[go: up one dir, main page]

CN104293123B - 涂料组合物及应用该涂料组合物的电子装置主板 - Google Patents

涂料组合物及应用该涂料组合物的电子装置主板 Download PDF

Info

Publication number
CN104293123B
CN104293123B CN201310300153.3A CN201310300153A CN104293123B CN 104293123 B CN104293123 B CN 104293123B CN 201310300153 A CN201310300153 A CN 201310300153A CN 104293123 B CN104293123 B CN 104293123B
Authority
CN
China
Prior art keywords
coating composition
mass percent
polyacrylic acid
ester
reactive resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310300153.3A
Other languages
English (en)
Other versions
CN104293123A (zh
Inventor
姜传华
王杰祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Medical Device Industry Development Co ltd
Suzhou Medical Device Industry Development Group Co ltd
Original Assignee
Shenzhen Futaihong Precision Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Futaihong Precision Industry Co Ltd filed Critical Shenzhen Futaihong Precision Industry Co Ltd
Priority to CN201310300153.3A priority Critical patent/CN104293123B/zh
Priority to TW102126562A priority patent/TWI598415B/zh
Priority to US14/328,896 priority patent/US20150024213A1/en
Publication of CN104293123A publication Critical patent/CN104293123A/zh
Application granted granted Critical
Publication of CN104293123B publication Critical patent/CN104293123B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0209—Multistage baking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/06—Crosslinking by radiation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明提供一种涂料组合物及应用该涂料组合物的电子装置主板。该涂料组合物包括热固化树脂、光固化树脂及固化剂，所述热固化树脂包括聚丙烯酸寡聚物与环氧类树脂，或聚丙烯酸寡聚物与聚脂多元醇，所述光固化树脂为丙烯酸单体，所述固化剂为二酸酐或异氰酸盐类。本发明还提供一种应用上述涂料组合物的电子装置主板。

