
Described magnesia be greater than 0.2mm by the granularity of 25 kilograms and be less than or equal to the magnesia of 0.3mm, the granularity of 35 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm and the granularity of 25 kilograms and be greater than 0mm and the magnesia being less than or equal to 0.078mm forms.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.03mm accounts for described resin-oatmeal total mass equals 85%.The diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is citric acid; Described resin-oatmeal is resol; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
Described composite anti-penetrating agent is made up of 0.5 kilogram of nano strontium carbonate, 1 kilogram of nanometer Strontium Sulphate and 0.25 kilogram of nano barium sulfate.
Preparation method's concrete steps of the tundish light paint of the present embodiment resin-bonded are as follows:
(1) according to the said components proportioning of the tundish light paint of resin-bonded, raw material is prepared;
(2) magnesia ready in step (1) is loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2), add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 25% of the quality of the middle gained mixture of step (4) used in construction, and then add composite anti-penetrating agent, manually smear after stirring or machine spraying.
The viscosity of the present embodiment coating is good, sclerosis is fast, plasticity-is strong, without slump phenomenon, volume density is 1.6g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 16Mpa, and vibration flowability is 280 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 30 minutes; Experiment proves, this coating mean life is 87 stoves, on average connects and waters time 87h.After the present embodiment adopts composite anti-penetrating agent, in the experiment of crucible method anti-erosion, and do not use composite anti-penetrating agent ratio in embodiment 1, permeation layer thickness reduces 28%.
Embodiment 8
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent, 0.2 kilogram of sodium salt dispersion agent and 1.75 kilograms of composite anti-penetrating agent.
Described magnesia is greater than 0.2mm by the granularity of 10 kilograms and is less than or equal to the magnesia of 0.3mm, the granularity of 15 kilograms is more than or equal to 0.35mm and is less than or equal to the magnesia of 0.5mm, the granularity of 5 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm, the granularity of 30 kilograms is more than or equal to 0.13mm and is less than or equal to the magnesia of 0.2mm, the granularity of 14 kilograms is greater than 0mm and is less than or equal to the magnesia of 0.04mm and the granularity of 11 kilograms and is more than or equal to 0.05mm and the magnesia composition being less than or equal to 0.088mm.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.02mm accounts for described resin-oatmeal total mass equals 30%, granularity is more than or equal to 0.025mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass equals 65%.The diameter of described hollow organic fibre is 10 ~ 20 μm, and the length of described hollow organic fibre is greater than 3mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is citric acid; Described resin-oatmeal is resol; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
Described composite anti-penetrating agent is made up of 0.5 kilogram of nano strontium carbonate, 1 kilogram of nanometer Strontium Sulphate and 0.25 kilogram of nano barium sulfate.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 1.The viscosity of the present embodiment coating is good, sclerosis fast, plasticity-is strong, without slump phenomenon, volume density 1.5g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 22Mpa, and vibration flowability is 285 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 30 minutes; Experiment proves, this coating mean life is 98 stoves, on average connects and waters time 98h.After the present embodiment adopts composite anti-penetrating agent, in the experiment of crucible method anti-erosion, and do not use composite anti-penetrating agent ratio in embodiment 2, permeation layer thickness reduces 27%.
Embodiment 9
A tundish light paint for resin-bonded, is made up of the component of following weight part: the magnesia of 85 kilograms, 6.0 kilogram resin powder, 2.5 kilograms of organic acids, 3 kilograms of hollow organic fibres, 3 kilograms of paper fibers, 0.3 kilogram of magnesia sintering agent, 0.2 kilogram of sodium salt dispersion agent and 1.75 kilograms of composite anti-penetrating agent.
Described magnesia be greater than 0.2mm by the granularity of 25 kilograms and be less than or equal to the magnesia of 0.3mm, the granularity of 35 kilograms is greater than 0.088mm and is less than or equal to the magnesia of 0.1mm and the granularity of 25 kilograms and be greater than 0mm and the magnesia being less than or equal to 0.078mm forms.
In described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.03mm accounts for described resin-oatmeal total mass equals 85%.The diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8 ㎜.
Described hollow organic fibre is hollow polyethylene fibre; Described organic acid is oxysuccinic acid and tartaric mixture, and oxysuccinic acid and tartaric mass ratio are 1:1.5; Described resin-oatmeal is the mixture of Precondensed UreaFormaldehyde Resin, melmac, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac, and the mass ratio of Precondensed UreaFormaldehyde Resin, melmac, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac is 1:1.5:0.5:3; Described magnesia sintering agent is magnesium chloride hexahydrate; Described sodium salt dispersion agent is tripoly phosphate sodium STPP.
