CN104294680B - A kind of aramid fiber dyeing method - Google Patents
A kind of aramid fiber dyeing method Download PDFInfo
- Publication number
- CN104294680B CN104294680B CN201410494200.7A CN201410494200A CN104294680B CN 104294680 B CN104294680 B CN 104294680B CN 201410494200 A CN201410494200 A CN 201410494200A CN 104294680 B CN104294680 B CN 104294680B
- Authority
- CN
- China
- Prior art keywords
- dyeing
- aramid fiber
- phenylethanone
- dye liquor
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229920006231 aramid fiber Polymers 0.000 title claims abstract description 14
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims abstract description 22
- VHSDVSHRALYMDC-UHFFFAOYSA-N 3-(3,3-dihydroxypropylidene)-1,1-dihydroxyurea Chemical compound OC(O)CC=NC(=O)N(O)O VHSDVSHRALYMDC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000001804 emulsifying effect Effects 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 18
- 230000008961 swelling Effects 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000012805 post-processing Methods 0.000 description 6
- 238000002203 pretreatment Methods 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229920000271 Kevlar® Polymers 0.000 description 3
- 241001279158 Silonia silondia Species 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000004761 kevlar Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 239000013527 degreasing agent Substances 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
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- Coloring (AREA)
Abstract
The open a kind of aramid fiber dyeing method of the present invention, including dyeing, wash, drying, during dyeing, adds 1-Phenylethanone. and the dihydroxymethyl dihydroxy ethylidene-urea of 1 3% of 5 10% in dye liquor.With existing swelling method or carrier dyeing process, the inventive method dye liquor adds the dye-uptake of dyestuff when appropriate 1-Phenylethanone. and dihydroxymethyl dihydroxy ethylidene-urea can significantly improve aramid fiber dyeing as the dyeing auxiliaries of dyestuff, and improves color fastness.
Description
Technical field
The present invention relates to a kind of aramid fiber dyeing method.
Background technology
As synthetic fibers, aramid fiber has high intensity and toughness, and excellent high temperature resistant, resistance to acids and bases,
But shortcoming aramid fiber vitrification point is the highest, employing is conventionally synthesized fiber dyeing method dyestuff and is difficult to upper dye, existing solution party
After the most first sweller of method carries out pretreatment to aramid fiber, then dye, or use carrier dyeing process, the most still
There is the problems such as dye-uptake is relatively low, color fastness is poor.
Summary of the invention
The technical problem to be solved in the present invention is to overcome existing defect, it is provided that a kind of aramid fiber improving dye-uptake
Dyeing method.
In order to solve above-mentioned technical problem, the invention provides following technical scheme:
A kind of aramid fiber dyeing method, including dyeing, wash, drying, its feature is, during dyeing, adds in dye liquor
Enter the 1-Phenylethanone. of 5-10wt% and the dihydroxymethyl dihydroxy ethylidene-urea of 1-3wt%.
The mass ratio of 1-Phenylethanone. and dihydroxymethyl dihydroxy ethylidene-urea controls at 1:(0.2-0.5).
Further, dye liquor adds the emulsifying agent of 0.2-1wt%.
With existing swelling method or carrier dyeing process, the present invention adds on the basis of existing aramid fiber colouring method in dye liquor
Appropriate 1-Phenylethanone. and dihydroxymethyl dihydroxy ethylidene-urea, as the dyeing auxiliaries of dyestuff, can significantly improve dyestuff when aramid fiber dyes
Dye-uptake, and improve color fastness.
Detailed description of the invention
Below in conjunction with preferred embodiment, the present invention will be described, it will be appreciated that preferred embodiment described herein is only
For instruction and explanation of the present invention, it is not intended to limit the present invention.
Embodiment 1
The dihydroxymethyl dihydroxy ethylidene-urea of the 1-Phenylethanone. of 80g, the emulsifier op-10 of 6g and 30g is joined 184g
In water, stir 30 minutes, uniformly after obtain dyeing auxiliaries.
Dyeing: kevlar fabric pre-treatment → washing → drying → dyeing → washing → post processing → washing → drying
Wherein, during pre-treatment: treatment fluid (sodium hydroxide 10g/L, degreaser 2g/L), temperature 100 DEG C, 30 minutes time,
Bath raio 1:50.
During dyeing, formula for dye liquor: the red 6wt% of wheat Shillong, sodium nitrate 2wt%, dyeing auxiliaries 30wt%, dyeing condition: pH value=4
(regulating with acetic acid), temperature 120 DEG C, 50 minutes time, bath raio 1:20.
Post processing: treatment fluid (Oleum Terebinthinae 5g/L), pH value 4, temperature 85 DEG C, 20 minutes time, bath raio 1:40.
After dyeing, K/S value=31, fastness to wet rubbing 4 grades, dry fastness 5 grades.
Comparative example 1
When dyeing, formula for dye liquor is: the red 6wt% of wheat Shillong, sodium nitrate 2wt%, 1-Phenylethanone. 8wt%, emulsifier op-10
0.6%.Other dyeing is same as in Example 1.
After dyeing, K/S value=18, fastness to wet rubbing 3 grades, dry fastness 4 grades.
Embodiment 2
The dihydroxymethyl dihydroxy ethylidene-urea of the 1-Phenylethanone. of 80g, the emulsifier op-10 of 6g and 40g is joined 174g
In water, stir 30 minutes, uniformly after obtain dyeing auxiliaries.
Dyeing: kevlar fabric pre-treatment → washing → drying → dyeing → washing → post processing → washing → drying
Wherein, pre-treatment: sweller SW-A, 50 minutes time.