Description

涂料组合物及应用该涂料组合物的电子装置主板
技术领域
本发明是关于一种涂料组合物，尤其涉及一种防水涂料组合物及应用该涂料组合物的电子装置主板。
背景技术
为了使电子装置的主板具有防水效果，通常需于该主板表面涂覆防水涂料组合物，再采用紫外光照射该防水涂料组合物以使该防水涂料组合物于主板的表面固化形成防水薄膜。由于电子装置的主板表面凸凹不平，导致紫外光不能完全照射到主板的所有区域，使得主板表面未被紫外光照射的区域不能固化形成防水薄膜。同时紫外光照射的时间较短，使得涂料组合物在紫外光照射期间不能完全固化，从而影响主板的防水效果。
发明内容
鉴于此，本发明提供一种防水涂料组合物。
另，还有必要提供一种应用所述涂料组合物的电子装置主板。
一种涂料组合物，该涂料组合物包括热固化树脂、光固化树脂及固化剂，所述热固化树脂包括聚丙烯酸寡聚物与环氧类树脂，或聚丙烯酸寡聚物与聚脂多元醇，所述光固化树脂为丙烯酸单体，所述固化剂为二酸酐或异氰酸盐类。
一种应用所述涂料组合物的电子装置主板，包括主板及形成于该主板表面的防水薄膜，该防水薄膜为所述涂料组合物形成的薄膜。
上述的涂料组合物涂覆于基材表面后，对该涂料组合物进行第一次固化处理，以在基材表面的部分区域形成防水薄膜。经第一次固化处理后，涂料组合物中的热固化树脂与固化剂会自发的固化成膜，从而在基材的表面形成连续的防水薄膜，使得基材具有防水效果。
具体实施方式
本发明一较佳实施方式的涂料组合物中含有热固化树脂、光固化树脂、固化剂、光引发剂及溶剂。该涂料组合物中，该热固化树脂的质量百分比为20～25%、该光固化树脂的质量百分比为25～35%、该固化剂的质量百分比为2～4%、该光引发剂的质量百分比为1～4%、该溶剂的质量百分比为25～35%。该涂料组合物的比重为1～1.04kg/m3。该涂料组合物于常温下的蒸气压为5～7mmHg。
所述热固化树脂包括聚丙烯酸寡聚物与环氧类树脂，或聚丙烯酸寡聚物与聚脂多元醇。该热固化树脂中，该聚丙烯酸寡聚物的质量百分比为50～55%，该环氧类树脂的质量百分比为45～50%；或该聚丙烯酸寡聚物的质量百分比为25～35%，该聚脂多元醇的质量百分比范围为65～75%。该涂料组合物固化形成一防水薄膜时，该热固化树脂可提高该防水薄膜的疏水性与耐磨力。
所述聚丙烯酸寡聚物可为聚醚酯丙烯酸酯(Polyester Acrylate,PESA)、聚氨酯丙烯酸酯（Urethane Acrylate,UA）、丙烯酸酯树脂（Full Acrylic,FA）、胺基丙烯酸酯（Amine Acrylate,AA）或有机硅丙烯酸酯(Silicon Acrylate,SA)。
所述环氧类树脂中含有一个或一个以上的环氧基团。该环氧类树脂可为1,6-二(2,3-环氧丙氧基)己烷(1,6-bis(2,3-epoxypropoxy)hexane)、环己烷-1,2-二羧酸二(环氧乙基甲基)酯(1,2-Cyclohexanedicarboxylicacid,1,2-bis(2-oxiranylmethyl)ester)、邻苯二甲酸-1,2-二羧酸二(环氧乙基甲基)酯(1,2-Benzenedicarboxylicacid,1,2-bis(2-oxiranylmethyl)ester)。
所述聚酯多元醇可为二元醇与二元酸的聚合体或三元醇与二元酸的聚合体，如聚乙二醇(Polyethylene glycol,PEG)、聚丙二醇(Polypropylene glycol,PPG)、聚丁二醇(Polytetramethylene glycol,PTMG)。该聚酯多元醇的分子量可为1000～5000。
所述光固化树脂为丙烯酸单体。该丙烯酸单体可为三羟甲基丙烷三丙烯酸酯(trimethtylol propane triacrylate,TMPTA)、丙三醇二丙烯酸酯(tripropylene glycoldiacrylate,TPGDA)、二丙二醇二丙烯酸酯(dipropylene glycol diacrylate,DPGDA)、1,6-己二醇二丙烯酸酯(1,6-hexanediol diacrylate,HDDA)、或二季戊四醇六甲基丙烯酸酯(dipentaerythritol hexa(meth)acrylate，DPHA)，优选为二季戊四醇六甲基丙烯酸酯。