Described composite anti-penetrating agent is made up of 0.5 kilogram of nano strontium carbonate, 1 kilogram of nanometer Strontium Sulphate and 0.25 kilogram of nano barium sulfate.
The preparation method of the tundish light paint of the present embodiment resin-bonded is identical with embodiment 1.The viscosity of the present embodiment coating is good, sclerosis fast, plasticity-is strong, without slump phenomenon, volume density 1.6g/cm
3, the compressive strength after 110 DEG C × 16h toasts is 16Mpa, and vibration flowability is 303 millimeters.This coating is constructed under 70 ± 5 DEG C of environment, total thickness 120mm, and point three times constructions, often can harden all over construction for latter 25 minutes; Experiment proves, this coating work-ing life is 87 stoves, connects and waters time 87h.After the present embodiment adopts composite anti-penetrating agent, in the experiment of crucible method anti-erosion, and do not use composite anti-penetrating agent ratio in embodiment 3, permeation layer thickness reduces 30%.
Above-described embodiment is only for the invention example is clearly described, and the restriction not to the invention embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.All within the spirit and principles in the present invention any apparent change of extending out or variation be still among the protection domain of the invention claim.
Claims (7)
1. the tundish light paint of a resin-bonded, it is characterized in that, be made up of the component of following weight part: the granularity of 85 ~ 95 weight parts is greater than 0mm and is less than or equal to the magnesia of 0.5mm and/or forsterite, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part and 0.01 ~ 0.2 weight part sodium salt dispersion agent, 0.5 ~ 2 weight part composite anti-penetrating agent; Described composite anti-penetrating agent is made up of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate, the mass ratio of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate is 2:4:1, and the granularity of nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate is 1 ~ 5nm.
2. the tundish light paint of resin-bonded according to claim 1, it is characterized in that, described magnesia and/or forsterite be greater than 0.2mm by the granularity of 25 ~ 35 weight parts and be less than or equal to the magnesia of 0.5mm and/or forsterite, the granularity of 30 ~ 50 weight parts is greater than 0.088mm and the granularity of the magnesia and/or forsterite and 25 ~ 40 weight parts that are less than or equal to 0.2mm is greater than 0mm and is less than or equal to the magnesia of 0.088mm and/or forsterite forms.
3. the tundish light paint of resin-bonded according to claim 1, is characterized in that, the mass ratio of described organic acid and described resin-oatmeal is 1:3 ~ 3:1.
4. the tundish light paint of resin-bonded according to claim 1, is characterized in that, in described resin-oatmeal, granularity is greater than 0mm and the mass percent that the resin-oatmeal being less than or equal to 0.045mm accounts for described resin-oatmeal total mass is more than or equal to 85%.
5. the tundish light paint of resin-bonded according to claim 1, is characterized in that, described organic acid be in citric acid, oxysuccinic acid, tartrate and oxalic acid one or both and two or more; Described resin-oatmeal be in resol, epoxy resin, Precondensed UreaFormaldehyde Resin, melmac, Modified Water Soluble Phenolic Resin, modified soluble epoxy resin, modified soluble Precondensed UreaFormaldehyde Resin and modified soluble melmac one or both and two or more; Described magnesia sintering agent be in light burned magnesite powder, attaclay, magnesium chloride hexahydrate and magnesium sulfate heptahydrate one or both and two or more; Described sodium salt dispersion agent be in Sodium hexametaphosphate 99, tripoly phosphate sodium STPP, sodium tetrapolyphosphate, five sodium polyphosphates, hexapolyphosphate sodium, Trisodium Citrate, sodium carbonate, sodium tartrate and trisodium phosphate one or both and two or more.
6. the tundish light paint of resin-bonded according to claim 1, it is characterized in that, described hollow organic fibre is hollow polyethylene fibre or hollow polypropylene fibres, the diameter of described hollow organic fibre is 10 ~ 25 μm, and the length of described hollow organic fibre is greater than 0mm and is less than or equal to 8mm.