During dyeing, formula for dye liquor: disperse red 58 5wt%, sodium chloride 2wt%, dyeing auxiliaries 20wt%, dyeing condition: pH value=5
(regulating with acetic acid), temperature 120 DEG C, 50 minutes time, bath raio 1:20.
Post processing: treatment fluid (soap powder 2g/L), temperature 95 DEG C, 15 minutes time.
After dyeing, K/S value=41, fastness to wet rubbing 4 grades, dry fastness 5 grades.
Comparative example 2
When dyeing, formula for dye liquor is: disperse red 58 5wt%, sodium chloride 2wt%, 1-Phenylethanone. 5.3wt%, emulsifier op-10
0.4%.Other dyeing is same as in Example 2.
After dyeing, K/S value=29, fastness to wet rubbing 4 grades, dry fastness 4 grades.
Embodiment 3
The dihydroxymethyl dihydroxy ethylidene-urea of the 1-Phenylethanone. of 80g, the dodecylbenzene sodium sulfonate of 7g and 16g is joined
In 197g water, stir 30 minutes, uniformly after obtain dyeing auxiliaries.
Dyeing: kevlar fabric pre-treatment → washing → drying → dyeing → washing → post processing → washing → drying
Wherein, during pre-treatment: treatment fluid (sodium hydroxide 10g/L, degreaser 2g/L), temperature 100 DEG C, 30 minutes time,
Bath raio 1:50.
During dyeing, formula for dye liquor: the red 6wt% of wheat Shillong, sodium nitrate 2wt%, dyeing auxiliaries 30wt%, dyeing condition: pH value=4
(regulating with acetic acid), temperature 120 DEG C, 50 minutes time, bath raio 1:20.
Post processing: treatment fluid (Oleum Terebinthinae 5g/L), pH value 4, temperature 85 DEG C, 20 minutes time, bath raio 1:40.
After dyeing, K/S value=30.2, fastness to wet rubbing 4 grades, dry fastness 5 grades.
Finally it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention,
Although being described in detail the present invention with reference to previous embodiment, for a person skilled in the art, it still may be used
So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent.
All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention's
Within protection domain.
Claims (2)
1. an aramid fiber dyeing method, including dyeing, wash, drying, it is characterised in that during dyeing, adds in dye liquor
The 1-Phenylethanone. of 5-10wt% and the dihydroxymethyl dihydroxy ethylidene-urea of 1-3wt%.
Aramid fiber dyeing method the most according to claim 1, it is characterised in that add the emulsifying of 0.2-1wt% in dye liquor
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410494200.7A CN104294680B (en) | 2014-09-25 | 2014-09-25 | A kind of aramid fiber dyeing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410494200.7A CN104294680B (en) | 2014-09-25 | 2014-09-25 | A kind of aramid fiber dyeing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104294680A CN104294680A (en) | 2015-01-21 |
| CN104294680B true CN104294680B (en) | 2016-11-30 |
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| CN201410494200.7A Expired - Fee Related CN104294680B (en) | 2014-09-25 | 2014-09-25 | A kind of aramid fiber dyeing method |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86106248A (en) * | 1985-08-15 | 1987-03-04 | 纳幕尔杜邦公司 | Aromatic polyamide fiber and its setting treatment |
| CN1172513A (en) * | 1995-01-12 | 1998-02-04 | 希巴特殊化学控股公司 | Process for dyeing cellulosic textile fibre materials |
| CN101235598A (en) * | 2008-03-03 | 2008-08-06 | 浙江理工大学 | A method for dyeing aramid fabrics under high temperature and high pressure |
| CN101570940A (en) * | 2009-05-18 | 2009-11-04 | 江南大学 | Method for modification, dyeing and multifunctional composite finishing of aramid fiber |
| CN101603276A (en) * | 2009-07-15 | 2009-12-16 | 西安工程大学 | Low temperature dyeing method of aramid/flame retardant viscose blended fabric |
-
2014
- 2014-09-25 CN CN201410494200.7A patent/CN104294680B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86106248A (en) * | 1985-08-15 | 1987-03-04 | 纳幕尔杜邦公司 | Aromatic polyamide fiber and its setting treatment |
| CN1172513A (en) * | 1995-01-12 | 1998-02-04 | 希巴特殊化学控股公司 | Process for dyeing cellulosic textile fibre materials |
| CN101235598A (en) * | 2008-03-03 | 2008-08-06 | 浙江理工大学 | A method for dyeing aramid fabrics under high temperature and high pressure |
| CN101570940A (en) * | 2009-05-18 | 2009-11-04 | 江南大学 | Method for modification, dyeing and multifunctional composite finishing of aramid fiber |
| CN101603276A (en) * | 2009-07-15 | 2009-12-16 | 西安工程大学 | Low temperature dyeing method of aramid/flame retardant viscose blended fabric |
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| Publication number | Publication date |
|---|---|
| CN104294680A (en) | 2015-01-21 |
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| C06 | Publication | ||
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhang Lianfu Inventor after: Zhang Qi Inventor before: Wu Hongliang |
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| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20161021 Address after: 314400 Zhijiang Road, Haining Agricultural Comprehensive Development Zone, Jiaxing, Zhejiang, China Applicant after: HAINING HUAXIANG BLEACHING AND DYEING TECHNOLOGY CO.,LTD. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Applicant before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20161021 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Applicant after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 214000 Xishan City, Wuxi Province, northeast of the town of Tong Village Applicant before: WUXI DONGBEITANG HONGLIANG DYEING FACTORY |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161130 |