所述固化剂可为二酸酐类或异氰酸盐类。该二酸酐类可为二酸酐(cis-butenedioic anhydride)或戊二酸酐(Glutaricanhydride)。
所述二酸酐水解后生成COOH基团，该COOH基团可使该环氧类树脂发生开环反应，使得该二酸酐与该环氧类树脂交联于一起。发生交联反应后的环氧类树脂可与聚丙烯酸寡聚物的羟基发生聚合反应。
所述异氰酸盐中含有2个或2个以上的N=C=O官能团，该N=C=O官能团可与该聚脂多元醇的羟基及该聚丙烯酸寡聚物的氨基或羟基发生加成反应，以生成RNH-CO-NHR′或RNH-COOR′（R代表聚脂多元醇，R′代表聚丙烯酸寡聚物）。
所述光引发剂可为苯基酮类光引发剂。该苯基酮类光引发剂可为1-羟基环己基苯基酮(1-hydroxycyclohexyl phenyl ketone,简称184)、2-羟基-甲基苯基丙烷-1-酮(简称1173)、1,2-二苯基乙二酮(BenZil)、二苯甲酮（Benzophenone）、安息香(Benzoin)、及安息香的醚类衍生物，优选为1-羟基环己基苯基甲酮、或2-羟基-甲基苯基丙烷-1-酮。该光引发剂在紫外光的作用下可产生自由基，该自由基可引发该聚丙烯酸寡聚物与该光固化树脂的双键发生自由基聚合反应。
所述溶剂可为乙酸乙脂、乙酸丁脂、或二甲苯。
所述涂料组合物的制作方法，其包含如下步骤：
提供一搅拌桶。
向所述搅拌桶中加入所述溶剂。
调节所述搅拌桶的转速为200～400rpm，将树脂、丙烯酸单体、固化剂及光引发剂置入所述搅拌桶中搅拌20～40分钟，从而得到所述涂料组合物。
所述涂料组合物的使用方法，其包含如下步骤：
提供一待表面处理的基材，该基材可为电子装置的主板。该主板上可形成有电路，且该主板的表面凸凹不平。
采用喷涂、淋涂或浸涂的方式将所述涂料组合物涂覆于所述基材的表面。所述浸涂处理可为：提供一抽真空瓶；将该基材置入该抽真空瓶后，对该抽真空瓶进行抽真空直至该抽真空瓶的真空度为-5～5Pa，使得该基材表面无气泡；向该抽真空瓶内加入所述涂料组合物，使得该基材浸渍于该涂料组合物中3～7分钟，以将该涂料组合物吸附于该基材的表面。
第一次固化涂覆于基材表面的所述涂料组合物。所述第一次固化处理可采用紫外光UV照射所述涂料组合物。所述紫外光UV固化可为：采用能量为500～1500MJ的紫外光UV照射喷涂于基材表面的所述涂料组合物8～12秒。所述第一次固化处理的过程中，该光引发剂吸收紫外光产生自由基，该自由基可引发该聚丙烯酸寡聚物与该光固化树脂的双键发生自由基聚合反应。
对紫外光未完全照射到基材的区域进行第二次固化处理，所述第二次固化处理可采用常温固化处理的方式。该常温固化成膜过程中，该基材表面未固化成膜的涂料组合物发生自发性的固化成膜，从而在基材的表面获得连续的防水薄膜。该防水薄膜的厚度可为5～10μm。
所述常温固化处理可为：将所述基材于室温下放置6～8天。空气中存在的水分子会将该二酸酐水解生成COOH基团，该COOH基团可使该环氧类树脂发生开环反应，使得该二酸酐与该环氧类树脂交联于一起。发生交联反应后的环氧类树脂可与丙烯酸寡聚物的羟基发生聚合反应，从而在基材未被紫外光照射的区域形成防水薄膜。该异氰酸盐类的N=C=O官能团可与该聚脂多元醇的羟基及该聚丙烯酸寡聚物的氨基或羟基发生加成反应，以生成RNH-CO-NHR′或RNH-COOR′（R代表聚脂多元醇，R′代表聚丙烯酸寡聚物）。
所述常温固化处理可由热固化处理所替代，以缩短第二次固化处理所需的时间。
所述热固化处理可为：将所述基材置入一温度为50～70℃的烘箱中24～36小时。该热固化处理过程中，该二酸酐水解后生成COOH基团，该COOH基团可使该环氧类树脂发生开环反应，使得该二酸酐与该环氧类树脂交联于一起。发生交联反应后的环氧类树脂可与聚丙烯酸寡聚物的羟基发生聚合反应，从而在基材未被紫外光照射的区域形成防水薄膜。该异氰酸盐类的N=C=O官能团可与该聚脂多元醇的羟基及该聚丙烯酸寡聚物的氨基或羟基发生加成反应，以生成RNH-CO-NHR′或RNH-COOR′（R代表聚脂多元醇，R′代表聚丙烯酸寡聚物）。
测试结果
将形成有所述防水薄膜的基材于室温下浸渍于水中20～40分钟后，将该基材装配于一电子装置中，该电子装置未发生短路，可正常使用。