7. the preparation method of the tundish light paint of resin-bonded, it is characterized in that, concrete steps are as follows:
(1) be greater than 0mm according to the tundish light paint of resin-bonded by the granularity of 85 ~ 95 weight parts and be less than or equal to magnesia and/or the forsterite of 0.5mm, 0.3 ~ 6.0 parts by weight resin powder, 0.01 ~ 2.5 weight part organic acid, 0.1 ~ 3 weight part hollow organic fibre, 0.5 ~ 3 weight part paper fiber, the magnesia sintering agent of 0.1 ~ 0.3 weight part, 0.01 ~ 0.2 weight part sodium salt dispersion agent and 0.5 ~ 2 weight part composite anti-penetrating agent composition, described composite anti-penetrating agent is by nano strontium carbonate, nanometer Strontium Sulphate and nano barium sulfate composition, nano strontium carbonate, the mass ratio of nanometer Strontium Sulphate and nano barium sulfate is 2:4:1, nano strontium carbonate, the granularity of nanometer Strontium Sulphate and nano barium sulfate is 1 ~ 5nm, prepare raw material,
(2) ready magnesia in step (1) and/or forsterite are loaded in whipping appts;
(3) in the magnesia in the whipping appts in step (2) and/or forsterite, add paper fiber and hollow organic fibre successively and stir, the rotating speed of stirrer is 35r/min, and churning time is 5 ~ 10min, eliminates fibrous mass;
(4) in the mixture through step (3) process gained, add described resin-oatmeal, organic acid, magnesia sintering agent and sodium salt dispersion agent, after continuing stirring 10 ~ 15min, discharging is packed;
(5) during site operation, directly to the stirring that adds water in the mixture of step (4) process gained, the quality added water is 20 ~ 30% of the quality of the middle gained mixture of step (4) used in construction, and then add composite anti-penetrating agent, manually smear after stirring or machine spraying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410512572.8A CN104311045B (en) | 2014-09-28 | 2014-09-28 | Tundish light paint of a kind of resin-bonded and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410512572.8A CN104311045B (en) | 2014-09-28 | 2014-09-28 | Tundish light paint of a kind of resin-bonded and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104311045A CN104311045A (en) | 2015-01-28 |
| CN104311045B true CN104311045B (en) | 2016-03-02 |
Family
ID=52366395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410512572.8A Active CN104311045B (en) | 2014-09-28 | 2014-09-28 | Tundish light paint of a kind of resin-bonded and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104311045B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040159A (en) * | 2015-08-30 | 2015-11-11 | 常州思宇环保材料科技有限公司 | Preparation method of far-infrared alginate fiber medical gauze |
| CN106083092B (en) * | 2016-06-22 | 2019-04-23 | 山东国茂冶金材料有限公司 | A kind of preferably inexpensive tundish dry material of anti-steel slag permeability and its preparation method |
| CN108002847A (en) * | 2016-10-28 | 2018-05-08 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing forsterite and preparation method thereof |
| CN108002851A (en) * | 2016-10-28 | 2018-05-08 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing mullite and preparation method thereof |
| CN108002849A (en) * | 2016-10-28 | 2018-05-08 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing magnesia and preparation method thereof |
| CN108002848A (en) * | 2016-10-28 | 2018-05-08 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing magnesium aluminate spinel and preparation method thereof |
| CN108017397A (en) * | 2016-10-28 | 2018-05-11 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing quartz sand and preparation method thereof |
| CN108017399A (en) * | 2016-10-28 | 2018-05-11 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing calcium hexaluminate and preparation method thereof |
| CN108002850A (en) * | 2016-10-28 | 2018-05-08 | 河南智联寰宇知识产权运营有限公司 | Refractory brick containing spodumene and preparation method thereof |
| CN106588045A (en) * | 2016-12-06 | 2017-04-26 | 武汉威林科技股份有限公司 | Tundish for continuous casting |
| CN107010988B (en) * | 2017-04-27 | 2019-08-16 | 濮阳濮耐高温材料（集团）股份有限公司 | A kind of dry working lining and preparation method thereof of anti-swelling cracking |
| CN108162261A (en) * | 2017-11-22 | 2018-06-15 | 安徽德全新型建材科技有限公司 | A kind of cleaning equipment of the mold of graphite polystyrene board |
| CN108530090B (en) * | 2018-05-07 | 2020-08-04 | 濮阳濮耐高温材料（集团）股份有限公司柳屯分厂 | Light tundish working lining and preparation method thereof |
| CN108526388B (en) * | 2018-05-30 | 2019-11-08 | 四川廷勋铸造材料有限公司 | A kind of cast paint and preparation method thereof for flow coat |