Claims (8)

1.一种涂料组合物，包括热固化树脂、丙烯酸单体及固化剂，其特征在于：所述涂料组合物进一步包括溶剂及光引发剂，所述热固化树脂包括聚丙烯酸寡聚物与环氧类树脂，或聚丙烯酸寡聚物与聚酯多元醇，所述固化剂为二酸酐类或异氰酸盐类，该涂料组合物中，该热固化树脂的质量百分比为20～25％、该丙烯酸单体的质量百分比为25～35％、该固化剂的质量百分比为2～4％、该光引发剂的质量百分比为1～4％、该溶剂的质量百分比为25～35％，所述热固化树脂、该丙烯酸单体、该固化剂、该光引发剂及该溶剂的质量百分比之和等于100％。
2.如权利要求1所述的涂料组合物，其特征在于：所述热固化树脂中，该聚丙烯酸寡聚物的质量百分比为50～55％，该环氧类树脂的质量百分比为45～50％，或该聚丙烯酸寡聚物的质量百分比为25～35％，该聚酯多元醇的质量百分比范围为65～75％。
3.如权利要求1所述的涂料组合物，其特征在于：所述聚丙烯酸寡聚物为聚醚酯丙烯酸酯、聚氨酯丙烯酸酯、胺基丙烯酸酯或有机硅丙烯酸酯。
4.如权利要求1所述的涂料组合物，其特征在于：所述环氧类树脂为1,6-二(2,3-环氧丙氧基)己烷、环己烷-1,2-二羧酸二(环氧乙基甲基)酯、或邻苯二甲酸-1,2-二羧酸二(环氧乙基甲基)酯。
5.如权利要求1所述的涂料组合物，其特征在于：所述聚酯多元醇为二元醇与二元酸的聚合体或三元醇与二元酸的聚合体，该聚酯多元醇的分子量为1000～5000。
6.如权利要求1所述的涂料组合物，其特征在于：所述光引发剂为苯基酮类光引发剂，该苯基酮类光引发剂为1-羟基环已基苯基酮、2-羟基-甲基苯基丙烷-1-酮、1,2-二苯基乙二酮、二苯甲酮、安息香、或安息香的醚类衍生物。
7.一种应用权利要求1-6中任一项所述涂料组合物的电子装置主板，包括主板及形成于该主板表面的防水薄膜，该防水薄膜为所述涂料组合物形成的薄膜。
8.如权利要求7所述的电子装置主板，其特征在于：所述防水薄膜的厚度为5～10μm。
CN201310300153.3A 2013-07-17 2013-07-17 涂料组合物及应用该涂料组合物的电子装置主板 Active CN104293123B (zh)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201310300153.3A CN104293123B (zh) 2013-07-17 2013-07-17 涂料组合物及应用该涂料组合物的电子装置主板
TW102126562A TWI598415B (zh) 2013-07-17 2013-07-24 塗料組合物及應用該塗料組合物的電子裝置主板
US14/328,896 US20150024213A1 (en) 2013-07-17 2014-07-11 Liquid coating composition and a coating method using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310300153.3A CN104293123B (zh) 2013-07-17 2013-07-17 涂料组合物及应用该涂料组合物的电子装置主板

Publications (2)

Publication Number Publication Date
CN104293123A CN104293123A (zh) 2015-01-21
CN104293123B true CN104293123B (zh) 2017-05-03

Family

ID=52313087

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310300153.3A Active CN104293123B (zh) 2013-07-17 2013-07-17 涂料组合物及应用该涂料组合物的电子装置主板

Country Status (3)

Country Link
US (1) US20150024213A1 (zh)
CN (1) CN104293123B (zh)
TW (1) TWI598415B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2841775T3 (es) 2016-08-24 2021-07-09 Basf Coatings Gmbh Procedimiento para la producción de una pintura con el uso de una pintura de base acuosa
US10007459B2 (en) * 2016-10-20 2018-06-26 Pure Storage, Inc. Performance tuning in a storage system that includes one or more storage devices
CN108912941B (zh) * 2017-03-22 2019-12-10 比亚迪股份有限公司 3d玻璃装饰用涂层组合物和3d玻璃及其制备方法
CN108948980A (zh) * 2017-05-22 2018-12-07 四会市中日化工实业有限公司 一种固化涂料

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555592B2 (en) * 2001-02-27 2003-04-29 Advance Materials Corporation Photothermosetting composition comprising acrylated epoxy resin
CN1515639A (zh) * 2003-01-09 2004-07-28 湖南亚大新材料科技股份有限公司 用于保护电子电路及电子元器件的紫外光固化组成物
TW200630447A (en) * 2004-11-19 2006-09-01 Showa Denko Kk Resin cured film for flexible printed wiring board and production process thereof
WO2012011260A1 (ja) * 2010-07-22 2012-01-26 日本化薬株式会社 光ディスク用紫外線硬化型樹脂組成物、硬化物及び光ディスク
MY173225A (en) * 2012-03-23 2020-01-07 Taiyo Ink Suzhou Co Ltd Photosensitive resin composition and its cured product, and printed circuit board
CN102827501A (zh) * 2012-08-02 2012-12-19 中山大桥化工企业集团中山智亨实业发展有限公司 双重固化清漆涂料
CN103194104A (zh) * 2013-03-21 2013-07-10 中山金利宝胶粘制品有限公司 塑料薄膜表面涂布组成物及其标签制品

Also Published As

Publication number Publication date
US20150024213A1 (en) 2015-01-22
TW201512324A (zh) 2015-04-01
TWI598415B (zh) 2017-09-11
CN104293123A (zh) 2015-01-21

Similar Documents

Publication Publication Date Title
CN104293123B (zh) 涂料组合物及应用该涂料组合物的电子装置主板
CN101657482B (zh) 新型聚酰亚胺前体组合物及其利用
CN104327217B (zh) 一种紫外光固化非硅离型剂及其制备方法
JPS6241982B2 (zh)
CN105705529A (zh) 固化型组合物、使用其的固化涂膜和印刷电路板
JPH0586416B2 (zh)
AU2012348467A1 (en) Precoating methods and compositions
US20140107246A1 (en) Ultraviolet cured polyesters from sustainable materials
CN106047094B (zh) Uv固化型的可降低最终粘性的保护膜及其制备方法
JP2017008124A (ja) 有機ケイ素化合物及び該有機ケイ素化合物を含む樹脂組成物と硬化被膜
CN102031055A (zh) 一种不含挥发性有机溶剂的uv喷涂面漆
JP2002293876A (ja) 活性エネルギー線硬化型樹脂の製造方法
TWI557143B (zh) 活性能量線硬化性組成物、使用其的活性能量線硬化性塗料及活性能量線硬化性印刷墨水
KR101815150B1 (ko) 패키징 emi 쉴드 마운팅 점착테이프 및 이의 제조방법
CN105131673A (zh) 一种紫外光固化阻燃底漆涂料及其制备方法
JP2010180319A (ja) ウレタン（メタ）アクリレート及びそれを含有するコーティング剤
JP2516183B2 (ja) パタ―ン形成方法
CN104245158B (zh) 带涂膜的薄膜的制造方法
JP2011102335A (ja) ウレタン樹脂の製造方法
JP3422103B2 (ja) 光硬化性樹脂組成物
JP7275533B2 (ja) 樹脂成形体の製造方法
CN114621614B (zh) 一种光固化涂料及其制备方法
CN108864401A (zh) 一种聚氨酯丙烯酸酯低聚物及其制备方法和一种水性涂料
JP4469064B2 (ja) 成分傾斜複合材料の製造方法
CN114539835A (zh) 光湿固化树脂组合物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20201127

Address after: 215000 No. 8 Jinfeng Road, hi tech Zone, Suzhou, Jiangsu, Suzhou

Patentee after: Suzhou science and Technology City Biomedical Technology Development Co.,Ltd.

Address before: 518109 F3 building, Foxconn science and Technology Industrial Park, Longhua Town, Shenzhen, Guangdong, A, China

Patentee before: Shenzhen Futaihong Precision Industry Co.,Ltd.

TR01 Transfer of patent right
CP01 Change in the name or title of a patent holder

Address after: 215000 No.8, Jinfeng Road, science and Technology City, Suzhou high tech Zone, Suzhou City, Jiangsu Province

Patentee after: Suzhou Medical Device Industry Development Co.,Ltd.

Address before: 215000 No.8, Jinfeng Road, science and Technology City, Suzhou high tech Zone, Suzhou City, Jiangsu Province

Patentee before: Suzhou science and Technology City Biomedical Technology Development Co.,Ltd.

Address after: 215000 No.8, Jinfeng Road, science and Technology City, Suzhou high tech Zone, Suzhou City, Jiangsu Province

Patentee after: Suzhou Medical Device Industry Development Group Co.,Ltd.

Address before: 215000 No.8, Jinfeng Road, science and Technology City, Suzhou high tech Zone, Suzhou City, Jiangsu Province

Patentee before: Suzhou Medical Device Industry Development Co.,Ltd.

CP01 Change in the name or title of a patent holder