| CN111592366B (en) * | 2020-04-28 | 2022-04-29 | 河南九环实业发展有限公司 | Environment-friendly multi-element nano wear-resistant corrosion-resistant vitrified lining material |
| CN115246733A (en) * | 2021-04-28 | 2022-10-28 | 宝山钢铁股份有限公司 | High-durability tundish coating and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033985A (en) * | 1987-12-31 | 1989-07-19 | 冶金部洛阳耐火材料研究所 | The carbon containing unshape refractory |
| CN1800105A (en) * | 2005-10-14 | 2006-07-12 | 河北理工大学 | Dry type working liner material for erosion resistance continuous casting tundish |
| CN101508586A (en) * | 2009-03-27 | 2009-08-19 | 武汉钢铁(集团)公司 | Paint for continuous casting pouring box work liner and preparing technique thereof |
| CN101717264A (en) * | 2009-11-19 | 2010-06-02 | 鞍山市和丰耐火材料有限公司 | Method for producing fire-proof spray coating of tundish for smelting purity steel |
-
2014
- 2014-09-28 CN CN201410512572.8A patent/CN104311045B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033985A (en) * | 1987-12-31 | 1989-07-19 | 冶金部洛阳耐火材料研究所 | The carbon containing unshape refractory |
| CN1800105A (en) * | 2005-10-14 | 2006-07-12 | 河北理工大学 | Dry type working liner material for erosion resistance continuous casting tundish |
| CN101508586A (en) * | 2009-03-27 | 2009-08-19 | 武汉钢铁(集团)公司 | Paint for continuous casting pouring box work liner and preparing technique thereof |
| CN101717264A (en) * | 2009-11-19 | 2010-06-02 | 鞍山市和丰耐火材料有限公司 | Method for producing fire-proof spray coating of tundish for smelting purity steel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104311045A (en) | 2015-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104311045B (en) | Tundish light paint of a kind of resin-bonded and preparation method thereof | |
| US10711456B2 (en) | Fire-proof thermal-insulation board of B02 autoclaved aerated lightweight concrete and method for preparing same | |
| CN102366812B (en) | A kind of preparation method of sodium silicate sand used for casting | |
| CN104353777B (en) | Cast iron lost foam paint and preparation method thereof | |
| CN102941312B (en) | Coating for water-based magnesia casting and preparation method thereof | |
| CN103771797B (en) | Two the mixing of slag prepares foam concrete block and preparation method thereof | |
| CN102815955B (en) | Anti-skinning spray coating material for cement kiln | |
| CN105837241B (en) | Cast steel and high temperature alloy ceramic foam filter and its manufacturing method | |
| MXPA00012503A (en) | Insulating refractory material. | |
| CN107200530A (en) | A kind of preparation method of Phasochange energy storage ceramic particle and its application in fiber concrete structure | |
| CN102366814B (en) | A kind of preparation method of coating for metal mold used in aluminum alloy low pressure casting | |
| CN102836949B (en) | Manufacturing method of heat insulation spray coating for centrifugally casting cylinder sleeve | |
| CN109734388B (en) | Mortar and preparation method and application thereof | |
| CN107009484A (en) | A kind of preparation method of high performance concrete Self-heat-insulation composite building block | |
| CN107012963A (en) | Non-load-bearing foam concrete composite heat-insulation baffle plate and preparation method thereof | |
| CN108640583A (en) | A kind of air entrained concrete straw building block and preparation method thereof | |
| CN110423103A (en) | A kind of middle water containing opening environmentally friendly chamotte and preparation method thereof | |
| CN106631056A (en) | Magnesia-calcia tundish dry vibrating material and preparation method thereof | |
| CN109261893A (en) | A kind of fused alumina zirconia alcohol-base foundry coating and preparation method thereof | |
| CN204621070U (en) | A kind of combined type high life low cost ladle pocket block | |
| CN108947583B (en) | Concrete exposed stone agent and preparation method thereof | |
| CN108788001A (en) | A kind of large size alloy cast steel part evaporative pattern water based paint | |
| CN102559961B (en) | Anti-steel-sticking treatment method of slag basins and slag tanks by using overflow steel tank ramming material | |
| CN106587960A (en) | Thermal-shock-resistant refractory brick and preparation method thereof | |
| CN103360097A (en) | Refractory slurry powder for air brick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170515 Address after: 115000 Liaoning Province, Yingkou City Nanhai City Industrial Park, No. 129 South Road Patentee after: Yingkou Punai Magnesium Materials Co., Ltd. Address before: 457100, Puyang County, Henan City, Puyang Province, West Ring Road, Puyang Pu high-temperature materials (Group) Limited by Share Ltd Patentee before: Puyang Refractories Group Co., Ltd. |